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At least 595 records · Page 33

An engineering perspective on evaluating mechanisms governing ductility in pure molybdenum

The United States lacks a stable domestic supply of 99 mTc, a critical medical imaging isotope generated from 99 Mo. Accelerator-based production using 100 Mo targets (aMo) introduces mechanical concerns due to the ductile-to-brittle transition temperature inherent to refractory metals like Mo. This study evaluates the tensile behavior of aMo targets from 25 to 1000 °C, compared to powder-metallurgy-processed natural Mo (PMo) and cast-and-rolled Mo (RMo), both as-received and after 5 ppm O 2 exposure in flowing He. RMo showed superior ductility (7.3% at 25 °C, 48% at 1000 °C) and strength, attributed to its fine, elongated grains and high geometrically necessary dislocation density. PMo exhibited variable ductility (up to 33%), while aMo remained brittle, with a maximum elongation of 10.4% at 600 °C. EBSD analysis revealed weak texture in PMo and aMo, but high defect density in aMo limited dislocation mobility. This work links processing, microstructure, and deformation mechanisms to guide fabrication of ductile refractory targets.

Hyer, Holden C. [Oak Ridge National Laboratory (OR↗

Microdeformation in Vredefort rocks; evidence for shock metamorphism

Planar microdeformations in quartz from basement or collar rocks of the Vredefort Dome have been cited for years as the main microtextural evidence for shock metamorphism in this structure. In addition, Schreyer describes feldspar recrystallization in rocks from the center of the Dome as the result of transformation of diaplectic glass, and Lilly reported the sighting of mosaicism in quartz. These textural observations are widely believed to indicate either an impact or an internally produced shock origin for the Vredefort Dome. Two types of (mostly sub) planar microdeformations are displayed in quartz grains from Vredefort rocks: (1) fluid inclusion trails, and (2) straight optical discontinuities that sometimes resemble lamellae. Both types occur as single features or as single or multiple sets in quartz grains. Besides qualitative descriptions of cleavage and recrystallization in feldspar and kinkbands in mica, no further microtextural evidence for shock metamorphism at Vredefort has been reported to date. Some 150 thin sections of Vredefort basement rocks were re-examined for potential shock and other deformation effects in all rock-forming minerals. This included petrographic study of two drill cores from the immediate vicinity of the center of the Dome. Observations recorded throughout the granitic core are given along with conclusions.

Reimold, W. U.↗

Rare earth elements in minerals of the ALHA77005 shergottite and implications for its parent magma and crystallization history

Analyses of mineral REE and selected minor and trace elements were carried out on individual grains of pyroxenes, whitlockite, maskelynite, and olivine of the Antarctic shergottite ALHA77005, and the results are used to interpret its parent magma and crystallization history. The results of mineral compositions and textural observations suggest that ALHA77005 is a cumulate with about half cumulus material (olivine + chromite) and half postcumulus phases. Most of the REEs in ALHA77005 reside in whitlockite whose modal concentration is about 1 percent. Mineral REE data support previous suggestions that plagioclase and whitlockite crystallized late, and that low-Ca pyroxene initiated crystallization before high-Ca pyroxene. The REE patterns for the intercumulus liquid, calculated from distribution coefficients for ALHA77005 pyroxene, plagioclase, and whitlockite, are in very good agreement and are similar to that of Shergotty.

Lundberg, Laura L.↗

Surface scattering properties estimated from modeling airborne multiple emission angle reflectance data

Here, researchers apply the Hapke function to airborne bidirectional reflectance data collected over three terrestrial surfaces. The objectives of the study were to test the range of natural surfaces that the Hapke model fits and to evaluate model parameters in terms of known surface properties. The data used are multispectral and multiple emission angle data collected during the Geologic Remote Sensing Field Experiment (GRSFE) over a mud-cracked playa, an artificially roughened playa, and a basalt cobble strewn playa at Lunar Lake Playa in Nevada. Airborne remote sensing data and associated field measurements were acquired at the same time. The airborne data were acquired by the Advanced Solid State Array Spectroradiometer (ASAS) instrument, a 29-spectral band imaging system. ASAS reflectance data for a cobble-strewn surface and an artificially rough playa surface on Lunar Lake Playa can be explained with the Hanke model. The cobble and rough playa sites are distinguishable by a single scattering albedo, which is controlled by material composition; by the roughness parameter, which appears to be controlled by the surface texture and particle size; and the symmetry factor of the single particle phase function, which is controlled by particle size and shape. A smooth playa surface consisting of compacted, fine-grained particles has reflectance variations that are also distinct from either the cobble site or rough playa site. The smooth playa appears to behave more like a Lambertian surface that cannot be modeled with the Hapke function.

