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At least 595 records · Page 33

Impact of undoped substrates on high performance silicon solar cells

Today's highest-efficiency silicon solar cells typically operate near the threshold between low-level and high-level injection. It is not well understood if pushing further into a regime in which the cell operating point is solidly in high-level injection at all times of the day has further benefits for the solar cell performance. From a reliability perspective, cells fabricated on lower doped silicon have a larger breakdown voltage. This advantage can affect the design of modules allowing higher voltages and a relaxation of the number of bypass diodes needed. In this project, we present a comprehensive assessment, both experimental and using simulation, of how bulk resistivity, light intensity, and operation temperature impact the performance of the silicon solar cell. This work incorporates a comprehensive device physics analysis assisted by numerical simulation. The source code is now available under General Public License (GPL3), and to further leverage the findings of this project and outreach people outside of the scientific community, we are working with www.pveducation.org (which receives >1 million visitors a year) to create interactive content using our simulation results. The simulation results indicate that high bulk resistivity wafers (>>10 Ωcm) require bulk Shockley-Read-Hall (SRH) lifetimes in the millisecond range to outperform wafers with standard bulk resistivities (<10 Ωcm). Additionally, above bulk resistivities of 10 Ωcm (the exact value depends on the bulk characteristics of the wafer), the cell efficiency is weakly dependent on the bulk resistivity. As a result, ingot manufactures may have an opportunity to further reduce wafer cost by growing higher resistivity ingots that are more tolerant to resistivity variations. This project is particularly relevant today, as solar cell architectures with improved surface passivation and milliseconds lifetimes wafers are commercially available, leveraging potential benefits of using higher bulk resistivities. Outside of interdigitated back contact (IBC) cell, reported studies on high resistivity silicon (>100 Ωcm) are very limited. To the best of our knowledge, this project provides for the first-time experimental insight on solar cells fabricated on wafers with bulk resistivities up to several thousand Ωcm, delivering a comprehensive vision of their performance under real-world temperature and light intensity operation conditions. We manufactured and characterized solar cells with bulk resistivities in the range of 1 Ωcm to >15k Ωcm. Under standard testing conditions (STC), we measured solar cells efficiencies over 20% over the entire range of bulk resistivities, using our baseline cell processing. To evaluate the cell performance in real-world operation conditions, the solar cells were measured at different temperatures (25-80°C) and at different light intensities (0.1-1 suns). The measurements show that the bulk resistivity does not impact the solar cell response to temperature and light intensity. Similar thermal coefficients (TC) were measured for standard and high bulk resistivities, and they are comparable with the TC values reported in the literature for standard bulk resistivities <10 Ωcm. After light soaking, the solar cell didn’t show signs of light-induced degradation (LID). This result was expected since n-type float zone (FZ) wafers were used in this work, i.e. low traces of boron and low concentration of oxygen (oxygen is typically found in the seed end of Czochralski (CZ) ingots). We measured for high bulk resistivities (>10 Ωcm) extremely high breakdown voltages (>1000V). In conclusion, the insight provided by this project can positively impact the levelized cost of energy (LCOE) of the photovoltaic systems through its effect on cell and ingot manufacturing yield, silicon cell power output, and module reliability.

14 SOLAR ENERGY↗

Experimental testing of particle attrition in CSP systems at high temperature

An alternate and sustainable form of energy is CSP systems, which capture and store the sun’s energy in the form of heat. Increasing the operational temperature of CSP systems will increase the efficiency of electricity production while operating at temperatures exceeding 700 degrees Celsius also creates novel operational problems. One approach for high-temperature CSP systems is to utilize solid particles as the primary heat transfer medium. As particles flow through this system, the movement of particles creates erosion in the forms of impact, abrasion, and attrition erosion. In the real world, while all three forms of erosion will occur simultaneously, it is imperative to understand the individual effect of each erosion over the lifetime of the powerplant. Besides material erosion and long-term durability concerns, thermal cycling of the particles could also introduce changes in particle thermal performance due to alterations in particle morphology. Current research on the issue of erosion has been limited to industrial applications and does not necessarily coincide with the operating conditions in CSP systems. We focus on attrition erosion resulting from particle-to-wall and particle-to-particle interactions. Research has shown that besides material hardness affecting how fast particles break down, attrition erosion increased as the size of the particles increased due to a higher chance of collision between the particles. Particle attrition is relevant to the CSP community as it may result in material loss, change the system's thermal performance, and generation of fines which could pose an environmental hazard. In this work, we focus on developing a test set up that can isolate and measure particle attrition when subjected to conditions relevant to Gen3 CSP systems.

