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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

Combustion of Interacting Droplet Arrays in a Microgravity Environment

Investigations into droplet interactions date back to Rex et al. Annamalai and Ryan and Annamalai published extensive reviews of droplet array and cloud combustion studies. In the majority of the reviewed studies, the authors examined the change in the burning rate constant, k, (relative to that of the single droplet) that results from interactions. More recently, Niioka and co-workers have examined ignition and flame propagation along arrays of interacting droplets with the goal of relating these phenomena in this simplified geometry to the more practical spray configuration. Our work has focussed on droplet interactions under conditions where flame extinction occurs at a finite droplet diameter. In our previous work, we reported that in normal gravity, reduced pressure conditions, droplet interactions improved flame stability and extended flammability limits (by inference). In our recent work, we examine droplet interactions under conditions where the flame extinguishes at a finite droplet diameter in microgravity. The microgravity experiments were in the NASA GRC 2.2 and 5.2 second drop towers, and the JAMIC (Japan Microgravity Center) 10 second drop tower. We also present progress on a numerical model of single droplet combustion that is in the process of being extended to model a binary droplet array.

Dietrich, D. L.↗

The Performance of Advanced III-V Solar Cells

Test results show triple junction solar cells with efficiencies as high as 27% at 28C and 136.7 mw/sq cm. Triple junction cells also achieve up to 27.5% at -120 C and 5 mw/sq cm, conditions applicable to missions to Jupiter. Some triple junction cells show practically no degradation as a result of Low Intensity Low Temperature (LILT) effects, while others show some; this degradation can be overcome with minor changes to the cell design.

Mueller, Robert L.↗

Maintaining Situation Awareness with Autonomous Airborne Observation Platforms

Unmanned Aerial Vehicles (UAVs) offer tremendous potential as intelligence, surveillance and reconnaissance (ISR) platforms for early detection of security threats and for acquisition and maintenance of situation awareness in crisis conditions. However, using their capabilities effectively requires addressing a range of practical and theoretical problems. The paper will describe progress by the "Autonomous Rotorcraft Project," a collaborative effort between NASA and the U.S. Army to develop a practical, flexible capability for UAV-based ISR. Important facets of the project include optimization methods for allocating scarce aircraft resources to observe numerous, distinct sites of interest; intelligent flight automation software than integrates high-level plan generation capabilities with executive control, failure response and flight control functions; a system architecture supporting reconfiguration of onboard sensors to address different kinds of threats; and an advanced prototype vehicle designed to allow large-scale production at low cost. The paper will also address human interaction issues including an empirical method for determining how to allocate roles and responsibilities between flight automation and human operations.

Freed, Michael↗

Plasma Environments and Spacecraft Charging for Lunar Programs

Space systems interacting with the space plasma environment charge to potentials of a few tens of volts positive in interplanetary space or on the lunar surface in daylight, a few hundred volts negative in the dark lunar plasma wake and in some regions of the Earth s radiation belts, and to multiple kilovolt negative potentials for worst case conditions in the Earth s magnetosphere near geostationary orbit. Good design practices are required to assure that space systems operate successfully in these environments without detrimental effects due to transient currents and insulator failure produced by electrostatic discharges. Cold lunar environments in particular are challenging because detrimental effects of charging are often exacerbated by cold, highly resistive dielectrics which can integrate charge for long periods of time. We will describe the cold plasma and energetic particle environments relevant to lunar missions responsible for surface and bulk charging of space systems and discuss program requirements under development for assuring that systems operate successfully in these environments.

Minow, Joseph I.↗

A Formal Approach to Empirical Dynamic Model Optimization and Validation

A framework was developed for the optimization and validation of empirical dynamic models subject to an arbitrary set of validation criteria. The validation requirements imposed upon the model, which may involve several sets of input-output data and arbitrary specifications in time and frequency domains, are used to determine if model predictions are within admissible error limits. The parameters of the empirical model are estimated by finding the parameter realization for which the smallest of the margins of requirement compliance is as large as possible. The uncertainty in the value of this estimate is characterized by studying the set of model parameters yielding predictions that comply with all the requirements. Strategies are presented for bounding this set, studying its dependence on admissible prediction error set by the analyst, and evaluating the sensitivity of the model predictions to parameter variations. This information is instrumental in characterizing uncertainty models used for evaluating the dynamic model at operating conditions differing from those used for its identification and validation. A practical example based on the short period dynamics of the F-16 is used for illustration.

