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At least 595 records · Page 33

Development of SiC-based Cladding for Accident Tolerant Fuels

Fuels and core structures in current light water reactors (LWR's) are vulnerable to catastrophic failure in severe accidents. This vulnerability is attributed primarily to the rapid oxidation kinetics of zirconium alloys in a water vapor environment at very high temperatures. Alternative materials to zirconium alloys with reduced oxidation kinetics are sought to enable enhanced accident-tolerant fuels and cores. Among the candidate alternatives, silicon carbide (SiC) - based materials, in particular continuous SiC fiber-reinforced SiC matrix ceramic composites (SiC/SiC composites), are considered to offer outstanding safety benefits. The primary objective of this work is to provide with updated overviews of the concepts, development status, and future prospect for the SiC-based accident-tolerant fuel (ATF) claddings. A systematic technology evaluation program plan was developed and updated to review the technologies needed, to identify and analyze critical gaps, and to lay out a road-map toward establishing key technologies. The technology review and the gap analysis in this exercise were based on an early study and community workshops. Many of the technical gaps identified are related with the three key feasibility issues: hydrothermal corrosion, mechanical failure, and fuel compatibility. Additional performance issues including accident-tolerance features and fission product retention during the normal operation have also been identified. The program plan was designed to systematically address the key gap issues and is formulated in a work breakdown structure. Simultaneously, the plan is being established to set a technical program for advancing the technological readiness levels of concept non-specific essential technologies in three top-level categories of Design and Failure, Environmental Effects, and Off-normal Behavior. The execution of the program plan is in progress across the U.S. Department of Energy laboratories, industries, universities, and international collaborators. The critical issues for SiC composite-based fuel cladding concepts were found to be related to the performance in the normal operation. In particular, radiation-assisted hydrothermal corrosion and the gaseous fission product (FP) retention are identified to be the most critical issues. The primary ORNL concept pursues the use of dual-purpose coating on the SiC composite cladding wall to mitigate the corrosion and the gas permeation issues at the same time, whereas the alternative approaches such as the dense monolithic SiC protective layer combined with the water chemistry control may be feasible. Surface metallization through variations of physical vapor deposition and electroplating are being demonstrated. The FP gas retention is an issue associated with the cracking for the ceramic matrix composite cladding. To establish the probabilistic failure behavior, the relevant test methods were developed in ASTM Committee C28 on Advanced Ceramics. Toward the end-plugging technology development, various methods for joining SiC to SiC had been developed and tested for mechanical properties, irradiation effects, and environmental effects. Multiple methods including the pressureless transient eutectic SiC joining and CVD-based SiC joining were identified particularly promising. In addition, a multi-physics, three-dimensional finite element-based modeling is in progress toward an integrated simulation of the SiC composite-cladded fuel evolutions. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Molecular Programming of Diorganyl Dichalcogenides for Rational Nanocrystal Design

Soft-chemistry nanocrystal synthesis leverages low-temperature, solution-phase reactions to access materials that can be kinetically stabilized rather than thermodynamically favored. Under such mild conditions, reaction pathways are governed not only by precursor composition but also by the molecular details that dictate how reactive atomic species are generated and delivered. Furthermore, harnessing this kinetic sensitivity offers a powerful opportunity: by deliberately programming precursor reactivity, nanocrystal composition, structure, and morphology can be rationally designed rather than empirically discovered.

Chalcogenides↗

Deep Underground Neutrino Experiment (DUNE), Far Detector Technical Design Report, Volume II: DUNE Physics

