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Big Sky Regional Carbon Sequestration Partnership (Phase III Final Scientific/Technical Report)

The Big Sky Carbon Sequestration Partnership (BSCSP) pursued a Phase III demonstration project at Kevin Dome in north central Montana. Kevin Dome covers approximately 700 square miles and is a naturally occurring CO 2 reservoir that is flanked by oil and gas fields. The carbon dioxide (CO 2 ) is in the upper Devonian Duperow (carbonate) formation and does not reach the spill point of the dome; therefore, the dome has potential as a CO 2 sequestration reservoir, a CO 2 supply, or as both if anthropogenic sources and enhanced oil recovery (EOR) operations are associated with the dome. Kevin Dome could potentially act as a buffer to continue accepting anthropogenic CO 2 when EOR flooding operations are interrupted or completed. The project objective was to produce one million tonnes of CO 2 from the gas cap of Kevin Dome, pipe it laterally, inject, and re-store it in the brine leg of the same formation to test the hub / buffer storage concept. This was to be accomplished by drilling up to five production wells, building a short pipeline and compression facilities, and drilling an injection well and several monitoring wells. BSCSP commenced outreach and site characterization activities including acquiring baseline data for near-surface insurance monitoring, acquiring 3-dimensional, 9-component surface seismic over the project area, drilling two test wells (one in the production area and one in the injection area), coring key intervals, and performing comprehensive logging. Well tests of those wells revealed two barriers to the project. The production (Danielson 33-17) well was perforated in multiple zones but failed to produce any significant CO 2 . This was despite being drilled in the near vicinity of a historic well that had produced 3700 MCF per day in a drill stem test. Modeling indicated that this was likely due to a phase change during production causing a temperature drop resulting in hydrate and/or water ice formation that clogged the formation. Tests of the injection zone (Wallewein 22-1) well indicated total dissolved solids (TDS) slightly below the EPA required 10,000 parts per million (ppm) for a Class VI underground injection control permit. While the project was initiated before Class VI rules were promulgated, and this was an experimental project (seemingly qualified for a Class V permit), the Environmental Protection Agency (EPA) indicated that injection would require a Class VI permit. The low salinity result was unexpected as contours plotted based on regional formation water quality data indicated an expected TDS above 20,000 ppm, and wells between the recharge zone and the Wallewein well tested above 10,000 ppm. Faced with the inability to obtain an injection permit, the demonstration project could not proceed. However, the project had generated valuable samples and data on a large natural analog including 32 sq. mi. of 3-D, 9-C seismic, 430 ft. of carbonate core covering seven different depositional environments taken from areas with, and without the presence of CO 2 , 30 ft. of core of two caprocks, a tight carbonate and an anhydrite, a full set of modern logs on both wells, and well tests. DOE decided to re-scope the project around completing studies utilizing this data. This report covers both the initial scope and the re-scope (Task / Section numbers preceded with an R). While the report covers a wide range of project activities, highlights of this work include: Development of a geostatic model using neural nets to match well logs to facies and using multi-waveform seismic to inform reservoir heterogeneity; Unique mechanical testing of permeability – stress relationship in two caprock materials; Development of full waveform inversion to generate a high resolution velocity model; Model development for dual permeability (fracture and matrix) systems to better account for matrix-matrix interactions; Joint seismic wave inversion (including the first quadr-joint inversion) exhibiting better imaging of a challenging reservoir zone in stiff rock; Core flow and core flood results on a reactive carbonate; and Innovative laboratory measurements of seismic response of fractured core as a function of fluid fill.

