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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Flux Switching Permanent Magnet Motor with Metal Amorphous Nanocomposite Soft Magnetic Material and Rare Earth Free Permanent Magnets

The power losses in high power-density motors due to high rotational speed and/or high pole counts may be reduced adopting metal amorphous nanocomposites (MANCs) featuring low power loss and a relatively high flux density (~1.3 T). We recently proposed a flux switching permanent magnet (FSPM) motor with a rating of 2.5 kW at 1400 Hz electrical speed by incorporating low loss (< 3 W/kg at 1 kHz) FeNi-based MANC material with projected iron loss of about 5 W. The motor design allows use of rare earth-free permanent magnets. For incorporation of MANC materials, an axial flux motor where the rotor and stator core are made from a wound ribbon core has been developed. We have performed a 3-d FEA to optimize the design and built and tested a prototype demonstrating that the low loss MANC material can be used for motor applications.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1991

Use of high spectral resolution airborne visible/infrared imaging spectrometer data for geologic mapping: An overview

Specific examples of the use of AVIRIS (Airborne Visible/Infrared Imaging Spectrometer) high spectral resolution data for mapping, alteration related to ore deposition and to hydrocarbon seepage, and alluvial fans are presented. Correction for atmospheric effects was performed using flat field correction, log residuals, and radiative transfer modeling. Minerals of interest (alunite, kaolinite, gypsum, carbonate iron oxides, etc.) were mapped based upon the wavelength position, depth and width of characteristic absorption features. Results were checked by comparing to existing maps, results from other sensors (Thematic Mapper (TM) and TIMS (Thermal Infrared Multispectral Scanner)), and laboratory spectra of samples collected in the field. Alteration minerals were identified and mapped. The signal to noise ratio of acquired AVIRIS data, long to 2.0 microns, was insufficient to map minerals of interest.

Carrere, Veronique↗
NASA NTRS1991

New evidence for a dramatic rise in atmosphere oxygen ca. 1,900 m.y. ago

Several lines of geologic evidence have pointed to a significant increase in P sub O2 about 2,000 m.y. ago, but the magnitude of P sub O2 before and after that time has been quite uncertain. The data that we have recently accumulated suggest that P sub O2 was approximately less than 2 x 10 (exp -3) atm more than 2,000 m.y. ago, and approximately greater than 0.03 atm more recently than ca. 1,900 m.y. ago. These estimates are based on the behavior of iron in Precambrian weathering horizons. More than ca. 2,000 m.y. ago, Fe(+2), released during the weathering of basalts was not oxidized to Fe(+3), and was removed in ground water from the upper layers of soil horizons. More recently than ca. 1,850 m.y. ago, Fe(+2) was oxidized to Fe(+3) and precipitated as iron oxides and hydroxides in such soil horizons and in the weathering products of a carbonate facies banded iron formation in Griqualand West, South Africa. The O2 content of the atmosphere must have increased dramatically about 1,900 m.y. ago to explain these observations. The reasons for the increase are still obscure, but are probably related to changes in the biologic productivity of the oceans. Eukaryotes appear to have developed shortly after the increase in P sub O2, perhaps in response to the subsequent increase in the supply of nitrate from the atmosphere to the oceans.

Holland, H. D.↗
NASA NTRS1993

Tambo Quemado: Extraordinary concentrations of REE and refractory trace elements caused by artificial heating

Buchwald examined samples of the IIIB iron Tambo Quemado (TAMQ) cut from the 130 kg main mass. He determined it had been artificially heated, at some time prior to being reported, in an attempt to obtain metal from it. Although the Widmanstatten structure appears relatively unaffected under macroscopic examination, microscopic study of etched sections reveals the effect of the heating. Taenite and plessite area boundaries are indistinct due to high temperature diffusion. Schreibersite, once present in significant amounts, has been melted. Schreibersites in the interior have resolidified in fine-grained eutectic textures surrounded by dark-etching metal rims supersaturated with phosphorus. Buchwald states that phosphate minerals were probably present originally, because graftonite, and its polymorph sarcopside (both essentially Fe3(PO4)2), are common in irons of the IIIB groups. Based on his metallographic study Buchwald estimates TAMQ was heated to 1000 C for about one hour. An interior sample from TAMQ was examined in order to determine what effect this unintended heating 'experiment' had upon the phosphate phases.

