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At least 595 records · Page 33

Multiplexed Colorimetric Solid-Phase Extraction

Multiplexed colorimetric solid-phase extraction (MC-SPE) is an extension of colorimetric solid-phase extraction (C-SPE) an analytical platform that combines colorimetric reagents, solid phase extraction, and diffuse reflectance spectroscopy to quantify trace analytes in water. In CSPE, analytes are extracted and complexed on the surface of an extraction membrane impregnated with a colorimetric reagent. The analytes are then quantified directly on the membrane surface using a handheld diffuse reflectance spectrophotometer. Importantly, the use of solid-phase extraction membranes as the matrix for impregnation of the colorimetric reagents creates a concentration factor that enables the detection of low concentrations of analytes in small sample volumes. In extending C-SPE to a multiplexed format, a filter holder that incorporates discrete analysis channels and a jig that facilitates the concurrent operation of multiple sample syringes have been designed, enabling the simultaneous determination of multiple analytes. Separate, single analyte membranes, placed in a readout cartridge create unique, analyte-specific addresses at the exit of each channel. Following sample exposure, the diffuse reflectance spectrum of each address is collected serially and the Kubelka-Munk function is used to quantify each water quality parameter via calibration curves. In a demonstration, MC-SPE was used to measure the pH of a sample and quantitate Ag(I) and Ni(II).

Gazda, Daniel B.↗

Ground Tests of High-Voltage Solar Arrays Immersed in a Low Density Plasma

Five different types of solar arrays have been tested in large vacuum chamber. Arc inception voltages, arc rates, and current collections are measured for samples with different coverglass materials and thickness, interconnect designs, and cell sizes. It is shown that the array with wrapthrough interconnects have the highest arc threshold and the lowest current collection. Coverglass design with overhang results in decrease of current collection and increase of arc threshold. Doubling coverglass thickness does not improve measured array parameters. Both arc inception voltage and current collection increase significantly with increasing a sample temperature to 80 C. Sustained discharges are initiated between adjacent cells with potential differences of 40 V for the sample with 300 pm coverglass thickness and 60 V for the sample with 150 urn coverglass thickness.

Vayner, Boris↗

Investigation of Advanced Processed Single-Crystal Turbine Blade Alloys

This investigation studied the influence of thermal processing and microstructure on the mechanical properties of the single-crystal, nickel-based superalloys PWA 1482 and PWA 1484. The objective of the program was to develop an improved single-crystal turbine blade alloy that is specifically tailored for use in hydrogen fueled rocket engine turbopumps. High-gradient casting, hot isostatic pressing (HIP), and alternate heat treatment (HT) processing parameters were developed to produce pore-free, eutectic-free microstructures with different (gamma)' precipitate morphologies. Test materials were cast in high thermal gradient solidification (greater than 30 C/cm (137 F/in.)) casting furnaces for reduced dendrite arm spacing, improved chemical homogeneity, and reduced interdendritic pore size. The HIP processing was conducted in 40 cm (15.7 in.) diameter production furnaces using a set of parameters selected from a trial matrix study. Metallography was conducted on test samples taken from each respective trial run to characterize the as-HIP microstructure. Post-HIP alternate HT processes were developed for each of the two alloys. The goal of the alternate HT processing was to fully solution the eutectic gamma/(gamma)' phase islands and to develop a series of modified (gamma)' morphologies for subsequent characterization testing. This was accomplished by slow cooling through the (gamma)' solvus at controlled rates to precipitate volume fractions of large (gamma)'. Post-solution alternate HT parameters were established for each alloy providing additional volume fractions of finer precipitates. Screening tests included tensile, high-cycle fatigue (HCF), smooth and notched low-cycle fatigue (LCF), creep, and fatigue crack growth evaluations performed in air and high pressure (34.5 MPa (5 ksi)) hydrogen at room and elevated temperature. Under the most severe embrittling conditions (HCF and smooth and notched LCF in 34.5 MPa (5 ksi) hydrogen at 20 C (68 F), screening test results showed increases in fatigue life typically on the order of 1OX, when compared to the current Space Shuttle Main Engine (SSME) Alternate Turbopump (AT) blade alloy (PWA 1480).