14 SOLAR ENERGY↗

Robust and Spectrally Selective Aerogels for Solar Receivers

The development of next generation concentrated solar thermal (CST) plants requires solar receivers to reach high temperatures (> 600°C) while minimizing costs. Efficiently generating such high temperatures using a line-focusing collector and an air-stable receiver has the potential to change the current CSP paradigm because it would: (1) result in large improvements in system-level efficiency of line-focusing systems by enabling the use of high-efficiency supercritical CO 2 power cycles; (2) decrease the LCOE of line-focusing systems to meet SETO 2030 goals; (3) maintain performance over the lifetime of the CSP plant by avoiding issues related to breakdown of vacuum. The use of aerogels as transparent insulating materials (TIMs) in solar thermal receivers has the potential to enable such improvements. Specifically, aerogels can be placed in front of a black (or partially selective) high-temperature absorber to allow sunlight to transmit to the absorber but block heat from escaping. These materials can improve the efficiency and simplify the complexity of thermal transport systems by enabling operation at moderate or no vacuum levels. These potential benefits have been explicitly identified by SETO as ‘high impact’. The use of mesoporous silica as a TIM has already led to large improvements in solar collection efficiency. Nevertheless, these materials inherently lose structural integrity and the ability to suppress radiation losses at high temperatures. Here, we address these challenges by leveraging 1-cycle atomic layer deposition of aluminum oxide onto a silica aerogel to form a thermally stable interfacial layer that is transparent to sunlight but broadly absorbs in the mid-infrared. This interfacial absorption results in a two-fold reduction in measured heat losses from an absorber at 700°C and solar thermal efficiency of 81% at 700°C under 60 Suns, based on measurements of heat loss and solar transmittance. Extended-duration heat treatment reveals that the multicomponent aerogel is stable at high temperatures relative to a silica aerogel. Furthermore, we experimentally demonstrate the concept of using infrared plasmon resonances to selectively enhance the thermal absorption coefficient of TIMs in order to strongly suppress thermal radiative losses at high temperatures. We term this mechanism plasmon-enhanced greenhouse selectivity (PEGS). Unlike silica aerogels, where much of the IR absorption is lost at high temperatures, local surface plasmon resonances (LSPRs) in doped oxide nanoparticles overlap a significant portion of the blackbody spectrum and are maintained at high temperatures. Overall, this work paves the way for next-generation solar thermal energy using thermally robust transparent insulating materials.

14 SOLAR ENERGY↗

Ghost particles and Project Poltergeist: Long-ago Lab physicists studied science that haunted them

A neutrino is a tiny, almost massless particle that travels at near light speeds. They were first formed in the early universe and are continually being produced in the nuclear reactions of stars, like the sun, and nuclear reactions on earth. The existence of these “ghost particles” was incredibly difficult to detect, but doing so has helped scientists better understand fundamental principles in physics. Los Alamos Manhattan Project scientist Frederick Reines, along with his colleague Clyde Cowan, is credited with the experimental discovery of the nearly massless elementary particle after his team definitively proved the neutrino’s existence in 1956. Reines received the Nobel Prize in Physics in 1995.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Direct Measurement of Mass-Temperature Distributions in the Core of Implosions on the National Ignition Facility (Full Technical Final Report)

