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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Multifunctional Optical Outcouplers for Efficient and Stable White OLEDs (Final Technical Report)

Replacing fluorescence by phosphorescence in OLED-based solid-state lighting can realize the Department of Energy’s efficiency target of 83% Internal Quantum Efficiency (IQE). The principal challenge, however, is to fix the poor stability of phosphorescent blue OLEDs. To address this, we have fabricated novel plasmonic architectures that improve device stability by decreasing the exciton lifetime of the emitters without drastically decreasing the light extraction efficiency. We describe the impact on stability of these structures in high efficiency blue phosphorescent OLEDs. Although the benefit is appreciable, we find that targeting ‘bright’ triplets on phosphorescent emitter molecules is an incomplete solution, and that it is also necessary to stabilize ‘dark’ triplets formed in the host and blocking layers. We demonstrate substantial improvements in stability using the latter approach, and conclude with a discussion of potential approaches to managing dark triplets in OLEDs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Dark energy with a triplet of classical U(1) fields

Here, we present a new mechanism for cosmic acceleration consisting of a scalar field coupled to a triplet of classical U(1) gauge fields. The gauge fields are arranged in a homogeneous, isotropic configuration, with both electric- and magneticlike vacuum expectation values. The gauge fields provide a masslike term via a Chern-Simons interaction that suspends the scalar away from its potential minimum, thereby enabling potential-dominated evolution. We show this mechanism can drive a brief period of acceleration, such as dark energy, without the need for fine-tunings. We obtain simple analytic results for the dark energy equation of state and dependence on model parameters. In this model, the presence of the gauge field generically leads to a suppression of long-wavelength gravitational waves, with implications for the experimental search for cosmic microwave background B modes and direct detection of a stochastic gravitational wave background.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1974

Solar prominences in the extreme ultraviolet as observed from the Apollo Telescope Mount

Observations of quiescent solar prominences with the Harvard College Observatory spectrometer aboard Skylab show that prominence material is optically thick in the Lyman alpha line and the Lyman continuum. The color temperature of the Lyman continuum has a mean of 6600 K and an upward gradient toward the top of the prominence. The departure coefficient of the ground state of hydrogen is found to be of the order of unity, as expected from theory. The optical depth of the C III sheath region is determined directly from the observation of the limb through the prominence and is used to infer the mean electron density and the temperature gradient of the sheath. The result implies that the sheath density is about 0.4, and the temperature gradient about 1.4 times the respective value in the C III transition zone of the quiet sun. The C III triplet-singlet ratio for the prominence is found to give a density compatible, within the uncertainty of the atomic parameters, with the density obtained from the optical depth.

Schmahl, E. J.↗
DOE OSTI2021

Ground-state phase diagram of the t-t ′ -J model

Significance Theoretical efforts to understand the superconducting cuprates have focused on a few simplified but challenging models: notably the Hubbard and the t - t ′ - J models. Using density matrix renormalization group (DMRG) simulations on width-8 cylinders, we study the ground-state phase diagram of the t - t ′- J model. The next nearest-neighbor hopping t ′ allows one to distinguish between hole ( t ′ < 0 ) and electron doping ( t ′ > 0 ). We find for the magnetic, charge, and single-particle properties that this model roughly captures the differences between the electron- and hole-doped cuprates. However, the superconducting properties differ. For hole doping ( t ′ < 0 ), there is an absence of superconductivity, while for electron doping ( t ′ > 0), we find d -wave superconductivity coexisting with antiferromagnetism and a secondary triplet p -wave pairing component.

Jiang, Shengtao↗
DOE OSTI2021

Search for doubly and singly charged Higgs bosons decaying into vector bosons in multi-lepton final states with the ATLAS detector using proton-proton collisions at $\sqrt{s}$ = 13 TeV

A search for charged Higgs bosons decaying into W ± W ± or W ± Z bosons is performed, involving experimental signatures with two leptons of the same charge, or three or four leptons with a variety of charge combinations, missing transverse momentum and jets. A data sample of proton-proton collisions at a centre-of-mass energy of 13 TeV recorded with the ATLAS detector at the Large Hadron Collider between 2015 and 2018 is used. The data correspond to a total integrated luminosity of 139 fb -1 . The search is guided by a type-II seesaw model that extends the scalar sector of the Standard Model with a scalar triplet, leading to a phenomenology that includes doubly and singly charged Higgs bosons. Two scenarios are explored, corresponding to the pair production of doubly charged H ±± bosons, or the associated production of a doubly charged H ±± boson and a singly charged H ± boson. No significant deviations from the Standard Model predictions are observed. H ±± bosons are excluded at 95% confidence level up to 350 GeV and 230 GeV for the pair and associated production modes, respectively.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Tuning the Functionalities of Porous Liquids for Emergent Gas-Capture Properties

