Structural and mechanical effects of interstitial sinks
Changes in structure and mechanical properties due to loss of interstitials to reactive metal coatings studied in dispersion strengthened niobium alloys
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Changes in structure and mechanical properties due to loss of interstitials to reactive metal coatings studied in dispersion strengthened niobium alloys
Phase diagram of titanium vanadium niobium molybdenum system
Microstructural and X-ray phase analysis of alloys of titanium niobium chromium system
Physical and mechanical properties of tantalum carbide and niobium carbide composites
Angular correlation of cascade gamma rays in niobium
Effect of low density inert gas flush on oxygen- niobium reaction
Structural changes in niobium base alloys induced by exposure to titanium interstitial sink at elevated temperature
Superconducting niobium thin film production
Equilibrium solubilities of niobium and tantalum in molten potassium
Solubility parameters for niobium and zirconium in lithium and potassium, and calcium solubility in eutectic sodium potassium alloy
High strength niobium alloy corrosion testing and evaluation of alkali metal containment
Stress corrosion test of biaxially stressed niobium-base refractory alloy with refluxing potassium
Band structure model for thermal conductivity of zirconium and niobium carbides
Emittance testing of calcium titanate and iron titanate coated stainless steel tubes and thermal cycling tests of iron titanate coated niobium-zirconium tubes
Oxidation protection of niobium and tantalum by their silicides
Critical surface between superconducting and normal state determined for commercial niobium stannide ribbon and Nb-Zr wire
This paper describes a superconducting hot electron bolometer mixer that uses diffusion rather than interactions with phonons as a cooling mechanism for the hot electrons. The bolometer is a 0.14 µm; wide niobium microbridge with a length less than 0.5 µm;. The submicron length ensures rapid diffusion of the hot electrons into contacting gold films. This mechanism is believed to be fast enough to allow mixer operation with intermediate frequencies of several GHz. An electron cooling time of 55 ps is inferred from DC resistance versus temperature measurements, indicating a roll-off frequency close to 3 GHz. Initial receiver measurements using a two-tuner waveguide mixer confirm heterodyne mixing at 532 GHz with an intermediate frequency of 1.4 GHz.
Nuclear Thermal Propulsion (NTP) has undergone development as an alternate in-space propulsion system to traditional chemical propulsion methods since the 1950s. In an NTP system, the energy released from fission in the core is utilized as the heat source to directly heat a propellant for propulsion, rather than chemical combustion in a traditional rocket. NTP has many desirable capabilities including flexible mission launch dates and reduced transit times due to it’s capability for high specific impulse. One of the main challenges with NTP systems is the structural integrity of the fuel. The fuel form required in the reactor core must withstand temperatures above 2700 Kelvin. Ceramic-metallic matrix fuel, ceramic-ceramic matrix fuel, and solid solution carbide fuels are the three strongest candidates for the extreme environments. Solid solution carbides have the potential to exhibit promising behavior as a fuel form in an NTP system. Of the multiple refractory metal carbides of interest, here we focus on zirconium carbide (ZrC), niobium carbide (NbC), and tantalum carbide (TaC). ZrC, NbC, and TaC powders were consolidated in monocarbide (ZrC, NbC, and TaC) and bi-carbide (ZrC-NbC, ZrC-TaC, NbC-TaC) forms using spark plasma sintering (SPS). In addition to the pure endpoint carbides, the examined compositions of the various bi-carbides ranged from 25-75 mol%. The sintering temperatures, pressures, and hold times were varied to determine the ideal sintering conditions. Grain size analysis, Archimedes’ density, scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersion spectroscopy (EDS) were used to determine and characterize the grain size, ideal density, porosity, phase stability, and chemical composition of each sample. The data from each sample was then used to generate a Master Sintering Curve (MSC) unique to each monocarbide or bi-carbide.