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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Modeling of Electromagnetic Scattering by Discrete and Discretely Heterogeneous Random Media by Using Numerically Exact Solutions of the Maxwell Equations

In this paper, we discuss some aspects of numerical modeling of electromagnetic scattering by discrete random medium by using numerically exact solutions of the macroscopic Maxwell equations. Typical examples of such media are clouds of interstellar dust, clouds of interplanetary dust in the Solar system, dusty atmospheres of comets, particulate planetary rings, clouds in planetary atmospheres, aerosol particles with numerous inclusions and so on. Our study is based on the results of extensive computations of different characteristics of electromagnetic scattering obtained by using the superposition T-matrix method which represents a direct computer solver of the macroscopic Maxwell equations for an arbitrary multisphere configuration. As a result, in particular, we clarify the range of applicability of the low-density theories of radiative transfer and coherent backscattering as well as of widely used effective-medium approximations.

Dlugach, Janna M.↗
NASA NTRS2013

Photo-Induced Deuterium Enrichment in Residues Produced from the UV Irradiation of Pyrimidine in H2O and H2O+NH3 Ices

Organic compounds found in meteorites often show isotopic signatures of their interstellar/protosolar heritage as enrichments in D and 15N. Meteoritic organics found to be enriched in D include amino acids, hydroxy and dicarboxylic acids, as well as polycyclic aromatic hydrocarbons (PAHs). Processes that can produce isotopic enrichments in presolar/protosolar materials include gas-phase ion-molecule reactions, gas-grain surface reactions, and unimolecular photo-dissociation reactions involving PAHs. Because many molecules in interstellar clouds are enriched in D, the presence of D anomalies in meteorites is thought to originate from preserved or slightly altered interstellar/protostellar materials. However, the link between isotopic enrichments seen in space and those in meteoritic compounds and their relationship remain unclear. In this work, we present results of hydrogen isotopic fractionation for compounds in organic residues produced from the UV irradiation using an H2- discharge UV lamp of H2O:pyrimidine = 20:1 and H2O:NH3:pyrimidine = 20:2:1 ice mixtures at low temperature (is less than 20 K). After irradiation, the resulting residues are dissolved in H2O and analyzed with gas chromatography-mass spectrometry coupled with isotope ratio mass spectrometry (GC-MS/IRMS) [1], following a protocol similar to that used for previous analyses of comparable samples [2,3]. We used this technique to measure compound-specific D/H isotopic ratios for the initial pyrimidine and for two photo-products present in the residues, namely, 2,2'-bipyrimidine and an unidentified bipyrimidine isomer [2-4]. Measuring D enrichments in bipyrimidines has the advantage that the H atoms on these molecules are not easily exchangeable with other compounds, in particular the H2O and NH3 present in the ices or the solvents used to extract the samples for GC-MS/IRMS measurements. The δD value for the initial pyrimidine, measured with a high-temperature conversion elemental analyzer connected to the IRMS, was found to be -30% per mille. Preliminary measurements made on a residue produced from the UV irradiation of an H2O:NH3:pyrimidine = 20:2:1 ice mixture indicate δD values of +118% per mille for 2,2'- bipyrimidine and +92% per mille for the other bipyrimidine isomer, and therefore show a significant D enrichment during the photo-processing and warm-up that lead to their formation [5]. New measurements are currently being performed on a number of residues produced from simpler H2O:pyrimidine = 20:1 ice mixtures under different experimental conditions and will be presented here.

Laboratory Astrochemistry↗
NASA NTRS2015

The Formation of N- and O-Heterocycles from the Irradiation of Benzene and Naphthalene in H2O- and NH3-Containing Ices

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in many astrophysical environments, and are likely present in interstellar clouds and protostellar disks [1]. In dense molecular clouds,PAHs and other gas-phase species are expected tocondense onto grains to form mixed molecular ice mantles dominated by small molecules like H2O, CH3OH, NH3, CO, and CO2 [2]. These icy mantleslikely undergo energetic processing from ionizing radiation in the form of cosmic rays and high-energy photons.

Materese, C. K.↗
NASA NTRS2019

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2). We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H+, He+, C+, and S+ with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the H+ electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

Dufour, Gwenaelle C.↗
NASA NTRS2019

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2).We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H+, He+, C+, and S+ with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the H+3 electron recombination rate. We also show that iongrain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

Gwenaelle Dufour↗
NASA NTRS2019

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2).We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H(+), He(+), C(+), and S(+) with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the H3(+) electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

Gwénaëlle Dufour↗
NASA NTRS2019

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2). We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H+, He+, C+, and S+ with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the ${{\rm{H}}}_{3}^{+}$ electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

astrochemistry – ISM: abundances – ISM: molecules ↗
NASA NTRS2026

Isotopic Evidence for A Cold and Distant Origin of 3I/Atlas

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation1−3. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.98 ± 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12 C/ 13 C ratios (141–191 for CO 2 and 123–172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures ≲ 30 K in a relatively metal-poor environment. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS may have accreted as long ago as 12 billion years, following a period of intense, early star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system.

