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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Modification of CO 2 /H 2 O selectivity of polymer for carbon capture materials

Today, the atmospheric carbon dioxide (CO 2 ) concentration is 421ppm, over one hundred ppm higher than it was at any point in the last 800,000 years (NASA, 2023). Multiple strategies are necessary to reduce the presence of carbon dioxide in the atmosphere. Besides limiting CO 2 output, carbon capture technology is essential to reduce the overall amount of CO 2 . The Microencapsulated CO 2 Sorbents (MECS) team at Lawrence Livermore National laboratory has developed technologies that can capture CO 2 inside microcapsules, where it can be temporarily stored and later released. In 2017, the commercial potential of these microcapsules was recognized. The brewing industry only requires about one third of the CO 2 it releases for carbonization and packaging, which Congwang Ye and Lionel Keene learned when they met with leaders of small breweries in Colorado to discuss employing carbon capture microcapsules in their processes to reduce their carbon footprint and production costs (Thomas, 2017). The breweries were interested in the technology, but the existing microcapsules require hydration, which is an expensive process for small brewers. In order to develop the microcapsules so they can be commercialized, it is essential to reduce their water loss to improve efficiency and reduce costs for the customers. One method to resolve this issue is to alter the membrane formulation by adding a material that is known to be hydrophobic to decrease the water permeability of the entire membrane. The goal of this project was to study the effect of dispersing a nanomaterial in the polymer membrane shells of microcapsules on the water vapor and carbon dioxide permeability of the membranes.

36 MATERIALS SCIENCE↗
NASA NTRS1981

An efficient method for computing the absorption of solar radiation by water vapor

Chou and Arking (1980) have developed a fast but accurate method for computing the IR cooling rate due to water vapor. Using a similar approach, the considered investigation develops a method for computing the heating rates due to the absorption of solar radiation by water vapor in the wavelength range from 4 to 8.3 micrometers. The validity of the method is verified by comparison with line-by-line calculations. An outline is provided of an efficient method for transmittance and flux computations based upon actual line parameters. High speed is achieved by employing a one-parameter scaling approximation to convert an inhomogeneous path into an equivalent homogeneous path at suitably chosen reference conditions.

Chou, M.-D.↗
DOE OSTI2025

Laboratory Testing and Performance Characterization of the High Efficiency Dehumidification System (HEDS) Technology

The high efficiency dehumidification system (HEDS) is a unique air handling unit (AHU) design with two water coils. Connected in series, these water coils can sensibly reheat the airstream after it is cooled and dehumidified, thereby mitigating (or sometimes eliminating) the need for conventional sensible reheat with additional energy from hot water, electric resistance or steam coils. Another unique design feature is the size of the HEDS primary cooling coil. While typical AHU cooling coils have a 6-row geometry, the HED's cooling coil has a deeper 10-row geometry enabling discharge air dew point temperatures at or below 55 degrees F despite warmer chilled water supply temperatures approaching (sometimes exceeding) 50 degrees F. The ability to meet acceptable discharge air dew points with warmer chilled water supply temperatures improves both operational efficiency and system resilience against chilled water plant operational or control issues. This report summarizes the 59 steady-state test results that form a comprehensive performance map of the HEDS technology including its reheat capability. The breadth of outdoor air conditions and flow rates over which the HEDS technology was tested and characterized encompasses the unit 1) operating as a dedicated outdoor air system or mixed air system and 2) controlled with constant air volume or variable air volume fan control.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS2011

Iridium-Doped Ruthenium Oxide Catalyst for Oxygen Evolution

NASA requires a durable and efficient catalyst for the electrolysis of water in a polymer-electrolyte-membrane (PEM) cell. Ruthenium oxide in a slightly reduced form is known to be a very efficient catalyst for the anodic oxidation of water to oxygen, but it degrades rapidly, reducing efficiency. To combat this tendency of ruthenium oxide to change oxidation states, it is combined with iridium, which has a tendency to stabilize ruthenium oxide at oxygen evolution potentials. The novel oxygen evolution catalyst was fabricated under flowing argon in order to allow the iridium to preferentially react with oxygen from the ruthenium oxide, and not oxygen from the environment. Nanoparticulate iridium black and anhydrous ruthenium oxide are weighed out and mixed to 5 18 atomic percent. They are then heat treated at 300 C under flowing argon (in order to create an inert environment) for a minimum of 14 hours. This temperature was chosen because it is approximately the creep temperature of ruthenium oxide, and is below the sintering temperature of both materials. In general, the temperature should always be below the sintering temperature of both materials. The iridium- doped ruthenium oxide catalyst is then fabricated into a PEM-based membrane- electrode assembly (MEA), and then mounted into test cells. The result is an electrolyzer system that can sustain electrolysis at twice the current density, and at the same efficiency as commercial catalysts in the range of 100-200 mA/sq cm. At 200 mA/sq cm, this new system operates at an efficiency of 85 percent, which is 2 percent greater than commercially available catalysts. Testing has shown that this material is as stable as commercially available oxygen evolution catalysts. This means that this new catalyst can be used to regenerate fuel cell systems in space, and as a hydrogen generator on Earth.