Olsen, E.↗
NASA NTRS2002

Surface Enhancement Improves Crack Resistance

The low plasticity burnishing (LPB) process produces a deep layer of surface compression in a quick and affordable manner to produce metal surfaces free of scratches, nicks, and gouges. The process, designed for easy inclusion in the manufacturing environment, can be performed with conventional Computer Numerical Control machine tools. This allows parts to be processed during manufacturing, rather than as a post process in a separate facility. A smooth, free-rolling spherical ball suspended in a fluid allows for single-point contact. The ball comes into mechanical contact only with the surface to be burnished, and can be moved in any direction. LPB can be applied to all types of carbon and alloy steel, stainless steel, cast iron, aluminum, titanium, and nickel- based super alloys. In addition to improving a surface's resistance to fatigue and damage, treatment stops the growth of shallow cracks. The LPB process is used on the leading edges of turbine blades to improve resistance to foreign object damage and crack growth. This means significant savings for aircraft owners, since maintenance requirements to inspect for fatigue damage, replace parts, and remove corrosion damage increase the cost of operation.

Source record↗
NASA NTRS2001

Composition and color of Martian soil from oxidation of meteoritic material

The conventional explanations for the formation of ferric oxides on Mars involve weathering under aqueous conditions. Mineralogical evidence, however, however, does not support extensive, global alteration by liquid water. An alternative method for producing the ferric oxides is based upon oxidation of meteoritic iron either soon after the impact event or over geologic timescales under present Martian conditions.

Mars↗
DOE OSTI2023

Machine Learning in Power System Operations: Training Data

Reliability and stability of the electric grid today has depended upon operations of the grid which include the protective relay. Today, the electricity sector faces new challenges with the shift of generation resource characteristics away from the traditional “big iron” generation to inverter-based resources (IBR) which shift the physics and assumption used in grid operation and protection. These changing conditions represent new challenges for protective relays (identification of faults) and increased challenges for protection engineers (correct settings and configuration, reduction of mis-operations), both issues recognized in research and industry. Finding new approaches to reduce mis-operations in relaying and new approaches to fault identification is critical to grid operations. Using today’s modern technology of embedded systems, edge computing, machine learning (ML), and communications we can help address challenges and augment and improve on existing power system operations methodologies.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Peptoid-based chelating ligands for selective metal chelation

The present disclosure provides peptoid-based chelating ligands, corresponding cyclic peptoids, and methods of making thereof. Functional groups may be tailored for high metal binding affinity and selectivity. The side chains of a cyclic peptoid according to the present disclosure may be selected based on, for example, high affinity for actinide or other metal ions, selectivity for actinide or other metal ions, the ability to recover a metal once it is bound to the peptoid, and whether the overall peptoid should be hydrophobic or hydrophilic. Unlike siderophores, peptoid-based chelating ligands of the present disclosure are not readily hydrolyzed under physiological conditions. Therefore, peptoid-based chelating ligands may be, for example, used to treat actinide (e.g., iron and lead) poisoning in vivo. Moreover, peptoid-based chelating ligands of the present disclosure may be used for medical imaging, chelation therapy, drug delivery, and separation technologies, for example.

Williams, Robert F.↗
DOE OSTI2024

Peptoid-based chelating ligands for selective metal chelation

The present disclosure provides peptoid-based chelating ligands, corresponding cyclic peptoids, and methods of making thereof. Functional groups may be tailored for high metal binding affinity and selectivity. The side chains of a cyclic peptoid according to the present disclosure may be selected based on, for example, high affinity for actinide or other metal ions, selectivity for actinide or other metal ions, the ability to recover a metal once it is bound to the peptoid, and whether the overall peptoid should be hydrophobic or hydrophilic. Unlike siderophores, peptoid-based chelating ligands of the present disclosure are not readily hydrolyzed under physiological conditions. Therefore, peptoid-based chelating ligands may be, for example, used to treat actinide (e.g., iron and lead) poisoning in vivo. Moreover, peptoid-based chelating ligands of the present disclosure may be used for medical imaging, chelation therapy, drug delivery, and separation technologies, for example.

