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At least 595 records · Page 33

The Compressibility Burble

Simultaneous air-flow photographs and pressure-distribution measurements have been made of the NACA 4412 airfoil at high speeds in order to determine the physical nature of the compressibility burble. The flow photographs were obtained by the Schlieren method and the pressures were simultaneously measured for 54 stations on the 5-inch-chord wing by means of a multiple-tube photographic manometer. Pressure-measurement results and typical Schlieren photographs are presented. The general nature of the phenomenon called the "compressibility burble" is shown by these experiments. The source of the increased drag is the compression shock that occurs, the excess drag being due to the conversion of a considerable amount of the air-stream kinetic energy into heat at the compression shock.

Stack, John↗

Electron acceleration to high energies at quasi-parallel shock waves in the solar corona

In the solar corona shock waves are generated by flares and/or coronal mass ejections. They manifest themselves in solar type 2 radio bursts appearing as emission stripes with a slow drift from high to low frequencies in dynamic radio spectra. Their nonthermal radio emission indicates that electrons are accelerated to suprathermal and/or relativistic velocities at these shocks. As well known by extraterrestrial in-situ measurements supercritical, quasi-parallel, collisionless shocks are accompanied by so-called SLAMS (short large amplitude magnetic field structures). These SLAMS can act as strong magnetic mirrors, at which charged particles can be reflected and accelerated. Thus, thermal electrons gain energy due to multiple reflections between two SLAMS and reach suprathermal and relativistic velocities. This mechanism of accelerating electrons is discussed for circumstances in the solar corona and may be responsible for the so-called 'herringbones' observed in solar type 2 radio bursts.

Mann, G.↗

DEEP CHANDRA, HST-COS, AND MEGACAM OBSERVATIONS OF THE PHOENIX CLUSTER: EXTREME STAR FORMATION AND AGN FEEDBACK ON HUNDRED KILOPARSEC SCALES

We present new ultraviolet, optical, and X-ray data on the Phoenix galaxy cluster (SPT-CLJ2344-4243). Deep optical imaging reveals previously undetected filaments of star formation, extending to radii of ∼50–100 kpc in multiple directions. Combined UV-optical spectroscopy of the central galaxy reveals a massive (2 × 10{sup 9} M{sub ⊙}), young (∼4.5 Myr) population of stars, consistent with a time-averaged star formation rate of 610 ± 50 M{sub ⊙} yr{sup −1}. We report a strong detection of O vi λλ1032,1038, which appears to originate primarily in shock-heated gas, but may contain a substantial contribution (>1000 M{sub ⊙} yr{sup −1}) from the cooling intracluster medium (ICM). We confirm the presence of deep X-ray cavities in the inner ∼10 kpc, which are among the most extreme examples of radio-mode feedback detected to date, implying jet powers of 2–7 × 10{sup 45} erg s{sup −1}. We provide evidence that the active galactic nucleus inflating these cavities may have only recently transitioned from “quasar-mode” to “radio-mode,” and may currently be insufficient to completely offset cooling. A model-subtracted residual X-ray image reveals evidence for prior episodes of strong radio-mode feedback at radii of ∼100 kpc, with extended “ghost” cavities indicating a prior epoch of feedback roughly 100 Myr ago. This residual image also exhibits significant asymmetry in the inner ∼200 kpc (0.15R{sub 500}), reminiscent of infalling cool clouds, either due to minor mergers or fragmentation of the cooling ICM. Taken together, these data reveal a rapidly evolving cool core which is rich with structure (both spatially and in temperature), is subject to a variety of highly energetic processes, and yet is cooling rapidly and forming stars along thin, narrow filaments.