Peters, B. J.↗

Adaptable structural synthesis using advanced analysis and optimization coupled by a computer operating system

A finite element program is linked with a general purpose optimization program in a 'programing system' which includes user supplied codes that contain problem dependent formulations of the design variables, objective function and constraints. The result is a system adaptable to a wide spectrum of structural optimization problems. In a sample of numerical examples, the design variables are the cross-sectional dimensions and the parameters of overall shape geometry, constraints are applied to stresses, displacements, buckling and vibration characteristics, and structural mass is the objective function. Thin-walled, built-up structures and frameworks are included in the sample. Details of the system organization and characteristics of the component programs are given.

Sobieszczanski-Sobieski, J.↗

Ellipsometric study of oxide films formed on LDEF metal samples

The optical constants of samples of six different metals (Al, Cu, Ni, Ta, W, and Zr) exposed to space on the Long Duration Exposure Facility (LDEF) were studied by variable angle spectroscopic ellipsometry. Measurements were also carried out on portions of each sample which were shielded from direct exposure by a metal bar. A least-squares fit of the data using an effective medium approximation was then carried out, with thickness and composition of surface films formed on the metal substrates as variable parameters. The analysis revealed that exposed portions of the Cu, Ni, Ta, and Zr samples are covered with porous oxide films ranging in thickness from 500 to 1000 A. The 410 A thick film of Al2O3 on the exposed Al sample is practically free of voids. Except for Cu, the shielded portions of these metals are covered by thin non-porous oxide films characteristic of exposure to air. The shielded part of the Cu sample has a much thicker porous coating of Cu2O. The tungsten data could not be analyzed.

Franzen, W.↗

A diagnostic analysis of the VVP single-doppler retrieval technique

A diagnostic analysis of the VVP (volume velocity processing) retrieval method is presented, with emphasis on understanding the technique as a linear, multivariate regression. Similarities and differences to the velocity-azimuth display and extended velocity-azimuth display retrieval techniques are discussed, using this framework. Conventional regression diagnostics are then employed to quantitatively determine situations in which the VVP technique is likely to fail. An algorithm for preparation and analysis of a robust VVP retrieval is developed and applied to synthetic and actual datasets with high temporal and spatial resolution. A fundamental (but quantifiable) limitation to some forms of VVP analysis is inadequate sampling dispersion in the n space of the multivariate regression, manifest as a collinearity between the basis functions of some fitted parameters. Such collinearity may be present either in the definition of these basis functions or in their realization in a given sampling configuration. This nonorthogonality may cause numerical instability, variance inflation (decrease in robustness), and increased sensitivity to bias from neglected wind components. It is shown that these effects prevent the application of VVP to small azimuthal sectors of data. The behavior of the VVP regression is further diagnosed over a wide range of sampling constraints, and reasonable sector limits are established.

Boccippio, Dennis J.↗

Characterizing the System Impulse Response Function from Photon-Counting LiDAR Data

NASA's Multiple Altimeter Beam Experimental LiDAR (MABEL) is an aircraft-based photon-counting laser altimeter designed as a simulator to test measurement techniques and algorithms for Advanced Topographic Laser Altimeter System (ATLAS), the sole instrument on NASA's Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) mission. By measuring the time of flight, pointing angle, and absolute position for individual photons, ICESat-2 provides detailed elevation measurements of earth's surface. Calculating accurate and precise elevations requires an understanding of how photons interact with surfaces, and characterization of the photon distribution after returning from surfaces. Neither MABEL nor ATLAS records the transmitted laser pulse shape, relying instead on aggregating several pulses worth of photons, often using histograms, to characterize the pulse shape. In this paper, we assess the limitations of using histograms and propose a more robust method to describe MABEL's system impulse-response function using an exponentially modified Gaussian distribution. We also provide standard error estimates for the arithmetic mean and standard deviation calculations, and for exponentially modified Gaussian parameters using a Monte Carlo sensitivity analysis. We apply this method to photon returns from a sea ice lead and from a dry salt lake bed as case studies for estimating the standard error associated with sample size for the arithmetic mean and standard deviation, and for the exponentially modified Gaussian parameters. We use these standard errors to calculate the minimum number of photons required to find both Gaussian and exponentially modified Gaussian distribution parameters within 3 cm of their parent population values.