Guinness, Edward A.↗

Surface and subsurface characterization of laser-interference structured Ti6Al4V

Ti6Al4V specimens were exposed to high-energy laser pulses of 1.24 J/cm 2 fluences per pulse using a two-beam optical configuration to attain laser-interference. In addition to the formation of periodic surface textures by laser-interference, scanning electron microscope (SEM) images demonstrated several microstructural changes on the surface processed. Moreover, the surface and subsurface of Ti6Al4V specimens were characterized for the as-received and laser-interference processed conditions using x-ray photoelectron spectroscopy (XPS) and electron energy dispersive spectroscopy (EDS). The XPS data showed that this laser technique is effective at removal of surface contaminants for Ti6Al4V. The XPS analysis also revealed the formation of an oxy-nitride layer on the laser treated material. Finally, the microstructure analysis indicates that grain refinement, dendrite and twin structures were found near the surface due to laser processing.

36 MATERIALS SCIENCE↗

The Mechanical and Corrosion Properties of Hot-Rolled TiB{sub 2}/Ni Composites

To quickly prepare TiB{sub 2}/Ni composites at low temperatures, a method combining spark plasma sintering and hot rolling was used. This paper presents the preparation, microstructural and mechanical properties, strengthening mechanism and corrosion properties of TiB{sub 2}/Ni composites in detail. X-ray diffraction analysis shows that the texture degree of the TiB{sub 2}/Ni composites after hot rolling greatly differed from that of the as-rolled pure Ni samples. The addition of TiB{sub 2} particles limited grain growth in the Ni matrix and led to grain refinement. Dislocation strengthening, grain refinement strengthening and load transfer strengthening contributed to a 30% increase in the tensile strength compared to that of the as-rolled pure Ni. In addition, the strengthening mechanism of the mechanical property reinforcement was analyzed. The electrochemical test results demonstrate that the as-rolled pure Ni exhibited a lower corrosion current density and corrosion resistance than the other as-rolled TiB{sub 2}/Ni composites fabricated in this paper. This work demonstrates a new approach for fabricating composites in less time at lower preparation temperatures than conventional methods.

36 MATERIALS SCIENCE↗

Laboratory duplication of comb layering in the Rhum pluton

A description is provided of the texture of harrisite comb layers, taking into account the results of crystallization experiments at controlled cooling rates, which have reproduced the textural change from 'cumulate' to comb-layered harrisite. Melted samples of harrisite were used in the dynamic crystallization experiments considered. The differentiation of a cooling rate run with respect to olivine grain size and shape is shown and three possible origins of hopper olivine in differentiated crystallization runs are considered. It is found that olivine nucleation occurred throughout cooling, except for the incubation period during early cooling. The elongate combed olivines in harrisite apparently grew as the magma locally supercooled to at least 30 C. It is suggested that the branching crystals in most comb layers, including comb-layered harrisite, probably grew along thermal gradients.

Donaldson, C. H.↗

Petrology and thermal history of type IA chondrules in the Semarkona (LL3.0) chondrite

Detailed petrologic studies have been made of 15 type IA, Fe-poor, porphyritic olivine chondrules in Semarkona (LL3.0). Major and minor element concentrations in olivines, pyroxenes, and mesostases, and bulk composition so the chondrules are measured along with zoning profiles in the olivine and pyroxene crystals. The mineral compositions and textures are best interpreted in terms of closed system crystallization in which the olivines and pyroxenes crystallized in situ from a melt corresponding to the bulk composition of the chondrule. Relict olivine grains are not found in the chondrules. Crystallization probably occurred at a cooling rate of the order of 1000 C/hr. Precursor materials of the chondrules were composed of two components, one refractory Ca-, Al-, and Ti-rich, and one less refractory Si-, Fe-, Cr-, and Mn-rich. The evidence is consistent with Semarkona being one of the least metamorphosed ordinary chondrites.