Inertial confinement fusion plasmas are characterized by several kilo-electron-volt (keV) electron temperatures and ion and electron densities approaching 100 to 1000 times solid. In these implosions which simulate the dynamics of our sun, spectroscopic dopants can lead to detailed exploration of the plasma gradients that are not possible in other places. This is both in the central core pressure and temperature as well as any “mix” resultant from ablation and hydrodynamic interactions. This work will show new Bayesian atomic physics models applied to ICF plasmas to give both the temperature and density of the internal hot spot to better describe the physical nature of these implosions along with trying to spatially resolve the mix coming from the ablator region. The mission impact is to demonstrate this effect and to lead to a more quantitative description of mix in inertial confinement plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ghost particles and Project Poltergeist: Long-ago Lab physicists studied science that haunted them

A neutrino is a tiny, almost massless particle that travels at near light speeds. They were first formed in the early universe and are continually being produced in the nuclear reactions of stars, like the sun, and nuclear reactions on earth. The existence of these “ghost particles” was incredibly difficult to detect, but doing so has helped scientists better understand fundamental principles in physics. Los Alamos Manhattan Project scientist Frederick Reines, along with his colleague Clyde Cowan, is credited with the experimental discovery of the nearly massless elementary particle after his team definitively proved the neutrino’s existence in 1956. Reines received the Nobel Prize in Physics in 1995.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Particle Mass Flow Control and Measurement for High-Temperature Particle Receivers

This work is developing particle flow control and measurement methods for next-generation concentrating solar power systems employing particle-based technologies. Particle receivers are being pursued to provide substantial performance improvements through higher temperatures (>700 °C) for more efficient and cost-effective CSP systems with direct storage for electricity generation, process heating, thermochemistry, and solar fuels production. This specific work will develop technologies that enable more efficient particle receivers and scalable methods to accommodate variable irradiances during commercial on-sun operation. The development of next-generation particle-receiver systems and methods with potentially high consequences for improved performance and cost savings for CSP applications is an appropriate role for the government.

14 SOLAR ENERGY↗

Erosion Experimentation in Solar Power Systems

An alternate and sustainable form of energy is concentrated solar power (CSP) systems, which capture and store the sun’s energy in the form of heat. To increase the efficiency and overall cost of the plant, particles were used as a heat transfer medium. As particles flow through this system, the movement of particles creates erosion, in the forms of abrasion and attrition. Experiments were tested at room temperature and 800 degrees Celsius for both abrasion wear and attrition erosion. In abrasion wear, specimens were placed inside a container, particles were added, and the specimen rotated in and out of the particles. In attrition erosion, a steel disk rotated amongst particles which resulted in particles rubbing against each other. Abrasion wear increased when temperature increased while attrition showed that the particles broke down as the amount of time increased. For attrition at 800 degrees Celsius, oxide was increased and mixed with the particles. Durability models will be created to predict attrition and abrasion based on the particle and specimen mechanical properties. This discovery shows that this method of utilizing particles for CSP plants would improve efficiency and decrease overall costs.

14 SOLAR ENERGY↗

Quality Data Essential for Modeling Water Cycles Effectively

The experimental and observational data is the backbone of effective modeling of all aspects of water cycles. As the computer technology used for these data gathering efforts has improved dramatically in the recent decades, the environmental conditions these instruments are subjected to remain pretty much the same. These measuring instruments are exposed to the sun light, wind, rain, snow and ice; and they are immersed in dirt, water and mud. All of these are damaging to the electronics components used for data gathering, storage, and transmission, which creates many different kinds of data quality issues that affect the quality and reliability of modeling and prediction efforts.

54 ENVIRONMENTAL SCIENCES↗

Robust and Spectrally Selective Aerogels for Solar Receivers (Final Technical Report)