Crespo, Luis G↗

Uncertainty Quantification of Expected Time-of-Arrival in UAV Flight Trajectory

One of the foremost requirements for accurate in-flight safety monitoring of autonomous unmanned aerial vehicles (UAVs) is tracking of their flight trajectory. Existing UAVs leverage autonomous flight functionalities based on trajectory generation algorithms developed in robotic applications such as polynomial or spline curves in order to facilitate kinematic smoothness, minimum vibrations and fuel efficiency. However in practice, the actual path may be subjected to unexpected local weather conditions, unexpected obstacles along the path or abrupt traffic changes in the low-altitude airspace resulting in large errors of the predicted time-of-arrival at way-points. In this study, an approach to quantify and propagate uncertainty in 4D trajectories is proposed. The paper presents a simple error interval propagation method based on the expected cruise speed of the UAV and its associated uncertainty. The uncertainty is then propagated in time to estimate reasonable confidence intervals on the times-of-arrival of the vehicle at each way-point as well as along the entire flight-path. The uncertainty propagation is demonstrated on a state-of-the-art trajectory generation algorithm based on non-uniform rational B-spline (NURBS) curves. Further, the effect of a stationary wind field is incorporated in the uncertainty propagation approach. The proposed method is implemented on synthetic and real data obtained from flight experiments with a small UAV.

Uncertainty Quantification↗

Failure Behavior and Control-Based Mitigation for a Parallel Hybrid Propulsion System

NASA is pursuing research to advance Electrified Aircraft Propulsion (EAP) technologies that address fuel burn and emission reduction goals. EAP brings the potential for improved performance over the state of the art. However, for these systems to be practical and certifiable, they need to possess adequate robustness to adverse conditions including a variety of system failures that are not applicable to conventional turbofans today. Numerous EAP concepts interface gas turbine engines with an electrical power system that includes electric machines and sometimes electrical energy storage. The expansion of the powertrain increases the probability of encountering a failure and introduces new failure modes. Failures within the electrical power system may also impact the gas turbine engine(s) to which the electrical powertrain is coupled. This effort investigates failures originating in the electrical power system and their impact on the parallel hybrid propulsion system. Reversionary control strategies are also demonstrated to reduce the impact of the failures. Failure mitigation strategies were devised and employed in simulation. Various failure scenarios were simulated including those occurring during steady state operation, transients, and takeoff and landing scenarios. The timing of the failure and delay in failure identification and activation of mitigation strategies are noteworthy variables in the study. While the system remained stable throughout all failure scenarios, delays in failure identification could result in undesirable conditions such as increased operating temperatures and reduced stall margin. The results demonstrate successful mitigation of failures through reversionary control modes and help to generate confidence in the robustness of the conceptual parallel hybrid propulsion system.

Failure behavior↗

Failure Behavior and Control Based Mitigation for a Parallel Hybrid Propulsion System

NASA is pursuing research to advance Electrified Aircraft Propulsion (EAP) technologies that address fuel burn and emission reduction goals. EAP brings the potential for improved performance over the state of the art. However, for these systems to be practical and certifiable, they need to possess adequate robustness to adverse conditions including a variety of system failures that are not applicable to conventional turbofans today. Numerous EAP concepts interface gas turbine engines with an electrical power system that includes electric machines and sometimes electrical energy storage. The expansion of the powertrain increases the probability of encountering a failure and introduces new failure modes. Failures within the electrical power system may also impact the gas turbine engine(s) to which the electrical powertrain is coupled. This effort investigates failures originating in the electrical power system and their impact on the parallel hybrid propulsion system. Reversionary control strategies are also demonstrated to reduce the impact of the failures. Failure mitigation strategies were devised and employed in simulation. Various failure scenarios were simulated including those occurring during steady state operation, transients, and takeoff and landing scenarios. The timing of the failure and delay in failure identification and activation of mitigation strategies are noteworthy variables in the study. While the system remained stable throughout all failure scenarios, delays in failure identification could result in undesirable conditions such as increased operating temperatures and reduced stall margin. The results demonstrate successful mitigation of failures through reversionary control modes and help to generate confidence in the robustness of the conceptual parallel hybrid propulsion system.