54 ENVIRONMENTAL SCIENCES↗

Andra's strategy and approach for operational safety of French underground facility Cigeo - 15127

According to the French Act on radioactive waste of 28 June 2006, Andra shall design a reversible repository. In response to this demand, Andra is developing the industrial project namely 'Cigeo', a reversible geological disposal facility for HLW and ILW located in Meuse/Haute-Marne. The previous safety cases of 2005, 2009 and 2012 give a sound basis to assess Cigeo's safety both for the operational and post-closure periods. Regarding operational safety, in this new stage of the project, the challenging issues for the preparation of the safety case are the following: - To adapt the various regulatory frameworks (nuclear and non-nuclear) to the underground facility - To design the underground facility and handling equipment's to reduce at first risks in the underground facility as such radioactive particles release, gas explosion, fire and co-activity and limit their consequence. - To establish waste acceptance criteria to be fulfilled by waste producers in line with operational safety and design options. The objective of the paper is to present the experience of Andra in operation safety of the underground facility of Cigeo. Operational safety for Cigeo is assessed as much as possible according to the existing French regulations and guidance for nuclear facilities. Indeed, compared to existing nuclear facilities, a geological repository is a specific case due to the existence of underground facilities with particularities such as: - ventilation management in a large scale underground facility, - fire risk management. As an input for the industrial design of Cigeo for operation, Andra defined a fire guidance and a specific reference safety guidance, based on the adaptation of the French nuclear regulatory texts for and when feasible to mines and tunnels regulatory texts and on its own experience gained through safety operational reports since 2005 and their reviews by the Safety Authority. - underground co-activity of nuclear operation with construction works. According to the common 'defense-in depth' principle for nuclear facilities, these guidelines for the industrial design of Cigeo for operation consider the successive levels of defense of: - Preventing the risk and its spreading by design and construction; - Detecting incidents and early fighting by design and operation dispositions (detection and control systems, survey procedure); - Controlling incidents and limiting of their consequences by safeguarding systems, specific procedures. At that stage, design options for Cigeo constitute an adequate response to the operational safety functions and requirements: - Two levels of containment are set up: the first one is ensured by the waste package, the second one is ensured from the surface facility to the disposal vaults by the transfer cask during the transfer of waste packages in the disposal vaults by the disposal vault itself and a nuclear ventilation with HEPA filter; - Favorable options for fire risk prevention and mitigation: transport system minimizing heat load (cable car for the transfer from the surface, electric transfer engines), twin access tunnels to ease fire-fighting and evacuation...; - Permanent complete physical separation of nuclear zone and construction zone (including ventilation systems). In practice, operation safety assessment of Cigeo, designed following the aforesaid reference safety guidelines, follows a common risk analysis (internal aggressions such as auxiliary losses, chemical and toxic risks, fall or collision, fire, human factors and external aggressions such as earthquake, air traffic, flooding) with the following steps: - Identification of the major risks and the design basis scenarios that have to be considered for dimensioning of the installations and the safety devices; - On the basis of these different situations, those who will have to be quantified are identified; one or more representative and envelop situations are chosen in order to evaluate robustness of the installation. Quantitative evaluation of these situations permits to: - identify the consequences on man, environment and installation, and in particular to gain confidence in the maintaining of the safety functions; - identify or define the technic and/or organisational dispositions classified as 'important elements for protection' (IEP); - Situations beyond dimensioning permit to verify the robustness of the installation. They permit, on one hand to identify possible complementary material or organisational dispositions; on the other hand, to define the 'hard core' i.e. structures, systems and components that permit to maintain the confinement function of radioactive substance. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Deactivation and Demolition (D and D) of the Toxic Substance Control Act (TSCA) Incinerator Oak Ridge, Tennessee - 19184