Valdez, Thomas I.↗
DOE OSTI2025

Energy-Efficient Selective Removal of Metal Ions from Mining Influenced Waters (MIW) Using H-Bonded Organic-Inorganic Framework (HOIFS) (CRADA Final Report)

The work developed a hydrogen-bonded organic–inorganic framework (HOIF), specifically zinc imidazole salicylaldoxime supramolecule (ZIOS), for selective Cu removal and recovery from acidic mining-impacted waters (AMD), with emphasis on scalable synthesis, membrane integration, durability in real AMD (RAMD), mechanistic understanding, and recovery/regeneration pathways. This research breaks new ground in selective resource recovery from AMD waters – no other sorbents can operate reliably in this pH range. This project is unique in what it has delivered and is of general use to the public for projects relating to critical materials recovery.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Bricks and Cans for Thermal Storage

Water-filled cans and bricks provide efficient thermal storage for solar space and hot-water heating. Tests indicate thermal storage mediums suitable in both passive and active solar heating systems.

Saha, H.↗
NASA NTRS1989

Recovery of hygiene water by multifiltration

A multifiltration hygiene water reclamation process that utilizes adsorption and particulate filtration techniques is described and evaluated. The applicability of the process is tested using a simulation of a 4-man subsystem operation for 240 days. It is proposed the process has a 10 year life, weighs 236 kg, and uses 88 kg of expendable filters and adsorption beds to process 8424 kg of water. The data reveal that the multifiltration is an efficient nonphase change technique for hygiene water recovery and that the chemical and microbiological purity of the product water is within the standards specified for the Space Station hygiene water.

Putnam, David F.↗
DOE OSTI2023

Liquid Phase Exfoliation of Chemically Prelithiated Bilayered Vanadium Oxide in Aqueous Media for Li-Ion Batteries

Bilayered vanadium oxides are attractive for energy storage due to their high initial specific capacities, which could be stabilized by integrating the bilayers with conductive nanoflakes often produced in a form of aqueous dispersions. Therefore, exfoliation of the bilayered vanadium oxides in water with high yield is desirable. Here, this work introduces the first aqueous exfoliation of chemically prelithiated bilayered vanadium oxide (i.e., δ-Li x V 2 O 5 ·nH 2 O or LVO) followed by vacuum filtration to produce a free-standing film, exhibiting a lamellar stacking of the bilayered vanadium oxide nanoflakes as evidenced by scanning electron microscopy. Due to the hydrated nature of bilayered vanadium oxides, the relationship between interlayer water content and the vacuum drying temperature (105 °C vs 200 °C) was studied using X-ray diffraction, thermogravimetric analysis, and Raman spectroscopy. It was found that vacuum drying the LVO nanoflakes at 200 °C enabled more efficient removal of crystallographic water than drying at 105 °C, and did not induce a phase transformation. Scanning transmission electron microscopy confirmed the layered structure of the samples, which was more well-ordered in the 200 °C case and had no clear boundaries between flakes at the atomic scale. Furthermore, electrochemical testing in nonaqueous Li-ion cells revealed that vacuum drying at 200 °C led to improvements in ion storage capacity and electrochemical stability. Improvements in electrochemical charge storage properties of the electrodes obtained via LVO exfoliation and free-standing film assembly in water dried at 200 °C reveal that conventional battery electrode drying protocols need to be revised as new electrochemically active materials are synthesized, such as hydrated layered oxides with expanded interlayer regions. The remaining capacity fading can be attributed to the structural LVO degradation, dissolution of vanadium oxide in electrolyte, and parasitic effects of the remaining interlayer water molecules. Our results establish an environmentally friendly and safe approach to obtain two-dimensional (2D) bilayered vanadium oxide nanoflakes and create a pathway to constructing novel 2D heterostructures for improved performance in energy storage applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

