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At least 595 records · Page 33

Analysis of anion exchange membrane water electrolyzer performance and its evolution over time

Understanding water, evolved gas, and ionic transport in membrane-electrode-assemblies (MEAs) is essential for the development of high performance and durable anion exchange membrane water electrolyzers (AEMWEs). This study evaluates the MEA conditioning process, operating conditions, and short-term stability in a 1 M potassium hydroxide (KOH) electrolyte, focusing on the underlying transport phenomena. We observe a significant initial voltage loss in continuous cell operation, which could be associated with gas bubble accumulation, transport layer or flow field passivation, and changes in the catalyst oxidation state. Further, we investigate the effects of materials and operational configurations, including the membrane type and thickness, and the electrolyte flow rate, including KOH being fed to both electrodes as well as to the anode only. Furthermore, the effect of membrane drying temperature on ex situ as well as in situ electrochemical performance is evaluated. Finally, we discuss 700 h of AEMWE operation at 1 A/cm 2 , highlighting the underlying degradation phenomena.

25 ENERGY STORAGE↗

Low-speed wind-tunnel tests of a large scale blended arrow advanced supersonic transport model having variable cycle engines and vectoring exhaust nozzles

A low-speed wind-tunnel investigation was conducted in a full-scale tunnel to determine the performance and static stability and control characteristics of a large-scale model of a blended-arrow advanced supersonic transport configuration incorporating variable-cycle engines and vectoring exhaust nozzles. Configuration variables tested included: (1) engine mode (cruise or low-speed), (2) engine exit nozzle deflection, (3) leading-edge flap geometry, and (4) trailing-edge flap deflection. Test variables included values of C sub micron from 0 to 0.38, values of angle of attack from -10 degrees to 30 degrees, values of angle of sideslip, from -5 degrees to 5 degrees, and values of Reynolds number, from 3.5 million to 6.8 million.

Parlett, L. P.↗

Electronic and Structural Properties of the Polymer-Electrolyte Interphase in Electrochemically Doped Polymers

The advance of soft, polymer-based (photo)electrochemical energy transformation and storage applications requires a framework for polymer and electrolyte design that includes a deep understanding of the polymer–electrolyte interphase. Here, we report on the investigations of two napthalenediimide (NDI)–bithiophene (T2)-based semiconducting copolymers using computational modeling and in situ, ex situ, and operando techniques to reveal how changes in electrolyte and polymer chemistry modulate the electronic and structural properties of polymer electrodes during electrochemical (de)doping. These systems are shown to host an ensemble of polarons, in contrast with the single polaron-like character often reported, whose properties vary with the nature of the local environment. Importantly, these polarons serve as reporters of the nanoscale environments in which they reside. We demonstrate that controlling the polymer and electrolyte chemistry regulates the nature of the charge carriers generated upon electrochemical doping and/or exciton dissociation in a photoelectrochemical solar cell: For instance, divalent counterions enable polaron and bipolaron formation at lower reducing potentials, while supporting more bipolaron formation than monovalent counterions. A novel application of NEXAFS reveals insights into charge (de)localization, providing a pathway for future investigation of electron transport mechanisms. Finally, simulations of polymer swelling of an amorphous interphase show that charge formation has a large impact on polymer swelling and ion penetration. These studies deliver insights to enable the control of charge-carrier and ion transport, the rates of electron transfer and catalytic efficiency, device stability, and overall device performance.

14 SOLAR ENERGY↗

Selected advanced aerodynamic and active control concepts development

A task for the Energy Efficient Transport program conducted: (1) The design and wind tunnel development of high-aspect-ratio supercritical wings, investigating the cruise speed regime and also high-lift. (2) The preliminary design and evaluation of an aircraft combining a high-aspect-ratio supercritical wing with a winglet. (3) Active Controls: The determination of criteria, configuration, and flying qualities associated with augmented longitudinal stability of a level likely to be acceptable for the next generation transport; and the design of a practical augmentation system. The baseline against which the work was performed and evaluated was the Douglas DC-X-200 twin engine derivative of the DC-10 transport. The supercritical wing development showed that the cruise and buffet requirements could be achieved and that the wing could be designed to realize a sizable advantage over today's technology. Important advances in high lift performance were shown. The design study of an aircraft with supercritical wing and winglet suggested advantages in weight and fuel economy could be realized. The study of augmented stability, conducted with the aid of a motion base simulator, concluded that a negative static margin was acceptable for the baseline unaugmented aircraft.