The preponderance of matter over antimatter in the early universe, the dynamics of the supernovae that produced the heavy elements necessary for life, and whether protons eventually decay -- these mysteries at the forefront of particle physics and astrophysics are key to understanding the early evolution of our universe, its current state, and its eventual fate. DUNE is an international world-class experiment dedicated to addressing these questions as it searches for leptonic charge-parity symmetry violation, stands ready to capture supernova neutrino bursts, and seeks to observe nucleon decay as a signature of a grand unified theory underlying the standard model. The DUNE far detector technical design report (TDR) describes the DUNE physics program and the technical designs of the single- and dual-phase DUNE liquid argon TPC far detector modules. Volume II of this TDR, DUNE Physics, describes the array of identified scientific opportunities and key goals. Crucially, we also report our best current understanding of the capability of DUNE to realize these goals, along with the detailed arguments and investigations on which this understanding is based. This TDR volume documents the scientific basis underlying the conception and design of the LBNF/DUNE experimental configurations. As a result, the description of DUNE's experimental capabilities constitutes the bulk of the document. Key linkages between requirements for successful execution of the physics program and primary specifications of the experimental configurations are drawn and summarized. This document also serves a wider purpose as a statement on the scientific potential of DUNE as a central component within a global program of frontier theoretical and experimental particle physics research. Thus, the presentation also aims to serve as a resource for the particle physics community at large.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Preliminary Design of the TEX-MOX Criticality Experimental Program using Optimization Algorithms Implemented in the IRSN PROMETHEE Tool

In the frame of its missions, IRSN is widely involved in design, evaluation and analyses of critical experiments in order to contribute to computer codes and nuclear data validation. The work described in this paper was carried out in the framework of the PRINCESS IRSN research project and is part of the IRSN/LLNL collaboration on the TEX program in the frame of the NCSP. The need for epithermal and intermediate energy range critical benchmarks is an established international criticality safety data need, underpinned by the subsequent use of data assimilation methods like GLLSM to reduce Nuclear Data uncertainties. The goal of the TEX program is to address this need by executing experiments with NCSP fissile assets, which can be used to create critical assemblies that span a wide range of fission energy spectra, from the thermal energy range (below 0.625 eV), through the intermediate energy range (0.625 eV to 100 keV), to the fast one (above 100 keV). The TEX program involves different materials of interest, such as TEX-Ta experiments using plutonium ZPPR plates proposed by LLNL. This paper presents an overview of the studies performed at IRSN using numerical optimization algorithms for the design of critical experiments involving Mixed U and Pu fuel plates, referred to as TEX-MOX program. This program ultimately aims to perform critical experiments to validate the MOX fuel configurations encountered in the MOX fuel fabrication process. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Two-Dimensional Neutronic and Fuel Cycle Analysis of the Transatomic Power Molten Salt Reactor

This status report presents the results from the first phase of the collaboration between Transatomic Power Corporation (TAP) and Oak Ridge National Laboratory (ORNL) to provide neutronic and fuel cycle analysis of the TAP core design through the Department of Energy Gateway for Accelerated Innovation in Nuclear, Nuclear Energy Voucher program. The TAP design is a molten salt reactor using movable moderator rods to shift the neutron spectrum in the core from mostly epithermal at beginning of life to thermal at end of life. Additional developments in the ChemTriton modeling and simulation tool provide the critical moderator-to-fuel ratio searches and time-dependent parameters necessary to simulate the continuously changing physics in this complex system. Results from simulations with these tools show agreement with TAP-calculated performance metrics for core lifetime, discharge burnup, and salt volume fraction, verifying the viability of reducing actinide waste production with this design. Additional analyses of time step sizes, mass feed rates and enrichments, and isotopic removals provide additional information to make informed design decisions. This work further demonstrates capabilities of ORNL modeling and simulation tools for analysis of molten salt reactor designs and strongly positions this effort for the upcoming three-dimensional core analysis.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Advanced Reactor Safeguards: 2022 Program Roadmap

The Advanced Reactor Safeguards (ARS) program was established in 2020 as part of appropriations for the Advanced Reactor Demonstration Program (ARDP) through the Office of Nuclear Energy in the Department of Energy. The goal of this program is to help address near term challenges that advanced nuclear reactor vendors face in meeting domestic Material Control and Accountancy (MC&A) and Physical Protection System (PPS) requirements for U.S. construction. The technical work in the program is meant to (1) support nuclear reactor vendors with advanced MC&A and PPS designs for next generation reactors, (2) provide technical bases for the regulator, and (3) promote the integration of Safeguards and Security by Design early in the design process. Existing domestic regulations for safeguards and security, as outlined in the Code of Federal Regulations, were written for large light water reactors, and rule-making efforts are underway to develop regulations more suited to different reactor designs. The ARS program seeks to remove roadblocks in the deployment of new and advanced reactors by solving regulatory challenges, reducing safeguards and security costs, and utilizing the latest technologies and approaches for robust plant monitoring and protection. This roadmap discusses the goals of the ARS program, current research, and program plan for the next five years.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Cellular fluidics

