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At least 595 records · Page 33

Removal of Burkholderia cepacia biofilms with oxidants

Iodine is used to disinfect the water system aboard US space shuttles and is the anticipated biocide for the international space station. Water quality on spacecraft must be maintained at the highest possible levels for the safety of the crew. Furthermore, the treatment process used to maintain the quality of water on research must be robust and operate for long periods with minimal crew intervention. Biofilms are recalcitrant and pose a major threat with regard to chronic contamination of spacecraft water systems. We measured the effectiveness of oxidizing biocides on the removal and regrowth of Burkholderia (Pseudomonas) cepacia biofilms. B. cepacia, isolated from the water distribution system of the space shuttle Discovery, was grown in continuous culture to produce a bacterial contamination source for biofilm formation and removal studies. A 10(7) CFU ml-1 B. cepacia suspension, in distilled water, was used to form biofilms on 3000 micrometers2 glass surfaces. Rates of attachment were measured directly with image analysis and were found to be 7.8, 15.2, and 22.8 attachment events h-1 for flow rates of 20.7, 15.2, and 9.8 ml min-1, respectively. After 18 h of formation, the B. cepacia biofilms were challenged with oxidants (ozone, chlorine, and iodine) and the rates of biofilm removal determined by image analysis. Fifty percent of the biofilm material was removed in the first hour of continous treatment with 24 mg l-1 chlorine or 2 mg l-1 ozone. Iodine (48 mg l-1) did not remove any measurable cellular material after 6 h continuous contact. After this first removal of biofilms by the oxidants, the surface was allowed to refoul and was again treated with the biocide. Iodine was the only compound that was unable to remove cellular debris from either primary or secondary biofilms. Moreover, treating primary biofilms with iodine increased the rate of formation of secondary biofilms, from 4.4 to 5.8 attachment events h-1. All the oxidants tested inactivated the B. cepacia associated with both primary and secondary biofilms. The amount of biocide needed to inactivate 50% of planktonic B. cepacia in 10 min at 25 degrees C was 8.4, 0.5, and 0.2 mg l-1 for iodine, chlorine, and ozone, respectively. The data suggest that iodine maynot be the best chemical for treating of biofilms when removal of cellular material is required.

NASA Discipline Environmental Health↗

Rough-Water Tests of Models of the Vosper and Plum Planing Boats

Models of two types of high-speed surface craft were tested in Langley tank no. 1 to obtain rough-water data for an evaluation by the David Taylor .Model Basin of the relative merits of the designs. Time-history records were obtained of trim, rise, and normal acceleration at two points in the hulls for various speeds and two sizes of waves.

Chambliss, Derrill B.↗

Finland Validation of the New Blended Snow Product

As part of an ongoing effort to validate satellite remote sensing snow products for the recentlydeveloped U.S. Air Force Weather Agency (AFWA) - NASA blended snow product, Satellite and in-situ data for snow extent and snow water equivalent (SWE) are evaluated in Finland for the 2006-2007 snow season Finnish Meteorological Institute (FMI) daily weather station data and Finnish Environment Institute (SYKE) bi-monthly snow course data are used as ground truth. Initial comparison results display positive agreement between the AFWA NASA Snow Algorithm (ANSA) snow extent and SWE maps and in situ data, with discrepancies in accordance with known AMSR-E and MODIS snow mapping limitations. Future ANSA product improvement plans include additional validation and inclusion of fractional snow cover in the ANSA data product. Furthermore, the AMSR-E 19 GHz (horizontal channel) with the difference between ascending and descending satellite passes (Diurnal Amplitude Variations, DAV) will be used to detect the onset of melt, and QuikSCAT scatterometer data (14 GHz) will be used to map areas of actively melting snow.