Jones, R. H.↗

Cathodoluminescence observations of in situ aqueous destruction of chondrules in the Murchison CM chondrite

A low-power cathodoluminescence (CL) mosaic of a 1x2 cm section of the Murchison CM chondrite contains chondrules of two types: one contains olivines with red CL and is thought to be the equivalent of group A chondrules of Sears et.; and one without observable CL, which is probably equivalent to their group B chondrules. Both types of chondrule contain dust mantles with a characteristic uniform red CL due to very fine-grained forsterites, but the mantles of group A chondrules have a complex internal structure and are much thicker than the relatively thin rims on the group B chondrules. The variety of internal textures and the progressive integration of the objects with the surrounding matrix suggests to us that these features are large group A chondrules in the process of being destroyed by aqueous alteration. Prior to aqueous alteration, group A chondrules in CM chondrites were larger than group B chondrules, which is contrary to the situation in ordinary chondrites and were apparently destroyed more rapidly than group B chondrules by aqueous alteration.

Sears, Derek W. G.↗

Assessing the Effects of Various Surface Textures and Features on Turbulent Heat Transfer in Hypersonic Flight

Experiments were conducted in the NASA Ames Hypervelocity Free Flight Aerodynamic Facility (ballistic range) to quantify the effects on turbulent convective heat transfer of distributed surface roughness, and of isolated features, representative of thermal protection systems on atmospheric entry vehicles. The surface textures and features were applied on the conic frusta of 45o sphere-cone models having a nose-to-base radius ratio of 0.5, similar to the forebody geometry of the Galileo and Pioneer-Venus entry probes. Test conditions were selected to provide turbulent roughness Reynolds numbers, k+, in the ranges expected for outer planet entry missions. Turbulent flow on the conic frustum was achieved by tripping the flow on the sphere-segment nose cap with distributed surface roughness, created by sand-blasting the nose cap. Surface textures included distributed, acreage, roughness, as well as cavity and groove discrete features. The majority of the data to be presented are results for distributed roughness, which includes both random, sand-grain-like roughness, and regular pattern roughness. The pattern roughness was designed to represent the roughness on woven thermal protection system materials, such as NASA’s 3-D Medium Density Carbon Phenolic (3MDCP), also known as HEEET, developed by the Heatshield for Extreme Entry Environments Technology project. The pattern roughness tested is a 3-D wavy surface, and includes three different roughness element height-to-spacing ratios representative of two configurations of 3MDCP, and spanning ratios measured both before, and after, ablation in an arc jet test facility. The patterns tested in the ballistic range were laser-etched on metal models, and represented an idealized version of the real-world materials in which each roughness element was nearly identical. Additional tests were performed wherein the laser-etched patterns were degraded by sand-blasting with various sized grit media, to produce regular patterns with superimposed irregular roughness, more representative of flight materials. Results of each will be compared. The discrete features tested included cylindrical cavities and rectangular grooves of various width-to-depth ratios. Cavities represent either heatshield damage, such as from micro-meteoroid and orbital debris (MMOD) damage, or from designed penetrations, such as on the Genesis sample return capsule. The grooves were scaled representations of seams between segments of HEEET material in a notional tiled thermal protection system. The tests examined the effects on turbulent heating downstream of the isolated features. The tests were conducted at speeds between 3 km/s and 4 km/s in air between 0.15 atm and 0.25 atm (Mach numbers between 9 and 12). Roughness Reynolds numbers, k+, ranged from 12 to 70 for the sand roughness, and as high as 200 for the pattern roughness. Boundary-layer parameters required for calculating k+ were evaluated using computational fluid dynamics simulations using the DPLR (Data Parallel Line Relaxation) code. Each model included both rough- and smooth-wall segments, and heat transfer augmentation factors were determined as the ratio of the rough-wall to smooth-wall heat flux measured on each test.

hypersonic↗

New Directions in the Quest for Unaltered Ci-Like Material From the Early Solar System

CI meteorites have bulk chemical compositions closely matching the solar photosphere (except volatiles) and thus are considered to represent the starting composition of the Solar System. The return of CI-like samples from asteroid (162173) Ryugu by Hayabusa2 has greatly bolstered studies of CI. However, both CI and the Ryugu samples are CI1, i.e., they were extensively altered by aqueous fluids on their parent bodies so the mineralogy, textures, and oxygen isotope compositions of their CI3 precursors have been obscured. Fortunately, they contain rare remnants of primordial minerals in the form of small anhydrous silicate and Ca-Al-rich grains, and detailed petrologic and isotopic studies of these grains have helped elucidate the nature of their precursors. Here, we continue our work on petrologic and isotopic studies of such phases in Ryugu particle C0137.

