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At least 613 records · Page 34

Delocalized electrons in atomic and molecular nanoclusters

The aim of the award (Program director: Dr. Mark Pederson) was to facilitate the attendance of researchers, students, and postdocs from the U.S. at the international workshop co-organized by the applicant. The award succeeded in making it possible for a number of US attendees to present their work and participate in the meeting, which was a significant event in the research community at the interdisciplinary interface of physical chemistry, nanoscience, atomic and molecular physics, condensed matter physics, and spectroscopy. The workshop did not issue proceedings, but the present report includes present the schedule, the abstracts, and the attendance list of the July 2016 Workshop. DOE sponsorship is gratefully acknowledged in the program.

74 ATOMIC AND MOLECULAR PHYSICS↗

Norris Bradbury and Edward Teller: A Fission-Fusion Reaction

On a bright, sunny day in October 1945, a boisterous and jubilant crowd assembled in front of Fuller Lodge to watch as the Army-Navy “E” Award, a prestigious national honor given for “Excellence in Production” during World War II, was presented to the Los Alamos Laboratory. Major General Leslie Groves, the commanding officer of the Manhattan Project; Navy Commodore William S. (Deak) Parsons, the wartime leader of the Laboratory’s Ordnance Division; Robert Sproul, the President of the University of California; and J. Robert Oppenheimer accepted the award on behalf of the Laboratory.

99 GENERAL AND MISCELLANEOUS↗

Meson Spectroscopy from QCD - Final Technical Report

This report summarizes the research results produced by the award DE-SC0016952. The award led to several publications in the field of lattice QCD applied to hadron spectroscopy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Final Technical Report: "Achieving Regional Energy Efficiency Potential in the Southeast”

The overall objective of this award was to facilitate sharing of DOE resources and best practices as well as provide technical assistance to key stakeholders to support greater compliance with energy efficiency standards and increased energy savings. The outcomes of this award include greater awareness among key stakeholders on energy efficiency topics, increased deployment and utilization of DOE resources, and effective policies and programs to support energy efficiency in the Southeast.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Enabling Land-Use in E3SM Land Model (Final Report)

Human activity has significantly altered basic element cycles (e.g. of carbon and nitrogen), the water cycle, and the land surface (e.g. vegetation cover, albedo) at regional, continental, and planetary scales, and these alterations are influencing the regional and global environment, including the Earth’s climate system. The overall goal of this contribution to ACME/E3SM was to improve the coupling between models of land-use/land cover change. In particular, our effort was focused to enable ACME/E3SM v1 to use of the newest historical land use forcing data available, LUH2. The second-generation historical land-use harmonization dataset (LUH2, a separate but synergistic activity also lead by G. Hurtt, and supported by a DOE-SciDAC award) is now an entry card for participating in WCRP/CMIP6. Progress was made on all three of the proposed activities i.e. algorithm development, code development and testing, and model experiments to quantify improvements. Results have been disseminated via science team workgroups, telecons, meetings, Jira/Confluence, scientific meetings, and more broadly in related publications. This award has enabled novel science advancing the frontier on the topic of land-use change and climate. The innovative and synergistic scientific advances on modeling (this project) and data (DOE- SciDAC) is one of a kind and world leading.

54 ENVIRONMENTAL SCIENCES↗

DE-EE0006714 Final Report-Project Icebreaker™

Project Icebreaker, a 20 Megawatt offshore wind project 8 miles north of Cleveland, OH in Lake Erie, has been under development by the Lake Erie Energy Development Corporation since 2009. Significant development efforts were completed prior to the award of DE-EE0006714 (December 2014). This report describes the status of the work performed under award DE-EE0006714. The work was organized into several categories or tasks. The report presents the status of that work in each of eleven (11) main tasks: 1) State and Federal Permits; 2) Mono Bucket Foundation Engineering; 3) Construction and Installation Engineering; 4) Cable Route Survey; 5) Electrical System Design; 6) Power Off-take; 7) Project Costs and Risk Management; 8) Operations and Maintenance Planning; 9) Domestic Supply Chain Development; 10) Instrumentation Planning; and 11) Department of Energy Review.

