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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

The chemical kinetics and thermodynamics of sodium species in oxygen-rich hydrogen flames

Results are presented which, it is claimed, lead to a correction of previous misconceptions over the relative importance and kinetics of NaO2. It is shown that its rapid conversion to NaO and NaOH is such that it can severely perturb the NaOH/Na ratio and produce significant concentration overshoots over that predicted from the balance of the reaction of Na with H2O. This becomes increasingly the case in flames of large O2 concentrations and temperatures below 2500 K; and the corresponding large rate constants for the termolecular formation of the other alkali peroxides imply that similar considerations will be necessary for them. Depending on the rate constants for the exothermic conversions of MO2 to MO or MOH, the steady-state concentrations of MO2 could be more or less significant than for sodium. Owing to numerous reactions that produce these conversions, the MOH species will probably be the dominant species in all cases in oxygen-rich hydrogen or hydrocarbon flames, with MO concentrations at not greater than 1 percent of the bound metal.

Hynes, A. J.↗
NASA NTRS1984

Brominated organic species in the arctic atmosphere

Measurements are reported of four gas-phase, brominated organic species found in the Arctic atmosphere during March and April 1983. Volume mixing ratios for CH3Br, CH2BrCH2Br, CHBr3, and CH2Br2 were determined by gas chromatography/mass spectrometry analysis from samples taken Arctic wide, including at the geographic North Pole and during a tropopause folding event over Baffin Bay near Thule, Greenland. Methyl bromide mixing ratios were reasonably constant at 11 plus or minus 4 pptv, while the other three brominated organics showed a high degree of variability. Bromoform (2 to 46 pptv) was found to be the dominant contributor to gaseous organic bromine to the Arctic troposphere at 38 plus or minus 10 percent followed by CH2Br2 (3 to 60 pptv) at 29 plus or minus 6 percent. Both CH3Br and CH2BrCH2Br (1 to 37 pptv) reservoirs contained less than 20 percent of the organically bound bromine. Stratospheric samples, taken during a tropopause folding event, showed mixing ratios for all four species at levels high enough to support a stratospheric total volume mixing ratio of 249 pptv Br (888 ngBr/SCM).

Berg, W. W.↗
NASA NTRS1984

Microplankton species assemblages at the Scripps Pier from March to November 1983 during the 1982-1984 El Nino event

A semiweekly sampling program at the Scripps Institution of Oceanography pier was begun in 1983 during an El Nino event. Microplankton data for March to November 1983 show a temporal sequence of species assemblages of the 24 important taxa, with a residence time of 1 to 4 weeks. From March to early September, the assemblages consisted of typical neritic taxa. From mid-September to mid-November, the presence of oceanic warm-wave species was associated with positive temperature anomalies characteristic of the El Nino condition. During the period studied numerical abundances were low.

Reid, F. M. H.↗
NASA NTRS1984

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH2O, and other species. It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only about 10 to the -12th could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance, roughly X(HCN) = 10 to the -9th, appears to be due to photochemical reactions. After HCN, the most abundant organic-disequilibrium species in the troposphere is probably C2H6, derived from direct photolysis of CH4 at high altitudes, with a mole fraction of about 10 to the -10th at the H2O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.

Lewis, J. S.↗
NASA NTRS1985

Microplankton species assemblages at the Scripps Pier from March to November 1983 during the 1982-1984 El Nino event

A semiweekly sampling program at the Scripps Institution of Oceanography Pier was begun in 1983 during an El Nino event. Microplankton data for March to November 1983 show a temporal sequence of species assemblages of the 24 important taxa, with a residence time of 1 to 4 weeks. From March to early September, the assemblages consisted of typial neritic taxa. From mid-September to mid-November, the presence of oceanic warm-wave species was associated with positive temperature anomalies characteristic of the El Nino condition. During the period studied numerical abundances were low.

Reid, F. M. H.↗
NASA NTRS1986

The removal of soluble species by warm stratiform clouds

The development of a one-dimensional, time-dependent model to study the removal of soluble gases from a warm, precipitating stratiform cloud is reported. The model calculates the distributions of water vapor and condensed water, in the form of cloud drops and raindrops, as well as the in-cloud concentration of a soluble species in the gas and aqueous phases for a specified profile of pressure and temperature and an assumed updraft velocity. Highly soluble gases are found to be rapidly dissolved into cloud droplets and then slowly incorporated into raindrops as cloudwater is converted to rainwater. The rainout rate for highly soluble species is found to be ultimately limited by the rate at which new gaseous material can be transferred from the cloud-free air into the cloud. The model calculations indicate that turbulence represents an important mechanism by which highly soluble gases are transported into stratiform clouds.

