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At least 595 records · Page 33

Radial pulsations in DB white dwarfs?

Theoretical models of DB white dwarfs are unstable against radial pulsation at effective temperatures near 20,000-30,000 K. Many high-overtone modes are unstable, with periods ranging from 12 s down to the acoustic cutoff period of approximately 0.1 s. The blue edge for radial instability lies at slightly higher effective temperatures than for nonradial pulsations, with the temperature of the blue edge dependent on the assumed efficiency of convection. Models with increased convective efficiency have radial blue edges that are increasingly closer to the nonradial blue edge; in all models the instability persists into the nonradial instability strip. Radial pulsations therefore may exist in the hottest DB stars that lie below the DB gap; the greatest chance for detection would be observations in the ultraviolet. These models also explain why searches for radial pulsations in DA white dwarfs have failed: the efficient convection needed to explain the blue edge for nonradial DA pulsation means that the radial instability strip is 1000 K cooler than found in previous investigations. The multiperiodic nature of the expected pulsations can be used to advantage to identify very low amplitude modes using the uniform spacing of the modes in frequency. This frequency spacing is a direct indicator of the mass of the star.

Kawaler, Steven D.↗

Generation of lognormal synthetic Lyman-α forest spectra for P 1 D analysis

The one-dimensional flux power spectrum (P 1 D ) of the Lyman-α forest probes small-scale structure in the intergalactic medium (IGM) and is therefore sensitive to a variety of cosmological and astrophysical parameters. These include the amplitude and shape of the matter power spectrum, the thermal history of the IGM, the sum of neutrino masses, and potential small-scale fluctuations due to the nature of dark matter. However, P 1 D is also highly sensitive to observational and instrumental systematics, making accurate synthetic spectra essential for validating analyses and quantifying these effects, especially in high-volume surveys like the Dark Energy Spectroscopic Instrument (DESI). We present an efficient lognormal mock framework for generating one-dimensional Lyman-α forest spectra tailored for P 1 D analysis. Our method captures the redshift evolution of the mean transmitted flux and the scale-dependent shape and amplitude of the one-dimensional flux power spectrum by tuning Gaussian field correlations and transformation parameters. Across the DESI Early Data Release (EDR) redshift range (2.0 ≤ z ≤ 3.8), and a wide range of scales (10 -4 s km -1 ≤ k ≤ 1.0 s km -1 ), our mocks recover the mean flux evolution with redshift to sub-percent accuracy, and the P 1 D at the percent level. Additionally, we discuss potential extensions of this framework, such as the incorporation of astrophysical contaminants, continuum uncertainties, and instrumental effects. Such improvements would expand its utility in ongoing and upcoming surveys and enable a broader range of validation efforts and systematics studies for P 1 D inference and precision cosmology.

Lyman alpha forest↗

Mid-Latitude Temperatures at 87 km: Results From Multi-Instrument Fourier Analysis

Using a novel Fourier fitting method we combine two years of mid-latitude temperature measurements at 87 km from the High Resolution Doppler Imager, the Colorado State University lidar, and the Peach Mountain Interferometer. After accounting for calibration bias, significant local-time variations on the order of 10 K were observed. Stationary planetary waves with amplitudes up to 10 K were observed during winter, with weaker wave amplitudes occurring during other seasons. Because of calibration biases among these instruments, we could estimate the annual mean temperature to no better than 193.5 plus or minus 8.5 K.

FOURIER ANALYSIS↗

Quantifying and attributing time step sensitivities in present-day climate simulations conducted with EAMv1