17 WIND ENERGY↗

A Multiscale Approach to Modeling Carbon and Nitrogen Cycling within a High Elevation Watershed

This funding represents a small sub-award related the larger project titled: A Multiscale Approach to Modeling Carbon and Nitrogen Cycling within a High Elevation Watershed. The goal of the sub-award was to facilitate the characterization of carbon and radiocarbon data collected from the East River watershed outside Gothic, Colorado USA. During the period of funding from 8/1/15 until 7/31/17, we sampled 40 soil profiles and collected ~325 soil samples. This funding supported the collection, processing, and elemental analysis of each of these samples. In addition, the funding allowed for the further density separation of a subset of soil resulting in 60 measurements of 13 C and 14 C of bulk soil and density separates. Funding also supported installation of temperature and moisture data sensors arrays, soil gas wells, and soil water lysimeters. From this infrastructure, a steady stream data including soil gas, water, and physical information have been generated to support the larger research project.

54 ENVIRONMENTAL SCIENCES↗

Case Study: High Efficiency Dehumidification System (HEDS) Performance Modeling

JUMP connects innovators with industry partners to help bring new energy saving technologies to market. ORNL works with industry sponsors to develop calls for innovation that describe a technical challenge. The public and private sector businesses are then invited to submit their technology ideas to the JUMP program using an online interface by IdeaScale. Interested parties are encouraged to join the IdeaScale online community and to discuss technologies and to vote on them. A panel of technical experts then evaluates the idea submissions and, if a promising idea is identified, a JUMP winner is announced. In addition to the recognition given to the innovator by the JUMP program, typically the industry sponsor of the innovation call offers a monetary award. The industry sponsor and award winner then work together to refine the technology and further it towards the market. Since 2015 the JUMP program has included participation from a total of five national laboratories and fifteen industry sponsors in sixteen calls for innovation. The calls for innovation have engaged 1,446 online community members on 215 idea submissions. Seventy six percent of the businesses submitting ideas were small businesses.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Linear and Nonlinear Optical Properties of Metal Nanocomposite Materials

The scientific theme of this award stated in its title is “Linear and Nonlinear Optical Properties of Metal Nanoparticle Composites.” The motivation for the proposal was based on prior work that highlighted unusual third-order nonlinear optical response of metal-nanoparticle composites created by Vanderbilt researchers at the Oak Ridge National Laboratory (ORNL) by implanting metal ions into fused-silica and sapphire substrates and annealing them under appropriate conditions to produce a solid solution comprising noble-metal nanoparticles embedded in an insulating matrix. For example, the well-known localized surface plasmon resonance (LSPR) of gold and silver nanoclusters and nanoparticles was known to yield enhanced effects on the nonlinear absorption and nonlinear refractive index of these materials. The project soon expanded to embrace a wider range of materials and nanostructures, including particularly vanadium dioxide with its insulator-to-metal transition, a wide variety of substrate hosts, and zinc oxide with its multi-faceted band-edge exciton that can be coupled to plasmonic degrees of freedom in silver and aluminum. We employed second- and third-order nonlinear optical spectroscopies and confocal microscopy to quantify the coupling between nanoparticles and adsorbates across interfaces. Because ORNL closed the ion-beam surface-modification facility in 2004, we then developed a nanofabrication technique combining focused ion-beam lithography and pulsed laser deposition to create ordered arrays of metal and oxide nanoparticles in various planar geometries and heterostructures. By 2008, aided by finite-difference time-domain and finite-element calculations, we began to design and fabricate plasmonic “workbenches” on which we could excite quasiparticles (e.g., excitons, phonons, plasmons) using optical signals and electrical impulses, and map the material response down to femtosecond time and nanometer length scales. We developed additional nanofabrication capabilities (e.g., dual-layer electron-beam lithography, quantum-well fabrication and multilayer magnetron sputtering and electron-beam deposition) to create a variety of novel heterostructures as model nanocomposite systems. This led to several new opportunities to study the optical properties of these composites informed by views of potential device configurations. Among the scientific themes that emerged in published papers based on new materials and nanostructures were the following: ultrafast electron dynamics in metamaterials, including ultrafast THz microscopy of the insulator-to-metal transition in VO 2 nanoparticles; plasmon-driven electron injection to promote phase transitions in VO 2 ; and second-harmonic generation in nanostructures without inversion symmetry, in particular, the Archimedean spiral with overall sub-wavelength dimensions. We also explored dimensional and structural effects in plasmonic coupling, including exciton-plasmon coupling in ZnO nanowires; exciton-plasmon coupling in structures incorporating two-dimensional dichalcogenides; and tunable plasmon-induced transparency in plasmonic heterostructures incorporating phase-changing VO 2 . Finally, it should be noted that the work on Archimedean nanospirals and plasmon-exciton coupling led directly into a current quantum-optics research project on photon correlations in diamond nanoparticles, exemplified by the first publication from that effort [Ref. [47] in the bibliography]. A more detailed account setting in the appropriate scientific context all forty-eight papers supported by this award follows.