UCOR, an AECOM-led partnership with Jacobs, manages the cleanup of the 2,200-acre East Tennessee Technology Park for its client, the U.S. Department of Energy (DOE), in Oak Ridge, Tennessee. The site was contaminated with radioactive, hazardous and industrial wastes generated by more than 40 years of national defense and energy missions. In 1989, the U.S. Environmental Protection Agency (EPA) added the Oak Ridge Reservation to the National Priorities List of sites and facilities that pose a sufficient threat to human health or the environment to warrant cleanup. The U.S. Department of Energy is cleaning up the Oak Ridge Reservation under a Federal Facility Agreement with the EPA and the Tennessee Department of Environment and Conservation. Many types of waste have been managed and disposed as part of the multi-decade cleanup effort. One unique facility, the Toxic Substance Control Act (TSCA) Incinerator, was constructed at the Department of Energy's Est Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee. The Incinerator was constructed in the mid-1980's and underwent a series of test burns and readiness reviews to obtain the necessary environmental permits and operating approvals from state and federal regulatory agencies. With these in place, the incinerator began routine operations in 1991. It was designed and permitted for receiving, sorting, storing, preparing, and thermally destroying low-level radioactive and RCRA mixed waste contaminated with PCBs. The incinerator was named after a law passed in 1976 that provides the U.S. Environmental Protection Agency with authority to require reporting, record-keeping, testing, and restrictions relating to chemical substances and/or mixtures. During its operating lifetime, the one-of-a-kind thermal treatment facility burned materials regulated under TSCA and the Resource Conservation and Recovery Act (RCRA), most notably radiologically-contaminated polychlorinated biphenyls (PCBs). The TSCA Incinerator met or exceeded environmental regulations and DOE requirements for the treatment of these types of wastes. After more than 18 years of operation and more than 35 million pounds of waste safely incinerated, the TSCA Incinerator shut down operations on December 2, 2009. The TSCA Incinerator has been called a national resource for DOE sites from coast to coast. As the only U.S. facility permitted to incinerate specialized types of wastes, it not only accepted material from the Oak Ridge Reservation but also other facilities across the nationwide DOE complex. Over the years, a dynamic team of hard working and talented people operated and maintained the facility under the most stringent environmental permits and site requirements. The facility has played a key role in the treatment of radioactive PCB and hazardous wastes (mixed wastes) from the Oak Ridge Reservation, as well as from other facilities across the DOE complex. Through its support to over 20 sites in the DOE complex, environmental waste from past and ongoing operations has been safely and permanently treated. In the years since it was shut down, deactivation workers have been preparing TSCA for demolition. This work scope included triple cleaning, rinsing of all production equipment and tanks to RCRA clean criteria, filling sumps, encapsulating PCB and radioactive contamination, removal of universal waste (asbestos. lead and mercury), draining and disposal of residual water in tanks and transfer piping, and removing and disposing of carbon vessels, which were part of the water management system. In 2018, the facility was successfully deactivated and demolished, permanently removing one of the most unique facilities in the DOE complex. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Efficient Mesofluidic Separation of Large Particles in nuclear slurries - 20408

