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At least 595 records · Page 33

Thermodynamics. II - The extended thermodynamic system

The algebraic theory of thermodynamics developed in a previous paper is extended to include the algebraic structure that arises from the introduction of a physical body into the theory. The extension is based on very general definitions of both the thermodynamic states of a body and subsystems of that body. The algebraic analysis, which includes bodies in nonuniform states, shows that the set of all thermodynamic states of a body has the same algebraic structure as the set of thermodynamic states and that composite systems are induced by the algebraic structure of thermodynamic states. The analysis also justifies a variational treatment of thermodynamic bodies in uniform as well as nonuniform states. The variational calculation includes all conventional methods of calculation as special cases and helps to illuminate the origin and interpretation of the electrochemical potential.

Zeleznik, F. J.↗

Technology alternatives for the SPS

Emerging technologies may offer advantages over those selected for the reference design adopted for the SPS. While it is not possible to list all the technological innovations that may affect the SPS, it is feasible to develop a systematic methodology for assessing technical alternatives. This may be of value in evaluating proposed technologies and identifying high priority areas for research. Such a methodology includes involves (1) variation of guidelines; (2) analysis of system functions; (3) analysis of system sensitivity; (4) analysis of technology status and risk; and (5) external costs, problem areas, and criticisms of the SPS concept. The methodology is a first step towards the creation of a formal decision analytic framework which can support design choices and program decisions as development proceeds.

Glaser, P.↗

Identification of deuterium ions in the ionosphere of Venus

The dominant mass two ion in the ionosphere of Venus is identified as D(+) through analysis of the height variation of (mass two ion)/(H(+)) measured in the chemical equilibrium region by the ion mass spectrometer on the Pioneer Venus Orbiter. This result leads to (D)/(H) = (2.2 + or - 0.6) x 10 to the -2 at the turbopause, which agrees with the ratio measured in the lower atmosphere by the large probe mass spectrometer. The 100-fold deuterium enrichment supports previous suggestions that Venus has lost at least 0.3 percent of a terrestrial ocean.

Hartle, R. E.↗

Characteristics of Basaltic Lava Flows on Venus

Some ideas relating to the formation of lava flows on Venus are reviewed. The surface morphological features seen in the panoramic images made by the Venera 13 and 14 landers are examined in detail. The major element compositions measured by the Soviet probes indicate that the surface rocks at the Venera 13 site resemble a terrestrial tholeite composite whereas the Venera 14 rocks are similar to terrestrial alkali basalts. Few data exist on the rheological properties of such magma types on Earth; these properties are a strong function of magma volatile content, and there are important gaps in our knowledge of the typical volatiles to be associated with the magmas on Venus. However, the suggestion that Venusian magmas may be water poor together with consideration of the fact that the high Venusian surface temperatures may cause magmas to experience up to 50 K less cooling during their rise to the surface than corresponding terrestrial counterparts, leads to the finding that Venusian magmas may typically have plastic viscosities, E, up to a factor of three greater than terrestrial counterparts on eruption. A similar analysis of yield strength variations with temperature, magma composition and volatile content suggests that temperature will exert the main control and that Venusian magma yield strengths, Y, may be a factor of several times smaller than those of terrestrial equivalents.

Wilson, L.↗

Unstalled flutter stability predictions and comparisons to test data for a composite prop-fan model

The aeroelastic stability analyses for three graphite/epoxy composite Prop-Fan designs and post-test stability analysis for one of the designs, the SR-3C-X2 are presented. It was shown that Prop-Fan stability can be effectively analyzed using the F203 modal aeroelastic stability analysis developed at Hamilton Standard and that first mode torsion-bending coupling has a direct effect on blade stability. Positive first mode torsion-bending coupling is a destabilizing factor and the minimization of this parameter will increase Prop-Fan stability. It was also shown that Prop-Fan stability analysis using F203 is sensitive to the blade modal data used as input. Calculated blade modal properties varied significantly with the structural analysis used, and these variations are reflected in the F203 calculations.

Turnberg, J. E.↗

Design sensitivity analysis and optimization of built-up structures

Developments during the course of the research in design sensitivity analysis and optimization of built-up structures, with both sizing and shape design variables, show clearly that a unified variational approach to design sensitivity analysis can yield derivatives of structural response with respect to design. Rigorous and practically computable results for structural components and built-up structures have been demonstrated and used to solve design optimization problems.