Source record↗

Floating wind turbine system

A floating wind turbine system with a tower structure that includes at least one stability arm extending therefrom and that is anchored to the sea floor with a rotatable position retention device that facilitates deep water installations. Variable buoyancy for the wind turbine system is provided by buoyancy chambers that are integral to the tower itself as well as the stability arm. Pumps are included for adjusting the buoyancy as an aid in system transport, installation, repair and removal. The wind turbine rotor is located downwind of the tower structure to allow the wind turbine to follow the wind direction without an active yaw drive system. The support tower and stability arm structure is designed to balance tension in the tether with buoyancy, gravity and wind forces in such a way that the top of the support tower leans downwind, providing a large clearance between the support tower and the rotor blade tips. This large clearance facilitates the use of articulated rotor hubs to reduced damaging structural dynamic loads. Major components of the turbine can be assembled at the shore and transported to an offshore installation site.

Viterna, Larry A.↗

Free-flight investigation of the stability and control characteristics of a STOL model with an externally blown jet flap

The stability and control characteristics of a four-engine turbofan STOL transport model having an externally blown jet flap have been investigated by means of the flying-model technique in the Langley full-scale tunnel. The flight characteristics of the model were investigated under conditions of symmetric and asymmetric (one engine inoperative) thrust at lift coefficients up to 9.5 and 5.5, respectively. Static characteristics were studied by conventional power-on force tests over the flight-test angle-of-attack range including the stall. In addition to these tests, dynamic longitudinal and lateral stability calculations were performed for comparison with the flight-test results and for use in correlating the model results with STOL handling-qualities criteria.

Parlett, L. P.↗

Spatiotemporal structure of edge harmonic oscillation and its role in ELM-free QH-mode at KSTAR

In Quiescent H-mode (QH-mode), edge-localized modes (ELMs) are naturally replaced by a low-n edge harmonic oscillation (EHO), yet the self-regulating transport mechanism driven by the EHO remains insufficiently understood. Using high-spatiotemporal-resolution imaging diagnostics on KSTAR—electron cyclotron emission imaging and broadband electron cyclotron emission—we resolve the eigenmode structure of the EHO and elucidate its regulatory role in edge transport. The EHO is localized within the pedestal near the maximum pressure gradient, propagates in the ion-diamagnetic direction, and its radial envelope expands with increasing shear, suggesting that rotational shear is closely associated with the structural evolution of the EHO. Information-theoretic Transfer Entropy analysis identifies a distinct ‘dual-stabilization’ regulatory interaction pattern: the EHO is associated with enhanced outward energy transport to limit the pressure gradient, while the background shear flow is associated with preferential regulatory influence on the EHO saturation amplitude and energy flux. These results demonstrate that the QH-mode pedestal is sustained by a shear-associated regulation mechanism, where the coupling between rotational shear and mode structure appears closely linked to the sustained ELM-free state.

ECEI↗

Nanoscale Amorphization of Poly(Triarylamine) for Efficient and Stable Inverted Perovskite Photovoltaics