Efficient and effective particle separation is essential to cleanup of many nuclear wastes. For example, particle separation may be used to accelerate settle-decant bottlenecks that limit the throughput necessary to achieve the U.S. Department of Energy waste cleanup mission in a timely manner. Particle separation may be used to protect downstream processing equipment from pulses of solids that may be encountered near (within a few feet of) liquid-solid interfaces during waste transfer operations, thereby preventing work stoppages. Effective particle separation may permit efficient sludge washing. These are only a few of the ways in which particle separation is important. Yet, efficient and effective particle separation in nuclear processing environments remains challenging. For example, settle-decant operations permit larger and heavier particles to settle, leaving smaller, lighter particles suspended. However, settle-decant operations are slow, convection currents may resuspend solids, hindered settling of multicomponent slurries remains incompletely understood, and predictive models for settling in graduated cylinders fail to match limited observations of settling in large waste tanks. Additionally, pumping operations can cause turbulent resuspension of particles when the pump intake is close to the settled solids layer. Filtration techniques that use membranes or partially permeable barriers retain larger particles, permitting smaller particles to permeate. However, filters, including dead-end filtration, are prone to clogging and caking, operate at elevated pressures due to minimal void volume, and increase in pressure during operations, which require more control systems. Therefore, the need for high throughput particle separation techniques that operate with modest pressure drops persists. A novel mesofluidic separator presents the opportunity to effectively and efficiently accelerate the waste cleanup mission. The separator separates large particles from process streams across a broad range of particle sizes and has no moving parts or media to replace, regenerate, or clean. This separator design has an unusually large void volume, permitting operation at much higher flow rates (and lower pressures) than traditional filtration (e.g., dead-end filtration). Industrial-scale flow rates have been demonstrated. In performance testing, mesofluidic separators operate at might flow rates (>90 gpm (0.0006 m{sup 3}/s) in piping 3 inches (0.08 m) in diameter; Re>10{sup 5}), with modest pressure drop (∼25 psi (170 KPa) in testing). In complex, aggregating waste simulants, the separator loses <25% of flow projected over months without back pulsing or chemical cleaning. Mesofluidic separation presents infrastructure advantages, reduces risk, and provides mission impact. Infrastructure advantages include implementation within existing transfer systems, plug and play without facility modifications to safety systems, and operation at low pressures. The separator is flexible in location, may be positioned within or outside of waste tanks, and may replace or augment dead-end and cross-flow filters. Mesofluidic separation reduces risk by minimizing waste (no media to replace or regenerate and no cleaning chemicals to handle and dispose) and by minimizing filter change-out consistent with as low as reasonably achievable (ALARA) exposure to workers. The potential mission impact of these separators is substantial. The separator has potential to support, simplify, and accelerate in-farm transfers and waste feed delivery. Furthermore, the separator can free up settling and holding tanks in the Direct Feed Low-Activity Waste (DFLAW) mission by reducing or eliminating post-transfer settling and wait times with the potential to free up 1 Mgal (4000 m{sup 3}) of double-shell tank space. This paper quantitatively compares mesofluidic separation to dead-end filtration, discusses scale-up results, and considers the separator's potential to efficiently and effectively reduce the long-term environmental ability of particulate-rich nuclear wastes. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SolarAPP+ Performance Review: 2021 Data

Accelerating rooftop solar photovoltaic (PV) deployment has strained the capacity of local authorities responsible for permitting, inspection, and interconnection (PII). Given the ongoing expansion of rooftop PV, a growing number of authorities having jurisdiction (AHJs) and utilities are reforming PII processes to reduce delays. AHJs could significantly reduce PII timelines through reforms such as expedited reviews for small-scale systems, online customer portals, and over-the-counter permitting. However, independent reforms do not resolve issues associated with PII variability across AHJs, and many AHJs lack the resources to implement reforms. In response to these challenges, the National Renewable Energy Laboratory (NREL) developed the Solar Automated Permit Processing Plus (SolarAPP+) platform, in collaboration with local governments, code development organizations, and industry stakeholders. This report shows SolarAPP+ performance in 2021 across AHJs.

14 SOLAR ENERGY↗

Residential Solar Adoption Timelines and Impacts from the COVID-19 Pandemic

In this study we evaluate PII and other PV adoption timelines from 2017-2021. We use project-level data collected by the National Renewable Energy Laboratory (NREL) for the Solar Time-Based Residential Analytics and Cycle Time Estimator (SolarTRACE). Additionally, we conducted a survey of 171 AHJs about their experiences, challenges, and process changes during the first 18 months of the COVID-19 pandemic. The survey findings were supplemented with follow up interviews with 5 AHJs from 4 states. We find that the pandemic moderately increased the duration and variability of pre-install timelines (contract signing to install), particularly in the permit review phase (permit submit to approval). In contrast, post-install timelines (install to final utility interconnection) continued to decline during the pandemic. The net result is that overall project timelines (contract signing to final interconnection) continued to decline during the pandemic. Our findings suggest that AHJs and installers faced challenges throughout the pandemic but ongoing improvements in PII processes - particularly post-install processes - more than offset these challenges. Furthermore, the pandemic may have catalyzed or accelerated a widespread adoption of online/electronic permitting, among other process efficiency improvements.