Choi, Kyung K.↗

Three-dimensional analysis of potential vorticity associated with tropopause folds and observed variations of ozone and carbon monoxide

The usability and reliability of potential vorticity as a meteorological stratospheric tracer are evaluated. The concept of potential vorticity conservation during transport in which stratospheric and tropospheric air are mixing is tested. Aircraft data collected on April 20, 1984 in the western and southwestern U.S. are analyzed in order to derive potential vorticity data; vertical cross sections of constant-pressure data and temperature and wind speed gradients are examined. The tropopause fold observed during the April 20, 1984 aircraft flights is described. The potential vorticity, ozone mixing ratio, and carbon monoxide mixing ratio are compared; a positive correlation between potential vorticity and the ozone mixing ratio and a negative correlation between the potential vorticity and the carbon monoxide mixing ratio are detected. The data support the concepts of the conservation of potential vorticity, the entrainment and mixing of tropospheric air across the boundaries of the fold, and the applicability of potential vorticity as a stratospheric tracer.

Danielsen, Edwin F.↗

Characterization of fault recovery through fault injection on FTMP

The development of fault-injection procedures and statistical analysis techniques to characterize the fault recovery of fault-tolerant systems is described. Pin-level fault-injection was conducted on a fault-tolerant microprocessor computer in order to generate data to assess the utility of current fault-injection sampling methods. The validity of common reliability-modeling assumptions concerning the statistical distribution of recovery times is investigated. A multiple comparison analysis for detecting behavior variations, and a distribution fitting for determining the best fit for the data were conducted. It is observed that the detection behavior is not homogeneous across all data sets, and that none of the factors under experimental control can account for the observed groupings of behavior. It is determined that no single distribution fits all the data sets, and that stratified random sampling and statistically robust parameter-estimation techniques are required to characterize fault detection time.

Finelli, George B.↗

Wintertime disturbances in the tropical Pacific - FGGE IIIb and satellite comparisons

The synoptic development of moisture fields associated with moisture bursts near the ITCZ is described. Dropsonde and satellite (Tiros and GOES) data for the moisture structure along the winter ITCZ North Pacific are presented and examined. These observations were compared with ECMWF analysis along the ITCZ; consideration is given to relative humidity and burst dynamics. It is observed that the ECMWF analysis reproduces the synoptic variations reasonably well.

Mcguirk, J. P.↗

The observed day-to-day variability of Mars water vapor

The diurnal variability of atmospheric water vapor as derived from the Viking MAWD data is discussed. The detection of day to day variability of atmospheric water would be a significant finding since it would place constraints on the nature of surface reservoirs. Unfortunately, the diurnal variability seen by the MAWD experiment is well correlated with the occurrence of dust and/or ice hazes, making it difficult to separate real variations from observational effects. Analysis of the day to day variability of water vapor in the Martian atmosphere suggests that the observations are, at certain locations and seasons, significantly affected by the presence of water-ice hazes. Because such effects are generally limited to specific locations, such as Tharsis, Lunae Planum, and the polar cap edge during the spring, the seasonal and latitudinal trends in water vapor that have been previously reported are not significantly affected.

Jakosky, Bruce M.↗

Laboratory studies of photodissociation processes relevant to the formation of cometary radicals

