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At least 595 records · Page 33

Porcelain enamel passive thermal control coatings

This paper discusses the development and evaluation of a highly adherent, low solar absorptance, porcelain enamel thermal control coating applied to 6061 and 1100 aluminum for space vehicle use. The coating consists of a low index of refraction, transparent host frit and a high volume fraction of titania as rutile, crystallized in-situ, as the scattering medium. Solar absorptance is 0.21 at a coating thickness of 0.013 cm. Hemispherical emittance is 0.88. The change in solar absorptance is 0.03, as measured in-situ, after an exposure of 1000 equivalent sun hours in vacuum.

Leggett, H.↗

MISSE Thermal Control Materials with Comparison to Previous Flight Experiments

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment (MISSE), including inorganic coatings, anodized aluminum, and multi-layer insulation materials. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was limited for some samples. Materials flown on MISSE-1 and MISSE-2 were exposed to the space environment for nearly four years. Materials flown on MISSE-3, MISSE-4, and MISSE-5 were exposed to the space environment for one year. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. Effects of short duration versus long duration exposure on ISS are explored, as well as comparable data from previous flight experiments, such as the Passive Optical Sample Assembly (POSA), Optical Properties Monitor (OPM), and Long Duration Exposure Facility (LDEF).

Finckenor, Miria↗

Aperture Shield Materials Characterized and Selected for Solar Dynamic Space Power System

The aperture shield in a solar dynamic space power system is necessary to prevent thermal damage to the heat receiver should the concentrated solar radiation be accidentally or intentionally focused outside of the heat receiver aperture opening and onto the aperture shield itself. Characterization of the optical and thermal properties of candidate aperture shield materials was needed to support the joint U.S./Russian solar dynamic space power effort for Mir. The specific objective of testing performed at the NASA Lewis Research Center was to identify a high-temperature material with a low specular reflectance, a low solar absorptance, and a high spectral emittance so that during an off-pointing event, the amount of solar energy reflecting off the aperture shield would be small, the ratio of solar absorptance to spectral emittance would provide the lowest possible equilibrium temperature, and the integrity of the aperture shield would remain intact.

Source record↗

A New Look at Stellar Outflows: Spitzer Observations of the HH 46/47 System

We present the Early Release Observations of the HH 46/47 system and HH 46 IRS 1 source, taken with the three instruments aboard the Spitzer Space Telescope. The optically invisible southwest lobe, driven by the HH 47C bow shock, is revealed in full detail by the Infrared Array Camera (IRAC) images and displays a 'loop'-like morphology. Both of the mid-infrared outflow lobes are narrower than those of CO flow. We believe that the combination of emission by H2 rotational lines [S(11)-S(4)] and some atomic lines, which fall within the IRAC passbands, are responsible for the bulk of the observed emission, although contributions from the 3.3, 6.2, and 7.7 micron polycyclic aromatic hydrocarbon emission bands cannot be ruled out. Weak spectral features corresponding to these emitters are present in the Infrared Spectrograph spectrum of the HH 47A bow shock. The spectrum of HH 46 IRS 1 shows remarkable similarities to those of high-mass protostars, which include the presence of H2O, CO2, CH4, and possibly NH3, CH3OH, and ices. The high ice abundances and the lack of signs of thermal processing indicate that these ices in the envelope are well shielded from the powerful outflow and its cavity. Emission from the Bok globule at 24 micron is detected and displays a similar structure to that observed at 8 micron.

Herbig-Haro objects↗

Atmospheric correction of TIMS data

The Thermal Infrared Multispectral Scanner (TIMS) is a unique sensor for two reasons, it is multispectral in the thermal-infrared and it has on board, active calibration sources. The existence of the calibration permits the recorded DNs to be converted unambiguously to absolute energy units. However, to relate the data to energy originating from a target on the ground it is necessary to remove the atmospheric contribution to the signal, specifically its transmittance and emittance. These can be obtained fairly easily by use of the atmospheric model provided by LOWTRAN-6 and the data from the U.S. Weather Service network of bidaily radiosondes. Using these data with the TIMS responsivity curves an equation can be obtained which permits the unambiguous correction of the TIMS data for the atmosphere.