14 SOLAR ENERGY↗

Geothermal Interagency Collaboration Task Force: Summary of Findings

This report summarizes the findings of the Geothermal Interagency Collaboration Task Force (Task Force) and associated stakeholder forums and Tribal listening sessions. The Task Force included federal agencies and state agencies in California and Nevada with a nexus to geothermal regulatory and permitting approvals. The Task Force met twice over the course of 2022 to discuss current geothermal regulatory and permitting challenges and strategies for improved coordination and permit processing. In addition, the project team held four forums/listening sessions in 2022 with geothermal industry representatives, environmental non-governmental organizations, and Tribes to gain additional insight and perspective on the geothermal regulatory process and managing potential cultural and natural resource conflicts that may arise during geothermal development.

15 GEOTHERMAL ENERGY↗

County Land-Use Regulations for Solar Energy Development in Colorado

We present a survey of county-level policies on ground-mounted solar development across Colorado, including both solar-specific ordinances as well as general land-use code that might be applicable in counties without solar-specific policies. This report provides an accessible reference for stakeholders interested in identifying counties with particular regulations or in analyzing the diversity of regulations across Colorado. We defined a set of search criteria to find information on solar definitions and classifications, permitting processes, and use-specific requirements in each of Colorado's 64 counties. With those criteria, we reviewed relevant ordinances, land-use code, and comprehensive and master plans. If any uncertainties were identified, we contacted county officials for clarification. The findings are categorized and mapped to illustrate the distribution of key policies adopted across Colorado's counties on the following topics: solar definitions, solar siting policy documentation, categorization of PV systems for permitting, 1041 permitting, solar on agricultural land, panel height restrictions, fencing requirements, vegetation management, visual impacts, decommissioning plans, and financial assurance for decommissioning. Additionally, we identify and discuss policies that might impact the deployment of agrivoltaics, a dual land use combining both agriculture and solar on the same land, which might not fit neatly in existing zoning definitions and solar-specific regulations.

14 SOLAR ENERGY↗

SolarAPP+ Performance Review: Final Technical Report

The National Renewable Energy Laboratory (NREL) and its project partners have developed the novel Solar Automated Permit Processing plus (SolarAPP+) software platform that provides a flexible, web-based PV-permitting tool for residential systems that can be integrated with existing and complementary software platforms. The main objective of this research is to analyze the implementation of SolarAPP+. Analysis was conducted by identifying the benefits, tradeoffs, and overall performance of SolarAPP+, including achieving its goals of delivering automated, code compliant systems, influencing permitting cycle times, and improving application submittals and/or inspection performance. The NREL team published the results of this analysis in annual SolarAPP+ Performance Review technical reports.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Geothermal Development and the Use of Categorical Exclusions (Poster)

The federal environmental review process under the National Environmental Policy Act of 1969 (NEPA) can be complex and time consuming. Currently, a geothermal developer may have to complete the NEPA process multiple times during the development of a geothermal project. One mechanism to reduce the timeframe of the federal environmental review process for activities that do not have a significant environmental impact is the use of Categorical Exclusions (CXs), which can exempt projects from having to complete an Environmental Assessment or Environmental Impact Statement. This study focuses primarily on the CX process and its applicability to geothermal exploration. In this paper, we Provide generalized background information on CXs, including previous NEPA reports addressing CXs, the process for developing CXs, and the role of extraordinary circumstances; Examine the history of the Bureau of Land Management's (BLM) geothermal CXs;Compare current CXs for oil, gas, and geothermal energy; Describe bills proposing new statutory CXs; Examine the possibility of standardizing geothermal CXs across federal agencies; and Present analysis from the Geothermal NEPA Database and other sources on the potential for new geothermal exploration CXs. As part of this study, we reviewed Environmental Assessments (EAs) conducted in response to 20 geothermal exploration drilling permit applications (Geothermal Drilling Permits or Notices of Intents) since the year 2001, the majority of which are from the last 5 years. All 20 EAs reviewed for this study resulted in a Finding of No Significant Impact (FONSI). While many of these FONSI's involved proponent proposed or federal agency required mitigation, this still suggests it may be appropriate to create or expand an exploration drilling CX for geothermal, which would have a significant impact on reducing geothermal exploration timelines and up-front costs. Ultimately, federal agencies tasked with permitting and completing environmental reviews for geothermal exploration drilling activities and/or legislative representatives are the responsible parties to discuss the merits and implementation of new or revised CXs for geothermal development.