Kim, E. J.↗

Analysis of Water Surplus at the Lunar Outpost

This paper evaluates the benefits to the lunar architecture and outpost of having a surplus of water, or a surplus of energy in the form of hydrogen and oxygen, as it has been predicted by Constellation Program's Lunar Surface System analyses. Assumptions and a scenario are presented leading to the water surplus and the revolutionary surface element options for improving the lunar exploration architecture and mission objectives. For example, some of the elements that can benefit from a water surplus are: the power system energy storage can minimize the use of battery systems by replacing batteries with higher energy density fuel cell systems; battery packs on logistics pallets can also be minimized; mobility asset power system mass can be reduced enabling more consumables and extended roving duration and distance; small robotic vehicles (hoppers) can be used to increase the science exploration range by sending round-trip robotic missions to anywhere on the Moon using in-situ produced propellants.

Santiago-Maldonado, Edgardo↗

Evaluation of the Analysis Influence on Transport in Reanalysis Regional Water Cycles

Regional water cycles of reanalyses do not follow theoretical assumptions applicable to pure simulated budgets. The data analysis changes the wind, temperature and moisture, perturbing the theoretical balance. Of course, the analysis is correcting the model forecast error, so that the state fields should be more aligned with observations. Recently, it has been reported that the moisture convergence over continental regions, even those with significant quantities of radiosonde profiles present, can produce long term values not consistent with theoretical bounds. Specifically, long averages over continents produce some regions of moisture divergence. This implies that the observational analysis leads to a source of water in the region. One such region is the Unite States Great Plains, which many radiosonde and lidar wind observations are assimilated. We will utilize a new ancillary data set from the MERRA reanalysis called the Gridded Innovations and Observations (GIO) which provides the assimilated observations on MERRA's native grid allowing more thorough consideration of their impact on regional and global climatology. Included with the GIO data are the observation minus forecast (OmF) and observation minus analysis (OmA). Using OmF and OmA, we can identify the bias of the analysis against each observing system and gain a better understanding of the observations that are controlling the regional analysis. In this study we will focus on the wind and moisture assimilation.

Bosilovich, M. G.↗

Evaluation of Two Crew Module Boilerplate Tests Using Newly Developed Calibration Metrics

The paper discusses a application of multi-dimensional calibration metrics to evaluate pressure data from water drop tests of the Max Launch Abort System (MLAS) crew module boilerplate. Specifically, three metrics are discussed: 1) a metric to assess the probability of enveloping the measured data with the model, 2) a multi-dimensional orthogonality metric to assess model adequacy between test and analysis, and 3) a prediction error metric to conduct sensor placement to minimize pressure prediction errors. Data from similar (nearly repeated) capsule drop tests shows significant variability in the measured pressure responses. When compared to expected variability using model predictions, it is demonstrated that the measured variability cannot be explained by the model under the current uncertainty assumptions.

Horta, Lucas G.↗

Evaluating Radiometric Sensitivity of LandSat 8 Over Coastal-Inland Waters

The operational Land Imager (OLI) aboard Landsat 8 was launched in February 2013 to continue the Landsat's mission of monitoring earth resources at relatively high spatial resolution. Compared to Landsat heritage sensors, OLI has an additional 443-nm band (termed coastal/aerosol (CA) band), which extends its potential for mapping/monitoring water quality in coastal/inland waters. In addition, OLI's pushbroom design allows for longer integration time and, as a result, higher signal-to-noise ratio (SNR). Using a series of radiative transfer simulations, we provide insights into the radiometric sensitivity of OLI when studying coastal/inland waters. This will address how the changes in water constituents manifest at top-of-atmosphere (TOA) and whether the changes are resolvable at TOA (focal plane) relative to OLI's overall noise.

radiometric sensitivity↗

A Comparative Analysis of Phase-Change Wastewater Processing Approaches for Microgravity

Two phase-change wastewater processing candidates, the ISS Vapor Compression Distillation (VCD) System and the Cascade Distiller System (CDS), are compared based on dynamic modeling of both technologies. Differences in fluid handling and energy recovery for the technologies are described and contrasted. Model predictions are presented showing how temperatures, pressures, and compositions vary locally within each distiller. These dynamic variations are difficult to observe experimentally and have implications regarding non-condensable buildup and salt precipitation potential. Alternative architectures involving VCD and CDS components are analyzed in terms of predicted performance and equivalent system mass (ESM). The addition of a downstream brine processor to increase water recovery is also evaluated. Options for reducing overall ESM are discussed, including the possibility of developing a single precipitation-tolerant primary wastewater processor.

