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At least 613 records · Page 34

Shape effect on drying behavior of cement-based materials: Mechanisms and numerical analysis

The shape of the specimen or structure has a direct impact on the behavior of drying concrete. This effect is not taken into account in most of shrinkage models and codes. Only the current B4 model and its previous version B3 model incorporate a shape factor. The determination of this coefficient is based on the nonlinear moisture diffusion analysis, which can explain the shape effect on the shrinkage rate. However, the model integrates this coefficient in the ultimate shrinkage values as well. An experimental study has been performed to confirm and understand this behavior. The mass loss and drying shrinkage of cylinders showed higher rate and ultimate values than the prisms, for the same effective cross section thickness. To explain this result, the drying, the differential shrinkage, the internal stress and the damaged depth were determined for both shapes through numerical modeling. The main input data of the model were the measured mass loss and shrinkage. The calculated desorption isotherm curve of the cylinder was below that of the prism, which is consistent with its higher ultimate mass-loss. The determination of stress profiles indicates slower stress mitigation for the cylinder. The cylinder develops a larger relative damaged area, defined as the part of the specimen where cracking is likely to occur due to tensile stresses. The results actually show that differential shrinkage between the edge and the core is more pronounced for the cylinder and decreases with time.

36 MATERIALS SCIENCE↗

Role of alcohol-ethylene oxide polymers on the reduction of shrinkage of cement paste

Concrete drying shrinkage is a major practical problem, but it can be ameliorated by means of ''shrinkage-reducing agents'' (SRAs). Water vapor sorption isotherms and low temperature DSC measurements suggest that alcohol-ethylene oxide polymers (AEOPs) with a better hydrophilic-lipophilic (HL-) balance are present in meso-pores in which water molecules evaporate from 75% RH to 40% RH. Short-term drying shrinkage measurements show that the better HL-balanced AEOPs reduce irreversible shrinkage, which occurs mainly from 75% RH to 40% RH during the first drying. Based on the similarity between corresponding RH regions, it is concluded that the better HL balanced AEOP in relevant meso-pores hinders agglomeration of C-S-H during the first desorption to mitigate the irreversible shrinkage and reduce the first drying shrinkage.

36 MATERIALS SCIENCE↗

Piezoelectric response and failure behavior of cement paste under external loading

We study the elastic behavior and rupture mechanism of Calcium Silicate Hydrates (C-S-H) in response to tensile loading. For the three tensile axes, initial defects are spotted in the interlayer regions. However, the crack propagation is rather different depending on the axis of tensile. The cup-and-cone failure surface shows the ductile feature of C-S-H in the x and y directions; while the devastating rupture mode confirms the brittle feature of C-S-H in the z direction. Piezoelectricity was investigated using the charge fluctuation method. The polarization variation in response to small strain was also investigated and piezoelectric coefficients were derived. Furthermore, dependence of elastic and piezoelectric properties over external pressure was analyzed. Results reveal an improvement of the mechanical properties and the ultimate strength especially in the z direction; whereas the non-piezoelectricity remains unchanged despite the rearrangement of atoms induced by the external applied pressure.

36 MATERIALS SCIENCE↗

Geochemical and Geomechanical Effects on Wellbore Cement Fractures: Data Information for Wellbore Reduced Order Model

The primary objective of the National Risk Assessment Partnership (NRAP) program is to develop a defensible, generalized, and science-based methodology and platform for quantifying risk profiles at CO 2 injection and storage sites. The methodology must incorporate and define the scientific basis for assessing residual risks associated with long-term stewardship and help guide site operational decision-making and risk management. Development of an integrated and risk-based protocol will help minimize uncertainty in the predicted long-term behavior of the CO 2 storage site and thereby increase confidence in storage integrity. The risk profile concept has proven useful in conveying the qualitative evolution of risks for CO 2 injection and storage site. However, qualitative risk profiles are not sufficient for specifying long-term liability for CO 2 storage sites. Because there has been no science-based defensible and robust methodology developed for quantification of risk profiles for CO 2 injection and storage, NRAP has been focused on developing a science-based methodology for quantifying risk profiles for various risk proxies.

58 GEOSCIENCES↗