36 MATERIALS SCIENCE↗

Pilot Scale Operation and Testing of Syngas Chemical Looping For Hydrogen Production

The Syngas Chemical looping (SCL) process provides efficient and economic means to utilize the abundant fossil reserve of coal. The main problem associated with coal utilization is the CO 2 emissions resulting from its combustion. Even though CO 2 regulation or carbon tax is currently not in place, its enforcement is expected in the near future. Such a greenhouse gas emission control, if adopted in current power plant systems, will drive the efficiency down and increase the cost of electricity, due to the energy and capital-intensive nature of current CO 2 separation techniques. This highlights the need to develop technologies that present a solution to the rising cost of electricity in the future. The integrated gasification combined cycle (IGCC) presents an improvement to the above predicament, but it is capital intensive due to the extensive unit operations involved. The efficiency for a CO 2 capture incorporated IGCC system is around ~32%, resulting in approximately 45% increase in cost of electricity. This is definitely a better path to traverse than the conventional pulverized coal (PC) power plants as it has improved economics and efficiencies accompanied by product flexibility. The SCL process advances the benefits even further when integrated with the IGCC process. The SCL process removes the expensive WGS system and CO 2 separation columns, thereby saving on capital and operational expenses. This integration results in a 12 – 21% increase in efficiency accompanied by a reduction in cost of electricity by 15 – 28%, over conventional IGCC systems. Therefore, SCL process provides the best route to harness the energy from coal. The overall project objective was to construct and operate a syngas chemical looping pilot scale test unit at the NCCC. The project scope of work was divided into 3 phases. In Phase I, cold flow model studies using a 1:1 scale acrylic test unit constructed at Particulate Solids Research, Inc. (PSRI) was successfully completed confirming robust solid flow control is achievable in the non-mechanical system design. In Phase II, the high pressure, high temperature, chemical looping reactor was successfully designed with all necessary equipment and safety instrumentation/controls specified to allow for fabrication, site construction, and assembly to commence in Phase III. In Phase III, the SCL pilot plant was successfully assembled and all necessary functional checks and pre-startup safety reviews completed. During unit commission over the course of 200 hours of testing, operational issues were observed with premix burner used for system startup. With the grants awarded by the National Energy Laboratory (NETL) and the Ohio Development Services Agency (ODSA) under awards DE-FE0023915 and D-14-18, the SCL pilot unit underwent three auxiliary equipment modifications to resolve all of the startup operational issues encountered. The unit was successfully demonstrated with 300+hr continuous operation. Key results obtained include high syngas conversion of 97.95% with 16.03% oxygen carrier conversion in the moving bed reducer and >99% purity H 2 produced from the moving bed oxidizer.