15 GEOTHERMAL ENERGY↗

Geothermal Development and the Use of Categorical Exclusions Under the National Environmental Policy Act of 1969 (Presentation)

The federal environmental review process under the National Environmental Policy Act of 1969 (NEPA) can be complex and time consuming. Currently, a geothermal developer may have to complete the NEPA process multiple times during the development of a geothermal project. One mechanism to reduce the timeframe of the federal environmental review process for activities that do not have a significant environmental impact is the use of Categorical Exclusions (CXs), which can exempt projects from having to complete an Environmental Assessment or Environmental Impact Statement. This study focuses primarily on the CX process and its applicability to geothermal exploration. In this paper, we: Provide generalized background information on CXs, including previous NEPA reports addressing CXs, the process for developing CXs, and the role of extraordinary circumstances; Examine the history of the Bureau of Land Management's (BLM) geothermal CXs; Compare current CXs for oil, gas, and geothermal energy; Describe bills proposing new statutory CXs; Examine the possibility of standardizing geothermal CXs across federal agencies; and Present analysis from the Geothermal NEPA Database and other sources on the potential for new geothermal exploration CXs. As part of this study, we reviewed Environmental Assessments (EAs) conducted in response to 20 geothermal exploration drilling permit applications (Geothermal Drilling Permits or Notices of Intents) since the year 2001, the majority of which are from the last 5 years. All 20 EAs reviewed for this study resulted in a Finding of No Significant Impact (FONSI). While many of these FONS's involved proponent proposed or federal agency required mitigation, this still suggests it may be appropriate to create or expand an exploration drilling CX for geothermal, which would have a significant impact on reducing geothermal exploration timelines and up-front costs. Ultimately, federal agencies tasked with permitting and completing environmental reviews for geothermal exploration drilling activities and/or legislative representatives are the responsible parties to discuss the merits and implementation of new or revised CXs for geothermal development.

15 GEOTHERMAL ENERGY↗

RAPID Toolkit Creates Smooth Flow Toward New Projects

Uncertainty about the duration and outcome of the permitting process has historically been seen as a deterrent to investment in renewable energy projects, including new hydropower projects. What if the process were clearer, smoother, faster? That's the purpose of the Regulatory and Permitting Information Desktop (RAPID) Toolkit, developed by the National Renewable Energy Laboratory (NREL) with funding from the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy and the Western Governors' Association. Now, the RAPID Toolkit is being expanded to include information about developing and permitting hydropower projects, with initial outreach and information gathering occurring during 2015.

13 HYDRO ENERGY↗

Air Pollutant Emissions and Regulatory Implications of a Biorefinery Co-Processing Bio-Oil in a Petroleum Refinery: Preprint

Pyrolysis oil, often referred to as bio-oil when derived from biomass through a fast pyrolysis process, has attracted considerable attention because of the high carbonaceous matter and high heating value compared to the original biomass. Pyrolysis oil provides a viable link between the agriculture/forestry and (petro-) chemical industry. Utilizing existing fossil fuel infrastructure by introducing bio-oil in petroleum refineries to produce renewable hydrocarbon fuels (i.e., repurposing existing assets) is appealing due to its relatively low capital requirement. Our analysis examined the air pollutant emissions for a biorefinery utilizing an ex situ catalytic fast pyrolysis process to produce raw bio-oil, with a design capacity of 2,000 dry metric tons of biomass per day. Such a biorefinery is capable of providing sufficient bio-oil to a 4,200 barrels per day capacity of fluidized catalytic cracking unit if the bio-oil is co-processed at 5% (by volume) feed rate. This research is focused on understanding the potential air pollutant regulatory and permitting implications for a refinery co-processing 5% bio-oil with 95% vacuum gas oil in a fluidized catalytic cracking unit for two scenarios: the first case assumes that an ex situ biorefinery is collocated with a petroleum refinery, and the second one assumes that a petroleum refinery will receive bio-oil from a stand-alone biorefinery. We estimated the potential-to-emit values for 4 biorefinery and FCC sizes and assessed technically feasible emission control options that could help to avoid being subject to prevention of significant deterioration requirements due to petroleum refinery modifications to co-process bio-oil. This research fills gaps and overcomes barriers related to air permitting requirements for co-processing bio-oil in existing refineries for various stakeholders. The insights gained from this analysis can facilitate decision making and help expedite permitting processes for petroleum refineries, which seek opportunities to produce lower carbon fuels in their existing infrastructure.