Perovskite solar modules require hole-selective layers that combine efficient charge extraction, interfacial uniformity and scalable processing. Poly(triarylamine) (PTAA) is widely used in high-performance inverted perovskite photovoltaics, but its nanoscale crystallization and aggregation on indium tin oxide can disrupt film continuity, increase interfacial recombination and limit module stability. Here we show that 4-fluorobenzylphosphonic acid (4FBPA) modifies the surface of indium tin oxide to induce nanoscale amorphization of PTAA, forming a uniform sub-10-nm hole-selective layer. The molecule binds to indium tin oxide through a dehydration reaction, tunes the work function and surface free energy of the photoanode, and improves energy-level alignment with PTAA. The resulting amorphous PTAA film shows enhanced conductivity and hole extraction, suppresses non-radiative recombination at the buried interface and promotes more uniform perovskite growth. Inverted perovskite solar cells reach a power conversion efficiency of 26.63%, while blade-coated modules achieve a certified quasi-steady-state efficiency of 23.01%. The modules retain 95.9% of their initial efficiency after 2,600 hours of maximum-power-point operation under 1-sun illumination at 65 +- 5 degrees C in nitrogen. These results identify nanoscale amorphization of polymeric hole-selective layers as a route to efficient and stable inverted perovskite photovoltaics.

14 SOLAR ENERGY↗

Role of sheared E × B flow in self-organized, improved confinement states in magnetized plasmas

A great scientific success story of magnetic fusion research in the past several decades is the theoretical development and experimental testing of the process of turbulence decorrelation and stabilization by sheared E×B flow which shows that E×B shear effects are ubiquitous in magnetized plasmas. This concept of turbulence decorrelation and stabilization has the universality needed to explain the H-mode edge transport barriers seen in limiter and divertor tokamaks, stellarators, and mirror machines; the broader edge transport barrier seen in VHmode plasmas; and the core transport barriers formed in tokamaks. Similar effects are seen in linear devices. These examples of confinement improvement are of considerable physical interest; it is not often that a system self-organizes to reduce transport when an additional source of free energy is applied to it. The transport decrease associated with E×B velocity shear is also of great practical benefit to fusion research, since it contributed to substantially increased fusion yield in all DT magnetic fusion experiments conducted to date. The fundamental physics involved in transport reduction is the effect of E×B shear on the growth, radial extent, and phase correlation of turbulent eddies in the plasma. The same basic transport reduction process can be operational in various portions of the plasma because there are a number of ways to change the radial electric field Er. An important secondary theme in this area is the synergistic effect of E×B velocity shear and magnetic shear. Although the E×B velocity shear appears to have an effect on broader classes of microturbulence, magnetic shear can mitigate some potentially harmful effects of E×B velocity shear and facilitate turbulence stabilization. Our present understanding in this area is the result of a multi-decade, intertwined effort in theory, modeling and diagnostic development combined with continuing experimental investigations. These experiments have clearly demonstrated that increased E×B shear causes reductions in turbulence and transport. Finally, the experimental findings are generally consistent with the basic theoretical models although considerable work remains to be done before we have a fully predictive theory of transport in magnetized plasmas including E×B shear effects.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Enhanced Selectivity and Stability of Finned Ferrierite Catalysts in Butene Isomerization

Designing zeolite catalysts with improved mass transport properties is crucial for restrictive networks of either one- or two-dimensional pore topologies. In this paper we demonstrate the synthesis of finned ferrierite (FER), a commercial zeolite with two-dimensional pores, where protrusions on crystal surfaces behave as pseudo nanoparticles. Catalytic tests of 1-butene isomerization reveal a 3-fold enhancement of catalyst lifetime and an increase of 12 % selectivity to isobutene for finned samples compared to corresponding seeds. Electron tomography was used to confirm the identical crystallographic registry of fins and seeds. Time-resolved titration of Brønsted acid sites confirmed the improved mass transport properties of finned ferrierite compared to conventional analogues. These findings highlight the advantages of introducing fins through facile and tunable post-synthesis modification to impart material properties that are otherwise unattainable by conventional synthesis methods.

2D zeolite↗

Aeroelastic stability characteristics of an oblique wing aircraft

Two different studies are presented involving a transport category aircraft with an oblique or asymmetrically swept wing. The first study concerns itself with the effect on flutter of changes in certain of the aircraft structural and inertial parameters. The second portion examines the subcritical damping characteristics of a flexible oblique wing aircraft. For this purpose, a recent version of the NASTRAN computer code is used. A comparison is made between the flutter speeds found using the traditional k analysis and the results found from computation of subcritical response using the p-k or 'British' flutter method.