The natural world provides many examples of multiphase transport and reaction processes that have been optimized by evolution. These phenomena take place at multiple length and time scales and typically include gas–liquid–solid interfaces and capillary phenomena in porous media. Many biological and living systems have evolved to optimize fluidic transport. However, living things are exceptionally complex and very difficult to replicate, and human-made microfluidic devices (which are typically planar and enclosed) are highly limited for multiphase process engineering. In this paper, we introduce the concept of cellular fluidics: a platform of unit-cell-based, three-dimensional structures—enabled by emerging 3D printing methods—for the deterministic control of multiphase flow, transport and reaction processes. We show that flow in these structures can be ‘programmed’ through architected design of cell type, size and relative density. We demonstrate gas–liquid transport processes such as transpiration and absorption, using evaporative cooling and CO 2 capture as examples. We design and demonstrate preferential liquid and gas transport pathways in three-dimensional cellular fluidic devices with capillary-driven and actively pumped liquid flow, and present examples of selective metallization of pre-programmed patterns. Our results show that the design and fabrication of architected cellular materials, coupled with analytical and numerical predictions of steady-state and dynamic behaviour of multiphase interfaces, provide deterministic control of fluidic transport in three dimensions. Cellular fluidics may transform the design space for spatial and temporal control of multiphase transport and reaction processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advanced Reactor Safeguards & Security 2024 Program Roadmap

The Advanced Reactor Safeguards and Security (ARSS) program was established to provide research support addressing near term challenges that advanced nuclear reactor vendors face in meeting domestic Material Control and Accounting (MC&A), Physical Protection System (PPS), and Cybersecurity requirements for U.S. construction. The technical work in the program is meant to (1) support nuclear reactor vendors with advanced MC&A, PPS, and Cybersecurity designs for next generation reactors, (2) provide technical bases for the regulator, and (3) promote the integration of Safeguards and Security by Design early in the design process. Existing domestic regulations for safeguards and security, as outlined in the Code of Federal Regulations, were written for large light water reactors, and rule-making efforts are underway to develop regulations more suited to different reactor designs. The ARSS program seeks to remove roadblocks in the deployment of new and advanced reactors by solving regulatory challenges, reducing safeguards and security costs, and utilizing the latest technologies and approaches for robust plant monitoring and protection. This roadmap discusses the goals of the ARSS program, current research, and program plan for the next five years.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Preliminary Plan for Evaluation of Reactor Pressure Vessel Surveillance Materials from Palisades Nuclear Generating Station

The Palisades Nuclear Generating Station (PNGS), located in Michigan, is owned and operated by Entergy. It is a Combustion Engineering 2-loop pressurized water reactor (PWR) producing 805 MWe (2,565 MWth). The PNGS was built between 1967 and 1970, with approval to operate at full power in 1973; the plant’s original license was due to expire on March 24, 2011. An application for 20-year extension was filed in 2005 with the Nuclear Regulatory Commission and was granted on January 18, 2007. Although the plant was scheduled for decommissioning by 2031, Entergy currently plans to close the PNGS in 2022. The PNGS included in its reactor pressure vessel (RPV) surveillance program a capsule, designated A-60, containing specimens of one of the vessel plates and a weld metal with nickel content of about 1.36 wt% and copper content of about 0.20 wt%. This capsule was irradiated to a fluence of 1.8 x 10 20 n/cm 2 . The capsule was removed from its surveillance position in 1995 and has been resident in the spent fuel pool since that time. The material is also of special interest because of its very high nickel content and because of the potential for development of NiMnSi (nickel-manganese-silicon) precipitates, dubbed “late blooming phases.” The surveillance program also includes a capsule, designated T-150, dedicated specifically for thermal aging, which would provide results for at least 33 effective full power years, which is beyond the current thermal-aging database for such materials. Given that license extensions to 60 years of operation have been approved by the US Nuclear Regulatory Commission for most of the currently operating light water reactors in the United States, and that the first extension to 80 years was recently approved, there exists the probability that some RPVs will reach and possibly exceed a fast neutron fluence (> 1 MeV) of 1 x 10 20 n/cm 2 . This is a fluence regime with no US surveillance data and very little test reactor data, except for the Light Water Reactor Sustainability Program–sponsored University of California Santa Barbara Advanced Test Reactor (ATR) ATR-2 project. Thus, the materials in the A-60 capsule represent a valuable resource for directly exploring the effects of commercial surveillance irradiation on a typical plate and a high-nickel weld with similar materials irradiated in the ATR-2 test reactor project. This report provides background information for the surveillance program, previous results of surveillance materials testing, the preliminary plan for capsule retrieval and disassembly, and the plan for testing and microstructural examination of the mechanical test specimens of these unique materials to assess the features induced by very high irradiation fluence or very long thermal aging time

