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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Determining the Absorbance Spectra of Photochromic Materials From Measured Spectrophotometer Data

If a two-state photochromic material is optically bleached, the absorbance spectrum data measured by a spectrophotometer is in general comprised of components from both the ground state and the upper state. Under general conditions, it may be difficult to extract the actual upper state spectrum from the spectrum of the bleached material. A simple algorithm is presented here for the recovery of the pure absorbance spectra of the upper state of a material such as bacteriorhodopsin, given single wavelength bleaching illumination, steady-state conditions, and accurate knowledge of phototransition rates and thermal decay rates.

Downie, John D.↗
NASA NTRS2015

Determining the Covering Factor of Compton-Thick Active Galactic Nuclei with NuSTAR

The covering factor of Compton-thick (CT) obscuring material associated with the torus in active galactic nuclei (AGNs) is at present best understood through the fraction of sources exhibiting CT absorption along the line of sight (N(sub H) greater than 1.5 x 10(exp 24) cm(exp −2)) in the X-ray band, which reveals the average covering factor. Determining this CT fraction is difficult, however, due to the extreme obscuration. With its spectral coverage at hard X-rays (greater than 10 keV), Nuclear Spectroscopic Telescope Array (NuSTAR) is sensitive to the AGNs covering factor since Compton scattering of X-rays off optically thick material dominates at these energies. We present a spectral analysis of 10 AGNs observed with NuSTAR where the obscuring medium is optically thick to Compton scattering, so-called CT AGNs. We use the torus models of Brightman and Nandra that predict the X-ray spectrum from reprocessing in a torus and include the torus opening angle as a free parameter and aim to determine the covering factor of the CT gas in these sources individually. Across the sample we find mild to heavy CT columns, with N(sub H) measured from 10(exp 24) to 10(exp 26) cm(exp −2), and a wide range of covering factors, where individual measurements range from 0.2 to 0.9. We find that the covering factor, f(sub c), is a strongly decreasing function of the intrinsic 2-10 keV luminosity, L(sub X), where f(sub c) = (−0.41 +/- 0.13)log(sub 10)(L(sub X)/erg s(exp −1))+18.31 +/- 5.33, across more than two orders of magnitude in L(sub X) (10(exp 41.5) - 10(exp 44) erg s(exp −1)). The covering factors measured here agree well with the obscured fraction as a function of LX as determined by studies of local AGNs with L(sub X) greater than 10(exp 42.5) erg s(exp −1).

NGC 4945↗
DOE OSTI2023

First-Principles Understanding of Optical Excitations within Low-Dimensional Materials

The objective of this project is to utilize first-principles computational approaches to understand optical excitations within two-dimensional monolayers and heterostructures, with the ultimate goal of designing new materials by modifying the chemical and physical structure on the nanoscale. In 2D heterostructures, the nature and movement of the exciton is determined to a large extent by the electron-electron and electron-phonon strengths within individual monolayers, as well as the coupling between layers, all of which in turn depend on chemistry, solid-state screening properties, and quantum confinement. Controlling the nature and migration properties of excitons requires an understanding of the complex relationship between electrons, phonons, defects, disorder, and dynamics. The aim of this project is to determine, by analysis of highly accurate density functional theory (DFT) and many-body perturbation theory (MBPT) calculations, how these complexities can be decomposed into simple, tunable parameters. The specific goals of this project are to 1) understand electron conductivity, absorption and transparency of monolayer semiconductors and metals; 2) develop a theory of excitons near defects in low dimensions; and 3) understand the influence of inter-layer interactions in heterostructures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Melt Blending: A Tool to Simplify Plastic Scintillator Synthesis

Plastic scintillators are widely used as radiation detection media in homeland security and nuclear physics applications. Their attributes include low cost, scalability to large detector volumes, and additive compounding to enable additional material and detection features, such as pulse shape discrimination (PSD), gamma-ray spectroscopy, aging resistance, and coincidence timing. However, traditional chemically cured plastic scintillators (CCS) require long reaction times, and hazardous wet chemical procedures performed by specially trained personnel, and can leave residual monomer, resulting in deleterious optical and material properties. Here, we synthesize melt blended scintillators (MBSs) in 2.5 days using easily accessible solid-state compounding of commercially-available poly(styrene) with 30–60 wt% fluorene-based compound “P2” to create monolithic detectors with < 100 ppm residual monomer, in several form factors. Further, the best scintillation performance was recorded for 60 wt% P2 in Styron 665, including gamma-ray light yield 139% of EJ- 200 commercial scintillator and PSD figure of merit (FOM) value of 2.65 at 478 keVee, approaching P2 organic glass scintillator (OGS). The capability of MBS to generate fog-resistant scintillators and poly(methyl methacrylate) (PMMA)-based scintillators for use in challenging environments is also demonstrated.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2024