Martin A Cordiner↗
NASA NTRS2000

The Abundances of Solid N2 and Gaseous CO2 in Interstellar Dense Molecular Clouds

We present 2338-2322 per centimeter (4.277-4.307 micrometer) infrared spectra of a number of N2-containing mixed molecular ices and demonstrate that the strength of the infrared "forbidden" band due to the N=N stretch near 2328 per centimeter (4.295 micrometer) is extremely sensitive to the composition of the ice. The strength of the 2328 per centimeter N2 fundamental is significantly enhanced relative to that of pure N2 ice when NH3, H2O, or CO2 are present, but is largely unaffected by the presence of CO, CH4 or O2. We use the laboratory data in coil junction with ISO data that probes several lines-of-sight through dense molecular clouds to place limits on the abundance of interstellar solid phase N2 and the composition of the ices. Deriving upper limits is complicated by the presence of overlapping absorptions due to CO2 gas in the clouds and, in some cases, to photospheric CO in the background star. These upper limits are just beginning to be low enough to constrain interstellar grain models and the composition of possible N2-bearing interstellar ices. We outline the search criteria that will need to be met if solid interstellar N2 is to be detected in the future. We also discuss some of the implications of the presence of warm CO2 gas along the lines-of-sight to embedded protostars and demonstrate that its presence may help resolve certain puzzles associated with the previously derived gas/solid CO2 ratios and the relative abundances of polar and nonpolar ices towards these objects. Finally, we briefly comment on the possible implications of these results for the interpretation of N2 detections on outer solar system bodies.

Sandford, Scott A.↗
NASA NTRS1976

Hydrogen molecules in interstellar space

The most important results obtained from Copernicus satellite observations of ultraviolet H2 absorption features are summarized. The properties of the hydrogen molecule are described along with the radiative processes in which it can be involved. Techniques and equipment used in observing H2 absorption features from space are reviewed. The results are discussed in terms of the fraction of hydrogen in molecular form, rotational excitation of H2, physical conditions within interstellar gas clouds, and approaching clouds characterized by high excitation and negative radial velocity. It is shown that: (1) an appreciable fraction of the hydrogen in denser and thicker clouds is molecular, (2) at least some of the interstellar clouds are far from pressure equilibrium, (3) the approaching clouds are apparently dense thick sheets moving toward the sun as viewed in the local standard of rest, (4) these clouds are probably shock waves produced in the interstellar gas by old supernova remnants or expanding H II regions, and (5) the abundances relative to H of such elements as O, Mg, Si, and Cl in these clouds are nearly equal to the solar values, which is in contrast to the depletions observed in many other interstellar clouds.

Spitzer, L.↗
NASA NTRS1988

The turbulent interstellar medium and pressure-bounded molecular clouds

The existence of turbulence throughout the interstellar medium suggests that an appropriate value for the average pressure may be P/K larger than about 10,000. Negative-index polytropic models of interstellar clouds in equilibrium with an external medium at these pressures are predicted to have sizes, line widths, masses, and size-line width and size-density relations in good agreement with those observed and inferred for dark clouds. Thus these observed features of interstellar clouds do not require that they be completely self-gravitating or 'virialized' in the commonly used sense.

Maloney, Philip↗
NASA NTRS1979

A search with Copernicus for interstellar N2 in diffuse clouds

Multiple Copernicus scans of two N2 band regions (near 958.5 and 960.2A) of Delta Sco and Epsilon Per are reported. The observations indicate upper limits for the number of N2 molecules equal to 1.0-3.8 times 10 to the -12th/sq cm and 1.2-4.4 times 10 to the -12th/sq cm, respectively; the limits depend on the cloud temperature. It is suggested that the limits are consistent with the column densities predicted by chemical models for diffuse interstellar clouds, and the predicted relative abundances are presented in terms of the ratio of N(N2)/(2N(H2) + N(Hl)).

Lutz, B. L.↗
NASA NTRS1985

The effect of a weak shock on interstellar gas toward the Rho Ophiuchi cloud

The effect of a low-velocity shock on depletion in interstellar clouds is studied. High-resolution Copernicus observations of interstellar absorption lines toward four stars in the Rho Ophiuchi cloud complex were used to measure differential depletion in interstellar clouds separated by velocities of 10-15 km/s. Optical observations of CH and CH(+) were used as indicators of shock strength and direction of propagation. Observations indicate the presence of a shock with velocity about 10 km/s expanding away from the sun into the Rho Oph cloud. The existence of this shock is supported by the other observations quoted in the literature. Two distinct regions in the lines of sight have been found. A low-density, less depleted, predominantly atomic region is associated with preshock gas, while postshock gas accounts for a predominantly molecular, more highly depleted region. Apparently a weak shock, has the effect of enhancing grain formation or grain growth as a result of increased density in the postshock gas. It is possible for grain growth by accretion to occur in the shocked gas on time scales short compared with the cloud-crossing time of the shock.