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Covered Product Categories (Fact Sheet)

Overview of the U.S. Department of Energy Federal Energy Management Program Energy-Efficient Product Procurement Program and its designated product category list.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

EVOLUTION OF SPACE REACTOR QUALIFICATION METHODS AND A PATH FORWARD FOR NEW SPACE REACTORS UNDER CONSIDERATION

These slides outline the evolution of space reactor system qualifications and provide a potential framework for qualification of current space reactor concepts. Qualification approaches for SNAP 10A, SP-100, TOPAZ II, and Prometheus reactor systems will be discussed. Several qualification approaches from past reactors will be reviewed including: a component qualification approach demonstrated in the SNAP reactor program, a system level approach in the SP-100 program, adding additional features to an existing design in the TOPAZ program, and a combination of a computational and basic testing approach for the Prometheus reactor. Past and present test facilities will also be discussed and the impact of test facility availability (or existence) is discussed. A suggested approach that complies with the updated Presidential Directive (NSPM-20, August 2019) that is derived from previous program approaches will be discussed for qualification of future space reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Solar Ready: An Overview of Implementation Practices

This report explores three mechanisms for encouraging solar ready building design and construction: solar ready legislation, certification programs for solar ready design and construction, and stakeholder education. These methods are not mutually exclusive, and all, if implemented well, could contribute to more solar ready construction.

14 SOLAR ENERGY↗

Sustained Energy Savings Achieved through Successful Industrial Customer Interaction with Ratepayer Programs: Case Studies

Many states have implemented ratepayer-funded programs to acquire energy efficiency as a predictable and reliable resource for meeting existing and future energy demand. These programs have become a fixture in many U.S. electricity and natural gas markets as they help postpone or eliminate the need for expensive generation and transmission investments. Industrial energy efficiency (IEE) is an energy efficiency resource that is not only a low cost option for many of these efficiency programs, but offers productivity and competitive benefits to manufacturers as it reduces their energy costs. However, some industrial customers are less enthusiastic about participating in these programs. IEE ratepayer programs suffer low participation by industries across many states today despite a continual increase in energy efficiency program spending across all types of customers, and significant energy efficiency funds can often go unused for industrial customers. This paper provides four detailed case studies of companies that benefited from participation in their utility’s energy efficiency program offerings and highlights the business value brought to them by participation in these programs. The paper is designed both for rate-payer efficiency program administrators interested in improving the attractiveness and effectiveness of industrial efficiency programs for their industrial customers and for industrial customers interested in maximizing the value of participating in efficiency programs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Implications of a regional resource adequacy program on utility integrated resource planning: Study for the Western United States

LBNL collaborated with the Western Interstate Energy Board and the University of Texas, Austin to investigate the implications of a regional resource adequacy (RA) program on utility integrated resource planning. This report is focused on an active policy discussion to develop a novel voluntary program to share capacity resource and improve RA in the Western Interconnection. This report identifies two RA components of IRP that will be highly impacted by a regional RA program: resource capacity accreditation and RA targets. There are at least four resources that will require specific attention for their capacity credit calculation: (1) variable renewable resources, (2) demand-side resources, (3) hydropower, and (4) contracts. It will then be necessary to decide on a RA target reliability metric (e.g., a planning reserve margin) that is at least the minimum requirement in IRPs to ensure consistency in RA requirement calculations. The report finds that load forecasting and transmission expansion analyses will be moderately impacted, but that most of IRP components will not be significantly impacted. The report includes (i) a review of traditional resource adequacy practices in IRP; (ii) a case study of an existing regional RA program that interacts with IRP (Southwest Power Pool) and (iii) an overview of the NWPP regional resource adequacy proposal that is the object of this work. This paper does not (1) advocate for or against a regional RA program for the NWPP, (2) make detailed design recommendations for this program, or (3) assess its benefits and costs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE Advanced Gas Reactor Fuel Development and Qualification Program