Rickman, Doug↗

Ultralow Voltage GaN Vacuum Nanodiodes in Air

The III-nitride semiconductors have many attractive properties for field-emission vacuum electronics, including high thermal and chemical stability, low electron affinity, and high breakdown fields. In this work, we report top-down fabricated gallium nitride (GaN)-based nanoscale vacuum electron diodes operable in air, with record ultralow turn-on voltages down to ~0.24 V and stable high field-emission currents, tested up to several microamps for single-emitter devices. We leverage a scalable, top-down GaN nanofabrication method leading to damage-free and smooth surfaces. Gap-dependent and pressure-dependent studies provide new insights into the design of future, integrated nanogap vacuum electron devices. The results show promise for a new class of high-performance and robust, on-chip, III-nitride-based vacuum nanoelectronics operable in air or reduced vacuum.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Further advances in silicon solar cell technology for space application

Recent improvements relating to the design of high efficiency cells are presented. A conceptual design using passivation techniques is discussed, which potentially increases the open circuit voltage to approximately 650 mV. This concept is supported by experimental data using only silicon passivation beneath contacts. The use of thin thermal oxides of silicon for passivation between contacts is also discussed. A number of novel structures have also been fabricated to investigate reduction in the thermal alpha of planar and sculptured cells. It is shown that this may be as low as 0.63 on glassed gridded back cells, and that the IR rejection beyond 1.1 microns may approach 100 percent if the backside is AR coated. Finally, experimental data is given to support the existence of free electron absorption in heavily doped emitters on sculptured cells.

Lillington, D. R.↗

Development of high-emittance scales on thoriated nickel-chromium-aluminum-base alloys

The surface regions of a DSNiCrAl alloy have been doped, by a pack diffusion process, with small amounts of Mn, Fe, or Co, and the effect of these dopants on the total normal emissivity of the scales produced by subsequent high temperature oxidation has been measured. While all three elements lead to a modest increase in emissivity, (up to 23% greater than the undoped alloy) only the change caused by manganese is thermally stable. However, this increased emissivity is within 85 percent of that of TDNiCr oxidized to form a chromia scale. The maganese-doped alloy is some 50 percent weaker than undoped DSNiCrAl after the doping treatment, and approximately 30 percent weaker after oxidation.

Seltzer, M. S.↗

A color graphics presentation of the Space Shuttle Orbiter windward surface entry temperature distribution

The windward surface temperature response measured during the fifth entry of the Space Shuttle Columbia is presented as solid filled color contour plots. These plots show the data from 92 instruments, at selected points in time, in a manner which makes the temperature extremes and gradients immediately obvious. Several physical phenomena, such as separated flow caused by the deflected body flap, local heating at the elevon-elevon gap, an overview of the propagation of boundary-layer transition over the Orbiter windward surface, and the thermal response of eight catalytically coated tiles, can be observed or inferred from the displayed temperatures. In addition, the maximums from each instrument have been contoured and are presented with a companion plot showing the percentage of surface area covered by each contour level. Also, the flight data are presented using the colors which correspond to the surface emittance as a function of temperature. To show the temperature transients, a computer-generated movie has been produced showing the temperature contours from 100 s to 1500 s after entry interface.