Abstract. This study assesses the relative importance of time integration error in present-day climate simulations conducted with the atmosphere component of the Energy Exascale Earth System Model version 1 (EAMv1) at 1∘ horizontal resolution. We show that a factor-of-6 reduction of time step size in all major parts of the model leads to significant changes in the long-term mean climate. Examples of changes in 10-year mean zonal averages include the following: up to 0.5 K of warming in the lower troposphere and cooling in the tropical and subtropical upper troposphere, 1 %–10 % decreases in relative humidity throughout the troposphere, and 10 %–20 % decreases in cloud fraction in the upper troposphere and decreases exceeding 20 % in the subtropical lower troposphere. In terms of the 10-year mean geographical distribution, systematic decreases of 20 %–50 % are seen in total cloud cover and cloud radiative effects in the subtropics. These changes imply that the reduction of temporal truncation errors leads to a notable although unsurprising degradation of agreement between the simulated and observed present-day climate; to regain optimal climate fidelity in the absence of those truncation errors, the model would require retuning. A coarse-grained attribution of the time step sensitivities is carried out by shortening time steps used in various components of EAM or by revising the numerical coupling between some processes. Our analysis leads to the finding that the marked decreases in the subtropical low-cloud fraction and total cloud radiative effect are caused not by the step size used for the collectively subcycled turbulence, shallow convection, and stratiform cloud macrophysics and microphysics parameterizations but rather by the step sizes used outside those subcycles. Further analysis suggests that the coupling frequency between the subcycles and the rest of EAM significantly affects the subtropical marine stratocumulus decks, while deep convection has significant impacts on trade cumulus. The step size of the cloud macrophysics and microphysics subcycle itself appears to have a primary impact on cloud fraction in the upper troposphere and also in the midlatitude near-surface layers. Impacts of step sizes used by the dynamical core and the radiation parameterization appear to be relatively small. These results provide useful clues for future studies aiming at understanding and addressing the root causes of sensitivities to time step sizes and process coupling frequencies in EAM. While this study focuses on EAMv1 and the conclusions are likely model-specific, the presented experimentation strategy has general value for weather and climate model development, as the methodology can help researchers identify and understand sources of time integration error in sophisticated multi-component models.

54 ENVIRONMENTAL SCIENCES↗

Transport phenomena in the micropores of plug-type phase separators

This study numerically investigates the transport phenomena within and across a porous-plug phase separator. The effect of temperature differential across a single pore and of the sidewall boundary conditions, i.e., isothermal or linear thermal gradient, are presented and discussed. The effects are quantified in terms of the evaporation mass flux across the boundary and the mean surface temperature. A two-dimensional finite element model is used to solve the continuity, momentum, and energy equations for the liquid. Temperature differentials across the pore interface of 1.0, and 1.5 K are examined and their effect on evaporation flux and mean surface temperature is shown. For isothermal side boundary conditions, the evaporation flux across the pore is directly proportional and linear with Delta T. For the case of an imposed linear thermal gradient on the side boundaries, Biot numbers of 0.0, 0.15, and 0.5 are examined. The most significant effect of Biot number is to lower the overall surface temperature and evaporation flux.

Fazah, M. M.↗

Elastohydrodynamic film thickness measurements with advanced ester, fluorocarbon, and polyphenyl ether lubricants to 589 K (600 F)

Elastohydrodynamic (EHD) film thicknesses have been measured, by means of an X-ray technique, under conditions that closely simulate the ball-race contact in advanced turbine engine thrust bearings. The experiments were conducted with a rolling-disk machine using disks which yield a contact zone similar to that in the actual bearing. Both the rolling and spinning motions of the ball relative to the race were simulated by the apparatus. Four lubricants were evaluated at temperatures to 600 F and maximum Hertz stresses to 350,000 psi. The X-ray film thickness data correlated well with observations of surface distress (or lack thereof) in full-scale bearing tests with the same lubricants under similar conditions of temperature and load. The predicted variation of film thickness with speed and viscosity as verified, although the magnitude of measured film thickness was generally one-half to one-third of predicted values. An effect of stress greater than predicted was consistently observed in the higher stress range.

Parker, R. J.↗

Kinetics study of the reactions of NO with FO, ClO, BrO, and IO at 298 K

The kinetics of the four considered reactions were studied by means of the discharge flow/mass spectrometric technique. The discharge flow/mass spectrometer has been described by Sander et al. (1981). The flow velocity in the investigation was varied in the range from 750 to 2100 cm/s, while total pressures in the range from 1.0 torr to 2.1 torr were employed. The results of the study are compared to the values of current literature. With minor exceptions, the new results are in excellent agreement with the data of the previous studies. It is pointed out that the reported results will have a minimal impact on the predictions of atmospheric photochemical model calculations as they have confirmed prior expectations.