Williams, Robert F.↗
NASA NTRS1999

10 000-hr Cyclic Oxidation Behavior of 68 High-Temperature Co-, Fe-, and Ni- Base Alloys Evaluated at 982 deg. C (1800 deg. F)

Power systems with operating temperatures in the range of 815 to 982 C (1500 to 1800 F) frequently require alloys that can operate for long times at these temperatures. A critical requirement is that these alloys have adequate oxidation resistance. The alloys used in these power systems require thousands of hours of operating life with intermittent shutdown to room temperature. Intermittent power plant shutdowns, however, offer the possibility that the protective scale will tend to spall (i.e., crack and flake off) upon cooling, increasing the rate of oxidative attack in subsequent heating cycles. Thus, it is critical that candidate alloys be evaluated for cyclic oxidation behavior. It was determined that exposing test alloys to ten 1000-hr cycles in static air at 982 10 000-hr Cyclic Oxidation Behavior of 68 High-Temperature Co-, Fe-, and Ni-Base Alloys Evaluated at 982 C (1800 F) could give a reasonable simulation of long-time power plant operation. Iron- (Fe-), nickel- (Ni-), and cobalt- (Co-) based high-temperature alloys with sufficient chromium (Cr) and/or aluminum (Al) content can exhibit excellent oxidation resistance. The protective oxides formed by these classes of alloys are typically Cr2O3 and/or Al2O3, and are usually influenced by their Cr, or Cr and Al, content. Sixty-eight Co-, Fe-, and Ni-base high-temperature alloys, typical of those used at this temperature or higher, were used in this study. At the NASA Lewis Research Center, the alloys were tested and compared on the basis of their weight change as a function of time, x-ray diffraction of the protective scale composition, and the physical appearance of the exposed samples. Although final appearance and x-ray diffraction of the final scale products were two factors used to evaluate the oxidation resistance of each alloy, the main criterion was the oxidation kinetics inferred from the specific weight change versus time data. These data indicated a range of oxidation behavior including parabolic (typical of isothermal oxidation), paralinear, linear, and mixed-linear kinetics.

Barrett, Charles A.↗
NASA NTRS1974

X-ray electron study of lunar regolith from the Sea of Fertility and the Sea of Tranquillity

X-ray electron spectra were obtained of the 2p-levels of Fe, Ti, Si, Al, and Mg, and of the 1s-level in lunar regolith from the Sea of Fertility and the Sea of Tranquillity. The spectra of the same elements were recorded for approximately 30 rock forming minerals, oceanic gabbro, meteoritic eucrite, and several iron meteorites. Analysis of the results based on line positions showed that all the elements studied have the usual degrees of oxidation, and that oxygen atoms are their nearest neighbors. The predominant coordination number of Al is 4. Analysis and comparison of the Fe2p spectra in regolith, various iron meteorites, and stainless steel leads to these conclusions: Metallic iron in lunar regolith is in a highly dispersed state and is unusually stable with respect to oxidation by the oxygen of the earth's atmosphere.

Vinogradov, A. P.↗
DOE OSTI2024

An Emerging Trend in the Synthesis of Iron Titanate Photocatalyst Toward Water Splitting

Hydrogen gas is a prominent focus in pursuing renewable and clean alternative energy sources. The quest for maximizing hydrogen production yield involves the exploration of an ideal photocatalyst and the development of a simple, cost-effective technique for its generation. Iron titanate has garnered attention in this context due to its photocatalytic properties, affordability, and non-toxic nature. Over the years, different synthesis routes, different morphologies, and some modifications of iron titanate have been carried out to improve its photocatalytic performance by enhancing light absorption in the visible region, boosting charge carrier transfer, and decreasing recombination of electrons and holes. The use of iron titanate photocatalyst for hydrogen evolution reaction has seen an upward trend in recent times, and based on available findings, more can be done to improve the performance. This review paper provides a comprehensive overview of the fundamental principles of photocatalysis for hydrogen generation, encompassing the synthesis, morphology, and application of iron titanate-based photocatalysts. The discussion delves into the limitations of current methodologies and present and future perspectives for advancing iron titanate photocatalysts. By addressing these limitations and contemplating future directions, the aim is to enhance the properties of materials fabricated for photocatalytic water splitting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