photoncounting↗

Technology test bed engine real-time failure control

The Real-Time Failure Control (RTFC) program involves development of a failure detection algorithm, for the Space Shuttle Main Engine (SSME). This failure detection approach is signal-based and entails monitoring SSME measurement signals based on predetermined as well as on-line computed mean and standard deviation values. Twenty-four engine measurements are monitored in the algorithm and provisions are made to add more parameters if needed. Each of the first values of every measurement signal at the algorithm start is checked against safety limits placed around a pre-computed engine-to-engine mean value (MV) with a bandwidth equal to a given multiple of the pre-computed standard deviation (SD). If several parameters are out of the bounds of these limits a failure is signaled. During the first two seconds (after algorithm start) a moving average (MA) and a SD is computed on-line in real-time. The moving average of each parameter is computed by averaging the incoming signal measurement with the four most recent previous signal measurements. The moving average is updated at every sampling interval (40 msec) and is checked against a similar safety band around the initial signal value for each parameter. If several anomalies are registered, a failure is signaled by the algorithm. At the end of the two-second interval the MA is fixed as the mean value for the rest of the algorithm operation and a safety band is placed above and below this value equal to a multiple of the computed SD. However, the safety band is adjusted by adjusting the mean value when propellant tank repressurization and venting take place. 'Influence Coefficients' are used to make the necessary adjustments to the safety limits of those parameters that are affected by repressurization and venting or valve closure and opening. The MA is, in both cases, continuously updated and checked against the safety band. Once more, if several parameters exceed the limits a failure is signaled. At the start of every scheduled power transient the algorithm is stopped. It is re-initiated after two seconds from the termination of the power transient and the process is repeated. The final report is divided into four major sections. The most encompassing of all is the discussion section that has sub-sections on: (1) RTFC algorithm development, (2) RTFC simulations; (3) RTFC current limitations; and (4) enhancements planned for.

Panossian, Hagop V.↗

Cosmological implications of ROSAT observations of groups and clusters of galaxies

We have combined ROSAT Position Sensitive Proportional Counter (PSPC) and optical observations of a sample of groups and clusters of galaxies to determine the fundamental parameters of these systems (e.g., the dark matter distribution, gas mass fraction, baryon mass fraction, mass-to-light ratio, and the ratio of total-to-luminous mass). Imaging X-ray spectroscopy of groups and clusters show that the gas is essentially isothermal beyond the central region, indicating that the total mass density (mostly dark matter) scales as rho(sub dark) varies as 1/r squared. The density profile of the hot X-ray emitting gas is fairly flat in groups with rho(sub gas) varies as 1/r and becomes progressively steeper in hotter richer systems, with rho(sub gas) varies as 1/r squared in the richest clusters. These results show, that in general, the hot X-ray-emitting gas is the most extended mass component in groups and clusters, the galaxies are the most centrally concentrated component, and the dark matter is intermediate between the two. The flatter density rofile of the hot gas compared to the dark matter produces a gas mass fraction that increases with radius within each object. There is also a clear trend of increasing gas mass fraction (from 2% to 30%) between elliptical galaxies and rich clusters due to the greater detectable extent of the X-ray emission in richer systems. For the few systems in which the X-ray emission can be traced to the virial radius (where the overdensity delta is approximately equal 200), the gas mass fraction (essentially the baryon mass fraction) approaches a roughly constant value of 30%, suggesting that this is the true primordial value. Based on standard big bang nucleosynthesis, the large baryon mass fraction implies that Omega = 0.1 - 0.2. The antibiased gas distribution suggests that feedback from galaxy formation and hydrodynamics play important roles in the formation of structure on the scale of galaxies to rich clusters. All the groups and clusters in our sample have mass-to-light ratios of M/L(sub V) approximately 100 - 150 solar mass/solar luminosity, which strongly contrasts with the traditional view that the mass-to-light ratio of rich clusters is significantly greater than individual galaxies or groups with M/L(sub V) approximately 250 - 300 solar mass/solar luminosity. We also show that M/L(sub V is essentially constant within the virial radius of clusters (where delta is greater than or approximately 200), which is consistent with the peaks formalism of biased galaxy formation. While the mass-to-light ratios of groups and clusters are comparable (indicating a constant mass fraction of optically luminous material), the ratio of the total mass-to-luminous mass (gas plus stars) monotonically decreases between galaxies and clusters. The decrease in M(sub total)/M(sub lum) arises from two factors: (1) the composition of baryonic matter varies from a predominance of optically luminous material (stars) on the scale of galaxies (approximately 10 kpc) to a predominance of X-ray luminous material (hot gas) on the scale of rich clusters (approximately 1 Mpc), and (2) the hot gas has a more extended spatial distribution than the gravitating matter. The observed decrease M(sub total)/M(sub lum) between galaxies and clusters indicates that the universe actually becomes `brighter' on mass scales between 10(exp 12) and 10(exp 15) solar mass, in the sense that a greater fraction of the gravitating mass is observable.