The development of next generation concentrated solar thermal (CST) plants requires solar receivers to reach high temperatures (> 600°C) while minimizing costs. Efficiently generating such high temperatures using a line-focusing collector and an air-stable receiver has the potential to change the current CSP paradigm because it would: (1) result in large improvements in system-level efficiency of line-focusing systems by enabling the use of high-efficiency supercritical CO2 power cycles; (2) decrease the LCOE of line-focusing systems to meet SETO 2030 goals; (3) maintain performance over the lifetime of the CSP plant by avoiding issues related to breakdown of vacuum. The use of aerogels as transparent insulating materials (TIMs) in solar thermal receivers has the potential to enable such improvements. Specifically, aerogels can be placed in front of a black (or partially selective) high-temperature absorber to allow sunlight to transmit to the absorber but block heat from escaping. These materials can improve the efficiency and simplify the complexity of thermal transport systems by enabling operation at moderate or no vacuum levels. These potential benefits have been explicitly identified by SETO as ‘high impact’. The use of mesoporous silica as a TIM has already led to large improvements in solar collection efficiency. Nevertheless, these materials inherently lose structural integrity and the ability to suppress radiation losses at high temperatures. Here, we address these challenges by leveraging 1-cycle atomic layer deposition of aluminum oxide onto a silica aerogel to form a thermally stable interfacial layer that is transparent to sunlight but broadly absorbs in the mid-infrared. This interfacial absorption results in a two-fold reduction in measured heat losses from an absorber at 700°C and solar thermal efficiency of 81% at 700°C under 60 Suns, based on measurements of heat loss and solar transmittance. Extended-duration heat treatment reveals that the multicomponent aerogel is stable at high temperatures relative to a silica aerogel. Furthermore, we experimentally demonstrate the concept of using infrared plasmon resonances to selectively enhance the thermal absorption coefficient of TIMs in order to strongly suppress thermal radiative losses at high temperatures. We term this mechanism plasmon-enhanced greenhouse selectivity (PEGS). Unlike silica aerogels, where much of the IR absorption is lost at high temperatures, local surface plasmon resonances (LSPRs) in doped oxide nanoparticles overlap a significant portion of the blackbody spectrum and are maintained at high temperatures. Overall, this work paves the way for next-generation solar thermal energy using thermally robust transparent insulating materials.

14 SOLAR ENERGY↗

Pandora Telescope Isolation Systems Engineering Project

The collective imagination of humanity has always been captured by the possibility of other habitable planets. Only with recent advances in spacecraft and our understanding of astrophysics, has it become possible to study the atmospheres of planets orbiting stars other than our sun, also known as extrasolar planets or exoplanets. We know from the Keplar Space telescope, launched in the early 1990s, that there are more planets than stars in the Milky Way. The Transiting Exoplanet Survey Satellite, TESS, will continue the search for exoplanets outside our solar system. Two other well know telescopes with the capability to study exoplanets are the James Webb Space Telescope (JWST) and Hubble Space Telescope (HST). Together they provide full spectral coverage to do short deep dives into planets of interest, but tasking these satellites is both expensive and hard to obtain. A new mission dedicated to the characterization of exoplanets and the stars they orbit is needed to fill the gap.

42 ENGINEERING↗

Behind the Meter Solar+Storage: Market data and trends [Slides]

As the distributed solar market evolves toward more dynamic forms of deployment, interest in paired solar-plus-storage applications continues to gain steam, but details on the current state of the market are relatively sparse. To fill that void, Berkeley Lab has released an in-depth analysis of this budding market segment. This report draws on the Lab’s Tracking the Sun dataset to characterize trends in deployment, system sizing and equipment selection, installer-market development, and system pricing. The report also provides indicative analyses of the financial and resilience value that host customers in several key markets presently receive by pairing storage with solar.

14 SOLAR ENERGY↗

Enabling Sustainable Landscape Design for Continual Improvement of Operating Bioenergy Supply Systems

This unique and highly effective project catalyzed collaboration among government, university, and private sector partners through a multi-state research and technology transfer project designed to support continuous improvement of bioenergy feedstock supply systems. Conceived and built upon the foundation created by prior DOE investments in the Billion Ton Study, Sun Grant Regional Project, and many other feedstock production, harvest, storage and transportation studies, this project addressed seven tasks with more than 29 subtasks. All goals were met with key accomplishments being: (1) on-farm establishment of potential perennial plant mixtures that could not only become sustainable feedstock sources but also enhance soil health, (2) a reduction in potential wind and water erosion by improving corn stover harvest techniques and incorporating cover crops into current row-crop production systems, (3) reduced potential for surface and groundwater contamination while also increasing potential biodiversity and sustainability of Midwestern USA landscapes, and (4) development of site-specific land management, data visualization, and sustainability assessment tools. Twenty-two Case Studies highlighting accomplishments and lessons learned through this public-private partnership investment are incorporated into this final report. On-farm and replicated field plot studies were used to provide the real-world data needed to verify baseline assumptions for extensive feedstock logistic modeling and greenhouse gas (GHG) assessments needed to develop sustainable bioenergy and bio-product industries at national and international scales.