Failure behavior↗

Synergistic Retrievals of Ice in High Clouds From Elastic Backscatter Lidar, Ku-band Radar and Submillimeter Wave Radiometer Observations

In this study, we investigate the synergy of elastic backscatter lidar, Ku-band radar, and sub-millimeter-wave radiometer measurements in the retrieval of ice from satellite observations. The synergy is analyzed through the generation of a large dataset of IceWater Content (IWC) profiles and simulated lidar, radar and radiometer observations. The characteristics of the instruments e.g. frequencies, sensitivities, etc. are set based on the expected characteristics of instruments of the Atmosphere Observing System (AOS) mission. A hold-out validation methodology is used to assess the accuracy of the IWC profiles retrieved from various combinations of observations from the three instruments. Specifically, the IWC and associated observations are randomly divided into two datasets, one for training and the other for evaluation. The training dataset is used to train the retrieval algorithm, while the evaluation dataset is used to assess the retrieval performance. The dataset of IWC profiles is derived from CloudSat reflectivity and CALIOP lidar observations. The retrieval of the ice water content IWC profiles from the computed observations is achieved in two steps. In the first step, a class, out of 18 potential classes characterized by different vertical distribution of IWC, is estimated from the observations. The 18 classes are predetermined based on the k-Means clustering algorithm. In the second step, the IWC profile is estimated using an Ensemble Kalman Smoother (EKS) algorithm that uses the estimated class as a priori information. The results of the study show that the synergy of lidar, radar, and radiometer observations is significant in the retrieval of the IWC profiles. Nevertheless, it should be mentioned that this synergy was found under idealized conditions, and additional work might be required to materialize it in practice. The inclusion of the lidar backscatter observations in the retrieval process has a larger impact on the retrieval performance than the inclusion of the radar observations. As ice clouds have a significant impact on atmospheric radiative processes, this work is relevant to ongoing efforts to reduce uncertainties in climate analyses and projections.

Mircea Grecu↗

Jemez Pueblo Agriculture: Monitoring Rangeland Conditions to Inform Drought and Land Management in New Mexico

The Jemez Pueblo, a community located in the semi-arid high desert region of northcentral New Mexico, faces challenges with drought mitigation and livestock management. NASA DEVELOP partnered with the Pueblo of Jemez Natural Resources Department and The Nature Conservancy to provide recent and historical rangeland conditions to aid present decision-making, which relies on cultural practices, site familiarity, available resources, and physical data. This partnership offers the opportunity to support management practices by leveraging remote sensing and virtual fencing technologies. Our project explored Rangeland Analysis Platform (RAP) products incorporating NASA Earth observation Landsat 5 TM, Landsat 7 ETM+, Landsat 8 OLI, and Landsat 9 OLI-2 remote-sensed imagery as an agricultural land management tool. We performed linear regression analysis to evaluate RAP data to field data and explored RAP annual herbaceous biomass, ground cover trends, and climatic factors at the pasture level. We then computed study area summary statistics, performed pixel-by-pixel trend analysis across the study period, and evaluated ground cover trends near water sources. Based on available data, RAP was poorly correlated to bare ground and herbaceous biomass, generally underestimating the former and overestimating the latter. To improve the evaluation of RAP products, we suggest increasing the spatiotemporal distribution of the field dataset. According to RAP, from 1986 to 2023, the site became hotter and drier, bare ground increased, and annual forbs and grasses increased while perennials decreased. RAP products did not agree with field-collected data; however, the trends over time may be useful for informing rangeland management actions.