Type 3 Porous Liquids (PLs) are a class of materials with the potential to revolutionize gas capture, storage, and utilization. These PLs are formed by suspending sorbent nanoparticles (e.g., metal−organic frameworks) in sterically excluded solvents, creating permanent porosity for gas capture in a processable, low-viscosity phase. Herein, a computational study revealed sorbent surface functionalization strategies to enhance CO 2 sorption, and the molecular structural signatures underpinning the enhancements in gas uptake. PLs composed of a ZIF-8 surface functionalized with 3-amino-1,2,4-triazole (Atz) in glyceryl triacetate were targeted for emergent CO 2 capture, exceeding that of the unfunctionalized ZIF-8 PL. ZIF-8 was surface functionalized with Atz at various surface coverage fractions (f), and classical molecular dynamics simulations predicted an increase in CO 2 sorption capacity with increasing f, up to f = 0.75. Additionally, detailed structural analyses revealed that solvent orientational order, derived from the solvent triplet-angle distribution, can identify the gas-capture potential of a PL without requiring computationally expensive direct modeling of the CO 2 sorption. Combined with experimental validation, initial computational screening of PL compositions promises to accelerate the discovery of PL compositions for novel gas separation materials platforms.

gas capture↗
DOE OSTI2023

Rashba spin-orbit coupling enhanced magnetoresistance in junctions with one ferromagnet

We explain how Rashba spin-orbit coupling (SOC) in a two-dimensional electron gas (2DEG), or in a conventional s-wave superconductor, can lead to a large magnetoresistance even with one ferromagnet. However, such enhanced magnetoresistance is not generic and can be nonmonotonic and change its sign with Rashba SOC. For an in-plane rotation of magnetization, it is typically negligibly small for a 2DEG and depends on the perfect transmission which emerges from a spin-parity-time symmetry of the scattering states, while this symmetry is generally absent from the Hamiltonian of the system. The key difference from considering the normal-state magnetoresistance is the presence of the spin-dependent Andreev reflection at superconducting interfaces. In the fabricated junctions of quasi-2D van der Waals ferromagnets with conventional s-wave superconductors (Fe 0.29 ⁢TaS 2 /NbN) we find another example of enhanced magnetoresistance where the presence of Rashba SOC reduces the effective interfacial strength and is responsible for an equal-spin Andreev reflection. The observed nonmonotonic trend in the out-of-plane magnetoresistance with the interfacial barrier is an evidence for the proximity-induced equal-spin-triplet superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Proton and neutron contributions to the quadrupole transition strengths in 39 Ca and 39 K studied by lifetime measurements of mirror transitions

The E2 transition matrix elements of isobaric multiplets are expected to follow a linear trend as a function of isospin projection. However, measurements of the 2 + → 0 + transitions in the A = 38 triplet of Ca, K, and Ar show a deviation from this trend with an enhanced transition strength in 38 Ca with respect to its mirror 38 Ar. We have studied analogue 11/2 – → 7/2 – E2 transitions in 39 Ca and its mirror partner 39 K to determine if this enhancement persists in neighboring Ca isotopes. Recoil-distance lifetime measurements of 39 Ca and 39 K were performed utilizing a 42 Sc secondary beam, the TRIPLEX plunger, the GRETINA array, and the S800 spectrograph. Our data provide a lifetime measurement of the (11/2 – ) state in 39 Ca as well as an improved lifetime result for the (9/2 – ) state, while the 39 K data are used to validate the present analysis. Furthermore, a comparison of the present data to shell-model calculations suggests an enhanced transition strength in 39 Ca, pointing to both proton and neutron contributions to core excitations across the Z = N = 20 shell gaps in close proximity to 40 Ca.

