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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

The effect of oxygen concentration on the boundary-lubricating characteristics of a C ether and a polyphenyl ether to 300 C

Ball-on-disk sliding friction experiments were carried out at 17 m/min (100 rev/min) to investigate the effect of oxygen concentration varying from 20% (air) to 0.001% (nitrogen) on the boundary-lubricating characteristics of an unformulated C ether in the temperature range 20-300 C. Results were then compared with those obtained for a five-ring polyphenylether in air and in nitrogen. The C ether yielded lower wear and lower friction coefficients than a five-ring polyphenylether in both air and nitrogen over most of the temperature range. Friction polymer was observed around the wear scars of most test specimens, with much greater quantities of friction polymer produced in a low-oxygen environment. Thus, with respect to friction polymer production, the C ether behaved very much like the polyphenylether.

Jones, W. R., Jr.↗
NASA NTRS1984

Laboratory discharge studies of a 6 V alkaline lantern-type battery Eveready Energizer no. 528, under various ambient temperatures (-15 deg C and + 22 deg C) and loads (30 omega and 60 omega)

The voltages of two Eveready No. 528 batteries, one the test battery, the other the control battery, were simultaneously recorded as they were discharged across 30 omega loads using a dual chart recorder. The test battery was initially put in a freezer at -15 + or - 3 C. After its voltage had fallen to .6 V, it was brought back out into the room at 22 + or - 3 C. A second run was made with 60 omega loads. Assuming a 3.0 V cut-off, the total energy output of the test battery at -15 C was 26 WHr 30 omega and 35 WHr 60 omega, and the corresponding numbers for the control battery at 22 C were 91 WHr and 100 WHr. When the test battery was subsequently allowed to warm up, the voltage rose above 4 V and the total energy output rose to 80 WHr 30 omega and 82 WHR 60 omega.

Ahrens, S. T.↗
NASA NTRS1989

The (C-13)/(C-12) ratio in cosmic ray sources

Published measurement data on the production C-13 during interstellar propagation of cosmic rays (Webber et al., 1987; Guzik et al., 1985) are combined with observational data to determine the relative abundance of C-13 in the cosmic-ray source. The theoretical basis and implementation of the calculations are described in detail, and the results are presented in graphs. (C-13)/(C-12) is estimated as 0.003 + or - 0.005, consistent with the solar ratio (0.011), not consistent with the local abundance ratio (0.023), and in agreement with the source ratio predicted by Prantzos et al. (1985) using the isotopic abundances of WR-star ejecta.

Webber, W. R.↗
NASA NTRS1993

Cosmic evolution of extragalactic C 1, C 2, and CO luminosity

Carbon is the fourth most abundant element in the Galaxy with an abundance of approximately 4 x 10(exp -4) relative to hydrogen. Of all abundant metals it is the easiest to observe in the interstellar medium (ISM). Carbon can be found in four dominant forms: dust grains, C 2, C 1, and CO. The latter is the most abundant molecule (next to H2) in molecular clouds. All three gas-phase forms produce strong sub-mm wavelength emission lines and are the principal tracers of the warm and dense neutral phases of the ISM. We calculate the gas-phase abundances of neutral carbon (C 1), ionized carbon (C 2), and carbon monoxide (CO) as a function of cosmic time or redshift z in an idealized scenario of galactic evolution.

Bally, John↗
NASA NTRS2009

Characterization of 6H-SiC JFET Integrated Circuits Over A Broad Temperature Range from -150 C to +500 C

The NASA Glenn Research Center has previously reported prolonged stable operation of simple prototype 6H-SiC JFET integrated circuits (logic gates and amplifier stages) for thousands of hours at +500 C. This paper experimentally investigates the ability of these 6H-SiC JFET devices and integrated circuits to also function at cold temperatures expected to arise in some envisioned applications. Prototype logic gate ICs experimentally demonstrated good functionality down to -125 C without changing circuit input voltages. Cascaded operation of gates at cold temperatures was verified by externally wiring gates together to form a 3-stage ring oscillator. While logic gate output voltages exhibited little change across the broad temperature range from -125 C to +500 C, the change in operating frequency and power consumption of these non-optimized logic gates as a function of temperature was much larger and tracked JFET channel conduction properties.