Qin, YU↗
NASA NTRS1987

Irregular and diurnal variability in asynoptic measurements of stratospheric trace species

The consequences of irregular and diurnal variability on the interpretation of asynoptic measurements of stratospheric trace species are explored. In particular, the fidelity with which the continuous behavior may be recovered from discrete asynoptic measurements is examined. Dynamically created tracer variability in the form of an advected space-time random process is discussed. Diagnostics such as power spectra and time-mean fields are derived asynoptically and compared with the true behavior. Diurnal variations of a photochemically active species are considered, describing variability in terms of a solar waveform which propagates through a latitudinal envelope. Several diagnostics of the behavior are derived asynoptically and compared with the true variability.

Salby, Murry L.↗
NASA NTRS1988

Oxygen chemistry of shocked interstellar clouds. III - Sulfur and oxygen species in dense clouds

The chemical evolution of oxygen and sulfur species in shocked dense clouds is studied. Reaction rate constants for several important neutral reactions are examined, and revised values are suggested. The one-fluid magnetohydrodynamic shock structure and postshock chemical evolution are calculated for shocks of velocity v(s) = 10 km/s through clouds of initial number density n(0) = 100,000/cu cm and of molecule/atom ratios H2/H = 10, 1000, and 100,000 with most sulfur contained initially in molecules SO2 and SO. Abundances of SO2, SO, CS, and OCS remain near their preshock values, except in clouds containing substantial amounts of atomic hydrogen, where significant destruction of sulfur-oxygen species occurs. Abundances of shock-enhanced molecules HS and H2O are sensitive to the molecule/atom ratio. Nonthermal oxygen-hydrogen chemistry has a minor effect on oxygen-sulfur molecules in the case H2/H = 10.

Leen, T. M.↗
NASA NTRS1989

Chemistry and transport in a three-dimensional stratospheric model - Chlorine species during a simulated stratospheric warming

The distributions in the stratosphere of a variety of chemical species were calculated for a 6-day period during the February 1979 stratospheric major warming, using winds derived from a spectral forecast model which included O(x), NO(x), HO(x), and ClO(x) chemistries as well as longitudinally varying reaction rate coefficients and photolysis rates for these molecules. The results obtained indicate a particular importance of chemistry and transport for the Cl-containing species ClO, ClONO2, HCl, and HOCl. Dynamical effects dominate the variability of HCl, while diurnal effects dominate that of ClONO2 and ClO. The effects of strong planetary wave activity may be seen in terms of large longitudinal variability of the total HCl and ClONO columns in the stratosphere; in the middle and high northern latitudes, it is sufficiently large to exceed the diurnal variability of the column.

Kaye, Jack A.↗
NASA NTRS1989

Comparison of model results transporting the odd nitrogen family with results transporting separate odd nitrogen species

A fast two-dimensional residual circulation stratospheric family transport model, designed to minimize computer requirements, is developed. The model was used to calculate the ambient and perturbed atmospheres in which odd nitrogen species are transported as a family, and the results were compared with calculations in which HNO3, N2O5, ClONO2, and HO2NO2 are transported separately. It was found that ozone distributions computed by the two models for a present-day atmosphere are nearly identical. Good agreement was also found between calculated species concentrations and the ozone response, indicating the general applicability of the odd-nitrogen family approximations.

Douglass, Anne R.↗
NASA NTRS1990

Computer codes for the evaluation of thermodynamic properties, transport properties, and equilibrium constants of an 11-species air model

The computer codes developed provide data to 30000 K for the thermodynamic and transport properties of individual species and reaction rates for the prominent reactions occurring in an 11-species nonequilibrium air model. These properties and the reaction-rate data are computed through the use of curve-fit relations which are functions of temperature (and number density for the equilibrium constant). The curve fits were made using the most accurate data believed available. A detailed review and discussion of the sources and accuracy of the curve-fitted data used herein are given in NASA RP 1232.

Thompson, Richard A.↗
NASA NTRS1989

Influence of multiple ion species on low-frequency electromagnetic wave instabilities

The effect of multiple (singly ionized) coexisting newborn ion species on the stability of low-frequency electromagnetic waves was investigated using a plasma model in which solar wind magnetoplasma is made up of isotropic Maxwellian electron and proton populations with a common number density of 4.95/cu cm and temperatures equal to 17.2 eV and 6.9 eV, respectively. It is shown that the effect of multiple ions on wave growth, for given background magnetoplasma conditions and relative densities, depends not only on their mass but also on the physical nature of the wave modes. If the ion masses are disparate, each one of the coexisting ion beams tends to stimulate instabilities without undue influence from the other species. If the masses of newborn ions are similar, they can strongly catalyze wave growth of fluidlike nonresonant modes, but bring about weak growth enhancements in cyclotron resonant instabilities.