09 BIOMASS FUELS↗

Regional Feedstock Partnership Biomass Quality Assessment Final Report

The United States (U.S.) Department of Energy (DOE) developed the Billion-Ton Vision to enable production of one-billion tons of sustainable, reliable biomass for the bioenergy industry by 2030 (Perlack et al., 2005). The Sun Grant Regional Feedstock Partnership (RFP) was organized to fill information gaps and validate biomass yield assumptions related to the Billion-Ton Study (Owens, 2018; Owens, Karlen, and Lacey, 2016). Along with the more than 130 scientific publications generated from these studies, yield and sustainability data from the RFP field trials not only validated the Billion-Ton estimates, but were critical in developing both the U.S. Billion-Ton Update report in 2011 and the 2016 Billion-Ton Report (DOE, 2011; 2016). The intention of this biomass quality assessment report is to build on these initial successes from the RFP field trials by focusing on variability in biomass quality data necessary to evaluate conversion performance. This report contains a summary of chemical quality results from samples collected as part of the RFP field trials. This report focuses on assessment of the impact of experimental agronomic designs on biomass properties followed by analyses of the impact of environmental and production variables on biomass properties. Datasets include species and other genetic variables, fertilizer treatments, harvest information, and yield, as well as other publicly available data such as precipitation, temperature, soil properties, and drought. The key outcomes from this chemical quality focused assessment have included: • Complete evaluation of the impacts of agronomic designs, genetics, and environmental conditions on chemical properties for Miscanthus, switchgrass, sorghum, energycane, mixed perennial grasses, and shrub willow short-rotation feedstocks • Over 30 peer review publications and technical reports focused on variability in quality data • Development of spatial and temporal environmental quality prediction maps for Miscanthus and switchgrass feedstocks allowing for comprehensive evaluation of variability in feedstock chemical quality across U.S. regions and over multiple harvest years

09 BIOMASS FUELS↗

Solar Photovoltaics: Supply Chain Deep Dive Assessment

This is one of a series of reports and deep dive assessments produced in response to Executive Order 14017 “America’s Supply Chains,” which directs the Secretary of Energy to submit a report on supply chains for the energy sector industrial base. The Executive Order is helping the federal government to build more secure and diverse U.S. supply chains, including energy supply chains. Over the past decade, solar power has gone from an emerging, niche technology to a mature energy industry. By 2035, solar power could supply 40% or more of U.S. electricity demand, dramatically accelerating the decarbonization of buildings, transportation, and industry; and, if current technology trends continue, it could do so without increasing the price of electricity. The rapid expansion of solar energy has the potential to yield broad benefits in the form of economic activity and workforce development. The solar industry already employs roughly 230,000 people in the United States, at an average wage that is higher than the national average for most comparable positions. By decarbonizing the electricity sector by 2035, the U.S. solar industry could employ 500,000–1,500,000 people by 2030. The components that are assembled to install a photovoltaic power system are produced by a global supply chain. Photovoltaic (PV) modules (also called panels) are made of cells that use a variety of technologies. There are two leading types of solar modules used in the United States, with crystalline silicon (c-Si) modules representing 84% of the market and cadmium telluride (CdTe) modules representing 16% of the market. Modules of either type require mounting structures to provide mechanical support (racking), which may be configured to follow the sun (tracking). The output of any PV module is direct current (dc), which is almost always converted to alternating current (ac) by an inverter.