Neudeck, Philip G.↗
NASA NTRS2011

Assessment of Durable SiC JFET Technology for +600 C to -125 C Integrated Circuit Operation

Electrical characteristics and circuit design considerations for prototype 6H-SiC JFET integrated circuits (ICs) operating over the broad temperature range of -125 C to +600 C are described. Strategic implementation of circuits with transistors and resistors in the same 6H-SiC n-channel layer enabled ICs with nearly temperature-independent functionality to be achieved. The frequency performance of the circuits declined at temperatures increasingly below or above room temperature, roughly corresponding to the change in 6H-SiC n-channel resistance arising from incomplete carrier ionization at low temperature and decreased electron mobility at high temperature. In addition to very broad temperature functionality, these simple digital and analog demonstration integrated circuits successfully operated with little change in functional characteristics over the course of thousands of hours at 500 C before experiencing interconnect-related failures. With appropriate further development, these initial results establish a new technology foundation for realizing durable 500 C ICs for combustion engine sensing and control, deep-well drilling, and other harsh-environment applications.

Neudeck, P. G.↗
DOE OSTI2025

TEM Characterization of Nanostructured Grade 91 Neutron Irradiated to 6 DPA at 300 °C and 500 °C

Previously, samples of coarse grained (CG, grain diameter > 1 µm), ultra-fine grained (UFG, 1 µm> grain diameter> 100 nm), and nanocrystalline (NC, 100 nm> grain diameter) grade 91 steel were neutron irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). Grade 91 is a ferritic/martensitic steel alloy with a nominal composition of Fe-9%Cr-1%Mo by weight, and it is being studied for applications in advanced nuclear reactor designs including as a fuel cladding material in gas cooled reactors. To assess the viability of this alloy for nuclear applications, the role of grain boundary size has not been sufficiently explored as a mechanism for developing radiation-tolerant materials. To achieve an UFG microstructure the material was processed using equal channel angular pressing (ECAP), and the NC microstructure was achieved through high pressure torsion (HPT). Such samples of various geometries for different types of characterization were irradiated to a dose of 6 displacements per atom (DPA) at separate temperature conditions of 300 °C and 500 °C. Thus, there were a total of 6 experimental conditions, three grain sizes (CG, UFG, and NC), each irradiated at two different temperature conditions (300 °C and 500 °C).

36 - MATERIALS SCIENCE↗
DOE OSTI2016

C-N-P interactions control climate driven changes in regional patterns of C storage on the North Slope of Alaska

As climate warms, changes in the carbon (C) balance of arctic tundra will play an important role in the global C balance. The C balance of tundra is tightly coupled to the nitrogen (N) and phosphorus (P) cycles because soil organic matter is the principal source of plant-available nutrients and determines the spatial variation of vegetation biomass across the North Slope of Alaska. Warming will accelerate these nutrient cycles, which should stimulate plant growth.

C balance↗
DOE OSTI2019

Performance of Polymer Electrolyte Fuel Cell Electrodes with Atomically Dispersed (AD) Fe-C-N ORR Catalyst

Activity of (AD)Fe-N-C catalyst with low Fe content is investigated in differential cells prepared by hot pressing anode gas diffusion electrodes (0.2 mgPt/cm2) to N211 membrane and brush painting the cathode catalyst ink. Polarization curves obtained in H2/O2 show double Tafel slopes which, in conjunction with the redox potential observed in cyclic voltammetry traces, forms the basis for a distributed ORR (oxygen reduction reaction) kinetic model with potential-dependent available sites. Application of this model to polarization data in H2/air provides the basis for formulating an oxygen transport model and leads to 7.7 ± 0.6 mA/cm2 catalyst activity at 0.9 V, 31.5-34.3 mA/cm2 cell performance at 0.8 V, and 0.8-2 s/cm O2 transport resistance. A coupled kinetic, O2 transport and proton transport illustrates the projected improvements needed in catalyst activity and electrode structure to approach the automotive target of 1000 mW/cm2 stack power density while meeting the 1.45 kW/oC heat rejection constraint at 1.5 cathode stoichiometry. The model indicates that we need twelve-fold higher mass activity for reducing the kinetic losses, doubling of active site density and an engineered electrode structure for 50% lower proton transport resistance, as well as a 50% reduction in electrode thickness to limit the O2 transport losses