Opto-twistronic Hall effect in a three-dimensional spiral lattice

Studies of moire systems have elucidated the exquisite effect of quantum geometry on the electronic bands and their properties, leading to the discovery of new correlated phases. However, most experimental studies have been confined to a few layers in the 2D limit. The extension of twistronics to its 3D limit, where the twist is extended into the third dimension between adjacent layers, remains underexplored due to the challenges in precisely stacking layers. Here, in this study, we focus on 3D twistronics on a platform of self-assembled spiral superlattice of multilayered WS 2 . Our findings reveal an opto-twistronic Hall effect in the spiral superlattice. This mesoscopic response is an experimental manifestation of the noncommutative geometry that arises when translational symmetry is replaced by a non-symmorphic screw operation. We also discover signatures of altered laws of optical excitation, manifested as an unconventional photon momentum-lattice interaction owing to moire of moire modulations in the 3D twistronic system. Crucially, our findings mark the initial identification of higher-order quantum geometrical tensors in light-matter interactions. This breakthrough opens new avenues for designing quantum materials-based optical lattices with large nonlinearities, paving the way for the development of advanced quantum nanophotonic devices.

Ji, Zhurun↗
NASA NTRS1992

LDEF active optical system components experiment

A preliminary report on the Active Optical System Components Experiment is presented. This experiment contained 136 components in a six inch deep tray including lasers, infrared detectors and arrays, ultraviolet light detectors, light-emitting diodes, a light modulator, flash lamps, optical filters, glasses, and samples of surface finishes. Thermal, mechanical, and structural considerations leading to the design of the tray hardware are discussed. In general, changes in the retested component characteristics appear as much related to the passage of time as to the effects of the space environment, but organic materials, multilayer optical interference filters, and extreme-infrared reflectivity of black paints show unexpected changes.

M D Blue↗
NASA NTRS1977

Optical polarimetry: Instrumentation and applications; Proceedings of the Seminar, San Diego, Calif., August 23, 24, 1977

Instrumentation used in optical polarimetry is discussed with reference to high-resolution spectropolarimetry, an orbiter cloud photopolarimeter, X-ray polarimeters, and the design of a self-nulling ellipsometer. Consideration is given to surface and thin-film ellipsometry noting studies of electrochemical surface layers, surface anisotropy, polish layers on infrared window materials, and anodic films. Papers on biological, chemical, and physical polarimetry are presented including birefringence in biological materials, vibrational optical activity, and the optical determination of the thermodynamic phase diagram of a metamagnet. Remote sensing is discussed in terms of polarization imagery, the optical polarimetry of particulate surfaces, and techniques and applications of elliptical polarimetry in astronomy and atmospheric studies.

Azzam, R. M. A.↗
NASA NTRS1975

Water color and circulation southern Chesapeake Bay, part 1

Satellite imagery from two EREP passes over the Rappahannock Estuary of the Chesapeake region is analyzed to chart colored water types, to delineate color boundaries and define circulatory patterns. Surface observations from boats and helicopters concurrent with Skylab overpass define the distributions of suspended sediment, transparency, temperature, salinity, phytoplankton, color of suspended material and optical ratio. Important features recorded by the imagery are a large-scale turbidity maximum and massive red tide blooms. Water movement is revealed by small-scale mixing patterns and tidal plumes of apparent sediment-laden water. The color patterns broadly reflect the bottom topography and the seaward gradient of suspended material between the river and the bay. Analyses of red, green and natural color photos by microdensitometry demonstrate the utility of charting water color types of potential use for managing estuarine water quality. The Skylab imagery is superior to aerial photography and surface observations for charting water color.