14 SOLAR ENERGY↗

NIF-TAS Miniature Calibration Station

“On Aug. 8, 2021, an experiment at Lawrence Livermore National Laboratory’s (LLNL’s) National Ignition Facility (NIF) made a significant step toward ignition, achieving a yield of more than 1.3 megajoules (MJ). This advancement puts researchers at the threshold of fusion ignition, an important goal of the NIF, and opens access to a new experimental regime.” NIF experiments are conducted by symmetrically focusing 192 laser beams from NIF (three football fields in length) into the Target Chamber (10-meter diameter sphere) onto a target 2mm in size. The reaction produces a hot spot the diameter of a human hair, generating more than 10 quadrillion watts of fusion power for 100 trillionths of a second. These high pressures and temperatures created by the NIF have only been seen on the surface of the sun. To achieve fusion ignition, the target must be compressed to high pressures and temperatures, which requires symmetric compression. This symmetry requires precise alignment of the laser beams to the target. To achieve this precise symmetry a Target Alignment System (TAS) was developed to aid in aligning the beams to the target. The accomplishment on Aug 8 th could not have been accomplished without the TAS. TAS has proven to be a critical contributor to the success of NIF experiments. Each TAS is composed of several Charge Couple Device (CCD) sensors and various support electronics. Unfortunately, these CCDs are no longer available in industry as they have become outdated and obsolete. There is a limited amount of spare CCDs in the facility. As the NIF continues to increase its energy output of its fusion ignition shot experiments (heigh yield shots), more neutrons are being emitted from the Target Chamber. These neutrons are very damaging to the TAS electronics and its sensors, thus degrading and reducing its life expectancy dramatically. The increase of neutrons exceeds the damage threshold of the CCDs. This would increase the demand for more frequent TAS refurbishments and calibrations. The increase in resources to perform these refurbishments and calibrations would not be sustainable. In efforts to prolong the life of each TAS system it was determined that the TAS should be removed for every High Yield Shot and then reinstalled. The high precision fully calibrated TAS can easily be knocked out of alignment during these installs and reinstall exchanges and being transported in and out of the NIF. The Miniature Calibration Station System was developed to verify that the critical calibration parameters have been preserved during every TAS exchange. The Miniature Calibration Station System (Mini-Cal) would need to be a scaled down (in size and scope), portable version of the offline TAS calibration station to verify the critical TAS parameters are still within tolerances.

42 ENGINEERING↗

Multispectral and Thermal Imager Onboard Aerial Platforms Instrument Handbook

The MicaSense Altum imager is an off-the-shelf, synchronized multispectral and thermal camera, combined with a Global Positioning System (GPS) unit and downwelling light sensor (DLS). The Altum takes images of the land surface within its field of view (FOV) across five visible bands and one longwave infrared thermal band. The sensor records the radiance and converts it to digital numbers. Imagery is radiometrically corrected, taking into account the sensor calibration, lens distortions, vignette effects, sun angle, and atmospheric effects (scattering and absorption). The photogrammetry software Agisoft PhotoScan v 1.4 is used to align and stitch the images into a larger composite image using the technique of structure from motion image capture to construct a dense cloud and 3D model of the surface, which is used to produce a digital elevation model of the terrain surveyed and orthomosaic imagery. Land surface leaf area index, albedo, and surface skin temperature are provided for the user. The user can perform raster calculations on the imagery to produce various other vegetative indices, which are used to indicate plant health and land surface characteristics, including Normalized Difference Vegetation Index (NDVI), Green Normalized Difference Vegetation Index (GNDVI), Normalized Difference Water Index (NDWI), surface temperature, and Enhanced_vegetation_index (EVI). This code is provided with the readme file for each data set. The images have a resolution of 20-60 cm/pixel, which are subsampled to 100 cm/pixel.

47 OTHER INSTRUMENTATION↗

Development Support for NREL's System Advisor Model (SAM): Cooperative Research and Development, CRADA Number CRD-20-16998 (Final Report)

The variable nature of renewable generation, which depends on the sun shining and wind blowing for example, presents challenges for adequate and least-cost resource planning. The deployment of renewable generation assets is anticipated to increase due to various drivers, such as declining costs, favorable government policies, and increasing procurement by corporations and consumers. High levels of renewable penetration are anticipated to pose flexibility, reliability, and cost challenges to the electrical system. The development and implementation of new features into performance modeling software, such as the National Renewable Energy Laboratory's (NREL) System Advisor Model (SAM), is one way to help think through these challenges and develop appropriate strategies.

14 SOLAR ENERGY↗