Breakdown of the DOE Advanced Gas Reactor Fuel Development and Qualification Program. Including discussion topics on TRISO technology Status Circa 2000, New Production Reactor (NPR) Fuel Experience, Fuel Qualification, US DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification Program, Initial AGR Program Reference HTGR Design, Fuel Qualification Approach, Fuel Performance Modeling, Fuel Fabrication, Selected AGR-1, AGR-2, and AGR-5/6/7 Fuel Property Means, AGR Program TRISO Fuel Key Performance Data, Irradiation Performance: Fission Gas R/B, Irradiation Testing Results, Kernel and Coating Behavior During Irradiation, Locating and Studying Failed Particles Greatly Improves Understanding of Fuel Performance, Fission Product Release from UCO Fuel Compacts: AGR-1 and AGR-2 Examples, HTGR Accident Safety Testing of TRISO Fuel, Evaluating Behavior During D-LOFC Accidents, Safety Test Results for US UCO Fuel, Particle Failure Evaluation, Fuel Performance Summary, Ongoing Work and Outstanding Data Needs, Core Oxidation, Industry Engagement, and Coated-Particle-Fueled Reactor Concepts and Fuel Designs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

SkyMine Beneficial CO 2 Use Project

This Final Report addresses accomplishments achieved during Phase 1 and Phase 2 of the SkyMine® Carbon Mineralization Commercial Scale Pilot Project. The primary objectives of this project were to design, construct, and operate a system to capture CO₂ from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO₂ into products having commercial value as an example of Carbon Capture and Beneficial Re-Use, show the economic viability of the CO₂ capture and conversion process, and thereby advance the technology to a level of commercial scale completion with the ability for further proliferation. The project also substantiates market opportunities for the technology by sales of chemicals into existing markets, and has identified opportunities to improve technology performance and reduce costs during the normal course of operations. The primary objectives of Phase 1 of the project were to elaborate proven SkyMine® process chemistry to commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2. During Phase 2, Pilot System Engineering Design, Construction and Testing, supporting research and development was conducted at a field test unit to collect data that aided in detailed designs of the commercial scale pilot unit; final detailed designs were completed; the commercial scale pilot plant is in its final stages of construction; and a test program has been designed and will be implemented to collect data from the facility to evaluate the technical viability of the process for resulting in an overall net reduction in CO 2 emitted into the atmosphere through a process that is run and conducted in a carbon negative manner. The objective of Phase 2b was to build the commercial scale pilot plant to be operated and tested in Phase 2c. By June 30, 2015, the plant was +99% constructed and completed.

54 ENVIRONMENTAL SCIENCES↗

DDE Design Status Report Nov 2011

The National Nuclear Security Agency Global Threat Reduction Initiative employs the Reduced Enrichment for Research and Test Reactors (RERTR) Fuel Development program to facilitate maturation of Low Enriched Uranium (LEU) fuel technology in order to enable conversion of High Power Research Reactors (HPRR) to LEU fuels. The RERTR Fuel Development program has overseen design, fabrication, irradiation, and examination of numerous tests on small to medium sized specimens containing LEU fuels. To enable the three nearest term HPRR conversions, including the Massachusetts Institutes of Technology Reactor (MITR), University of Missouri Research Reactor (MURR), and National Bureau of Standard Reactor (NBSR), the FD pillar is currently focused on qualification of the 'Base Monolithic Design'. The Base Monolithic Design consists of uranium-10 wt% molybdenum alloy (U-10Mo) in the form of a monolithic foil, with thin zirconium interlayers, clad in aluminum by hot isostatic press. The licensing basis of the aforementioned HPRR's restricts them from testing lead test elements of their respective LEU fuel element designs. In order to provide the equivalent of a lead test assembly, one Design Demonstration Experiment (DDE) is planned for each of the three NRC licensed reactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