09 BIOMASS FUELS↗

Air Pollutant Emissions and Regulatory Implications of a Biorefinery Co-Processing Bio-Oil in a Petroleum Refinery

Pyrolysis oil, often referred to as bio-oil when derived from biomass through a fast pyrolysis process, has attracted considerable attention because of the high carbonaceous matter and high heating value compared to the original biomass. Pyrolysis oil provides a viable link between the agriculture/forestry and (petro-) chemical industry. Utilizing existing fossil fuel infrastructure by introducing bio-oil in petroleum refineries to produce renewable hydrocarbon fuels (i.e., repurposing existing assets) is appealing due to its relatively low capital requirement. Our analysis examined the air pollutant emissions for a biorefinery utilizing an ex situ catalytic fast pyrolysis process to produce raw bio-oil, with a design capacity of 2,000 dry metric tons of biomass per day. Such a biorefinery is capable of providing sufficient bio-oil to a 4,200 barrels per day capacity of fluidized catalytic cracking unit if the bio-oil is co-processed at 5% (by volume) feed rate. This research is focused on understanding the potential air pollutant regulatory and permitting implications for a refinery co-processing 5% bio-oil with 95% vacuum gas oil in a fluidized catalytic cracking unit for two scenarios: the first case assumes that an ex situ biorefinery is collocated with a petroleum refinery, and the second one assumes that a petroleum refinery will receive bio-oil from a stand-alone biorefinery. We estimated the potential-to-emit values for 4 biorefinery and FCC sizes and assessed technically feasible emission control options that could help to avoid being subject to prevention of significant deterioration requirements due to petroleum refinery modifications to co-process bio-oil. This research fills gaps and overcomes barriers related to air permitting requirements for co-processing bio-oil in existing refineries for various stakeholders. The insights gained from this analysis can facilitate decision making and help expedite permitting processes for petroleum refineries, which seek opportunities to produce lower carbon fuels in their existing infrastructure.

09 BIOMASS FUELS↗

The Role of Moist Processes in the Intrinsic Predictability of Indian Ocean Cyclones

The role of moist processes and the possibility of error cascade from cloud scale processes affecting the intrinsic predictable time scale of a high resolution convection permitting model within the environment of tropical cyclones (TCs) over the Indian region are investigated. Consistent with past studies of extra-tropical cyclones, it is demonstrated that moist processes play a major role in forecast error growth which may ultimately limit the intrinsic predictability of the TCs. Small errors in the initial conditions may grow rapidly and cascades from smaller scales to the larger scales through strong diabatic heating and nonlinearities associated with moist convection. Results from a suite of twin perturbation experiments for four tropical cyclones suggest that the error growth is significantly higher in cloud permitting simulation at 3.3 km resolutions compared to simulations at 3.3 km and 10 km resolution with parameterized convection. Convective parameterizations with prescribed convective time scales typically longer than the model time step allows the effects of microphysical tendencies to average out so convection responds to a smoother dynamical forcing. Without convective parameterizations, the finer-scale instabilities resolved at 3.3 km resolution and stronger vertical motion that results from the cloud microphysical parameterizations removing super-saturation at each model time step can ultimately feed the error growth in convection permitting simulations. This implies that careful considerations and/or improvements in cloud parameterizations are needed if numerical predictions are to be improved through increased model resolution. Rapid upscale error growth from convective scales may ultimately limit the intrinsic mesoscale predictability of the TCs, which further supports the needs for probabilistic forecasts of these events, even at the mesoscales.