79 ASTRONOMY AND ASTROPHYSICS↗

Vanadium K Xanes Studies of EET79001 Impact-Melt Glasses Revisited

Some impact-melt glasses in shergottites are rich in Martian atmospheric noble gases and sulfur suggesting a possible association with regolith-derived secondary mineral assemblages in the shocked samples. Previously, we studied two glasses, # 506 (Lith C in Lith A) and # 507 (Lith C in Lith B) from EET79001 [1,2] and suggested that sulfur initially existed as sulfate in the glass precursor materials and, on shock-melting of the precursors, the sulfate was reduced to sulfides in the shock glasses. To examine the validity of this hypothesis, we used V K microXANES techniques to measure the valence states of vanadium in the Lith C glasses from Lith A and Lith B in EET79001 [3] to complement and com-pare with previous analogous measurements on,78 glass (Lith C in Lith A) [4,5]. We reported the preliminary results in [3]. Vanadium is ideal for addressing the redox issue because it has multiple valence states and is a well-studied element. Vanadium in basalts exists mostly as V(sup 3+), V(sup 4+) and V(sup 5+) in terrestrial samples, mainly as V(sup 3+) with minor V(sup 2+) and minor V(sup 4+) in lunar samples and as roughly equal mixtures of V(sup 3+) and V(sup 4+) in Martian meteorites. In this report, we discuss the application of the V K XANES results to decipher the nature of shock reduction occurring in the silicate glasses during the impact process.

Sutton, S. R.↗

THE TURBULENCE VELOCITY POWER SPECTRUM OF NEUTRAL HYDROGEN IN THE SMALL MAGELLANIC CLOUD

We present the results of the Velocity Coordinate Spectrum (VCS) technique to calculate the velocity power spectrum of turbulence in the Small Magellanic Cloud (SMC) in 21 cm emission. We present an updated version of the VCS technique that takes into account regular motions, which is an important factor in our SMC VCS analysis. We have obtained a velocity spectral index of −3.85, a cold phase sonic Mach number of 5.6, and an injection scale of 2.3 kpc. The spectral index is steeper than the Kolmogorov index, which is expected for shock-dominated turbulence. The injection scale of 2.3 kpc suggests that HI supershells or tidal interactions with the Large Magellanic Cloud are the dominant drivers of turbulence in this dwarf galaxy. This implies that turbulence may be driven by multiple mechanisms in galaxies and that galaxy–galaxy interactions may play an important role in addition to supernova feedback.

79 ASTRONOMY AND ASTROPHYSICS↗

Multi-dimensional resilience: A quantitative exploration of disease outcomes and economic, political, and social resilience to the COVID-19 pandemic in six countries

The COVID-19 pandemic has highlighted a need for better understanding of countries’ vulnerability and resilience to not only pandemics but also disasters, climate change, and other systemic shocks. A comprehensive characterization of vulnerability can inform efforts to improve infrastructure and guide disaster response in the future. In this paper, we propose a data-driven framework for studying countries’ vulnerability and resilience to incident disasters across multiple dimensions of society. To illustrate this methodology, we leverage the rich data landscape surrounding the COVID-19 pandemic to characterize observed resilience for several countries (USA, Brazil, India, Sweden, New Zealand, and Israel) as measured by pandemic impacts across a variety of social, economic, and political domains. We also assess how observed responses and outcomes (i.e., resilience) of the COVID-19 pandemic are associated with pre-pandemic characteristics or vulnerabilities, including (1) prior risk for adverse pandemic outcomes due to population density and age and (2) the systems in place prior to the pandemic that may impact the ability to respond to the crisis, including health infrastructure and economic capacity. Our work demonstrates the importance of viewing vulnerability and resilience in a multi-dimensional way, where a country’s resources and outcomes related to vulnerability and resilience can differ dramatically across economic, political, and social domains. This work also highlights key gaps in our current understanding about vulnerability and resilience and a need for data-driven, context-specific assessments of disaster vulnerability in the future.