Lange, Kevin↗

Modelling Bambara Groundnut Yield in Southern Africa: Towards a Climate-Resilient Future

Current agriculture depends on a few major species grown as monocultures that are supported by global research underpinning current productivity. However, many hundreds of alternative crops have the potential to meet real world challenges by sustaining humanity, diversifying agricultural systems for food and nutritional security, and especially responding to climate change through their resilience to certain climate conditions. Bambara groundnut (Vigna subterranea (L.) Verdc.), an underutilised African legume, is an exemplar crop for climate resilience. Predicted yield performances of Bambara groundnut by AquaCrop (a crop−water productivity model) were evaluated for baseline (1980−2009) and mid-century climates (2040−2069) under 20 downscaled Global Climate Models (CMIP5-RCP8.5), as well as for climate sensitivities (AgMIPC3MP) across 3 locations in Southern Africa (Botswana, South Africa, Namibia). Different land - races of Bambara groundnut originating from various semi-arid African locations showed diverse yield performances with diverse sensitivities to climate. S19 originating from hot-dry conditions in Namibia has greater future yield potential compared to the Swaziland landrace Uniswa Red-UN across study sites. South Africa has the lowest yield under the current climate, indicating positive future yield trends. Namibia reported the highest baseline yield at optimum current temperatures, indicating less yield potential in future climates. Bambara groundnut shows positive yield potential at temperatures of up to ~31degC, with further warming pushing yields down. Thus, many regions in Southern Africa can utilize Bambara groundnut successfully in the coming decades. This modelling exercise supports decisions on genotypic suitability for present and future climates at specific locations.

farm crops↗

Assessment of Soil Moisture Retrievals Using SMAP and ELBARA-III Measurements in a Tibetan Meadow Ecosystem

This study presents results evaluating retrievals of liquid water content for both thawed and frozen soils based on simultaneous SMAP and ELBARA-III measurements in a Tibetan meadow ecosystem. A good agreement is found between time series of the SMAP and ELBARA-III T(sub B(sup P)) measurements (R≥0.87). Differences noted between the two data sets are linked to distinct liquid water content variations found in the specific footprints, and the SMAP measurements are better explained by the in-situ liquid water content. Furthermore, the in-situ liquid water content shows better agreements with both SMAP and ELBARA-III measured T(sub B(sup P)) at horizontal polarization in the cold season, while the measurements at vertical polarization are more consistently varying with the liquid water content for the warm season. With the implementation of new vegetation and surface roughness parameterizations, the dynamics of in-situ liquid water content are better reproduced by corresponding retrievals for both thawed and frozen soils, leading to the reduction of the unbiased root mean-square error (ubRMSE) by more than 31 % in comparison to these retrievals using SMAP default parameterizations. Notably, the single channel algorithm configured with the new parameterizations using SMAP measured vertical polarization during the ascending overpass provides the best liquid water content retrievals with an ubRMSE of 0.035 cu m -cu m that outperforms the SMAP mission specification.