cattle grazing management↗

Development of a One-Domain Volume-Averaged Navier–Stokes Solver

The interaction between a high-enthalpy flow and a thermal protection material is inherently multiscale and multiphysics. In conventional aerothermal analyses, the external flow and material response are generally modeled using separate computational domains coupled through boundary conditions at the material surface. Although this approach has supported many practical applications, it requires assumptions about the location and behavior of the interface and may become difficult to apply when material decomposition, internal reactions, and surface recession substantially alter the porous structure. This report presents the development of a one-domain formulation in which the free-fluid and porous-material regions are represented within a single computational domain. The formulation is based on the volume-averaged Navier–Stokes (VANS) equations, derived from the governing equations for reacting, compressible flow and condensed material. Volume averaging transfers the influence of the unresolved material microstructure to the macroscale equations through effective transport properties, interfacial source terms, and dispersion fluxes. Particular attention is given to regions in which porosity and permeability vary rapidly, including the diffuse transition between a porous material and the surrounding fluid. The resulting equations are implemented in the Porous-material Analysis Toolbox based on OpenFOAM (PATO). The report describes the pressure–velocity coupling strategy used by the solver, examines spatial filtering techniques for deriving effective properties, and evaluates the influence of a smoothly varying interface permeability. Numerical demonstrations include canonical porous-flow configurations, a flow-tube configuration representative of FiberForm® permeability experiments, and the oxidation of a porous carbon material. The purpose of this work is to establish a mathematical and computational foundation for a unified treatment of flow and thermal protection material response. The present formulation is intended to support the progressive inclusion of additional physical processes, including multicomponent transport, finite-rate gas–surface chemistry, pyrolysis, internal oxidation, and material recession. It also provides a framework for connecting pore-scale simulations and microstructural characterization with macroscale aerothermal-response calculations. This report is intended for researchers and engineers working in computational fluid dynamics, porous-media transport, material response, and thermal protection system modeling. It documents both the theoretical development and the initial numerical assessment of the one-domain approach, while identifying the closure of effective and dispersion terms as an important subject for continued investigation.

Ablation↗

Flight Tests on U.S.S. Los Angeles. Part II : Stress and Strength Determination

The tests described in this report furnished data on the actual aerodynamic forces, and the resulting stresses and bending moments in the hull of the U. S. S. "Los Angeles" during as severe still-air maneuvers as the airship would normally be subjected to, and in straight flight during as rough air as is likely to occur in service, short of squall or storm conditions. The maximum stresses were found to be within the limits provided for in accepted practice in airship design. Normal flight in rough air was shown to produce forces and stresses about twice as great as the most severe still-air maneuvers. No light was thrown upon the forces which might occur in extreme or exceptional conditions, such as the storm which destroyed the "Shenandoah". The transverse aerodynamic forces on the hull proper were found to be small and irregular. Owing to the necessity of conserving helium, it was impossible to fly the airship in a condition of large excess of buoyancy or weight in order to determine the air pressure distribution at a fixed angle of pitch. However, there is every reason to believe that in that condition the forces on the actual airship are as close to the wind-tunnel results as can be determined by present type of pressure measuring apparatus. It is considered that most important data obtained are the coefficients of tail-surface forces and hull-bending moments. These are tabulated in this report.

Burgess, C P↗

Failure Analysis for Molten Salt Thermal Energy Storage Tanks for In-Service CSP Plants