A GPU-based 2D shallow water quality model

In this paper, a 2D shallow water flow solver integrated with a water quality model is presented. The interaction between the main water quality constituents included is based on the Water Quality Analysis Simulation Program. Efficiency is achieved by computing with a combination of a Central Processing Unit (CPU) and a Graphics Processing Unit (GPU) device. This technique is intended to provide robust and accurate simulations with high computation speedups with respect to a single-core CPU in real events. The proposed numerical model is evaluated in cases that include the transport and reaction of water quality components over irregular bed topography and dry–wet fronts, verifying that the numerical solution in these situations conserves the required properties (C-property and positivity). The model can operate in any steady or unsteady form allowing an efficient assessment of the environmental impact of water flows. The field data from an unsteady river reach test case are used to show that the model is capable of predicting the measured temporal distribution of dissolved oxygen and water temperature, proving the robustness and computational efficiency of the model, even in the presence of noisy signals such as wind speed.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1983

Theoretical performance of a vortex generator type of cloud droplet sampler

One of the goals of the NASA global tropospheric research program is understanding the chemical processes which influence the chemistry of the natural troposphere. An important element of this program is the study of the role of heterogenous chemistry in global tropospheric chemical cycles. Any study of the part which clouds play in the chemistry of tropospheric trace constituents requires a determination of cloud water chemical composition. There exists, therefore, a need for highly efficient collector devices which can obtain unbiased samples of cloud water in sufficient quantities aboard an aircraft platform. A promising concept which could meet the dual requirements of accurate sampling and efficient collection of cloud water droplets in the vortex generator. This concept involves an inertial separator which uses the centrifugal force of a rotating airstream. The separator is built into a commercial device which has been used for many years as a dust separator for air breathing engines. Attention is given to the optimization of the sampler design.

Miller, I. M.↗
DOE OSTI2020

Domestic Hot Water Temperature Maintenance Technology Review

Domestic hot water temperature maintenance (HWTM) is an important topic in facility management, and there are often opportunities to optimize systems to achieve energy, water, and maintenance savings. The main purpose of an HWTM system is to provide reliable hot water temperature at all fixtures with minimal wait time. This is done by replacing the standby heat losses from hot water sitting idle in pipes during periods of low demand. Traditionally, most commercial buildings do this by having water recirculate back to the water heater to be reheated. Other currently available HWTM systems are also discussed in this resource. HWTM systems can help maintain water at appropriate temperatures, minimize heat loss, and minimize delivery times to fixtures to improve the function of a building. This webpage includes a summary of HWTM options along with important considerations regarding occupant safety and comfort, and maintenance strategies for optimal and efficient operations. Domestic hot water (DHW) generation systems are referred to but are not the focus of this resource.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

ERLs and Sustainability

In any new accelerator proposal, sustainability issues will be heavily scrutinized, be that in electricity and water use, the overall efficiency of the facility, including reusing the heat for other purposes (space heating, biogas production, etc.) or energy recycling. These aspects are important for all new facilities, but ERLs bring a new dimension. Directly returning the energy of an unused beam into RF that can be used for acceleration with practically no losses is a unique feature of ERLs. While not all of the energy can be recovered, the overall efficiency of the process is extremely high. This advantage starts with a reduction in the RF power needed for acceleration, which translates into smaller RF sources and their associated power transformers (reducing the resources needed for their production), and less electric power and water cooling required (reduced operating costs as well as a reduced carbon footprint). Given the inherent advantages of ERLs, it is to be expected that their sustainability profile will eclipse other colliders with similar physics potential.

Hutton, Andrew↗
NASA NTRS2011

Wet active chevron nozzle for controllable jet noise reduction

Disposed at or toward the trailing edge of one or more nozzles associated with a jet engine are injection ports which can selectively be made to discharge a water stream into a nozzle flow stream for the purpose of increasing turbulence in somewhat of a similar fashion as mechanically disposed chevrons have done in the known art. Unlike mechanically disposed chevrons of the known art, the fluid flow may be secured thereby increasing the engine efficiency. Various flow patterns, water pressures, orifice designs or other factors can be made operative to provide desired performance characteristics.

Thomas, Russell H.↗
NASA NTRS1982

Theory and tests of two-phase turbines

A theoretical model for two-phase turbines was developed. Apparatus was constructed for testing one- and two-stage turbines (using speed decrease from stage to stage). Turbines were tested with water and nitrogen mixtures and refrigerant 22. Nozzle efficiencies were 0.78 (measured) and 0.72 (theoretical) for water and nitrogen mixtures at a water/nitrogen mixture ratio of 68, by mass; and 0.89 (measured) and 0.84 (theoretical) for refrigerant 22 expanding from 0.02 quality to 0.28 quality. Blade efficiencies (shaft power before windage and bearing loss divided by nozzle jet power) were 0.63 (measured) and 0.71 (theoretical) for water and nitrogen mixtures and 0.62 (measured) and 0.63 (theoretical) for refrigerant 22 with a single stage turbine, and 0,70 (measured) and 0.85 (theoretical) for water and nitrogen mixtures with a two-stage turbine.