L-band microwave radiometry↗

Retrieval of Snow Water Equivalent by the Precipitation Imaging Package (PIP) over Northern Great Lakes

Performance of the Precipitation Imaging Package (PIP) for estimating the snow water equivalent (SWE) is evaluated through a comparative study with the collocated National Oceanic and Atmospheric Administration National Weather Service snow stake field measurements. The PIP together with a vertically pointing radar, a weighing bucket gauge, and a laser-optical disdrometer was deployed at the NWS Marquette, Michigan office building for a long-term field study supported by the National Aeronautics and Space Administration’s Global Precipitation Measurement mission Ground Validation program. The site was also equipped with a weather station. During the 2017-18 winter, PIP functioned nearly uninterrupted at frigid temperatures accumulating 2345.8 mm of geometric snow depth over a total of 499 hours. This long record consists of 30 events, and the PIP-retrieved and snow stake field measured SWE differed less than 15% in every event. For the windy events, the wind corrected stake field record agreed better with the PIP-retrieved SWE. Two of the major events with the longest duration and the highest accumulation are examined in detail. The particle mass with a given diameter was much lower during a shallow, colder, uniform lake-effect event than in the deep, less cold, and variable synoptic event. This study demonstrated that PIP is a robust instrument for operational use, and is reliable for deriving the bulk properties of falling snow.

Ali Tokay↗

Estimation of Snow Mass Information via Assimilation of C-Band Synthetic Aperture Radar Backscatter Observations Into an Advanced and Surface Model

This study assimilated Sentinel-1 C-band backscatter observations over snow-covered terrain into the Noah-Multiparameterization land surface model using support vector machine (SVM) regression and an ensemble Kalman filter to improve the modeled terrestrial snow mass estimates. The data assimilation (DA) experiment was conducted across Western Colorado from September 2016 to August 2017. As part of the DA experiments, the impact of a rule-based update was evaluated by comparing snow water equivalent (SWE) estimates via DA (with [ DAv1 ] and without [ DAv2 ] the rule-based update) against SNOTEL SWE measurements. Results confirmed that rule-based update helped minimize SVM controllability issues, and in turn, improved the accuracy of SWE estimates relative to both open loop (OL) and DAv2 . Comparison of SWE estimates from Sentinel-1 DAv1 against SNOTEL SWE revealed that 75% of stations showed improvements in bias and correlation coefficient relative to the OL. Assimilated SWE estimates also showed statistical improvements during both the snow accumulation and snow ablation periods. However, unbiased root mean square error showed a slight increase during the snow ablation period due to the large variability in the electromagnetic response of C-band backscatter over deep and/or wet snow. Improvement of the SWE estimates also resulted in improving river discharge estimates compared to in situ measurements. River discharge using Sentinel-1 DAv1 improved the Nash–Sutcliffe efficiency at all available stations. These results suggest that physically constrained SVM can serve as an efficient observation operator for snow mass DA through explicit consideration of the first-order C-band scattering mechanisms over different terrestrial snow conditions.

Jongmin Park↗

Detailed Evaluation of Electric Demand Load Shifting Potential of Heat Pump Water Heaters

Future utilities will emphasize home appliances to reduce greenhouse gas emissions while providing electric load shifting and demand profile management. Heat pump water heaters (HPWH) have demonstrated the ability to cut water heating energy by more than 65% compared with conventional electric resistance waters (ERWH). Laboratory research was conducted on the load shifting potential of grid-connected heat pump water heaters (HPWH), compared to ERWHs. Testing applied different CTA-2045 command designs. Highly-controlled laboratory experiments were conducted on one ERWH and four HPWHs, including a prototype incorporating the new CTA-2045-B protocol feature allowing ‘advanced’ load up above the tank setpoint. The prototype unit with the B-protocol increased tank temperature by 15oF (8.3C) under the advanced load up providing an increase of 1.8 kWh of storage for a 50-gallon (189 liter) tank. The prototype includes a built-in mixing valve to meet anti-scalding codes. With the load-shaping ability of CTA-2045-B, utilities might be able to store excess renewable energy in connected tanks when renewable wind and solar resource production is high. Tests were performed under baseline conditions (no load shift) and under several load-shifting schemes, including load up and advanced load up, ahead of shed commands. Grid-connected HPWHs reduced peak demand by as much as 0.5 kW, depending on tank volume, time of day, control scheme, and draw profile.