Thermal Energy Storage (TES) is a fundamental component in concentrating solar power (CSP) plants to increase the plant's dispatchability, capacity factor, while reducing the levelized cost of electricity. In central receivers CSP plants, nitrate molten salts have been used for several years for operation temperatures of up to 565 degrees C. Despite many efforts to advance nitrate salt to higher operation temperatures (even considering a replacement with molten chloride salts) to achieve higher energy conversion efficiencies, the 565 degrees C temperature is currently considered the state-of-the art. Although molten salt tanks have been broadly deployed in commercial CSP plants worldwide, several failures have been reported in these tanks after a few months or years of operation, causing significant economic loss and mistrust in CSP technologies. Most of these failures are associated with the infancy of the technology and multiple issues related to tank design, fabrication, commissioning, and aggressive operation. A technical standard dedicated to the design and fabrication of molten nitrate TES tanks does not exist today. Current in-service molten salt tanks have been generally designed based on the American Petroleum Institute's (API) 650 and ASME Section II standards. The API 650 code provides guidelines for dimensions and fabrication for oil storage tanks up to 260 degrees C. The ASME standard provides allowable stress values for various materials at a range of temperatures and conditions. Both standards seem to be limited for molten salt TES tanks where high temperatures, thermal cycling, and transient conditions are expected. In 2020, NREL released the Concentrating Solar Power Best Practices Study (NREL/TP-5500-75763) that summarized multiple issues in CSP plants, along with potential alternatives and recommendations to address those issues based on information collected from participants representing about 80% of operating CSP plants in the world. One of the recommendations from this study was the development of accurate and validated models to evaluate the plant's transient operation, capable of capturing the effect of short-term clouds and operator response, while being flexible in being adapted to various spatial and temporal resource data. The "Failure Analysis for Molten Salt Thermal Energy Tanks for In-Service CSP Plants" project was inspired on this recommendation and was focused on (1) the development and validation of a physics-based model for a representative, commercial-scale molten salt tank, (2) performing simulations to evaluate the behavior of the tank as a function of typical plant operation conditions, (3) understanding tank failures mechanisms, (4) determining the residual stress and distortion in the tank floor after welding fabrication and evaluating their impact in the stresses developed in the tank during operation, (5) assessing the impact of key operation parameters on the temperature and stress distribution, (6) conduct a preliminary evaluation of design features to reduce stress and improve tank's reliability, and (7) estimate the tank's service life based on the stress developed under diverse operation scenarios. From the analysis conducted in the project and presented in this report, it was found that maximum stresses surpassing the yield strength point of the stainless steel (SS) 347H are developed on the tank floor near the perimeter. These large stresses are strongly influenced by the initial residual stresses and distortion of the tank floor after welding fabrication. During operation, large stresses are developed in the tank floor at high operation temperatures with large salt inventory levels during transient operation. High stresses are also related to elevated temperature gradients in the tank floor that could be attributed to insufficient mixing within the salt inflow and the salt inventory. Based on the analysis, creep is the predominant failure mechanism. However, the large stress levels could favor the plastic deformation into buckles, and crack formation due to stress relaxation cracking during cycle operation. A lifetime below 3 years was estimated for the typical plant operation conditions and a specific initial residual stress and deformation distribution of the tank floor. The estimated life agrees with the service time to failure reported in several commercial molten salt tanks. Desing and operation guidelines can be extracted from the analysis presented in this report, which could be adopted by tank manufacturers and CSP operators to advance toward an ultimate solution for tank failures by reducing residual and operational stresses to achieve a tank service life of more than 30 years. Addressing failures in molten salt TES tanks is fundamental for the CSP industry's survivability, but it is also important for other industrial and power generation applications using this technology, including nuclear and concentrating solar thermal.

14 SOLAR ENERGY↗

Device-Level Multidimensional Thermal Dynamics With Implications for Current and Future Wide Bandgap Electronics

Researchers have been extensively studying wide-bandgap (WBG) semiconductor materials such as gallium nitride (GaN) with an aim to accomplish an improvement in size, weight, and power of power electronics beyond current devices based on silicon (Si). However, the increased operating power densities and reduced areal footprints of WBG device technologies result in significant levels of self-heating that can ultimately restrict device operation through performance degradation, reliability issues, and failure. Typically, self-heating in WBG devices is studied using a single measurement technique while operating the device under steady-state direct current measurement conditions. However, for switching applications, this steady-state thermal characterization may lose significance since the high power dissipation occurs during fast transient switching events. Therefore, it can be useful to probe the WBG devices under transient measurement conditions in order to better understand the thermal dynamics of these systems in practical applications. In this work, the transient thermal dynamics of an AlGaN/GaN high electron mobility transistor (HEMT) were studied using thermoreflectance thermal imaging and Raman thermometry. Also, the proper use of iterative pulsed measurement schemes such as thermoreflectance thermal imaging to determine the steady-state operating temperature of devices is discussed. These studies are followed with subsequent transient thermal characterization to accurately probe the self-heating from steady-state down to submicrosecond pulse conditions using both thermoreflectance thermal imaging and Raman thermometry with temporal resolutions down to 15 ns.

42 ENGINEERING↗

An Innovative Insight into Performance Degradation of NCM111 Cathode Induced by Suspension of Operation

The lifespan of lithium-ion batteries varies enormously from fundamental study to practical applications. This big difference has been typically ascribed to the high degree of uncertainty in unpredictable and complicated operation conditions in real-life applications. Here, in this paper, we report that the pause of the charging–discharging process, which is frequently operated in practice but rarely studied in academics, is an important reason for the performance degradation of the NCM111 cathode. It is found that the pause during cycling could trigger a remarkable drop in capacity, giving rise to ~30% more capacity decay compared with the continuously cycled sample. In situ synchrotron X-ray diffraction analysis reveals that the harmful H1–H2 phase transition, which typically appears in the initial cycle but disappears in subsequent cycles, is reactivated by the pausing process. The anisotropic lattice strains that occur during the H1–H2 transition result in mechanical fractures that terminate with an inert NiO-type rock-salt phase on the surface of particles. The present study indicates that the discontinuous usage of rechargeable batteries is also a key factor for cycle life, which might provide a distinct perspective on the performance decay in practical applications.