Sulfate radical-based advanced oxidation processes (SR-AOP) attracted a lot of attention due to their capability and adaptability in wastewater treatment. Although heterogeneous cobalt-based catalysts have been extensively studied and have emerged superior for peroxymonosulfate (PMS) activation, leaching of cobalt is still a major concern. Herein, we report a photo-assisted PMS activation approach using cobalt doped mesoporous iron oxide with exceptional activity and stability up to 7 cycles with very low cobalt leaching (0.5 ppm). The highest activity was obtained by 1 mol % cobalt doped mesoporous iron oxide. Orange II dye was completely degraded by the reactive oxygen species (ROS) generated under visible light irradiation within 1 min. ROS were evaluated using two distinct techniques (Fluorescence probes and Electron Paramagnetic Resonance (EPR). ROS quenching experiments were also used to highlight the dominant pathway. This study correlates the structural and electronic changes induced with cobalt doping to the exceptional activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Iron-corrected Single-epoch Black Hole Masses of DESI Quasars at Low Redshift

We present a study on the possible overestimation of single-epoch supermassive black hole (SMBH) masses in previous works, based on more than 55,000 type 1 quasars at 0.25 < z < 0.8 from the Dark Energy Spectroscopic Instrument (DESI). We confirm that iron emission strength serves as a good tracer of the Eddington ratio, and estimate SMBH masses using an iron-corrected R–L relation for Hβ, where R is the broad-line region size and L is the continuum luminosity. Compared with our measurements, previous canonical measurements without the iron correction are overestimated by a factor of 1.5 on average. The overestimation can be up to a factor of 5 for super-Eddington quasars. The fraction of super-Eddington quasars in our sample is about 5%, significantly higher than 0.4% derived from the canonical measurements. Using a sample featuring both Hβ and Mg II emission lines, we calibrate Mg II -based SMBH masses using iron-corrected, Hβ-based SMBH masses and establish an iron-corrected R–L relation for Mg II . The revised relation features a flatter luminosity dependence with a slope of 0.36 and incorporates an additional term of −0.21R Fe , where R Fe denotes the relative iron strength. We use this formula to build a catalog of about 0.5 million DESI quasars at 0.6 < z < 1.6. If these iron-corrected R–L relations for Hβ and Mg II are valid at high redshift, current mass measurements of luminous quasars at z ≥ 6 would have been overestimated by a factor of 2.3 on average, alleviating the tension between SMBH mass and growth history in the early universe.

active galactic nuclei↗
DOE OSTI2023

A Hydrogen Iron Flow Battery with High Current Density and Long Cyclability Enabled Through Circular Water Management

The hydrogen‐iron (HyFe) flow cell has great potential for long‐duration energy storage by capitalizing on the advantages of both electrolyzers and flow batteries. However, its operation at high current density (high power) and over continuous cycling testing has yet to be demonstrated. In this paper, we discuss our design and demonstration of a water management strategy that supports high current and long cycling performance of a HyFe flow cell. Water molecules associated with the movement of protons from the iron electrode to the hydrogen electrode are sufficient to hydrate the membrane and electrode at a low current density of 100 mA cm −2 during the charge process. At higher charge current density, more aggressive measures must be taken to counter back‐diffusion driven by the acid concentration gradient between the iron and hydrogen electrodes. Our water management approach is based on water vapor feeding in the hydrogen electrode, and water evaporation in the iron electrode, thus enabling the high current density operation of 300 mA cm −2 .

25 ENERGY STORAGE↗
DOE OSTI2023

A Hydrogen Iron Flow Battery with High Current Density and Long Cyclability Enabled Through Circular Water Management

The hydrogen‐iron (HyFe) flow cell has great potential for long‐duration energy storage by capitalizing on the advantages of both electrolyzers and flow batteries. However, its operation at high current density (high power) and over continuous cycling testing has yet to be demonstrated. In this article, we discuss our design and demonstration of a water‐management strategy that supports high current and long‐cycling performance of a HyFe flow cell. Water molecules associated with the movement of protons from the iron electrode to the hydrogen electrode are sufficient to hydrate the membrane and electrode at a low current density of 100 mA cm −2 during the charge process. At higher charge current density, more aggressive measures must be taken to counter back‐diffusion driven by the acid concentration gradient between the iron and hydrogen electrodes. Our water‐management approach is based on water vapor feeding in the hydrogen electrode and water evaporation in the iron electrode, thus enabling high current density operation of 300 mA cm −2 .

Yan, Litao↗