heat pump water heater, Demand flexibility, load s↗

A Propane Hydronic Heat Pump with Energy Storage

Propane is an environment-friendly refrigerant, having a 20-year GWP (global warming potential) of 0.072 and a 100-year GWP of 0.02, as compared to R-410A having a GWP > 2000. It has superior thermodynamic cycle performance and heat transfer characteristics. However, propane is classified as a A3 refrigerant, which is highly flammable, and not allowed to be used indoor if the system charge is higher than 150 grams. It is a challenge to use propane in residential applications requiring a rated capacity larger than 10 k Watts. A hydronic heat pump, i.e., containing propane in an outdoor unit and distributing the cooling and heating capacity through a hydronic coil to the indoor space addresses the flammability issue, while maintaining a high efficiency. We developed a hydronic heat pump with propane, it uses a two-stage compressor, a brazed plate indoor heat exchanger, and a microchannel outdoor heat exchanger. It achieves a rated cooling capacity larger than 10 k Watts, and a cooling SEER (cooling seasonal energy efficiency rating) > 16.0 (cooling seasonal COP > 4.7) and a heating HSPF (heating seasonal performance factor) > 9.5 (heating seasonal COP > 2.78), while requiring a system charge < 1200 grams. Additionally, the hydronic heat pump was evaluated in a laboratory water heating loop to heat a 50-gallon water tank in a full condensing mode. Experiments of heating the tank water from 58F(14.4°C) to 150F(65.6°C) were conducted under ambient temperatures from 17F(-8.3°C) to 75F(23.9°C), at the compressor high and low stages.

Shen, Bo↗

Dynamic soil columns simulate Arctic redox biogeochemistry and carbon release during changes in water saturation

Thawing Arctic permafrost can induce hydrologic change and alter redox conditions, shifting the balance of soil organic matter (SOM) decomposition. There remains uncertainty about how soil saturation and redox transitions impact dissolved and gas phase carbon fluxes, and efforts to link hydrobiogeochemical processes to ecosystem-scale models are limited. This study evaluates SOM decomposition of Arctic tundra soils using column experiments, water chemistry measurements, microbial community analysis, and a PFLOTRAN reactive transport model. Soil columns from a thermokarst channel (TC) and an upland tundra (UC) were exposed to cycles of saturation and drainage, which controlled carbon emissions. During saturation, an outflow of dissolved organic carbon from the UC soil correlated with elevated reduced iron and decreased pH; during drainage, UC carbon dioxide fluxes were 70% higher than TC fluxes. Intermittent methane release was observed for TC, consistent with higher methanogen abundance. Slower drainage in the TC soil correlated with more subtle biogeochemical changes. PFLOTRAN simulations captured experimental trends in soil carbon fluxes, oxygen concentrations, and water contents. The model was then used to evaluate additional soil water drainage rates. This study emphasizes the importance of considering hydrologic change when evaluating and simulating SOM decomposition in dynamic Arctic tundra environments.