Crittenden, J. B.↗

Few-Layer to Multilayer Germanium(II) Sulfide: Synthesis, Structure, Stability, and Optoelectronics

Among 2D/layered semiconductors, group IV monochalcogenides such as SnS(e) and GeS(e) have attracted attention as phosphorene/black phosphorus analogues with anisotropic structures and predicted unusual properties. In contrast to SnS, for which bottom-up synthesis has been reported, few-layer GeS has been realized primarily via exfoliation from bulk crystals. Here, we report the synthesis of large (up to >20 μm), faceted single crystalline GeS flakes with anisotropic properties using a vapor transport process. In situ electron microscopy is used to identify the thermal stability and sublimation pathways, and demonstrates that the GeS flakes are self-encapsulated in a thin, sulfur-rich amorphous GeS x shell during growth. Here, the shell provides exceptional chemical stability to the layered GeS core. In contrast to exfoliated GeS, which rapidly degrades during exposure to air, the synthesized GeS–GeS x core–shell structures show no signs of chemical attack and remain unchanged in air for extended time periods. Measurements of the optoelectronic properties by photoluminescence spectroscopy show a tunable bandgap due to out-of-plane quantum confinement in flakes with thickness below 100 nm. Cathodoluminescence (CL) spectroscopy with nanoscale excitation provides evidence for interfacial charge transfer due to a type II heterojunction between the crystalline core and amorphous shell. Measurements by locally excited CL yield a minority carrier (electron) diffusion length in the p-type GeS core l diff = 0.27 μm, on par with diffusion lengths in the highest-quality layered chalcogenide semiconductors.

42 ENGINEERING↗

Cost competitive space transportation system for geostationary payloads

A geostationary satellite system designer will have a number of launch vehicles to consider in the system designs for the 1980s. The Space transportation System (the shuttle orbiter plus upper stage) offers the opportunity for lower system cost in comparison with the expendable launch vehicles. An analysis of a spin stabilized solid rocket motor stage has demonstrated the feasibility of this upper stage concept. A cost competitive Space Transportation System (STS) for geostationary payloads is made possible by achievement of the STS cost goals, multiple launch from the STS orbiter, and a user-provided spin stabilized upper stage.

Jones, C. R.↗

Tin–Lead Alloying for Efficient and Stable All-Inorganic Perovskite Solar Cells

Cesium containing all-inorganic perovskites have received considerable interest in photovoltaics research because of their potential for improved stability compared to their organic-inorganic hybrid counterparts. However, the inorganic perovskites studied thus far still suffer from lower power conversion efficiency and long-term instability, due to an unfavorable bandgap and either phase instability or air-sensitivity. Herein, A strategy to mitigate these concerns is investigated by alloying tin and lead on the B site to form tin-lead alloyed low-bandgap (~1.34 eV) inorganic CsSn 0.3 Pb 0.7 I 3 perovskites. Solar cells made using this material in an inverted full-structured architecture with a PEDOT:PSS hole transport materials (HTM) attain power conversion efficiency (PCE) up to 9.41% (stabilized PCE 7.23%). Furthermore, a simple HTM-free device without PEDOT:PSS layer is demonstrated more stable than the full-structured device and exhibits a PCE of 7.60% (stabilized PCE 7.31%) – the highest efficiency to date for an inorganic perovskite with a bandgap below 1.40 eV. This simplified device structure shows good reproducibility and stability. Finally, this work provides a possible route for fabricating low-cost, high stability devices with competitive efficiencies.