David, Laurence P.↗

An assessment of the impact of system spectral response parameters on spectral shape and algal bloom detection for the GeoXO ocean color instrument (OCX)

NOAA’s Geostationary Extended Observations (GeoXO) program is planning to include a hyperspectral ocean color instrument (OCX) in geostationary orbit slated for operations by the early 2030s. Shared international focus has led to a diverse legacy of space-based remote sensing ocean color missions that have and will continue to provide ocean color products into the future at a variety of spatial, temporal, and spectral resolutions. This work reports on an investigation of the impacts of system spectral response parameters on spectral shape and algal bloom detection for the planned OCX instrument. A large dataset in-situ spectra, from a variety of locations and water cases collected with an above water spectrometer, was used to simulate OCX observations of varying system spectral response parameters. The OCX Performance Operational Requirements Document (PORD) level spectral resolution and sampling are varied concurrently and the location of band centers is varied independently. The impacts to the spectral shape using hyperspectral signature analysis, as well as the impacts to two heritage multispectral algal bloom detection algorithms – red band difference (RBD) and Karenia brevis bloom index (KBBI) – are assessed considering both changes in resolution/sampling and band center location. This work provides a quantitative assessment of the impacts of system spectral response requirements on both the spectral shape of observations as well as the algal bloom detection to provide insight on how various instrument performance parameters influence science and operational utility of OCX.

Monica Cook↗

Flight motor set 360L007 (STS-33R)

Flight motor set 360L007 was launched as part of NASA space shuttle mission STS-33R. As with all previous redesigned solid rocket motor launches, overall motor performance was excellent. There were no debris concerns for either motor. Both motors exhibited unbonds on one factory joint weatherseal. All ballistics contract end item specification parameters were verified, with the exception of ignition interval and rise rates. Ignition interval and rise rates could not be verified due to the elimination of developmental flight instrumentation from fourth flight and subsequent, but the low sample rate data that were available showed nominal propulsion performance. All ballistic and mass property parameters closely matched the predicted values and were well within the required contract end item specification levels that could be assessed. All 108 Ground Environment Instrumentation (GEI) measurements performed properly throughout the prelaunch phase. Evaluation of the GEI measurements again verified thermal model analysis data and showed agreement with predicted environmental effects. No launch commit criteria thermal violations occurred. All joint heaters operated normally, but a high voltage reading was noted on the left hand aft heater, which was immediately determined to be a voltage sensor error and not a heater anomaly due to no current increase. Postflight inspection again verified superior performance of the insulation, phenolics, metal parts, and seals. Postflight evaluation indicated both nozzles performed as expected during flight. All combustion gas was contained by insulation in the field and case-to-nozzle joints.