Elliott, D. G.↗
DOE OSTI2024

Optically thin light-absorbers for increasing photochemical energy-conversion efficiencies

Photochemical energy conversion is more efficient when a single light-absorbing unit is split into multiple light-absorbing units (N) that are each 1/N as thick as the single light-absorbing unit and thus use the same amount of material as the single light-absorbing unit. For electrocatalytic parameters relevant to water electrolysis, the maximum efficiency for solar-to-fuel conversion from a 1.75 eV bandgap material increases from approximately 1% for a single light-absorbing unit to greater than 20% for 128 identical stacked light-absorbing units. Alterations in utilization of photons results in a better match of the light-absorber power output to the load of the chemical transformation and in the case of high-quality light-absorbers there is an added benefit from radiative coupling between the light-absorbing units via photon recycling.

Ardo, Shane↗
NASA NTRS2016

Design, Development, and Testing of a Water Vapor Exchanger for Spacecraft Life Support Systems

Thermal and environmental control systems for future exploration spacecraft must meet challenging requirements for efficient operation and conservation of resources. Maximizing the use of regenerative systems and conserving water are critical considerations. This paper describes the design, development, and testing of an innovative water vapor exchanger (WVX) that can minimize the amount of water absorbed in, and vented from, regenerative CO2 removal systems. Key design requirements for the WVX are high air flow capacity (suitable for a crew of six), very high water recovery, and very low pressure losses. We developed fabrication and assembly methods that enable high-efficiency mass transfer in a uniform and stable array of Nafion tubes. We also developed analysis and design methods to compute mass transfer and pressure losses. We built and tested subscale units sized for flow rates of 2 and 5 cu ft/min (3.4–8.5 cu m/hr). Durability testing demonstrated that a stable core geometry was sustained over many humid/dry cycles. Pressure losses were very low (less than 0.5 in. H2O (125 Pa) total) and met requirements at prototypical flow rates. We measured water recovery efficiency across a range of flow rates and humidity levels that simulate the range of possible cabin conditions. We measured water recovery efficiencies in the range of 80 to 90%, with the best efficiency at lower flow rates and higher cabin humidity levels. We compared performance of the WVX with similar units built using an unstructured Nafion tube bundle. The WVX achieves higher water recovery efficiency with nearly an order of magnitude lower pressure drop than unstructured tube bundles. These results show that the WVX provides uniform flow through flow channels for both the humid and dry streams and can meet requirements for service on future exploration spacecraft. The WVX technology will be best suited for long-duration exploration vehicles that require regenerative CO2 removal systems while needing to conserve water.

Izenson, Michael G.↗
NASA NTRS2009

Continuous-Flow System Produces Medical-Grade Water

A continuous-flow system utilizes microwave heating to sterilize water and to thermally inactivate endotoxins produced in the sterilization process. The system is designed for use in converting potable water to medical-grade water. Systems like this one could be used for efficient, small-scale production of medical- grade water in laboratories, clinics, and hospitals. This system could be adapted to use in selective sterilization of connections in ultra-pure-water-producing equipment and other equipment into which intrusion by microorganisms cannot be tolerated. Lightweight, port - able systems based on the design of this system could be rapidly deployed to remote locations (e.g., military field hospitals) or in response to emergencies in which the normal infrastructure for providing medical-grade water is disrupted. Larger systems based on the design of this system could be useful for industrial production of medical-grade water. The basic microwave-heating principle of this system is the same as that of a microwave oven: An item to be heated, made of a lossy dielectric material (in this case, flowing water) is irradiated with microwaves in a multimode microwave cavity. The heating is rapid and efficient because it results from absorption of microwave power throughout the volume of the lossy dielectric material. In this system, a copper tube having a length of 49.5 cm and a diameter of 2.25 cm serves as both the microwave cavity and the sterilization chamber. Microwave power is fed via a coaxial cable to an antenna mounted inside the tube at mid-length (see figure). Efficient power transfer occurs due to the shift in wavelength associated with the high permittivity of water combined with the strong coupling of 2.45-GHz microwaves with rotational-vibrational transitions of the dipolar water molecule.

Akse, James R.↗