54 ENVIRONMENTAL SCIENCES↗

Hydrogen Recombiner Catalyst Evaluations for Waste Storage

Radiolysis of water in nuclear waste storage generates hydrogen gas that can accumulate within sludge style waste and be rapidly released during agitation events, creating a significant flammability hazard. Engineering controls are therefore required to limit hydrogen concentrations during both quiescent storage and transient disturbances. Catalytic recombination of hydrogen in waste storage offgas is a proven mitigation strategy, maintaining hydrogen levels below flammability limits and managing sudden concentration spikes. Conventional recombiners rely on platinum and/or palladium catalysts, with development efforts focused on extending service life, increasing active surface area, and ensuring safe deployment in radioactive environments. Savannah River National Laboratory (SRNL) is evaluating a newly developed hydrogen recombiner catalyst from Canadian Nuclear Laboratories as a cost-effective and durable alternative for nuclear waste applications. Testing was conducted in SRNL’s Shielded Cells facility, which enables reduced-scale experimental modeling under radiation fields and near-use-case conditions relevant to radioactive waste storage. Catalyst performance was evaluated using a custom offgas characterization system designed for near-zero flow conditions. The experimental apparatus consisted of a gas-tight 2.7 L PTFE vessel equipped with temperature monitoring, gas flow controls, and a variable-speed mixer to simulate sludge agitation. Offgas composition was monitored using a dedicated gas chromatograph with argon carrier gas and a krypton internal standard. Measurements were obtained for an empty vessel, the vessel containing a well characterized radioactive tank waste sample, and the same configuration with the candidate catalyst installed. Results demonstrate that the new catalyst effectively reduced hydrogen concentrations in the offgas within the constraints of the experimental design. In addition to confirming catalytic activity, the testing provided valuable insights into experimental optimization and considerations for future performance evaluations. These findings support the potential scalability of the technology and highlight its applicability to broader nuclear waste management operations, offering improved safety and reduced operational costs through enhanced catalyst durability and lower replacement frequency.

Tener, Zachary P. [Savannah River National Laborat↗

Rapid Fabrication Techniques for Liquid Rocket Channel Wall Nozzles

The functions of a regeneratively-cooled nozzle are to (1) expand combustion gases to increase exhaust gas velocity while, (2) maintaining adequate wall temperatures to prevent structural failure, and (3) transfer heat from the hot gases to the coolant fluid to promote injector performance and stability. Regeneratively-cooled nozzles are grouped into two categories: tube-wall nozzles and channel wall nozzles. A channel wall nozzle is designed with an internal liner containing a series of integral coolant channels that are closed out with an external jacket. Manifolds are attached at each end of the nozzle to distribute coolant to and away from the channels. A variety of manufacturing techniques have been explored for channel wall nozzles, including state of the art laser-welded closeouts and pressure-assisted braze closeouts. This paper discusses techniques that NASA MSFC is evaluating for rapid fabrication of channel wall nozzles that address liner fabrication, slotting techniques and liner closeout techniques. Techniques being evaluated for liner fabrication include large-scale additive manufacturing of freeform-deposition structures to create the liner blanks. Abrasive water jet milling is being evaluated for cutting the complex coolant channel geometries. Techniques being considered for rapid closeout of the slotted liners include freeform deposition, explosive bonding and Cold Spray. Each of these techniques, development work and results are discussed in further detail in this paper.

Gradl, Paul R.↗

Life‐cycle greenhouse gas emissions associated with nuclear power generation in the United States

Under the 2022 Inflation Reduction Act, tax credits of up to $3/kgH 2 are available to hydrogen producers if they generate emissions at levels below 0.45 kgCO 2 e/kgH 2 , spurring producers to explore how hydrogen production via electrolysis using electricity generated by nuclear power may qualify for such tax credits. With uranium as a primary fuel for nuclear power plants (NPPs) and no on-site emissions, the upstream emissions associated with nuclear fuel supply chains largely determine the carbon intensity of nuclear energy. Using the GREET (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model, we evaluated the life-cycle greenhouse gas (GHG) emissions of uranium production and the use of uranium to generate electricity in light water reactor (LWR) NPPs. We evaluated the process chemicals and energy inputs throughout the nuclear fuel supply chain to identify the major contributors to nuclear fuel cycle GHG emissions. Such emissions are estimated at 3.0 gCO 2 e/kWh at NPPs in the United States. The greatest share of nuclear fuel cycle GHG emissions—comprising 53% of total emissions—are associated with electricity consumption throughout the fuel supply chain. We extended the analysis to include an evaluation of the carbon intensity of H 2 production via electrolysis using nuclear power from LWRs. Finally, we examined the impact of future (2035 and 2050) electricity supply chain scenarios on nuclear fuel cycle GHG emissions. Our analysis revealed a decrease of 33% (2035) and 46% (2050) in the carbon intensity of nuclear electricity relative to current nuclear fuel cycle GHG emissions.

greenhouse gas emissions↗