59 BASIC BIOLOGICAL SCIENCES↗

Proton Radiography at Los Alamos

The proton radiography (pRad) facility at Los Alamos National Lab uses high energy protons to acquire multiple frame flash radiographic sequences at megahertz speeds: that is, it can make movies of the inside of explosions as they happen. The facility is primarily used to study the damage to and failure of metals subjected to the shock forces of high explosives as well as to study the detonation of the explosives themselves. Applications include improving our understanding of the underlying physical processes that drive the performance of the nuclear weapons in the United States stockpile and developing novel armor technologies in collaboration with the Army Research Lab. The principle and techniques of pRad will be described, and examples of some recent results will be shown.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Some practical turbulence modeling options for Reynolds-averaged full Navier-Stokes calculations of three-dimensional flows

New turbulence modeling options recently implemented for the 3-D version of Proteus, a Reynolds-averaged compressible Navier-Stokes code, are described. The implemented turbulence models include: the Baldwin-Lomax algebraic model, the Baldwin-Barth one-equation model, the Chien k-epsilon model, and the Launder-Sharma k-epsilon model. Features of this turbulence modeling package include: well documented and easy to use turbulence modeling options, uniform integration of turbulence models from different classes, automatic initialization of turbulence variables for calculations using one- or two-equation turbulence models, multiple solid boundaries treatment, and fully vectorized L-U solver for one- and two-equation models. Validation test cases include the incompressible and compressible flat plate turbulent boundary layers, turbulent developing S-duct flow, and glancing shock wave/turbulent boundary layer interaction. Good agreement is obtained between the computational results and experimental data. Sensitivity of the compressible turbulent solutions with the method of y(sup +) computation, the turbulent length scale correction, and some compressibility corrections are examined in detail. The test cases show that the highly optimized one-and two-equation turbulence models can be used in routine 3-D Navier-Stokes computations with no significant increase in CPU time as compared with the Baldwin-Lomax algebraic model.

Bui, Trong T.↗

Supersonic Testing of 0.8 m Disk Gap Band Parachutes in the Wake of a 70 Deg Sphere Cone Entry Vehicle

Supersonic wind tunnel testing of Viking-type 0.8 m Disk-Gap-Band (DGB) parachutes was conducted in the NASA Glenn Research Center 10'x10' wind-tunnel. The tests were conducted in support of the Mars Science Laboratory Parachute Decelerator System development and qualification program. The aerodynamic coupling of the entry-vehicle wake to parachute flow-field is under investigation to determine the cause and functional dependence of a supersonic canopy breathing phenomenon referred to as area oscillations, characteristic of DGB's above Mach 1.5 operation. Four percent of full-scale parachutes (0.8 m) were constructed similar to the flight-article in material and construction techniques. The parachutes were attached to a 70-deg sphere-cone entry-vehicle to simulate the Mars flight configuration. The parachutes were tested in the wind-tunnel from Mach 2 to 2.5 in a Reynolds number range of 2x105 to 1x106, representative of a Mars deployment. Three different test configurations were investigated. In the first two configurations, the parachutes were constrained horizontally through the vent region to measure canopy breathing and wake interaction for fixed trim angles of 0 and 10 degrees from the free-stream. In the third configuration the parachute was unconstrained, permitted to trim and cone, similar to free-flight (but capsule motion is constrained), varying its alignment relative to the entry-vehicle wake. Non-intrusive test diagnostics were chosen to quantify parachute performance and provide insight into the flow field structure. An in-line loadcell provided measurement of unsteady and mean drag. Shadowgraph of the upstream parachute flow field was used to capture bow-shock motion and wake coupling. Particle image velocimetry provided first and second order flow field statistics over a planar region of the flow field, just upstream of the parachute. A photogrammetric technique was used to quantify fabric motion using multiple high speed video cameras to record the location in time and space of reflective targets placed on the canopy interior. The experimental findings including an updated drag model and the physical basis of the area oscillation phenomenon will be discussed.