The strength of the C2(d 3 Pi g yields a 3 Pi u) Swan band emission in the spectra of cometary comae identifies this species as a prominent constituent of the coma gas. It was previously suggested that the formation of cometary C2 proceeds via the secondary photolysis of the C2H radical. The detection of C2H in the interstellar medium and the recent analysis of the radial variation in C2(delta V=O) surface brightness of Comet Halley support the postulate that C2 is a third-generation molecule. Measurement of the C2 and C2H translational energy distributions produced from the multiphoton dissociation (MPD) of acetylene at 193 nm are identified . Time-resolved FTIR emission studies of the nascent C2H radical formed in the C2H2 yields C2H + H reaction verify that this species is produced both vibrationally and electronically excited. A survey of the internal energy distributions of the C2 fragments produced from the MPD of acetylene using a high intensity ArF laser is currently in progress in the laboratory. Recent experiments have focused on the measurement of rotational energy distribution for the C2(A 1 Pi u, a 3 Pi u) fragments. The C2(a 3 Pi u) detection capability is currently being improved by performing this experiment in a molecular beam, thus allowing for discrimination between initial emission and laser-induced fluorescence (LIF). Although the experiments performed to date provide considerable evidence in support of C2H yields C2 + H reaction, there is an important distinction to be made when comparing the laboratory conditions to those typically found in comets. The C2H radicals generated in the laboratory experiments are formed vibrationally and/or electronically excited. Any rotationally/vibrationally excited C2H present in cometary comae will quickly undergo radiative relaxation in the infrared to their lowest rotational and vibrational state. Experiments are currently under way to confirm the cometary formation of C2 via the VUV dissociation of cold C2H.

Urdahl, R. S.↗

Derivatives of buckling loads and vibration frequencies with respect to stiffness and initial strain parameters

A uniform variational approach to sensitivity analysis of vibration frequencies and bifurcation loads of nonlinear structures is developed. Two methods of calculating the sensitivities of bifurcation buckling loads and vibration frequencies of nonlinear structures, with respect to stiffness and initial strain parameters, are presented. A direct method requires calculation of derivatives of the prebuckling state with respect to these parameters. An adjoint method bypasses the need for these derivatives by using instead the strain field associated with the second-order postbuckling state. An operator notation is used and the derivation is based on the principle of virtual work. The derivative computations are easily implemented in structural analysis programs. This is demonstrated by examples using a general purpose, finite element program and a shell-of-revolution program.

Haftka, Raphael T.↗

Evidence for a supermassive black hole in the nucleus of the Seyfert galaxy NGC 5548

The international campaign to monitor the variable Seyfert 1 galaxy NGC 5548 with the IUE has provided an extensive and well-sampled set of spectroscopic observations. These observations are used to study the response of the C IV 1550 A emission-line profile to changes in the photoionizing continuum. Near the end of the IUE campaign, the continuum flux at 1440 A and the total C IV flux dopped by factors of 2.9 and 1.8, respectively, in 16 days. The red wing of the C IV profile responded more rapidly to the sharp continuum drop than the blue wing, indicating that clouds in the inner broad-line region (BLR) are undergoing gravitational infall. These results provide direct evidence that the central engine is a supermassive object, presumably a black hole, with a mass on the order of 10 to the 7th solar masses. Analysis of the profile variations also demonstrates that excess emission in the blue wing of C IV is from a component that is physically distinct from the bulk of the BLR.

Crenshaw, D. Michael↗

Optical variability and pigment biomass in the Sargasso Sea as determined using deep-sea optical mooring data

A 9-month time series of optical data, composed of three separate deployments, from the Biowatt 1987 deep-sea mooring located in the oligotrophic waters of the Sargasso Sea at 32 deg N, 70 deg W, is presented. These data were analyzed using several biooptical models for the purpose of providing a continuous estimate of the spectral diffuse attenuation coefficient and pigment biomass. Results of the first 70-day deployment demonstrate the utility of optical observations as proxy measures of biological parameters, and facilitate a preliminary analysis of the temporal variations and a comparison of the present biooptical observations with concurrent physical observations. Biooptical properties exhibit variation in response to physical forcings, such as diel variations of incident solar irradiance, episodic wind forcing, advective mesoscale eddy layer depth, and succession of phytoplankton. The mooring data are discussed in the context of contemporaneous shipboard observations as well as in terms of future ocean satellite observations.