Brinca, Armando L.↗
NASA NTRS1989

Mechanics of chemical species transport in the marine atmospheric boundary layer

Marine atmospheric boundary layer (MABL) drafts are modeled as steady-state plumes using the approach proposed by Telford (1966), and the model response to varying forcing and boundary conditions is examined. Since most of the chemical species are passive tracers within the MABL, variations in the implied fluxes are determined as a combination of the boundary conditions for the chemical species and the thermodynamic forcing implied by the stability and thermal boundary conditions.

Hanson, Howard P.↗
NASA NTRS1989

Middle Atmosphere Program. Handbook for MAP. Volume 31: Reference models of trace species for the COSPAR international reference atmosphere

A set of preliminary reference atmosphere models of significant trace species which play important roles in controlling the chemistry, radiation budget, and circulation patterns of the atmosphere were produced. These models of trace species distributions are considered to be reference models rather than standard models; thus, it was not crucial that they be correct in an absolute sense. These reference models can serve as a means of comparison between individual observations, as a first guess in inversion algorithms, and as an approximate representation of observations for comparison to theoretical calculations.

Keating, G. M.↗
NASA NTRS1990

Are there interactions of iodine and sulfur species in marine air photochemistry?

The effects of dimethyl sulfide (DMS) and methyl iodide (MI) emissions are analyzed using a two-dimensional photochemical model of a marine tropical tropospheric synoptic system. The model traces the atmospheric transformation cycles of the emissions to aerosols. The study is focused on remote tropical ocean regions and includes simulations of the spatial and diurnal variations of various iodine and sulfur species, and the species OH, HO2, and H2O2. One line of analysis leads to the conclusion that the reaction IO + DMS yields DMSO + I may play a significant role in destroying DMS if it proceeds at the published fast rate. Alternative lines of analyses are presented.

Chatfield, Robert B.↗
NASA NTRS1991

Simulation of the present-day atmospheric ozone, odd nitrogen, chlorine and other species using a coupled 2-D model in isentropic coordinates

A zonally averaged two-dimensional model for chemical species in the atmosphere (Olaguer et al., 1990), with coupled dynamics, radiation transfer, and chemistry, is used to study the present-day atmospheric ozone, odd nitrogen, chlorine, other species. The model utilizes all zonally averaged physical equations of momentum, energy, and mass and determines self-consistently the advective and diffusive tranasport parameters from the temperature specific to the period of observation. A comparison of the model results with observations showed good agreement.

Yang, H.↗
NASA NTRS1991

Heat flow between species in one-dimensional particle plasma simulations

The theory of Eldridge and Feix (1962) is presently applied to characterize the rate of heat flow between two one-dimensional particle species. Formulas derived assuming initial Maxwellian distributions, while complex, are judged applicable to simulators. Tests of the theory by simulations using Langdon and Birdsall's (1985) standard code yield results which indicate that heat flow between species may become rapid when the actual (not necessarily the intended) temperatures differ: thereby presenting a substantial hazard.

Lawson, William S.↗
NASA NTRS1992

Species and temperature measurement in H2/O2 rocket flow fields by means of Raman scattering diagnostics

Validation of CFD codes developed for prediction and evaluation of rocket performance is hampered by a lack of experimental data. Nonintrusive laser based diagnostics are needed to provide spatially and temporally resolved gas dynamic and fluid dynamic measurements. This paper reports the first nonintrusive temperature and species measurements in the plume of a 110 N gaseous hydrogen/oxygen thruster at and below ambient pressures, obtained with spontaneous Raman spectroscopy. Measurements at 10 mm downstream of the exit plane are compared with predictions from a numerical solution of the axisymmetric Navier-Stokes and species transport equations with chemical kinetics, which fully model the combustor-nozzle-plume flowfield. The experimentally determined oxygen number density at the centerline at 10 mm downstream of the exit plane is four times that predicted by the model. The experimental number density data fall between those numerically predicted for the exit and 10 mm downstream planes in both magnitude and radial gradient. The predicted temperature levels are within 10 to 15 percent of measured values.

De Groot, Wim A.↗