EDL↗

CHOLLA: A NEW MASSIVELY PARALLEL HYDRODYNAMICS CODE FOR ASTROPHYSICAL SIMULATION

We present Computational Hydrodynamics On ParaLLel Architectures (Cholla ), a new three-dimensional hydrodynamics code that harnesses the power of graphics processing units (GPUs) to accelerate astrophysical simulations. Cholla models the Euler equations on a static mesh using state-of-the-art techniques, including the unsplit Corner Transport Upwind algorithm, a variety of exact and approximate Riemann solvers, and multiple spatial reconstruction techniques including the piecewise parabolic method (PPM). Using GPUs, Cholla evolves the fluid properties of thousands of cells simultaneously and can update over 10 million cells per GPU-second while using an exact Riemann solver and PPM reconstruction. Owing to the massively parallel architecture of GPUs and the design of the Cholla code, astrophysical simulations with physically interesting grid resolutions (≳256{sup 3}) can easily be computed on a single device. We use the Message Passing Interface library to extend calculations onto multiple devices and demonstrate nearly ideal scaling beyond 64 GPUs. A suite of test problems highlights the physical accuracy of our modeling and provides a useful comparison to other codes. We then use Cholla to simulate the interaction of a shock wave with a gas cloud in the interstellar medium, showing that the evolution of the cloud is highly dependent on its density structure. We reconcile the computed mixing time of a turbulent cloud with a realistic density distribution destroyed by a strong shock with the existing analytic theory for spherical cloud destruction by describing the system in terms of its median gas density.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamic compression effects of H 2 ⁡O in a dynamic diamond anvil cell: Origin of metastable ice VII and its crystal growth kinetics

We report on the structural verification of metastable ice VII solidifying in the phase space of ice VI at 1.80 GPa at room temperature. Using time-resolved (TR) x-ray diffraction and TR ruby luminescence paired with high-speed microphotography utilizing a dynamic diamond anvil cell, an initial compression rate range from 0.12 to 95.84 GPa/s was explored. The solidification pressure of metastable ice VII has a potential sigmoidal dependence upon compression rate with a turnover compression rate of ∼80 GPa/s. The preferred crystallization of ice VII in the stability field of ice VI is due to the increased nucleation rate of ice VII over ice VI at 1.77 GPa that is driven by the surface energy difference between the liquid and solid phases along with the change in Gibbs free energy of solidification. The dynamic pressure-volume–compression behaviors of ice phases (VI and VII) show a lattice stiffening in both phases, especially during the compression loading. It is also found that the compression rate greatly affects the solid-solid phase transition between ice VI and VII but does not affect the liquid-solid transition between water and ice VI as much. Lastly, a third phase transition was found to occur after metastable ice VII transforms into high-density amorphous (HDA) ice, which could be a disordered hydrogen-bonded network configuration of ice VII forming out of HDA ice facilitated by the decoupling of the oxygen movement and reorientation of the H 2⁡ O molecule. These results demonstrate the complexity of a seemingly simple molecule H 2⁡ O, how it can readily change its static properties with the modification of (de)compression rate, and highlight the need to use multiple TR structural and spectroscopic probes at higher time resolutions to realize the most comprehensive understanding.

Chemical bonding↗

Use of a Multiplexed Photonic Doppler Velocimetry (MPDV) System to Study Plastic Deformation of Metallic Steel Plates in High Velocity Impact

High-velocity impact experiments with a gas gun pose unique challenges, in terms of experimental setup and computational simulation, since the projectile-target interaction creates extreme pressure and temperature within few micro seconds. The objective of this study is to accurately measure the plastic deformation of plates under projectile impact that does not lead to full penetration. In this work, free surface velocities at the back side of target plates are measured using the newly developed Multiplexed Photonic Doppler Velocimetry (MPDV) system, which is an interferometric fiber-optic technique which can measure velocity from the Doppler shift of the light reflected from the moving back surface of the target. The MPDV system allows measurements of velocity from different locations on the target plate using multiple optical fiber probes oriented in specific directions and patterns. Data are reduced using a Fast Fourier transformation (FFT) technique to obtain the free surface velocity profiles. These velocity profiles can present insights into the dynamic behavior of impacted materials under shock loading conditions.