01 COAL, LIGNITE, AND PEAT↗

NETL 2009 Economic Impacts Methodology Report

This report documents the assessment of the FY09 economic impacts of expenditures, employment, and research and development awards at the NETL sites located in Pittsburgh, PA; Morgantown, WV; and Albany, OR. The national IO model was developed to assess the FY09 economic impacts of NETL site expenditures, awards, and employment at the national level. This work serves as an annual update to the FY08 analysis National and State Economic Impact of NETL (December 2009).

99 GENERAL AND MISCELLANEOUS↗

High Temperature 300°C Measurement While Drilling System

Many countries around the world, including the USA, have untapped geothermal energy potential. Enhanced Geothermal Systems (EGS) technology is needed to economically utilize this resource. Temperatures in some EGS reservoirs can exceed 300°C. To effectively utilize EGS resources, an array of injection and production wells must be accurately placed in the formation fracture network. Therefore, EGS can greatly benefit from a high temperature directional drilling system. Most commercial services for directional drilling systems are rated for 175°C while geothermal wells require operation at much higher temperatures. Two U.S. Department of Energy (DOE) Geothermal Technologies Office (GTO) projects have been initiated to develop a 300°C capable directional drilling system, the first developing a drill bit, directional motor, and drilling fluid (award number DE-EE0002782), and the second adding navigation and telemetry systems. This report is for the second project, “High Temperature 300°C Measurement While Drilling System”, award number DE-EE0005505. The “High Temperature 300°C Measurement While Drilling (MWD)” system complements the already developed drilling system with real time navigation capability. It is comprised of 175°C directional measurement electronics including the required sensors for measuring inclination and azimuth in 3 axes. It is embedded in a cooling and temperature isolation system to protect the electronics and sensors from the higher temperature outside the system, which can reach 300°C. Building the cooling and isolation system from non-magnetic materials and keeping a required distance to any magnetic component, such as alternator parts, ensures a high quality measurement of the earth’s magnetic field. This is required to achieve the specified navigation accuracy. The MWD system has a turbine driven alternator that is capable of delivering the required electrical energy to the electronic system at a 300°C borehole temperature. Measured data will be communicated to the surface by mud-pulse-telemetry. For this purpose the tool has a mud-pulse-valve that is controlled by the measurement electronics to establish a serial data communication via the mud stream. The mud-pulse-valve is also built to operate under 300°C borehole conditions. Three prototypes of the 300°C MWD were built and tested. These systems are available for a joint application with the previously developed 300°C drilling system, in a geothermal well.

15 GEOTHERMAL ENERGY↗

Program Management Plan EnCore ® Accident Tolerant Fuel (ATF) Program

This Program Management Plan (PMP) is developed to support Westinghouse’s vision of developing and commercializing the Accident Tolerant Fuel. The near term goal of this Program is to deliver 2 fuel assemblies that consists of LTRs for Exelon Byron Unit 2 in spring of 2019. The longer term goal of this program is deployment of LTAs in 2022 of a mixture of coated zirconium cladding and SiC cladding with ADOPT and U3Si2 fuels. This is a high complexity program and is one of the largest research and development programs in Westinghouse and as such, the project scope is expected to change continuously. Integrated change control will be invoked as necessary. The Program consists of multiple funding streams (internal through Westinghouse innovation funding), external (through the DOE). The DOE funding consists of two phases: 1. Phase 2 – funded by DOE award number DE-NE0008222. 2. Phase 2B – funded by DOE – Westinghouse proposal reference # LTR-AMER-MKG-18-826, Rev. 1, August 23, 2018 (10/18 to 2/21), Award No. DE-NE0008824. 3. Cost share contributions from Westinghouse and program partners.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Task 1: Evaluation of M&S tools for micro-reactor concepts