Garecht, Diane↗

Flight motor set 360L006 (STS-34). Volume 1: System overview

Flight motor set 360L006 was launched at approximately 11:54 a.m. Central Daylight Time (CDT) on 18 October 1989 as part of NASA space shuttle mission STS-34. As with all previous redesigned solid rocket motor launches, overall motor performance was excellent. All ballistic contract end item (CEI) specification parameters were verified with the exceptions of ignition interval and rise rates. Ignition interval and rise rates could not be verified due to the elimination of developmental flight instrumentation from fourth flight and subsequent, but the low sample rate data that were available showed nominal propulsion performance. All ballistic and mass property parameters closely matched the predicted values and were well within the required CEI specification levels that could be assessed, with the exception of the RH-motor vacuum-delivered specific impulse. It exceeds the upper-limit CEI specification due to a bias imposed on the raw data by the OPT/Taber gage measurement differences. Evaluation of the ground environment instrumentation measurements again verified thermal model analysis data and showed agreement with predicted environmental effects. No launch commit criteria thermal violations occurred. Postflight inspection again verified superior performance of the insulation, phenolics, metal parts, and seals. Postflight evaluation indicated both nozzles performed as expected during flight, although splashdown loads tore the left-hand, 45-deg actuator bracket from the nozzle. All combustion gas was contained by insulation in the field and nozzle-to-case joints. Recommendations were made concerning improved thermal modeling and measurements. The rationale for these recommendations, the disposition of all anomalies, and complete result details are contained.

Garecht, Diane M.↗

How to compare the surface of Io to laboratory samples

Since one does not know the photometric functions of various parts of Io, one cannot convert the observed geometric albedo of the satellite to a parameter more directly measurable in the laboratory. One must therefore convert laboratory reflectances to geometric albedos before quantitative comparisons between Io's surface and a laboratory sample are made. This procedure involves determining the wavelength dependence of the sample's photometric function. For substances such as sulfur, whose reflectance varies strongly with wavelength, it is incorrect to assume that the photometric function, and hence the ratio (laboratory reflectance/geometric albedo) is independent of wavelength. To illustrate this point, measurements of the color dependence of this ratio for sulfur are presented for the specific case in which the measured laboratory reflectance is the sample's normal reflectance. In general, unless the laboratory reflectance is precisely the geometric albedo, a wavelength-dependent correction factor must be determined before the laboratory sample can be compared quantitatively with Io's surface.

Veverka, J.↗

Properties of the X-ray emitting gas in early-type galaxies

The properties of the X-ray emitting gas in a sample of 81 E and S0 galaxies observed with the Einstein Observatory are studied. Measured fluxes for 55 of the galaxies and upper limits for 26 of them are reported. An attempt is made to use consistent optical parameters for the galaxies, including a correction to the velocities for the Virgocentric flow. The sample is then used to explore the contribution from discrete sources, the global physical properties of the hot gas, and the implications for heating by supernovae and gravity. Finally, the question of the presence of heavy halos is addressed.

Canizares, Claude R.↗

Flight Motor Set 360T010 (STS-31R). Volume 1: System Overview

Flight motor set 360T010 was launched at approximately 7:34 a.m. CST (090:114:12:33:50.990 GMT) on 24 Apr. 1990 after one launch attempt (attempt on 10 Apr. 1990 was scrubbed following an indication of erratic operation of the Orbiter No. 1 Auciliary Power Unit No. 1). There were no problems with the solid rocket motor launches, overall motor performance was excellent. There were no debris concerns from either motor. Nearly all ballistic contract end item specification parameters were verified with the exception of ignition interval, pressure rise rate, and ignition time thrust imbalance. These could not be verified due to elimination of developmental flight instrumentation on 360L004 (STS-30R) and subsequent, but low sample rate data that were available showed nominal propulsion performance. All ballistic and mass property parameters that could be assessed closely matched the predicted values and were well within the required contract end item specification levels. All field joint heaters and igniter joint heaters performed without anomalies. Evaluation of the ground environment instrumentation measurements again verified thermal model analysis data and showed agreement with predicted environmental effects. No launch commit criteria violations occurred. Postflight inspection again verified nominal performance of the insulation, phenolics, metal parts, and seals. Postflight evaluation indicated both nozzles performed as expected during flight. All combustion gas was contained by insulation in the field and case-to-nozzle joints.