MPDV, multiplexing, high-velocity impact, velocime↗

Brightest Fermi-LAT flares of PKS 1222+216: implications on emission and acceleration processes

We present a high time resolution study of the two brightest γ-ray outbursts from a blazar PKS 1222+216 observed by the Fermi Large Area Telescope (LAT) in 2010. The γ-ray light curves obtained in four different energy bands, 0.1-3, 0.1-0.3, 0.3-1, and 1-3 GeV, with time bins of six hours, show asymmetric profiles with similar rise times in all the bands but a rapid decline during the April flare and a gradual one during the June flare. The light curves during the April flare show an ∼2 day long plateau in 0.1-0.3 GeV emission, erratic variations in 0.3-1 GeV emission, and a daily recurring feature in 1-3 GeV emission until the rapid rise and decline within a day. The June flare shows a monotonic rise until the peak, followed by a gradual decline powered mainly by the multi-peak 0.1-0.3 GeV emission. The peak fluxes during both the flares are similar except in the 1-3 GeV band in April, which is twice the corresponding flux during the June flare. Hardness ratios during the April flare indicate spectral hardening in the rising phase followed by softening during the decay. We attribute this behavior to the development of a shock associated with an increase in acceleration efficiency followed by its decay leading to spectral softening. The June flare suggests hardening during the rise followed by a complicated energy dependent behavior during the decay. Observed features during the June flare favor multiple emission regions while the overall flaring episode can be related to jet dynamics.

79 ASTRONOMY AND ASTROPHYSICS↗

MPT Prediction of Aircraft-Engine Fan Noise

A collection of computer programs has been developed that implements a procedure for predicting multiple-pure-tone (MPT) noise generated by fan blades of an aircraft engine (e.g., a turbofan engine). MPT noise arises when the fan is operating with supersonic relative tip Mach No. Under this flow condition, there is a strong upstream running shock. The strength and position of this shock are very sensitive to blade geometry variations. For a fan where all the blades are identical, the primary tone observed upstream of the fan will be the blade passing frequency. If there are small variations in geometry between blades, then tones below the blade passing frequency arise MPTs. Stagger angle differences as small as 0.1 can give rise to significant MPT. It is also noted that MPT noise is more pronounced when the fan is operating in an unstarted mode. Computational results using a three-dimensional flow solver to compute the complete annulus flow with non-uniform fans indicate that MPT noise can be estimated in a relatively simple way. Hence, once the effect of a typical geometry variation of one blade in an otherwise uniform blade row is known, the effect of all the blades being different can be quickly computed via superposition. Two computer programs that were developed as part of this work are used in conjunction with a user s computational fluid dynamics (CFD) code to predict MPT spectra for a fan with a specified set of geometric variations: (1) The first program ROTBLD reads the users CFD solution files for a single blade passage via an API (Application Program Interface). There are options to replicate and perturb the geometry with typical variations stagger, camber, thickness, and pitch. The multi-passage CFD solution files are then written in the user s file format using the API. (2) The second program SUPERPOSE requires two input files: the first is the circumferential upstream pressure distribution extracted from the CFD solution on the multi-passage mesh, the second file defines the geometry variations of each blade in a complete fan. Superposition is used to predict the spectra resulting from the geometric variations.