cyclones↗

Modeling Arctic boundary layer cloud streets at grey-zone resolutions

To better understand how model resolution affects the formation of Arctic boundary layer clouds, we investigated the influence of grid spacing on simulating cloud streets that occurred near Utqiagvik (formerly Barrow), Alaska on 2 May 2013 and were observed by the Moderate Resolution Imaging Spectroradiometer (MODIS). The Weather Research and Forecasting model was used to simulate the clouds using nested domains with increasingly fine resolution ranging from a horizontal grid spacing of 27 km in the boundary-layer-parameterized mesoscale domain to a grid spacing of 0.111 km in the large-eddy-permitting domain. We investigated the model-simulated mesoscale environment, horizontal and vertical cloud structures, boundary layer stability, and cloud properties, all of which were subsequently used to interpret the observed roll-cloud case. Increasing model resolution led to a transition from a more buoyant boundary layer to a more shear-driven turbulent boundary layer. The clouds were stratiform-like in the mesoscale domain, but as the model resolution increased, roll-like structures, aligned along the wind field, appeared with ever smaller wavelengths. A stronger vertical water vapor gradient occurred above the cloud layers with decreasing grid spacing. With fixed model grid spacing at 0.333 km, changing the model configuration from a boundary layer parameterization to a large-eddy-permitting scheme produced a more shear-driven and less unstable environment, a stronger vertical water vapor gradient below the cloud layers, and the wavelengths of the rolls decreased slightly. In this study, only the large-eddy-permitting simulation with gird spacing of 0.111 km was sufficient to model the observed roll clouds.

Lai, Hui-Wen↗

Quantifying CO 2 Plume Stabilization at Carbon Storage Projects, North Dakota, USA

This study presents an approach for quantifying when injected carbon dioxide (CO 2 ) stabilizes pursuant to carbon capture and storage (CCS) project permitting and site closure requirements. The distribution of mobile-phase CO 2 (CO 2 plume) will evolve within the storage reservoir during and after injection through both physical and chemical trapping mechanisms. CCS policies generally agree that the CO 2 plume’s migratory behavior in post-injection should demonstrate nonendangerment to the environment but do not provide specific guidance on how to meet the definition of plume stabilization, generating some uncertainty for operators. Plume stability herein means the CO 2 plume 1) changes size minimally and predictably in the storage reservoir such that it will not cross key boundaries identified in the permit and 2) does not pose a threat to human health, underground sources of drinking water (USDWs), and the environment because of lateral migration to areas where leakage pathways may exist. Published literature on plume metrics was reviewed to determine which metric(s) may be most appropriate for determining CO 2 plume stability. A technical approach that defines plume stabilization by estimating the rate of change in the geographic footprint of the CO 2 plume with respect to time was developed and illustrated using a case study from North Dakota, USA, as a proposed solution for CCS operators to apply at the project permitting stage. Any prospective CCS operator may benefit from using the same approach to inform the selection of pore space lease and monitoring areas and develop post-injection site care plans.

03 NATURAL GAS↗

Levelized cost of energy for a Backward Bent Duct Buoy

The Reference Model Project, supported by the U.S. Department of Energy, was developed to provide publically available technical and economic benchmarks for a variety of marine energy converters. The methodology to achieve these benchmarks is to develop public domain designs that incorporate power performance estimates, structural models, anchor and mooring designs, power conversion chain designs, and estimates of the operations and maintenance, installation, and environmental permitting required. The reference model designs are intended to be conservative, robust, and experimentally verified. The Backward Bent Duct Buoy (BBDB) presented in this paper is one of three wave energy conversion devices studied within the Reference Model Project. Comprehensive modeling of the BBDB in a Northern California climate has enabled a full levelized cost of energy (LCOE) analysis to be completed on this device.

marine hydrokinetic energy development↗