Nichols, M. M.↗
DOE OSTI2020

Unusual superparamagnetic behavior in bulk Ba 0.198 La 0.784 Ti 0.096 Fe 0.8 O 3-δ

Here, we report the observation of superparamgnetic behavior induced by the substitution La 3+ by Ba 2+ at A-sites and Fe +3 by Ti 4+ at B-sites. Ba 0.198 La 0.784 Ti 0.096 Fe 0.8 O 3-δ was synthesized via solid state reaction. The Rietveld refinements revealed an orthorhombic (Pbnm). The low-mag STEM results showed that the particles were found to exhibit square like shape and formed in single crystal with high degree of crystallinity. The particle size ranges of 50 300 nm. Element mapping demonstrates a complementary distribution between Ba and La, while homogenous distribution is found for Fe and O. The optical band gap determined from UV-vis analysis is equal to 1.93 eV which is smaller than the reported one for LaFeO 3 and BaTiO 3 . The hysteresis loops at 300 K and 10 K show superparamagnetic behavior, which deviate extremely from the antiferromagnetic nature of LaFeO 3 perovskite. The temperature dependent magnetization demonstrates that the material kept a net magnetization of 12.29 (emu/g) at very low temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Direct dark matter searches with metal halide perovskites

Polar materials with optical phonons in the meV range are excellent candidates for both dark matter direct detection via dark photon-mediated scattering and light dark matter absorption. In this study, we propose, for the first time, the metal halide perovskites MAPbI 3 , MAPbCl 3 , and CsPbI 3 for these purposes. Our findings reveal that CsPbI 3 is the best material, significantly improving exclusion limits compared to other polar materials. For scattering, CsPbI 3 can probe dark matter masses down to the keV range. For absorption, it enhances sensitivity to detect dark photon masses below ∼10 meV. The only material that has so far been investigated and that could provide competitive bounds is CsI, which, however, demonstrates lower stability as device platform compared to CsPbI 3 . Moreover, CsI is isotropic while the anisotropic structure of CsPbI 3 enables daily modulation analysis, showing that a significant percentage of daily modulation exceeding 1% is achievable for dark matter masses below 40 keV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1997

Poling of Microwave Electro-Optic Devices

The desire to transmit high frequency, microwave RF signals over fiber optic cables has necessitated the need for electro-optic modulation devices. However, in order to reap these potential benefits, it is necessary to develop the devices and their associated fabrication processes, particularly those processes associated with the poling of the devices. To this end, we entered into a cooperative research agreement with Richard Kunath of NASA LeRC. A graduate student in my group, Tony Kowalczyk, worked closely with the group at NASA to develop processes for construction of a microwave frequency electro-optic modulator. Materials were commercially obtained from Amoco Chemical and in collaboration with Lockheed-Martin. The photolithography processes were developed at NASA LeRC and the electric-field poling process was carried out in our laboratory at CWRU. During the grant period, the poling process conditions were investigated for these multilayer devices. Samples were poled and the resulting nonlinear optical properties were evaluated in our laboratory. Following the grant period, Kowalczyk went to NASA under a NRC fellowship, and I continued to collaborate as a consultant. Publications listed at the end of this report came out of this work. Another manuscript is in preparation and will be submitted shortly.

Singer, Kenneth D.↗
DOE OSTI2023

Photostability of blue phosphorescent films on plasmonic surfaces

Organometallic phosphors are an important class of emissive materials used in high-efficiency organic light-emitting devices. However, problems of low photostability arise for blue-emitting phosphors due to chemical and environmental degradation and triplet quenching processes. Various approaches have been developed to improve the photostability of such phosphors, including the design of new organometallic molecules and control of host-dopant composition in thin films. Here, we demonstrate a different approach for improving the photostability of blue organometallic phosphors that uses localized surface plasmon resonances to increase the triplet recombination rate. The increased recombination rate improves the photostability of the phosphor due to the reduction in triplet quenching pathways. We show that the lifetime of phosphorescence is decreased significantly by nanoparticle-based plasmonic surfaces, which improves the photostability of the blue organometallic phosphor by up to a factor of 3.6. Other plasmonic surfaces are also tested and exhibit less significant photostability improvements due to a reduced spectral overlap of the plasmonic modes with the emitter and lower mode confinement. The use of plasmonic surfaces to improve phosphor photostability at blue wavelengths is distinct from other approaches because it involves modification to the local electromagnetic environment of the phosphor rather than modifications to the phosphor molecular structure or the emitting material composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Interferometric measurements of refractive index and dispersion at high pressure

Abstract We describe a high precision interferometer system to measure the pressure dependence of the refractive index and its dispersion in the diamond anvil cell (DAC). The reflective Fabry–Perot fringe patterns created by both a white light and a monochromatic beam are recorded to determine both the sample thickness and its index at the laser wavelength and to characterize the dispersion in the visible range. Advances in sample preparation, optical setup, and data analysis enable us to achieve $$10^{-4}$$ 10 - 4 random uncertainty, demonstrated with an air sample, a factor of five improvement over the best previous DAC measurement. New data on $${\text{H}}_{2}\text{O}$$ H 2 O liquid water and ice VI up to 2.21 GPa at room temperature illustrate how higher precision measurements of the index and its optical dispersion open up new opportunities to reveal subtle changes in the electronic structure of water at high pressure.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1973