Connell, Stuart D.↗

MELDI2 Do No Harm Test Series

Mars 2020 will fly the Mars Entry, Descent, and Landing Instrumentation II (MEDLI2) sensor suite consisting of a total of seventeen instrumented thermal sensor plugs, eight pressure transducers, two heat flux sensors, and one radiometer embedded in the thermal protection system (TPS). Of the MEDLI2 instrumentation, eleven instrumented thermal plugs and seven pressure transducers will be installed on the heatshield of the Mars 2020 vehicle while the rest will be installed on the backshell. The goal of the MEDLI2 instrumentation is to directly inform the large performance uncertainties that contribute to the design and validation of a Mars entry system. A better understanding of the entry environment and TPS performance could lead to reduced design margins enabling a greater payload mass-fraction and smaller landing ellipses. To prove that the MEDLI2 system will not degrade the performance of the Mars 2020 TPS, an Aerothermal Do No Harm (DNH) test series was designed and conducted. Like Mars 2020's predecessor, Mars Science Laboratory (MSL), the heatshield material will be Phenolic Impregnated Carbon Ablator (PICA); the Mars 2020 entry conditions are enveloped by the MSL design environments, therefore the development and qualification testing performed during MEDLI is sufficient to show that the similar MEDLI2 heatshield instrumentation will not degrade PICA performance. However, given that MEDLI did not include any backshell instrumentation, the MEDLI2 team was required to design and execute a DNH test series utilizing the backshell TPS material (SLA-561V) with the intended flight sensor suite. To meet the requirements handed down from Mars 2020, the MEDLI2 DNH test series emphasized the interaction between the MEDLI2 sensors and sensing locations with the surrounding backshell TPS and substrucutre. These interactions were characterized by performing environmental testing of four 12" by 12" test panels, which mimicked the construction of the backshell TPS and the integration of the MEDLI2 sensors as seen in Figure 1. The testing included thermal vacuum/ cycling, random vibration, shock, and arc jet testing. The test panels were fabricated by Lockheed Martin, establishing techniques that will be utilized during the Mars 2020 vehicle installation. Each test panel included one thermal sensor plug (two embedded thermocouples), one heat flux sensor, and multiple pressure port holes for evaluation. This presentation will discuss the planning and execution of the MEDLI2 DNH test series. Selected highlights and results of each environmental test will be presented, and lessons learned will be addressed that will feed forward into the planning for the MEDLI2 flight system certification testing.

Heatshield↗

Mars2020 Entry, Descent, and Landing Instrumentation 2 (MEDLI2) Do No Harm Test Series

A total of seventeen instrumented thermal sensor plugs, eight pressure transducers, two heat flux sensors, and one radiometer are planned to be utilized on the Mars 2020 missions thermal protection system (TPS) as part of the Mars Entry, Descent, and Landing Instrumentation II (MEDLI2) project. Of the MEDLI2 instrumentation, eleven instrumented thermal plugs and seven pressure transducers will be installed on the heatshield of the Mars 2020 vehicle while the rest will be installed on the backshell. The goal of the MEDLI2 instrumentation is to directly inform the large performance uncertainties that contribute to the design and validation of a Mars entry system. A better understanding of the entry environment and TPS performance could lead to reduced design margins enabling a greater payload mass-fraction and smaller landing ellipses. To prove that the MEDLI2 system will not degrade the performance of the Mars 2020 TPS, an Aerothermal Do No Harm (DNH) test series was designed and conducted. Like Mars 2020s predecessor, Mars Science Laboratory (MSL), the heatshield material will be Phenolic Impregnated Carbon Ablator (PICA); the Mars 2020 entry conditions are enveloped by the MSL design environments, therefore the development and qualification testing performed during MEDLI is sufficient to show that the similar MEDLI2 heatshield instrumentation will not degrade PICA performance. However, given that MEDLI did not include any backshell instrumentation, the MEDLI2 team was required to design and execute a DNH test series utilizing the backshell TPS material (SLA-561V) with the intended flight sensor suite. To meet the requirements handed down from Mars 2020, the MEDLI2 DNH test series emphasized the interaction between the MEDLI2 sensors and sensing locations with the surrounding backshell TPS and substrucutre. These interactions were characterized by performing environmental testing of four 12 by 12 test panels, which mimicked the construction of the backshell TPS and the integration of the MEDLI2 sensors as seen in Figure 1. The testing included thermal vacuumcycling, random vibration, shock, and arc jet testing. The test panels were fabricated by Lockheed Martin, establishing techniques that will be utilized during the Mars 2020 vehicle installation. Each test panel included one thermal sensor plug (two embedded thermocouples), one heat flux sensor, and multiple pressure port holes for evaluation.This presentation will discuss the planning and execution of the MEDLI2 DNH test series. Selected highlights and results of each environmental test will be presented, and lessons learned will be addressed that will feed forward into the planning for the MEDLI2 flight system certification testing.