Martin, F. W., Jr.↗

Progress in p(+)n InP solar cells fabricated by thermal diffusion

In SPRAT XI, we proposed that p(sup +)n diffused junction InP solar cells should exhibit a higher conversion efficiency than their n(sup +)p counterparts. This was mainly due to the fact that our p(sup +)n (Cd,S) cell structures consistently showed higher V (sub OC) values than our n(sup +)p (S,Cd) structures. The highest V(sub OC) obtained with the p(sup +)n (Cd,S) cell configuration was 860 mV, as compared to the highest V(sub OC) 840 mV obtained with the n(sup +)p (S,Cd) configuration (AMO, 25 C). In this work, we present the performance results of our most recent thermally diffused cells using the p(sup +)n (Cd,S) structure. We have been able to fabricate cells with V(sub OC) values approaching 880 mV. Our best cell with an unoptimized front contact grid design (GS greater than or equal to 10%) showed a conversion efficiency of 13.4% (AMO, 25 C) without an AR coating layer. The emitter surface was passivated by a -50A P rich oxide. Achievement of such high V(sub OC) values was primarily due to the fabrication of emitter surfaces, having EPD densities as low as 2E2 cm(sup -2) and N(sub a)N(sub d) of about 3E18 cm (sup -3). In addition, our preliminary investigation of p(sup +)n structures seem to suggest that Cd-doped emitter cells are more radiation resistant than Zn-doped emitter cells against both high energy electron and proton irradiation.

Faur, Mircea↗

Mars Radiator Characterization Experimental Program

Radiators are an enabling technology for the human exploration and development of the moon and Mars. As standard components of the heat rejection subsystem of space vehicles, radiators are used to reject waste heat to space and/or a planetary environment. They are typically large components of the thermal control system for a space vehicle or human habitation facility, and in some cases safety factors are used to oversize them when the operating environment cannot be fully characterized. Over-sizing can impose significant weight and size penalties that might be prohibitive for future missions. Radiator performance depends on the size of the radiator surface, its emittance and absorptance, the radiator temperature, the effective sky temperature surrounding the radiator, solar radiation and atmospheric irradiation levels, convection to or from the atmosphere (on Mars), and other conditions that could affect the nature of the radiator surface, such as dust accumulation. Most particularly, dust is expected to be a major contributor to the local environmental conditions on either the lunar or Martian surface. This conclusion regarding Mars is supported by measurements of dust accumulation on the Mars Sojourner Rover solar array during the Pathfinder mission. This Final Report describes a study of the effect of Martian dust accumulation on radiator performance. It is comprised of quantitative measurements of effective emittance for a range of dust accumulation levels on surfaces of known emittance under clean conditions. The test radiator coatings were Z-93P, NS-43G, and Silver Teflon (10 mil) film. The Martian dust simulant was Carbondale Red Clay. Results were obtained under vacuum conditions sufficient to reduce convection effects virtually to zero. The experiments required the development of a calorimetric apparatus that allows simultaneous measurements of the effective emittance for all the coatings at each set of experimental conditions. A method of adding dust to multiple radiator coupons was developed and shown to be capable of depositing dust on the surfaces with acceptable uniformity. In these experiments, the dust layer accumulates under earth gravity and in the presence of an earth atmosphere. An invention disclosure for the dust deposition apparatus is being filed through NASA and University of Houston.