ACTIVE-SITES↗
DOE OSTI2024

Measurement of the e + e − → Λ Σ ¯ 0 + c . c . cross sections at s from 2.3094 to 3.0800 GeV

The Born cross sections and effective form factors of the process e + e − → Λ Σ ¯ 0 + c . c . are measured at 14 center-of-mass energy points from 2.3094 to 3.0800 GeV, based on data corresponding to an integrated luminosity of ( 478.5 ± 4.8 ) pb − 1 collected with the BESIII detector. A nonzero Born cross section is observed at the center-of-mass energy of 2.3094 GeV with a statistical significance of more than five standard deviations, and the cross sections at other energies are obtained with improved precision compared to earlier measurements from the Collaboration. The Born cross-section line shape is described better by a shape considering the strong-interaction effects than by a pQCD motivated functional form. Published by the American Physical Society 2024

Astronomy & Astrophysics↗
DOE OSTI2024

Study of excited Ξ states in ψ ( 3686 ) → K − Λ Ξ ¯ + + c . c .

Based on a sample of ( 448.1 ± 2.9 ) × 10 6 ψ ( 3686 ) events collected with the BESIII detector at BEPCII, the decays of ψ ( 3686 ) → K − Λ Ξ ¯ + + c . c . with Ξ ¯ + → Λ ¯ π + , Λ ¯ → p ¯ π + are studied. We investigate the two excited resonances, Ξ ( 1690 ) − and Ξ ( 1820 ) − , which are each observed with large significance ( ≫ 10 σ ) in the K − Λ invariant mass distributions. A partial wave analysis is performed, and the spin-parities of Ξ ( 1690 ) − and Ξ ( 1820 ) − are measured to be 1 2 − and 3 2 − , respectively. The masses, widths, and product branching fractions of Ξ ( 1690 ) − and Ξ ( 1820 ) − are also measured. Published by the American Physical Society 2024

Astronomy & Astrophysics↗
DOE OSTI2018

Search for flavor-changing neutral currents in top quark decays t → H c and t → H u in multilepton final states in proton-proton collisions at s = 13 TeV with the ATLAS detector

Flavor-changing neutral currents are not present in the Standard Model at tree level and are suppressed in loop processes by the unitarity of the Cabibbo-Kobayashi-Maskawa matrix; the corresponding rates for top quark decay processes are experimentally unobservable. Extensions of the Standard Model can generate new flavor-changing neutral current processes, leading to signals which, if observed, would be unambiguous evidence of new interactions. A data set corresponding to an integrated luminosity of 36.1 fb -1 of pp collisions at a center-of-mass energy of √ s = 13 TeV recorded with the ATLAS detector at the Large Hadron Collider is used to search for top quarks decaying to up or charm quarks with the emission of a Higgs boson, with subsequent Higgs boson decay to final states with at least one electron or muon. In conclusion, no signal is observed and limits on the branching fractions B (t → H c) < 0.16 % and B (t → H u) < 0.19 % at 95% confidence level are obtained (with expected limits of 0.15% in both cases).

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Observation of e⁺e⁻ → pp$\bar{p}\bar{n}\pi^-$ + c. c.

Using data taken at 29 center-of-mass energies between 4.16 and 4.70 GeV with the BESIII detector at the Beijing Electron Positron Collider corresponding to a total integrated luminosity of approximately 18.8 fb -1 , the process e⁺e⁻ → pp$\overline{p}\overline{n}\pi^-$ + c. c. is observed for the first time with a statistical significance of 11.5σ. The average Born cross sections in the energy ranges of (4.160, 4.380) GeV, (4.400, 4.600) GeV and (4.610, 4.700) GeV are measured to be (21.5 ± 5.7 ± 1.2) fb, (46.3 ± 10.6 ± 2.5) fb and (59.0 ± 9.4 ± 3.2) fb, respectively, where the first uncertainties are statistical and the second are systematic. The line shapes of the $\overline{p}\overline{n}$ and ppπ⁻ invariant mass spectra are consistent with phase space distributions, indicating that no hexaquark or di-baryon state is observed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2016