Spectral reflectance and emittance of particulate materials. I - Theory. II - Application and results

The sizes, shapes, and complex refractive indices of particles are calculated in a study of the IR spectral reflectance of a semiinfinite medium composed of irregular particles of different materials. Geometric optics techniques with corrections for additional absorption due to particle edges and asperities is used in scattering and absorption calculations for particles larger than the wavelength. A Lorentz-Lorenz model is used to derive the averaged complex index of the medium, assuming that its individual particles are ellipsoids. Experimental results obtained on a Michelson interferometer for the spectral emittance of particulate mineral materials are compared with theoretical results. Good agreement between the experimental and theoretical results suggests the applicability, in remote IR spectroscopy, of the theoretical concepts applied in this study.

Emslie, A. G.↗
NASA NTRS2002

Vapor transport growth of organic solids in microgravity and unit gravity: some comparisons and results to date

Thin films of an organic nonlinear optical (NLO) material, N, N-dimethyl-p-(2,2-dicyanovinyl) aniline (DCVA), have been grown in space and on the ground by physical vapor transport in an effusive ampoule arrangement. The thin film growth technique developed on the ground is a direct result of information gleaned from experiments in microgravity. This paper covers the results of our experimental investigations for establishing "ideal" terrestrial conditions for deposition of a DCVA film. The active control during the deposition process was exercised by three deposition variables: the material source temperature, the background pressure external to the growth ampoule and the substrate temperature. Successful growth occurred when the difference in temperature between the source material and the copper substrate was 14 degrees C and the background nitrogen pressure was such that the transport was either diffusive or convective. A qualitative diffusion limited boundary was estimated to occur at a pressure of approximately 20 torr. We have probed the DCVA thin films with visible-near infrared reflection absorption spectroscopy, polarized Fourier transform infrared spectrometry, differential interference contrast optical microscopy, and stylus profilometry.

short duration↗
NASA NTRS1983

A multiwavelength study of the short-period cataclysmic variable V442 Ophiuchi

The results of a program of observations of the cataclysmic variable V442 Oph from UV to IR wavelengths are reported. The observations comprise IUE SWP and LWR-camera spectra from October, 1981; UBVr and R photometry at Manastash Ridge Observatory from August, 1980; UBV photometry and IR measurements at Kitt Peak from July, 1981; and Coudespectroscopy at Mt. Wilson from June, 1980, and at Mt Lemmon from July, 1982. Tables of data, plots of H-alpha and He-II radial velocity, sample spectra, light curves, and a log-log diagram of F(lambda) vs lambda are given. Flux-ratio analysis of the IR data indicates a disk with very little optically thin material anad an outer-edge temperature of about 7920 K. The calculated period (3.37 h) and mass-accretion rate (1 x 10 to the -8th solar mass/yr) are compared to those of similar objects, and V442 Oph is found to be similar in this respect to systems like H2252-035. Its lack of a rotational period and the weakness of the optical and UV line emissions, however, are more like the old nova V603 Aql.

Shafter, A. W.↗
NASA NTRS2004

Mission Concept for the Single Aperture Far-Infrared (SAFIR) Observatory

We have developed a preliminary but comprehensive mission concept for SAFIR, as a 10 m-class far-infrared and submillimeter observatory that would begin development later in this decade to meet the needs outlined above. Its operating temperature (< or = 4K) and instrument complement would be optimized to reach the natural sky confusion limit in the far-infrared with diffraction-limited performance down to at least the atmospheric cutoff, lambda > or approx. 40 microns. This would provide a point source sensitivity improvement of several orders of magnitude over that of the Spitzer Space Telescope (previously SIRTF) or the Herschel Space Observatory. Additionally, it would have an angular resolution 12 times finer than that of Spitzer and three times finer than Herschel. This sensitivity and angular resolution are necessary to perform imaging and spectroscopic studies of individual galaxies in the early universe. We have considered many aspects of the SAFIR mission, including the telescope technology (optical design, materials, and packaging), detector needs and technologies, cooling method and required technology developments, attitude and pointing, power systems, launch vehicle, and mission operations. The most challenging requirements for this mission are operating temperature and aperture size of the telescope, and the development of detector arrays. SAFIR can take advantage of much of the technology under development for JWST, but with much less stringent requirements on optical accuracy.

Benford, Dominic J.↗