Witte, Larry C.↗

Grid-Integrated Production of Fischer-Tropsch Synfuels from Nuclear Power

Idaho National Laboratory (INL) investigates the relative economic profitability of an integrated energy system (IES) coupling an NPP with a synfuel production process at selected case study locations across the United States. In the synfuel IES, a high-temperature steam electrolysis (HTSE) plant is thermally and electrically coupled with an NPP to produce zero-carbon hydrogen. The synthetic fuel is produced from this H 2 combined with a CO 2 supply using the reverse water gas shift process followed by the Fischer-Tropsch (FT) reaction. This analysis considers a system in which the CO 2 is sourced from regional CO 2 emitters via the construction and operation of pipeline-based CO 2 supply networks. Locating the FT plant at the same site as the NPP and HTSE plants enables the NPP to provide zero-carbon heat and power to the HTSE plant and zero-carbon power to the FT plant as well as avoid the requirement for long-distance H 2 product transport from the HTSE plant to the FT plant. Hydrogen storage is used to enable the NPP to dispatch power to the electrical grid (instead of the HTSE plant) when grid demand increases, thus enabling the FT plant to continue to operate in a steady-state production mode. The ability to cease hydrogen production for several hours within each day enables the NPP to provide power to the grid to balance the electricity market during peak periods and maximize revenues for the nuclear synfuel IES. The FT process design considered has a 99% carbon conversion efficiency. The use of nuclear energy and nuclear energy-derived hydrogen enables synfuel production to achieve this high level of carbon utilization. Additionally, the life-cycle carbon emissions of the nuclear-based synfuel production process are very low, with WTW emissions of approximately 25 gCO 2 e/MJ, including steam credits (generated from FT process excess heat), and approximately 7 gCO 2 e/MJ, if steam credits are excluded. This compares favorably with the WTW emissions of 90.5 gCO 2 e/MJ for a compression-ignition, direct injection (CIDI) vehicle with a fuel economy of 31.6 miles per gallon gasoline equivalent (MPGGE), using low-sulfur diesel produced using conventional petroleum production and refining processes. Several NPPs in various regions of the U.S. are considered as case study analyses. Supply locations and transportation via pipeline of the CO 2 feedstock to the NPP site are analyzed through the National Energy Technology Laboratory (NETL) CO 2 Transport Cost model. The team finds that the amount of CO 2 generated by different sectors is sufficient for the synfuel production process at all locations considered. The CO 2 transportation costs are functions of the distance of the source to the NPP location, the CO 2 capture cost at the source, and the quantity of CO 2 transported. Historical electricity prices for the NPP case study locations are collected and analyzed. Monthly average prices, price range, and duration of negative-price periods vary among these locations. For each location, an auto-regressive moving average (ARMA) model is trained on historical electricity price data. ARMA validation is done to ensure the synthetic price distributions represent one of historical prices with high fidelity. Synthetic time series from these ARMA models are used in a coupled dispatch and system optimization in the Holistic Energy Resource Optimization Network (HERON) to compute the differential net present value (NPV) of the IES. The team finds that this econometric is positive, ranging from $14M–1.3bn (2020) depending on the location. The optimal synfuel IES configuration to obtain this increase in NPV often maximizes the size of the synfuel production process with regards to the size of the NPP. However, the team shows that the NPP still plays a stabilizing role for the grid: In periods of high prices and high loads, more electricity from the NPP is sent to the grid. A high variability of electricity prices and extreme maximum prices tend to drive up electricity production. While it requires significant investment, the synfuel IES could increase the economic profitability for the existing fleet of LWRs across the country while still maintaining the grid stabilizer role of NPPs. During its lifetime, the main costs for the nuclear synfuel IES are the carbon feedstock transportation costs, followed by the capital expenses (CAPEX) and operation and maintenance (O&M) costs while the revenue comes first from the IRA H 2 production tax credit (PTC) and then from the sales of synfuel products. The profitability of the synfuel IES is most sensitive to the value of the hydrogen PTC and the synfuel products as well as the cost of the carbon feedstock, highlighting the importance of governmental incentives regarding hydrogen, carbon emissions, and synfuel in driving the deployment of future nuclear synfuel IESs.

08 HYDROGEN↗

Structural evaluation of candidate space shuttle thermal protection systems

The characteristics and development of a lightweight reusable thermal protection system for the space shuttle are discussed. The test articles consisted of metallic substrates with upper surfaces covered with all-silica, reusable, surface insulation material. The material is processed in the form of tiles. The external surfaces of the tiles are provided with a coating system which consists of a borosilicate coating with a silicon carbide emittance agent and impregnation with a hydrophobic agent. The finished tiles are attached to the metal substrate by adhesive bonding. Charts and graphs of the properties of the material are provided.

Burns, A. B.↗

X-ray astronomy from Uhuru to HEAO-1

The nature of galactic and extragalactic X-ray sources is investigated using observations made with nine satellites and several rockets. The question of X-ray pulsars being neutron stars or white dwarfs is considered, as is the nature of Population II and low-luminosity X-ray stars, the diffuse X-ray emission from clusters of galaxies, the unidentified high-galactic-latitude (UHGL) sources, and the unresolved soft X-ray background. The types of sources examined include binary pulsars, Population II X-ray stars (both nonbursters and bursters) inside and outside globular clusters, coronal X-ray emitters, and active galactic nuclei. It is concluded that: (1) X-ray pulsars are strongly magnetized neutron stars formed in the evolution of massive close binaries; (2) all Population II X-ray stars are weakly magnetized or nonmagnetic neutron stars accreting from low-mass companions in close binary systems; (3) the diffuse emission from clusters is thermal bremsstrahlung of hot matter processed in stars and swept out by ram pressure exerted by the intergalactic gas; (4) most or all of the UHGL sources are active galactic nuclei; and (5) the soft X-ray background is emission from a hot component of the interstellar medium.