Study of the B + c → J/ΨD + s and B + c → J/ΨD* s + decays with the ATLAS detector

The decays B + c → J/ΨD + s and B + c → J/ΨD* s + are studied with the ATLAS detector at the LHC using a dataset corresponding to integrated luminosities of 4.9 and 20.6 fb –1 of pp collisions collected at centre-of-mass energies √s = 7 TeV and 8 TeV, respectively. Furthermore, signal candidates are identified through J/ψ → μ + μ - and D (*)+ s → Φπ + (γ/π 0 ) decays.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Conversion of CO 2 to Methanol and Ethanol on Pt/CeO x /TiO 2 (110): Enabling Role of Water in C–C Bond Formation

The surface chemistry of alcohol synthesis from CO 2 hydrogenation has been investigated using kinetic testing, ambient pressure x-ray photoelectron spectroscopy (AP-XPS) and DFT calculations over a multicomponent system where Pt and ceria nanoparticles coexisted on a titania template, Pt/CeO x /TiO 2 (110). Due to its high ability to bind and activate CO 2 , not seen for typical Cu-ZnO catalysts, the Pt-CeO x -TiO 2 interface is excellent for the hydrogenation of CO 2 to methanol with some ethanol also being produced (21% selectivity). The results of AP-XPS and DFT calculations indicate that the active state involves a mixture of Ti 4+ /Ti 3+ , Ce 3+ and Pt 0 /Pt + . A fast pathway for the formation of CH 3 O species is only plausible when Ce 3+ and Pt are present. The addition of water to the reaction feed facilitates the first hydrogenation of CO 2 and substantially enhances the surface coverage of C-containing species (CH 3 O, HCOO, CO 3 , CH x ), facilitating the formation of C-C bonds and the production of ethanol (38% selectivity).

36 MATERIALS SCIENCE↗
DOE OSTI2016

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: An in situ study of C–C and O–H bond scission

Ambient-Pressure X-ray Photoelectron Spectroscopy (AP-XPS) and Infrared Reflection Absorption Spectroscopy (AP-IRRAS) have been used to elucidate the active sites and mechanistic steps associated with the ethanol steam reforming reaction (ESR) over Ni–CeO 2 (111) model catalysts. Our results reveal that surface layers of the ceria substrate are both highly reduced and hydroxylated under reaction conditions while the small supported Ni nanoparticles are present as Ni 0 /NixC. A multifunctional, synergistic role is highlighted in which Ni, CeO x and the interface provide an ensemble effect in the active chemistry that leads to H 2 . Ni 0 is the active phase leading to both C–C and C–H bond cleavage in ethanol and it is also responsible for carbon accumulation. On the other hand, CeO x is important for the deprotonation of ethanol/water to ethoxy and OH intermediates. The active state of CeO x is a Ce 3+ (OH) x compound that results from extensive reduction by ethanol and the efficient dissociation of water. Additionally, we gain an important insight into the stability and selectivity of the catalyst by its effective water dissociation, where the accumulation of surface carbon can be mitigated by the increased presence of surface OH groups. As a result, the co-existence and cooperative interplay of Ni 0 and Ce 3+ (OH) x through a metal–support interaction facilitate oxygen transfer, activation of ethanol/water as well as the removal of coke.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Electronic structure of C and N co-doped TiO{sub 2}: A combined hard x-ray photoemission spectroscopy and density functional theory study

We have studied the electronic structure of C and N co-doped TiO{sub 2} using hard x-ray photoelectron spectroscopy and first-principles density functional theory calculations. Our results reveal overlap of the 2p states of O, N, and C in the system which shifts the valence band maximum towards the Fermi level. Combined with optical data we show that co-doping is an effective route for band gap reduction in TiO{sub 2}. Comparison of the measured valence band with theoretical photoemission density of states reveals the possibility of C on Ti and N on O site.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