39 ≤ A ≤ 58↗
DOE OSTI2022

The dynamic nature of risk in DOE facilities in the surveillance and maintenance program–with observations for risk communications

Here, we explore three case studies of facilities at two US Department of Energy (DOE) former nuclear weapons research and production sites—the Oak Ridge National Laboratory and the Hanford site—whose risk profiles have changed during their long-term management under the DOE's surveillance and maintenance (S&M) program. These case studies provide examples of the challenges faced in communicating to external stakeholders, such as federal and state regulators, local communities surrounding the site, as well as the general public, the circumstances surrounding unexpected events or the emergence/discovery of new risk-important information at historically high-risk sites. We identify common topics of importance from these case studies and suggest a taxonomy for risk communicators to use in informing the dialogues with individuals and organizations that may not be technically oriented or fully informed on the subject matter. The taxonomy is based on technical insights from the quintessential definition of risk known as the Kaplan–Garrick “risk triplet” as well as insights from regulatory guidance documents on risk communication with external stakeholders originally developed for the commercial nuclear power industry.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
NASA NTRS2006

Electron-He(+) P-wave Elastic Scattering and Photoabsorption in Two-electron Systems

In a previous paper [Bhatia, Phys. Rev. A 69,032714 (2004)], electron-hydrogen P-wave scattering phase shifts were calculated using the optical potential approach based on the Feshbach projection operator formalism. This method is now extended to the singlet and triplet electron-He(+) P-wave scattering in the elastic region. Phase shifts are calculated using Hylleraas-type correlation functions with up to 220 terms. Results are rigorous lower bounds to the exact phase shifts and they are compared to phase shifts obtained from the method of polarized orbitals and close-coupling calculations. The continuum functions calculated here are used to calculate photoabsorption cross sections. Photoionization cross sections of He and photodetachment cross sections of H(-) are calculated in the elastic region, i.e. leaving He(+) and H in their respective ground states, and compared with previous calculations. Radiative attachment rates are also calculated.

Bhatia, A. K.↗
NASA NTRSDate not supplied

Mixing and Recovery Performance of Triplet Impinging Injectors with Varying Flow Areas for Detonative Combustion

Detonation combustion devices such as rotating detonation rocket engines (RDREs) have been proposed as an alternative to traditional deflagration engines as detonative combustion has a higher theoretical thermodynamic efficiency. Improved performance of an RDRE depends heavily on the propellant injection and mixing. Impingement type injectors have been shown to achieve higher characteristic velocity or combustion efficiency for both detonative and deflagrative engines. This work is exploratory in nature and focuses on unlike triplet impinging injectors to study how the flow area of the injector affects the mixing of propellants and recovery under the transient, high-peak pressure conditions unique to RDREs. A ratio of fuel flow area to oxidizer flow area is set to achieve a given mass flow rate and thus propellant mixture ratio. Four different fluid flow areas are studies while keeping the fuel/oxidizer ratio constant. This work has found that, while maintaining a fixed ratio fuel to oxidizer flow area, the injectors with smaller orifice areas show better resistance to backflow in steady state tests and have shorter recovery times in backflow experiments. Even with the shorter recovery times, it is found that the shortest recovery time is still an order of magnitude slower than the frequency of a single detonation wave traversing a 3” RDRE.

Michaela R. Hemming↗
DOE OSTI2024

RNA language models predict mutations that improve RNA function

Structured RNA lies at the heart of many central biological processes, from gene expression to catalysis. RNA structure prediction is not yet possible due to a lack of high-quality reference data associated with organismal phenotypes that could inform RNA function. We present GARNET (Gtdb Acquired RNa with Environmental Temperatures), a new database for RNA structural and functional analysis anchored to the Genome Taxonomy Database (GTDB). GARNET links RNA sequences to experimental and predicted optimal growth temperatures of GTDB reference organisms. Using GARNET, we develop sequence- and structure-aware RNA generative models, with overlapping triplet tokenization providing optimal encoding for a GPT-like model. Leveraging hyperthermophilic RNAs in GARNET and these RNA generative models, we identify mutations in ribosomal RNA that confer increased thermostability to the Escherichia coli ribosome. The GTDB-derived data and deep learning models presented here provide a foundation for understanding the connections between RNA sequence, structure, and function.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1966

Insulated Engine, 100-Pound Thrust

The design and test results of an insulated, 100-pound thrust engine capable of delivering high performance, providing long, steady state and pulse mode endurance, and maintaining a low outside surface temperature of 4000 F, are presented. Included are descriptions of the injector designs and insulation materials investigated, plus a discussion of the thermal analysis and test results. Continuous operation in excess of 29 minutes, and start capability in excess of 4900 pulses, have been demonstrated. To allow the use of available chamber materials and coating systems under insulated conditions, the major challenge to the designer was to define an injector design that would provide gas temperatures and performance of a predetermined value. The solution was the development of an unbalanced, 8-element triplet injector having an unequal fuel distribution within each element, capable of providing a specific impulse in excess of 290 pounds at reduced wall temperatures. The design consists of a columbium chamber and nozzle utilizing a silicide coating, a columbium injector, a composite insulation system of aluminum oxide