Ray, G. W.↗

Evaluation of water cooled supersonic temperature and pressure probes for application to 1366 K flows

Water cooled supersonic probes are developed to investigate total pressure, static pressure, and total temperature in high-temperature jet plumes and thereby determine the mean flow properties. Two probe concepts, designed for operation at up to 1366 K in a Mach 2 flow, are tested on a water cooled nozzle. The two probe designs - the unsymmetric four-tube cooling configuration and the symmetric annular cooling design - take measurements at 755, 1089, and 1366 K of the three parameters. The cooled total and static pressure readings are found to agree with previous test results with uncooled configurations. The total-temperature probe, however, is affected by the introduction of water coolant, and effect which is explained by the increased heat transfer across the thermocouple-bead surface. Further investigation of the effect of coolant on the temperature probe is proposed to mitigate the effect and calculate more accurate temperatures in jet plumes.

Lagen, Nicholas↗

Thin film temperature sensor

Thin film surface temperature sensors were developed. The sensors were made of platinum-platinum/10 percent rhodium thermocouples with associated thin film-to-lead wire connections and sputtered on aluminum oxide coated simulated turbine blades for testing. Tests included exposure to vibration, low velocity hydrocarbon hot gas flow to 1250 K, and furnace calibrations. Thermal electromotive force was typically two percent below standard type S thermocouples. Mean time to failure was 42 hours at a hot gas flow temperature of 1250 K and an average of 15 cycles to room temperature. Failures were mainly due to separation of the platinum thin film from the aluminum oxide surface. Several techniques to improve the adhesion of the platinum are discussed.

Grant, H. P.↗

Climate Change Projection in the Twenty-First Century Simulated by NIMS-KMA CMIP6 Model Based on New GHGs Concentration Pathways

Abstract The National Institute of Meteorological Sciences-Korea Meteorological Administration (NIMS-KMA) has participated in the Coupled Model Inter-comparison Project (CMIP) and provided long-term simulations using the coupled climate model. The NIMS-KMA produces new future projections using the ensemble mean of KMA Advanced Community Earth system model (K-ACE) and UK Earth System Model version1 (UKESM1) simulations to provide scientific information of future climate changes. In this study, we analyze four experiments those conducted following the new shared socioeconomic pathway (SSP) based scenarios to examine projected climate change in the twenty-first century. Present day (PD) simulations show high performance skill in both climate mean and variability, which provide a reliability of the climate models and reduces the uncertainty in response to future forcing. In future projections, global temperature increases from 1.92 °C to 5.20 °C relative to the PD level (1995–2014). Global mean precipitation increases from 5.1% to 10.1% and sea ice extent decreases from 19% to 62% in the Arctic and from 18% to 54% in the Antarctic. In addition, climate changes are accelerating toward the late twenty-first century. Our CMIP6 simulations are released to the public through the Earth System Grid Federation (ESGF) international data sharing portal and are used to support the establishment of the national adaptation plan for climate change in South Korea.

54 ENVIRONMENTAL SCIENCES↗

Assessment of Low-Level Pu Isotope Ratio Measurements Using Multicollector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS/MS) Equipped with a Pre-Mass Filter