The Westinghouse Electric Company (WEC) and Los Alamos National Laboratory (LANL) have been awarded a DOE ARPA-E MEITNER award for development of its eVinci microreactor design. Fundamentally, the attractiveness of heat pipe micro-reactors comes from the idea that the core is inherently self-regulating, simplifying the reactor design and requiring significantly fewer safety related components. While the WEC Design Team is focused on the experimental and fabrication tasks to ensuring self-regulation, the MEITNER Resource Team is focused on utilizing available codes to computationally show the core is indeed self-regulating. This requires the combination of fundamentally different codes to simulate the feedback mechanism between heat generation, temperature, and density.

42 ENGINEERING↗

Multi-speed transmission for commercial delivery medium duty PEDVs final report

This CRADA between EATON and Oak Ridge National Laboratory (ORNL) was part of the Office of Energy Efficiency and Renewable Energy (EERE), U.S. Department of Energy Vehicle Technologies Office (VTO) FOA DE-FOA-0000991, under Award Number DE-EE0006843. Thus, the following report is a subsection of the larger Award Number DE-EE0006843, covering only the portions that were collaborated on by ORNL and EATON. The EV Everywhere Grand Challenge [1] aimed at realizing plug-in electric drive vehicles (PEDVs) that meet or exceed the performance of internal combustion drive vehicles (ICDV) based on cost, convenience, and consumer satisfaction. The average range of a PEDV is approximately one-third the range of an ICDV.

Deter, Dean D.↗

U.S. Department of Energy Fuels & Lubricants Project on Lubricant Technology - Innovation, Discovery, Design, and Engineering (Final Report)

In 2016, the Vehicle Technologies Office (VTO) of the Department of Energy (DOE) issued a solicitation for the AOP Lab Call research in FY2017 on a number of topics related to vehicles. Topic 6A of the Lab Call focused on research related to advanced lubricants: '...(in) support of the lubricants program goal to, by 2020, demonstrate novel formulations for powertrain and driveline lubricants, compatible with new and legacy vehicles, to achieve at least a 4 percent real-world fuel economy improvement.' Argonne National Laboratory (ANL) in collaboration with Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) was awarded a 3-year multilab project on 'Lubricant Technology - Innovation, Discovery, Design, and Engineering.' Research on the project began in FY2017 at the three laboratories with industry participation; however, in FY2018, the project was terminated due to budgetary constraints. The following is the final report for the project and highlights progress made during the first year of research. The report is divided into sections that highlight the following: goals, objectives, milestones and deliverables; project highlights; outreach - publications, conferences, and reports; milestones accomplished; research progress.

30 DIRECT ENERGY CONVERSION↗

Effects of Exhaust Gas Recirculation (EGR) on Turbulent Combustion and Emissions in Advanced Gas Turbine Combustors with High-Hydrogen-Content (HHC) Fuels (Final Report)