backshell↗

GAMMA-RAY BURST SPECTRA AND SPECTRAL CORRELATIONS FROM SUB-PHOTOSPHERIC COMPTONIZATION

One of the most important unresolved issues in gamma-ray burst (GRB) physics is the origin of the prompt gamma-ray spectrum. Its general non-thermal character and the softness in the X-ray band remain unexplained. We tackle these issues by performing Monte Carlo simulations of radiation–matter interactions in a scattering dominated photon–lepton plasma. The plasma—initially in equilibrium—is driven to non-equilibrium conditions by a sudden energy injection in the lepton population, mimicking the effect of a shock wave or the dissipation of magnetic energy. Equilibrium restoration occurs due to an energy exchange between the photons and leptons. While the initial and final equilibrium spectra are thermal, the transitional photon spectra are characterized by non-thermal features such as power-law tails, high energy bumps, and multiple components. Such non-thermal features are observed at infinity if the dissipation occurs at small to moderate optical depths, and the spectrum is released before thermalization is complete. We model the synthetic spectra with a Band function and show that the resulting spectral parameters are similar to observations for a frequency range of 2–3 orders of magnitude around the peak. In addition, our model predicts correlations between the low-frequency photon index and the peak frequency as well as between the low- and high-frequency indices. We explore baryon and pair-dominated fireballs and reach the conclusion that baryonic fireballs are a better model for explaining the observed features of GRB spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

The Effect of Shock on the Amorphous Component in Altered Basalt

Investigation of the geochemical and mineralogical composition of the Martian surface provides insight into the geologic history of the predominantly basaltic crust. The Chemistry and Mineralogy (CheMin) instrument onboard the Curiosity rover has returned the first X-Ray diffraction data from the Martian surface. However, large proportions (27 +/- 14 with some estimates as high as 50 weight percentage) of an amorphous component have been reported. As a remedy to this problem, mass balance equations using geochemistry, volatile chemistry, and mineralogy have been employed to constrain the geochemistry of the amorphous component. However, "the nature and number of amorphous phases that constitute the amorphous component is not unequivocally known". Multiple hypotheses have been proposed to explain the origin of this amorphous component: Allophane (Al2O); Basaltic glass (Volcanic and impact); Palagonite (Altered basaltic glass); Hisingerite (Fe (sup 3 plus)-bearing phyllosilicate); S/Cl-rich component (sulfates and/or akaganeite); Nanophase ferric oxide component (npOx). Establishing a multi-phase amorphous component from a basaltic precursor that has undergone physical and chemical weathering within geochemical constraints is of paramount importance to better understand the composition of a large portion of the Martian surface (up to 50 weight percentage). Shocked basalts from Lonar Crater in India are valuable analogs for the Martian surface because it is a well-preserved impact crater in a basaltic target. Having undergone pre- and post-shock aqueous alteration, these rocks provide crucial data regarding the effect of shock on the amorphous component in altered basalt. By conducting mass balance equations similar to what has been performed for Gale crater materials, we attempt to calculate the geochemistry of the amorphous component in altered basalts ranging from unshocked to Class 5 (Table 1). This has the potential to reveal the nature and origin (i.e. primary igneous, shock metamorphic, and/or aqueous alteration occurring before or after the impact event) of the amorphous component in shocked basalt with the goal of unravelling the history of the Martian surface.

Eckley, S. A.↗