Roth, N. R.↗
NASA NTRS1982

A mechanism for plasma waves at the harmonics of the plasma frequency foreshock boundary

A bump-on-tail unstable reduced velocity distribution, constructed from data obtained at the upstream boundary of the electron foreshock by the GSFC electron spectrometer experiment on the ISEE-1 satellite, is used as the initial plasma state for a numerical integration of the 1D-Vlasov-Maxwell system of equations. The integration is carried through the growth of the instability, beyond its saturation, and well into the stabilized plasma regime. A power spectrum computed for the electric field of the stabilized plasma is dominated by a narrow peak at the Bohm-Gross frequency of the unstable field mode but also contains significant power at the harmonics of the Bohm-Gross frequency. The harmonic power is in sharp peaks which are split into closely spaced doublets. The fundamental peak at the Bohm-Gross frequency is split into a closely spaced triplet. The mechanism for excitation of the second harmonic is shown to be second order wave-wave coupling.

Klimas, A. J.↗
NASA NTRS1983

A mechanism for plasma waves at the harmonics of the plasma frequency in the electron foreshock boundary

A bump-on-tail unstable reduced velocity distribution, constructed from data obtained at the upstream boundary of the electron foreshock by the GSFC electron spectrometer experiment on the ISEE-1 satellite, is used as the initial plasma state for a numerical integration of the 1D-Vlasov-Maxwell system of equations. The integration is carried through the growth of the instability, beyond its saturation, and well into the stabilized plasma regime. A power spectrum computed for the electric field of the stabilized plasma is dominated by a narrow peak at the Bohm-Gross frequency of the unstable field mode but also contains significant power at the harmonics of the Bohm-Gross frequency. The harmonic power is in sharp peaks which are split into closely spaced doublets. The fundamental peak at the Bohm-Gross frequency is split into a closely spaced triplet. The mechanism for excitation of the second harmonic is shown to be second order wave-wave coupling. Previously announced in STAR as N83-17315

Klimas, A. J.↗
DOE OSTI2020

Track Seeding and Labelling with Embedded-space Graph Neural Networks

To address the unprecedented scale of HL-LHC data, the Exa.TrkX project is investigating a variety of machine learning approaches to particle track reconstruction. The most promising of these solutions, graph neural networks (GNN), process the event as a graph that connects track measurements (detector hits corresponding to nodes) with candidate line segments between the hits (corresponding to edges). Detector information can be associated with nodes and edges, enabling a GNN to propagate the embedded parameters around the graph and predict node-, edge- and graph-level observables. Previously, message-passing GNNs have shown success in predicting doublet likelihood, and we here report updates on the state-of-the-art architectures for this task. In addition, the Exa.TrkX project has investigated innovations in both graph construction, and embedded representations, in an effort to achieve fully learned end-to-end track finding. Hence, we present a suite of extensions to the original model, with encouraging results for hitgraph classification. In addition, we explore increased performance by constructing graphs from learned representations which contain non-linear metric structure, allowing for efficient clustering and neighborhood queries of data points. We demonstrate how this framework fits in with both traditional clustering pipelines, and GNN approaches. The embedded graphs feed into high-accuracy doublet and triplet classifiers, or can be used as an end-to-end track classifier by clustering in an embedded space. A set of post-processing methods improve performance with knowledge of the detector physics. Finally, we present numerical results on the TrackML particle tracking challenge dataset, where our framework shows favorable results in both seeding and track finding.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

A search for new resonances in multiple final states with a high transverse momentum Z boson in $\sqrt{s} $ = 13 TeV pp collisions with the ATLAS detector

A generic search for resonances is performed with events containing a Z boson with transverse momentum greater than 100 GeV, decaying into e + e – or μ + μ – . The analysed data collected with the ATLAS detector in proton-proton collisions at a centre-of-mass energy of 13 TeV at the Large Hadron Collider correspond to an integrated luminosity of 139 fb –1 . Two invariant mass distributions are examined for a localised excess relative to the expected Standard Model background in six independent event categories (and their inclusive sum) to increase the sensitivity. No significant excess is observed. Exclusion limits at 95% confidence level are derived for two cases: a model-independent interpretation of Gaussian-shaped resonances with the mass width between 3% and 10% of the resonance mass, and a specific heavy vector triplet model with the decay mode W' → ZW → ℓℓqq.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