Garecht, Diane↗

Temporal Evolution of a Streamer Complex: Coronal and In-Situ Plasma Parameters

In this paper we report on observations acquired by the Ultra Violet Coronagraph Spectrometer (UVCS) aboard the Solar and Heliospheric Observatory (SOHO), from 10 to 17 June 2000, at the time of a SOHO-Sun-Ulysses quadrature. UVCS took data at 1.6 and 1.9 solar radii, with a slit normal to the solar radius and centered along the radial to Ulysses. A streamer complex was sampled by UVCS, throughout the quadrature campaign, giving us the opportunity to derive plasma parameters in different streamers, and to compare them with plasma properties measured in situ. Large Angle Spectroscopic Coronagraph (LASCO) images above 2 solar radii helped us understand the temporal evolution of the streamer complex. We derive densities, temperatures and elemental abundances in two streamers, which have different temperatures and element abundances. In spite of these differences, both structures have the same FIP bias. The Fe/O ratio, which may be considered a proxy for the FIP effect, was measured (\it in situ} by the Solar Wind Ion Composition Spectrometer (SWICS) aboard the Ulysses spacecraft. Values of Fe/O measured in the corona, at the sites where in situ plasma originated, agree with in situ Fe/O values.

Bemporad, A.↗

Design method for four-reflector type beam waveguide systems

Discussed is a method for the design of four reflector type beam waveguide feed systems, comprised of a conical horn and 4 focused reflectors, which are used widely as the primary reflector systems for communications satellite Earth station antennas. The design parameters for these systems are clarified, the relations between each parameter are brought out based on the beam mode development, and the independent design parameters are specified. The characteristics of these systems, namely spillover loss, crosspolarization components, and frequency characteristics, and their relation to the design parameters, are also shown. It is also indicated that design parameters which decide the dimensions of the conical horn or the shape of the focused reflectors can be unerringly established once the design standard for the system has been selected as either: (1) minimizing the crosspolarization component by keeping the spillover loss to within acceptable limits, or (2) minimizing the spillover loss by maintaining the crossover components below an acceptable level and the independent design parameters, such as the respective sizes of the focused reflectors and the distances between the focussed reflectors, etc., have been established according to mechanical restrictions. A sample design is also shown. In addition to being able to clarify the effects of each of the design parameters on the system and improving insight into these systems, the efficiency of these systems will also be increased with this design method.

Betsudan, S.↗

First Optical Constants from 0.4 to 1.6 µm of Titan Aerosol Analogs Produced in the NASA Ames COSmIC Facility and Their Use in a New Analysis of Cassini VIMS Observations

We have determined the real and imaginary refractive indices (n and k, respectively), from the visible to the near infrared (0.4 to 1.6 μm), of five laboratory-generated organic refractory materials produced from gas-phase chemistry with the NASA Ames COSmIC facility. The solid samples were produced using a plasma discharge in the stream of a 200-K supersonic jet-cooled expansion of different gas mixtures to study the impact of the molecular precursors on the solid sample optical properties. Three samples were produced from N2:CH4 (95:5) gas mixtures using three different high voltages (700V, 800V and 1000V) to vary the energy in the plasma discharge. One sample was produced from a N2:CH4:C2H2 (94:5:5:0.5) gas mixture, with a high voltage of 1000 V. The fifth sample was produced in an Ar:CH4 (95:5) gas mixture with a high voltage of 1000 V to produce a nitrogen-free hydrocarbon sample. The optical constants, n and k, of these five samples were determined using spectral reflectance measurements. They appear to be positively correlated with the nitrogen content in the solid sample, i.e., a sample with larger nitrogen content exhibits higher n and k values. We have used these refractive indices as input parameters in a radiative transfer model to analyze Cassini Visible Infrared Mapping Spectrometer (VIMS) observations of Titan’s atmosphere. The results show that using the tholin samples with higher n and k values (higher nitrogen content) provides a better fit to the observational data than using the samples with lower n and k values (lower nitrogen content). The Titan tholins with higher nitrogen content therefore appear to be more representative of the Titan aerosols observed by VIMS.

Titan Aerosol Analogs↗