We present an initial investigation into the performance of a multicollector inductively coupled plasmamass spectrometer equipped with a pre-mass filter (Neoma MC-ICP-MS/MS) for making plutonium (Pu) isotope ratio measurements on solutions containing low level (i.e., pg mL –1 ) Pu concentrations. This assessment was achieved by comparison of the 240 Pu/ 239 Pu, 241 Pu/ 239 Pu, and 242 Pu/ 239 Pu ratios attained over a one month period on the MC-ICP-MS/MS with the long-term (∼1 year) performance observed on the predecessor MC-ICP-MS (Neptune Plus) instrument each equipped with an equipped with an APEXΩ desolvating nebulizer for repeated measurements of certified reference materials from New Brunswick Program Office (NBL PO) CRM 136a and CRM 137. The MC-ICP-MS/MS performance of repeated measurement of CRM 136a (n = 20) resulted in mean values of 240 Pu/ 239 Pu = 0.1448 ± 0.0006, 241 Pu/ 239 Pu = 0.00371 ± 0.00006, and 242 Pu/ 239 Pu = 0.00682 ± 0.00006 (k = 2). The CRM 137 (n = 20), analyzed during the same analytical sessions, produced mean values for 240 Pu/ 239 Pu = 0.2414 ± 0.0006, 241 Pu/ 239 Pu = 0.00464 ± 0.00007, and 242 Pu/ 239 Pu = 0.0157 ± 0.0001 (k = 2). These results closely align with the certificate values for CRM 136a and CRM 137 and are within the k = 2 envelopes defined by the long-term performance of the traditional MC-ICP-MS approach (Neptune Plus). Examination of the performance of the various Pu isotope ratios as a function of total Pu content revealed accurate results (<3% relative difference, or RD) above ∼50 fg total Pu. The results presented here demonstrate the capability of the MC-ICP-MS/MS making accurate and precise low level Pu isotopic measurements. While the intent of this work was not to investigate the functionality of the collision cell, the pre-mass filter was employed. Future studies are warranted to investigate the entire capability of the MC-ICP-MS/MS collision cell and pre-cell mass filter optimization for performing low level Pu isotope measurements, even in mixed matrix samples.

CRM↗

Precision Control of Thermal Transport in Cryogenic Single-Crystal Silicon Devices

We report on the diffusive-ballistic thermal conductance of multi-moded single-crystal silicon beams measured below 1 K. It is shown that the phonon mean-free-path is a strong function of the surface roughness characteristics of the beams. This effect is enhanced in diffuse beams with lengths much larger than, even when the surface is fairly smooth, 510 nm rms, and the peak thermal wavelength is 0.6 microns. Resonant phonon scattering has been observed in beams with a pitted surface morphology and characteristic pit depth of 30 nm. Hence, if the surface roughness is not adequately controlled, the thermal conductance can vary significantly for diffuse beams fabricated across a wafer. In contrast, when the beam length is of order, the conductance is dominated by ballistic transport and is effectively set by the beam cross-sectional area. We have demonstrated a uniformity of +/-8% in fractional deviation for ballistic beams, and this deviation is largely set by the thermal conductance of diffuse beams that support the micro-electro-mechanical device and electrical leads. In addition, we have found no evidence for excess specific heat in single-crystal silicon membranes. This allows for the precise control of the device heat capacity with normal metal films. We discuss the results in the context of the design and fabrication of large-format arrays of far-infrared and millimeter wavelength cryogenic detectors.

multi-moded single-crystal silicon beams↗

Bayesian inference of in-medium baryon-baryon scattering cross sections from HADES proton flow data

Within a Bayesian statistical framework using a Gaussian Process emulator for an isospin-dependent Boltzmann-Uehling-Uhlenbeck (IBUU) transport model simulator of heavy-ion reactions at intermediate energies, we infer from the HADES proton flow data the posterior probability distribution functions of in-medium baryon-baryon scattering cross section modification factor X with respect to free-space and the corresponding incompressibility K of nuclear matter as well as their correlation function. In conclusion, the mean value of X is found to be $X$ = $1.32_ {+0.28} ^ {-0.40} $ at 68% confidence level assuming the nuclear incompressibility K will not exceed 400 MeV, providing circumstantial evidence for enhanced baryon-braryon scattering cross sections in hot and dense nuclear matter.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

SIRTF/IRS cryogenic grating drive mechanism (ARC second positioning at 4 K)

The requirements, design, and test results of a grating drive mechanism for the Infrared Spectrograph (IRS) science instrument on the proposed superfluid helium-cooled Space Infrared Telescope Facility (SIRTF) are described. The IRS grating drive mechanism, tested in the fall of 1989, satisfied all performance requirements in vacuum at 4 K. Measured mechanism performance included: 1.4 arc sec root-mean-square (rms) error positioning resolution; 2.2 arc sec rms position repeatability error, less than 10 millijoules/deg dissipated power; and 170 deg angular range of travel. Mechanisms that precisely position optical elements at very low cryogenic temperatures (at/below 4 K) are vital to the operating success of a number of proposed infrared scientific instruments like those in SIRTF.