C A Goodrich↗

Microstructural Evolution of Steel During Magnetic Field-Assisted Processing

Advancing magnetic field-assisted processing, as an energy-efficient method for tailoring steel microstructures, requires a thorough understanding of how the high magnetic field impacts microstructural evolution, particularly its effect on prior austenite grain structures. The current investigation of a near-eutectoid composition, Fe-C alloy, uses electron backscatter diffraction to examine the morphology and orientation of martensite and pearlite microstructures, and to reconstruct the parent austenite microstructures present during equivalent heating under varied magnetic field strengths (0-T, 2-T, 5-T, and 9-T). It was observed that the magnetic field has a negligible effect on martensite lath/block width, slightly decreases prior austenite grain size, and increases the fraction of austenite grains with annealing twins. Additionally, the magnetic field increases the phase fraction of proeutectoid ferrite but has a negligible effect on pearlite block size and the distribution of boundary misorientation angles. No preferred texture was induced by the magnetic field, regardless of the applied field direction, in the proeutectoid ferrite phase or the martensite and prior austenite microstructures. Furthermore, the observed results contradict previous literature, and the differences are discussed.

Magnetic Materials↗

Development of a new generation of quench and partitioning steels: Influence of processing parameters on texture, nanoindentation, and mechanical properties

A novel quenching and partitioning process (Q&P) including the hot stamping (HS) process was studied, using two stamping temperatures (750 °C and 800 °C) and two quenching temperatures (318 °C and 328 °C). This combination is here called Hot Stamping and Quenching and Partitioning process (HSQ&P). The partitioning step was performed at 400 °C for 100 s in all cycles. Microstructural features were comprehensively studied using electron backscattered diffraction and nanoindentation techniques. HSQ&P samples showed a good combination of ductility and high-strength due to the presence of: retained austenite, inter-critical ferrite with low stored internal strain energy, grain refinement via DIFT-effect (deformation induced ferrite transformation), martensite, and bainite. Significant internal stress relief was caused by carbon partitioning, which was induced by the DIFT-effect and the partitioning stage. This also led to a considerable stored energy, which was characterized by the Kernel average dislocation and geometrically necessary dislocation analysis. In addition, predominant {110}//strain direction crystallographic texture was identified, which promotes slip deformation and enhances the mechanical properties. Moreover, remarkable amounts of fine film-like retained austenite oriented along compact crystallographic directions (i.e., $\langle$111$\rangle$ and $\langle$112$\rangle$) were observed. Finally, subsize tensile test verified the optimum mechanical behavior of HSQ&P specimens.

36 MATERIALS SCIENCE↗

Chemo‐mechanical Alterations Induced From CO 2 Injection in Carbonate‐Cemented Sandstone: An Experimental Study at 71 °C and 29 MPa

Abstract Carbon capture, utilization, and storage may lead to mechanical degradation of the subsurface reservoir from fluid‐rock interaction, which could lead to wellbore instability or reservoir compaction. To better understand potential relationship between mechanical degradation with various carbonate cement textures and compositions in sandstone reservoirs, six flow‐through experiments were conducted. Formation water (TDS = 5,390 mg/L) enriched with CO 2 flowed through two types of Pennsylvanian Morrow B Sandstone: an ankerite‐siderite‐cemented sandstone (disseminated cement texture) and a calcite‐cemented sandstone (poikilotopic cement texture). The experiments produced little change in permeability in the ankerite‐siderite‐cemented sandstone, but permeability increased up to more than 1 order of magnitude in the calcite‐cemented sandstone. Ultrasonic measurements and cylinder‐splitting tests (also known as Brazilian tests) suggested negligible mechanical degradation of the ankerite‐siderite‐cemented sandstone. Variable changes, with significant mechanical degradation in the static moduli, were observed in the calcite‐cemented sandstone. Thus, dissolution of the disseminated ankerite‐siderite cement (0.28–0.30%) had minimal impact on modifying the flow network and the mechanical integrity of the sandstone, whereas dissolution of the poikilotopic calcite cement (0.89–1.13%, quantified with fluid chemistry and visualized with X‐ray microcomputed tomography) impacted the mechanical strength of the sandstone by disconnecting framework grains. With the high water‐to‐rock mass ratios (7.3–8.2) and number of pore volumes (147–675) employed in these experiments, potential risks are most relevant to regions near injection wells. Ultimately, the chemo‐mechanical effects induced by CO 2 injection are strongly influenced by the cement texture and composition and the burial history of the reservoir rock.