14 SOLAR ENERGY↗

RF Stabilization for Storage of Antiprotons

Portable storage of antimatter is an important step in the experimental exploration of antimatter in propulsion applications. The High Performance Antiproton Trap (HiPAT) at NASA Marshall Space Flight Center is a Penning-Malmberg ion trap being developed to trap and store low energy antiprotons for a period of weeks. The antiprotons can then be transported for use in experiments. HiPAT is being developed and evaluated using normal matter, before an attempt is made to store and transport antiprotons. Stortd ions have inherent instabilities that limit the storage lifetime. RF stabilization at cyclotron resonance frequencies is demonstrated over a period of 6 days for normal matter ion clouds. A variety of particles have been stored, including protons, C+ ions, and H2+ ions. Cyclotron resonance frequencies are defined and experimental evidence presented to demonstrate excitation of cyclotron waves in the plasma for all three species of ions.

Pearson, J. Boise↗

Digital autopilots: Design considerations and simulator evaluations

The development of a digital autopilot program for a transport aircraft and the evaluation of that system's performance on a transport aircraft simulator is discussed. The digital autopilot includes three axis attitude stabilization, automatic throttle control and flight path guidance functions with emphasis on the mode progression from descent into the terminal area through automatic landing. The study effort involved a sequence of tasks starting with the definition of detailed system block diagrams of control laws followed by a flow charting and programming phase and concluding with performance verification using the transport aircraft simulation. The autopilot control laws were programmed in FORTRAN 4 in order to isolate the design process from requirements peculiar to an individual computer.

Osder, S.↗

Stabilized Approach Criteria: Bridging the Gap Between Theory and Practice

Approach and landing is the most common phase of flight for aviation accidents, accounting annually for approximately 65 percent of all accidents. A Flight Safety Foundation study of 16 years of runway excursions determined that 83 percent could have been avoided with a decision to go around. In other words, 54 percent of all accidents could potentially be prevented by going around. A critical industry policy designed to help prevent such accidents is the go-around policy. However, the collective industry performance of complying with go-around policies is extremely poor and only about three percent of unstable approaches result in a go-around. Improving the go-around compliance rate holds tremendous potential in reducing approach and landing accidents. There are many reasons for flight crews ignoring go-around policies related to pilot judgement and company policies. Examples are the collective industry norm to accept the noncompliance of go-around policies, management being disengaged from go-around noncompliance, and pilot fatigue and lack of situational awareness. One of the biggest factors is that pilots see current stabilized-approach criteria as too complex and restrictive for the operational environment. Following the American Airlines 1420 accident (Little Rock, 1999), where the aircraft overran the runway upon landing and crashed, the National Transportation Safety Board (NTSB) recommended that the Federal Aviation Administration (FAA) define detailed parameters for a stabilized approach, and develop detailed criteria indicating when a go-around should be performed. The experiment discussed in this presentation is the first step towards developing these go-around criteria for commercial transport aircraft.

pilot performance↗

Chemical Heterointerface Engineering on Hybrid Electrode Materials for Electrochemical Energy Storage

Abstract The chemical heterointerfaces in hybrid electrode materials play an important role in overcoming the intrinsic drawbacks of individual materials and thus expedite the in‐depth development of electrochemical energy storage. Benefiting from the three enhancement effects of accelerating charge transport, increasing the number of storage sites, and reinforcing structural stability, the chemical heterointerfaces have attracted extensive interest and the electrochemical performances of hybrid electrode materials have been significantly optimized. In this review, recent advances regarding chemical heterointerface engineering in hybrid electrode materials are systematically summarized. Especially, the intrinsic behaviors of chemical heterointerfaces on hybrid electrode materials are refined based on built‐in electric field, van der Waals interaction, lattice mismatch and connection, electron cloud bias and chemical bond, and their combination. The strategies for introducing chemical heterointerfaces are classified into in situ local transformation, in situ growth, cosynthesis, and other strategy. The recent progress about the chemical heterointerfaces engineering specially focusing on metal‐ion batteries, supercapacitors, and Li–S batteries are introduced in detail. Furthermore, the classification and characterization of chemical heterointerfaces are briefly described. Finally, the emerging challenges and perspectives about future directions of chemical heterointerface engineering are proposed.

Li, Wenbin↗