Clark, G. W.↗

Analytical study of effects of surface and environmental thermal properties on moisture in composites

The influence of surface and environmental thermal properties on the moisture absorption in fiber-reinforced polymeric-resin-matrix composite materials which have been subjected to convection and solar radiation was studied. Predicted moisture contents based on the conditions at the heated surface and in the ambient air were compared for both short term and long term exposures over a wide range of values for emittance, solar absorptance, convective heat transfer coefficient, solar radiation, ambient temperature, and orientation of the surface with respect to the sun. The calculations showed that absorptance and heat transfer coefficient have significant effects on the moisture content.

Tompkins, S. S.↗

LDEF thermal control coatings post-flight analysis

The optical, physical, and chemical properties of selected spacecraft thermal control coatings, exposed for 10 months and 5.8 years on the leading edge (Row 9) of the LDEF, are reported. The following coatings were used: quartz/silver optical solar reflector; silvered FEP Teflon; S-13GLO, YB-71, and A-276 white paints; black paint; and sputter deposited coatings over graphite-epoxy composite substrates. The solar absorptance, total normal emittance, scanning electron and X-ray photoelectron microscopy, and X-ray diffraction analyses will be compared for the control, the 10 month exposed, and the 5.8 year exposed specimens. Data suggests that the high atomic flux over the last 6 months of the LDEF mission may have influenced the results from from this coatings experiment.

Slemp, Wayne S.↗

Intrinsic emittance properties of an Fe-doped β-Ga 2 O 3 (010) photocathode: Ultracold electron emission at 300 K and the polaron self-energy

Measurements of the spectral emission properties of an iron-doped a β-Ga 2 O 3 (010) photocathode at 300 K reveal the presence of an ultracold contribution to the total electron beam emission with a 6 meV mean transverse energy (MTE) in the 3.5–4.4 eV photon energy range (282–354 nm). This extreme sub-thermal photoemission signal is consistent with direct emission of electrons photoexcited from the Fe dopant states into the low effective mass and positive electron affinity primary conduction band, and it is superimposed on a stronger signal with a larger MTE associated with an (optical)phonon-mediated momentum-resonant Franck–Condon (FC) emission process from a thermally populated and negative electron affinity upper conduction band. For photon energies above 4.5 eV, a transition from a long to a short transport regime is forced by an absorption depth reduction to below 100 nm and both MTE signals exhibit spectral trends consistent with phonon-mediated FC emission if the polaron formation self-energy is included in the temperature of the initial thermalized photoexcited electron distribution.

Angeloni, Louis A. [University of Illinois, Chicag↗

Spectral Radiative Properties of Ceramic Particles for Concentrated Solar Thermal Energy Storage Applications

This work investigates the spectral radiative properties of ceramic particles using a monochromator and a Fourier-transform infrared spectrometer (FTIR) with integrating spheres at wavelengths from 0.38 μm to 15 μm. Particles are encased between two transparent windows to obtain the directional-hemispherical reflectance of the particle bed. Two types of commercially available particles with three different sizes are examined. Integration over the solar spectrum reveals that the solar absorptance of the particle beds is between 0.940 and 0.957. The total emittance at 1000 K is also estimated by assuming the spectral emittance is independent of temperature. The optical constants of particles are modeled with effective medium approaches, considering the optical properties of individual constituent materials. The absorptance of the particle is estimated using the effective optical constants and compared with that of the particle bed from the measurement. Finally, this work facilitates the characterization of radiative properties of particles with a windowed method and provides a modeling scheme for approximating the radiative properties of composite ceramic materials.

14 SOLAR ENERGY↗