Smith, R. C.↗

Thermal emission spectroscopy of the middle atmosphere

The general objective of this research is to obtain, via remote sensing, simultaneous measurements of the vertical distributions of stratospheric temperature, ozone, and trace constituents that participate in the catalytic destruction of ozone (NO(sub y): NO, NO2, NO3, HNO3, ClONO2, N2O5, HNO4; Cl(sub x): HOCl), and the source gases for the catalytic cycles (H2O, CH4, N2O, CF2Cl2, CFCl3, CCl4, CH3Cl, CHF2Cl, etc.). Data are collected during a complete diurnal cycle in order to test our present understanding of ozone chemistry and its associate catalytic cycles. The instrumentation employed is an emission-mode, balloon-borne, liquid-nitrogen-cooled Michelson interferometer-spectrometer (SIRIS), covering the mid-infrared range with a spectral resolution of 0.020 cm(exp -1). Cryogenic cooling combined with the use of extrinsic silicon photoconductor detectors allows the detection of weak emission features of stratospheric gaseous species. Vertical distributions of these species are inferred from scans of the thermal emission of the limb in a sequence of elevation angles. The fourth SIRIS balloon flight was carried out from Palestine, Texas on September 15-16, 1986 with 9 hours of nighttime data (40 km). High quality data with spectral resolution 0.022 cm(exp -1), were obtained for numerous limb sequences. Fifteen stratospheric species have been identified to date from this flight: five species from the NO(sub y) family (HNO3, NO2, NO, ClONO2, N2O5), plus CO2, O3, H2O, N2O, CH4, CCl3F, CCl2F2, CHF2Cl, CF4, and CCl4. The nighttime values of N2O5, ClONO2, and total odd nitrogen have been measured for the first time, and compared to model results. Analysis of the diurnal variation of N2O5 within the 1984 and 1986 data sets, and of the 1984 ClONO2 measurements, were presented in the literature. The demonstrated ability of SIRIS to measure all the major NO(sub y) species, and therefore to determine the partitioning of the nitrogen family over a continuous diurnal cycle, is a powerful tool in the verification and improvement of photochemical modeling.

Kunde, V. G.↗

The validation of a human force model to predict dynamic forces resulting from multi-joint motions

The development and validation is examined of a dynamic strength model for humans. This model is based on empirical data. The shoulder, elbow, and wrist joints were characterized in terms of maximum isolated torque, or position and velocity, in all rotational planes. This data was reduced by a least squares regression technique into a table of single variable second degree polynomial equations determining torque as a function of position and velocity. The isolated joint torque equations were then used to compute forces resulting from a composite motion, in this case, a ratchet wrench push and pull operation. A comparison of the predicted results of the model with the actual measured values for the composite motion indicates that forces derived from a composite motion of joints (ratcheting) can be predicted from isolated joint measures. Calculated T values comparing model versus measured values for 14 subjects were well within the statistically acceptable limits and regression analysis revealed coefficient of variation between actual and measured to be within 0.72 and 0.80.

Pandya, Abhilash K.↗

Deformation in the Santa Barbara Channel from GPS measurements 1987-1991

An analysis of GPS data over the period 1987-91 confirms geologic and seismic evidence that the Santa Barbara Channel is a complicated actively deforming region. The data indicate north-south compression in the eastern channel, with little deformation in the west. Rotation may also be an important deformation mechanism. An analysis of strain rate variation over periods of 4.5, 17, and 100 yr suggests that deformation is nonuniform.

Larson, Kristine M.↗

Validation of cloud forcing simulated by the National Center for Atmospheric Research Community Climate Model using observations from the Earth Radiation Budget Experiment

Satellite measurements of the effect of clouds on the top of atmosphere radiative energy budget are used to validate model simulations from the National Center for Atmospheric Research Community Climate Model (NCAR CCM). The ability of the NCAR CCM to reproduce the monthly mean global distribution and temporal variability on both daily and seasonal time scales is assessed. The comparison reveals several deficiencies in the CCM cloud representation. Most notable are the difficulties in properly simulating the effect of clouds on the planetary albedo. This problem arises from discrepancies in the model's portrayal of low-level cloudiness and leads to significant errors in the absorbed solar radiation simulated by the model. The CCM performs much better in simulating the effect of clouds on the longwave radiation emitted to space, indicating its relative success in capturing the vertical distribution of cloudiness. The daily variability of the radiative effects of clouds in both the shortwave and longwave spectral regions is systematically overestimated. Analysis of the seasonal variations illustrates a distinct lack of coupling in the seasonal changes in the radiative effects of cloudiness between the tropics and mid-latitudes and between the Northern and Southern Hemisphere. Much of this problem also arises from difficulties in simulating low-level cloudiness, placing further emphasis on the need for better model parameterizations of boundary layer clouds.

Soden, B. J.↗