Meyers, K. A.↗
NASA NTRS1985

CNO isotopes in red giant stars

The production and distribution of the CNO nuclides is discussed in light of observed abundance ratios in red giants and in the interstellar medium. Isotope abundances have been measured in the atmospheres and in the recent ejecta of cool giants, including carbon stars, S-type stars and red supergiants as well as in oxygen-rich giants making their first ascent of the giant branch. Several of the observations suggest revision of currently accepted nuclear cross-sections and of the mixing processes operating in giant envelopes. By comparing red giant abundances with high-quality observations of the interstellar medium, conclusions are reached about the contribution of intermediate-mass stars to galactic nuclear evolution. The three oxygen isotopes, O-16, -17 and -18, are particularly valuable for such comparison because they reflect three different stages of stellar nucleosynthesis. One remarkable result comes from observations of O-17/O-18 in several classes of red giant stars. The observed range of values for red giants excludes the entire range of values seen in interstellar molecular clouds. Furthermore, both the observations of stars and interstellar clouds exclude the isotopic ratio found in the solar system.

Wannier, P. G.↗
NASA NTRS1991

A large supershell H II region complex in the Large Magellanic Cloud and the interstellar environment of SN 1987A

Results from narrow-bandpass optical imagery of the LMC, acquired prior to the supernova event are discussed, with special emphasis on the region about SN 1987A. The observations reveal the presence of an extremely large H II region complex, mostly embedded in an even larger dust ring. The H II region is roughly 1 kpc in diameter. This region is ionized by over 700 luminous OB stars that comprise the 'star clouds' dispersed throughout the region. The 1.5 x 2 kpc dimension of the large dust ring or supershell enshrouding this H II region is traced out as enhanced extinction in narrow-bandpass imagery of the continuum at 4215 A. The results also indicate that SN 1987A occurred in the cavity carved out by the combined stellar winds and the previous supernova explosions produced by the large number of massive stars in the region.

Bruhweiler, Frederick C.↗
NASA NTRS1973

Molecule formation. I - In normal H I clouds. II - In interstellar shock waves.

The formation of simple molecules and their role in the chemistry and physics of the interstellar medium is considered. The requirements for recombination reactions to occur on interstellar grains with the subsequent buildup of a molecular mantle are discussed. Together with a discussion of depletion and heating of the evolving gas, this forms the basis for a treatment of the precollision history of dust and gas. All the chemical reactions included in the calculations are given, as well as the results of calculations for two values of the intercloud pressure and for a range of cloud masses. Shock waves in clouds whose precollision history has been calculated are treated, followed by discussion of the shock structure and the dynamics of the grains. The process of sputtering is treated, and expressions are given for the cooling rates, including cooling due to the molecules formed behind the shock front. All the chemical reactions included in the calculations are given, as well as the results of calculations for a range of shock velocities and initial molecular hydrogen abundances.

Aannestad, P. A.↗
NASA NTRS1994

Discussion session on star formation, molecular clouds and the interstellar medium

In this panel discussion contributions were made by K. Strom, L. Nordh and H. Zinnecker on the contributions of surveys to the study of star formation regions, by B. Burton on a survey of galactic H I and by E. Dwek on the detection of galactic supernovae by infrared surveys. The contributions of K. Strom, L. Nordh and E. Dwek are summarized here.

Strom, Karen M.↗
NASA NTRS2015

Ice Chemistry in Interstellar Dense Molecular Clouds, Protostellar Disks, and Comets

Despite the low temperatures (T less than 20K), low pressures, and low molecular densities found in much of the cosmos, considerable chemistry is expected to occur in many astronomical environments. Much of this chemistry happens in icy grain mantles on dust grains and is driven by ionizing radiation. This ionizing radiation breaks chemical bonds of molecules in the ices and creates a host of ions and radicals that can react at the ambient temperature or when the parent ice is subsequently warmed. Experiments that similar these conditions have demonstrated a rich chemistry associated with these environments that leads to a wide variety of organic products. Many of these products are of considerable interest to astrobiology. For example, the irradiation of simple ices has been shown to abiotically produce amino acids, nucleobases, quinones, and amphiphiles, all compounds that play key roles in modern biochemistry. This suggests extraterrestrial chemistry could have played a role in the origin of life on Earth and, by extension, do so on planets in other stellar systems.

Ice Irradiation↗