This Final Report documents the entire four years of the Cooperative Agreement DE-FE0011822, from October 1, 2013 through September 30, 2017, that was competitively awarded under Funding Opportunity Announcement DE-FOA-0000795 in support of the U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) University Turbine Systems Research (UTSR) Program. Under the UTSR Program, DOE typically issues Funding Opportunity Announcement (FOA) solicitations every 1-2 years so that U.S. colleges/universities may propose research & development (R&D) projects in specific technical topic areas (e.g., combustion, aerodynamics/heat transfer, advanced materials) that have been identified as both scientifically and industrially relevant to the gas turbine industry. The primary objectives of this Purdue University project (in collaboration with Princeton University through a sub-award) was to develop experimental methods, kinetic models, and numerical tools to help quantify and predict the impact of exhaust gas recirculation (EGR) on NOx and CO emissions, combustion kinetics, radiation heat transfer, turbulent combustion, and combustion instabilities for natural gas and high hydrogen content (HHC) fuels by using laminar and turbulent flow reactors and gas turbine combustors operating at high temperatures and pressures. This project has obtained detailed data for improving chemical kinetic models to study EGR effects and provide insight into the effects of EGR on flame speeds and turbulent flame structure, as well as assessing the impact of EGR on emissions in a high-pressure combustion test rig. The project was divided into six primary tasks: 1) Project Management and Program Planning; 2) Flow Reactor Investigation of EGR Chemical Kinetics; 3) Combustion Bomb Investigation of EGR Effects on Flame Speed; 4) Investigation of EGR Effects on Turbulent Flame Structure in Reactor-Assisted Turbulent Slot (RATS) Burner; 5) Investigation of EGR Effects in Purdue Staged Combustion Test Rig; and 6) Development and Validation of a Large Eddy Simulation (LES) Tool for Gas Turbine Combustion and Emission Modeling using HHC Fuels. Details on the execution and results of each of these tasks are provided in the main report. To assist the reader, each task is described in a chapter-like format with its own separate listing of tables, figures, and references so that the results of each task/subtask (i.e., technical sections covering various experiments and modeling work focused on a specific area) can be quickly obtained while also getting an overall feel of the project execution. This chapter-like format also allows for acknowledgement of support from other programs relative to specific tasks. In this manner, the reader can more conveniently digest the R&D results in the various task/subtask sections that may be of most interest to the reader. In addition to this Final Report, the Purdue/Princeton team was able to publish 7 journal articles and provide 7 presentations at national scientific meetings/conferences to disseminate results. A listing of these journal articles and presentations is provided at the end of this report

03 NATURAL GAS↗

Fort Yukon wood Energy Program Wood Boiler Deployment (Final Report)

The Fort Yukon Gwitchyaa Zhee Corporation (GZ) worked with partners on the development of an Integrated Biomass Energy Program for Fort Yukon. This integrated approach linked sustainable forest management with an in- village for -profit wood harvest and delivery business to displace diesel energy with wood energy for heat and power. The program was based on the concept of ecological, economic and social sustainability with a goal of displacing as much diesel and fuel oil as is technically feasible and sustainable; essentially systematically converting a village to significant amounts of wood use. Additionally, GZ worked with the Alaska Energy Authority (AEA) on the development of a rural power system upgrade (RPSU) project that replaced GZ’s existing antiquated diesel power plant and provided upgrades to the existing electrical distribution system. Due to the synergy of the two projects, the Biomass and RPSU projects were combined to provide improved operating efficiency, economy of scale and increased benefits to GZ, the Council of Athabascan Tribal Governments (CATG) and the community of Fort Yukon. The combined project is referred to as the Fort Yukon Combined heat and power (CHP) project. The purpose of the DOE Tribal Energy Program award was to support the preconstruction tasks and installation of wood boilers at the CATG clinic, and at the new GZ diesel power plant as part of an overall program to create a for- profit wood energy utility in Native Village of Fort Yukon. The CHP project provides biomass and diesel generation recovered heat via a new district heating system to the major commercial buildings in Fort Yukon. The CATG clinic will receive heat from a separate biomass boiler to their heating needs. The award from the Department of Energy (DOE) Tribal Energy Program was divided into two phases: Design/Permitting (phase 1) and Construction (phase 2). Phase 1 (Design & Permitting) is cost shared using State of Alaska Renewable Energy Funding (REF) funds through the Alaska Energy Authority (AEA). Phase 2 (Construction) was funded by DOE, AEA and US Department of Agriculture Rural Utility Service (USDA-RUS). Phase 1 of this grant, along with a separate grant from the Denali Commission provided funding for development of the wood delivery infrastructure necessary to support the CHP project. Under phase 2, This DOE grant supported final design of the boiler, bidding, purchase and transport of boilers, installation, technical support and engineering. The AEA and RUS grants supported permitting, final design, material and equipment purchase, and construction and installation of the new diesel power plant and district heating distribution system.

09 BIOMASS FUELS↗