Kubitschek, Michael J.↗

Chemistry Informed Machine Learning-Based Heat Capacity Prediction of Solid Mixed Oxides

Knowing heat capacity is crucial for modeling temperature changes with the absorption and release of heat and for calculating the thermal energy storage capacity of oxide mixtures with energy applications. The current prediction methods (ab initio simulations, computational thermodynamics, and the Neumann–Kopp rule) are computationally expensive, not fully generalizable, or inaccurate. Machine learning has the potential of being fast, accurate, and generalizable, but it has been scarcely used to predict mixture properties, particularly for mixed oxides. Here, we demonstrate a method for the generalizable prediction of heat capacity of solid oxide pseudobinary mixtures using heat capacity data obtained from computational thermodynamics and descriptors from ab initio databases. Further, models trained through this workflow achieved an error (mean absolute error of 0.43 J mol –1 K –1 ) lower than the uncertainty in differential scanning calorimetry measurements, and the workflow can be extended to predict other properties derived from the Gibbs free energy and for higher-order oxide mixtures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Role of Mesoscale Cloud Morphology in the Shortwave Cloud Feedback

A supervised neural network algorithm is used to categorize near-global satellite retrievals into three mesoscale cellular convective (MCC) cloud morphology patterns. At constant cloud amount, morphology patterns differ in brightness associated with the amount of optically thin cloud features. Environmentally driven transitions from closed MCC to other morphology patterns, typically accompanied by more optically thin cloud features, are used as a framework to quantify the morphology contribution to the optical depth component of the shortwave cloud feedback. A marine heat wave is used as an out-of-sample test of closed MCC occurrence predictions. Morphology shifts in optical depth between 65°S and 65°N under projected environmental changes (i.e., from an abrupt quadrupling of CO 2 ) assuming constant cloud cover contributes between 0.04 and 0.07 W m -2 K -1 (aggregate of 0.06) to the global mean cloud feedback.

54 ENVIRONMENTAL SCIENCES↗

Competing effects of soil fertility and toxicity on tropical greening

Tropical forests are expected to green up with increasing atmospheric CO 2 concentrations, but primary productivity may be limited by soil nutrient availability. However, rarely have canopy-scale measurements been assessed against soil measurements in the tropics. Here, we sought to assess remotely sensed canopy greenness against steep soil nutrient gradients across 50 1-ha mature forest plots in Panama. Contrary to expectations, increases in in situ extractable soil phosphorus (P) and base cations (K, Mg) corresponded to declines in remotely sensed mean annual canopy greenness (r 2 = 0.77– 0.85; p < 0.1), controlling for precipitation. The reason for this inverse relationship appears to be that litterfall also increased with increasing soil P and cation availability (r 2 = 0.88–0.98; p < 0.1), resulting in a decline in greenness with increasing annual litterfall (r 2 = 0.94; p < 0.1). As such, greater soil nutrient availability corresponded to greater leaf turnover, resulting in decreased greenness. However, these decreases in greenness with increasing soil P and cations were countered by increases in greenness with increasing soil nitrogen (N) (r 2 = 0.14; p < 0.1), which had no significant relationship with litterfall, likely reflecting a direct effect of soil N on leaf chlorophyll content, but not on litterfall rates. In addition, greenness increased with extractable soil aluminum (Al) (r 2 = 0.97; p < 0.1), but Al had no significant relationship with litterfall, suggesting a physiological adaptation of plants to high levels of toxic metals. Thus, spatial gradients in canopy greenness are not necessarily positive indicators of soil nutrient scarcity. Using a novel remote sensing index of canopy greenness limitation, we assessed how observed greenness compares with potential greenness. We found a strong relationship with soil N only (r 2 = 0.65; p < 0.1), suggesting that tropical canopy greenness in Panama is predominantly limited by soil N, even if plant productivity (e.g., litterfall) responds to rock-derived nutrients. Moreover, greenness limitation was also significantly correlated with fine root biomass and soil carbon stocks (r 2 = 0.62–0.71; p < 0.1), suggesting a feedback from soil N to canopy greenness to soil carbon storage. Altogether, these data point to the potential utility of a remote sensing product for assessing belowground properties in tropical ecosystems.

54 ENVIRONMENTAL SCIENCES↗