25 ENERGY STORAGE↗

Stirred-Reactor Coupon Analysis: An International Round Robin Study

The objective of this task was to determine the precision of the SRCA technique when used to determine the dilute condition corrosion rate. To this end, an interlaboratory round robin study was conducted per the instructions in ASTM Practice E691 to measure the precision with which the SRCA test method can be conducted. Twelve independent labs from eleven different institutions each evaluated four glass compositions in three different conditions. The ASTM procedures recommend at least 6 labs participate in a round robin testing the same 3 materials in the same conditions to determine precision. In this case, 12 labs each performed 12 independent tests. This was only possible thanks to the multi-glass testing capability of the SRCA test. A total of 108 duplicate pairs were used to calculate the repeatability of the tests, with the same glass tested in the same vessel, producing as identical conditions as possible for the replicates. These test results were quite tightly clustered, with a median difference from the average value of the pair of only 2.9%. Based on the calculations outlined in ASTM E177-20 and a measured standard deviation of 4.74%, the intralaboratory repeatability limit (r) was calculated to be within 13.3% of the expected value with 95% confidence level. The reproducibility limit (R) of the test was examined using all 277 data points from the round robin. Because of the differences in dissolution rates due to pH variability and intrinsically for the 12 conditions tested, the reproducibility limits for each condition and overall were calculated from the percent relative residual value for each test. The SRCA test is expected to be reproducible within 64% of the expected value with a 95% confidence level.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Rigor and Reproducibility in Electrocatalysis: Best Practices for Operando Studies

Operando measurements have rapidly expanded the scope of electrocatalysis by enabling direct observation of catalytic interfaces under working conditions and by linking structural, compositional, and spectroscopic observables to activity and selectivity. However, the growth of operando methods has outpaced the adoption of broadly shared experimental standards, creating persistent challenges in reproducibility, interpretation, and comparison across laboratories and platforms. This perspective synthesizes discussions from the 2025 National Science Foundation Workshop on Rigor and Reproducibility in Electrocatalysis and outlines a practical framework for the rigorous use of operando measurements in electrocatalysis. We highlight three recurring needs: careful implementation of complex methods to avoid overinterpretation; recognition that (subtle) differences in reactor architecture, hydrodynamics, and electrical boundary conditions can alter apparent kinetics and selectivity; and transparent reporting standards that enable meaningful cross-comparison without constraining measurement-specific cell innovation. Focusing on widely used techniques (including X-ray and vibrational spectroscopies, mass spectrometry, and electron microscopy), we discuss technique-specific pitfalls, cross-validation strategies, and recurring platform-agnostic considerations such as mass transport, current distribution, temporal-resolution mismatches, and catalyst evolution. This Perspective aims to strengthen the mechanistic inference and improve the reproducibility, comparability, and predictive value of operando electrocatalysis research.

X-ray absorption spectroscopy↗

Unveiling the support effect in Pt-based catalysts for the selective catalytic oxidation of NH 3 under realistic diesel engine conditions

Pt catalysts have been widely used for the selective catalytic oxidation of NH 3 (NH 3 -SCO) in practical applications due to their high activity at low temperatures. However, more stringent regulations require further enhancement of low-temperature NH 3 -SCO activity. In this study, we investigated the influence of different supports, including aluminum oxide (Al 2 O 3 ), silica (SiO 2 ), and chabazite (CHA), on the NH 3 -SCO performance of Pt catalysts. Furthermore, our findings demonstrate that the Pt/CHA catalyst exhibited superior NH 3 -SCO performance under realistic diesel engine conditions, characterized by high space velocity and the presence of water vapor. Notably, the Pt/CHA catalyst achieved a significantly lower T 50 (temperature at which 50% NH 3 conversion is achieved) of 218 °C under conditions with both CO 2 and H 2 O, with a 56 °C reduction compared to the state-of-the-art Pt/Al 2 O 3 catalyst. The exceptional NH 3 -SCO performance is attributed to the high abundance of metallic Pt 0 species and the presence of rich and stable acid sites that facilitate NH 3 adsorption and activation. Furthermore, these results highlight CHA as a promising support for the Pt catalyst in NH 3 -SCO applications for diesel engine emission control.

36 MATERIALS SCIENCE↗