Wu, Z.↗

Apollo 14 breccias - General characteristics and classification.

The Apollo 14 breccias are complex and are characterized by a wide range of clast types and textures. The principal fragment types in the breccias are (1) hornfelsed noritic microbreccias; (2) micronorite hornfels; (3) devitrified glass; and (4) ophitic and other kinds of basalt. Based on fragment population, nature of the matrix, grain size and porosity, metamorphic history, and bulk chemical composition, the Apollo 14 breccias can be classified chiefly into regolith microbreccias, Fra Mauro breccias, and spherule-rich microbreccias. Further subdivisions are based principally on the interpretation of metamorphic history. Twenty-six Apollo 14 breccias have been so classified. The complex fragment types contained in Apollo 14 breccias represent multiple episodes of heating and fragmentation. They probably are pre-Imbrian and were not produced by the impact effects of a single event. The variability of their fragment populations is important in the interpretation of pre-Imbrian geologic history.

Chao, E. C. T.↗

Petrological Traverse of the Olivine Cumulate Séítah Formation at Jezero Crater, Mars: A Perspective From SuperCam Onboard Perseverance

Séítah is the stratigraphically lowest formation visited by Perseverance in the Jezero crater floor. We present the data obtained by SuperCam: texture by imagery, chemistry by Laser-Induced Breakdown Spectroscopy, and mineralogy by Supercam Visible and Infrared reflectance and Raman spectroscopy. The Séítah formation consists of igneous, weakly altered rocks dominated by millimeter-sized grains of olivine with the presence of low-Ca and high-Ca pyroxenes, and other primary minerals (e.g., plagioclase, Cr-Fe-Ti oxides, phosphates). Along a ∼140 m long section in Séítah, SuperCam analyses showed evidence of geochemical and mineralogical variations, from the contact with the overlying Máaz formation, going deeper in the formation. Bulk rock and olivine Mg#, grain size, olivine content increase gradually further from the contact. Along the section, olivine Mg# is not in equilibrium with the bulk rock Mg#, indicating local olivine accumulation. These observations are consistent with Séítah being the deep ultramafic member of a cumulate series derived from the fractional crystallization and slow cooling of the parent magma at depth. Possible magmatic processes and exhumation mechanisms of Séítah are discussed. Séítah rocks show some affinity with some rocks at Gusev crater, and with some Martian meteorites suggesting that such rocks are not rare on the surface of Mars. Séítah is part of the Nili Fossae regional olivine-carbonate unit observed from orbit. Future exploration of Perseverance on the rim and outside of the crater will help determine if the observations from the crater floor can be extrapolated to the whole unit or if this unit is composed of distinct sub-units with various origins.

Mars 2020↗

TEM studies of a circumstellar rock

Reported here is the discovery of crystals of titanium carbide in a grain of silicon carbide which formed as a circumstellar dust particle in the atmosphere of a carbon-rich star. Just as in the case of terrestrial rocks, whose assemblage of minerals gives us clues to the composition and conditions of the environment in which they formed, the titanium carbide crystals and their textural relationship to the silicon carbide give us important clues to the nature of the stellar atmosphere in which they formed. From microscopic studies of the relationships between the atomic planes of the silicon carbide and the titanium carbide, we can show that the titanium carbide cannot have existed as already-formed crystals in a gas around which silicon carbide subsequently condensed. An alternative possibility is that both minerals grew quickly and simultaneously from condensing gas in the rapidly cooling and expanding stellar atmosphere. Other microscopic features of the silicon carbide, such as abundant atomic layer disorder and crystal twinning, similarly suggest rapid grain growth. However, another possibility is that the titanium carbide grew inside of the silicon carbide by diffusion of titanium atoms. Our calculations suggest that this scenario is less likely, given the relatively short times (a year or less) for which stellar condensates can be expected to be exposed to temperatures high enough to make diffusion sufficiently rapid.

Bernatowicz, Thomas J.↗

Shear assisted processing and extrusion of enhanced strength aluminum alloy tubing

Hollow extrusions are used in many industries to make strong, lightweight, and affordable structures. Shear Assisted Processing and Extrusion (ShAPE) enables the extrusion of many alloys, often with noteworthy properties. In this investigation, ShAPE was used to extrude 1 and 2 mm wall tubes of aluminum alloy 6063 measuring 12 mm in diameter at extrusion speeds up to 3.8 m/min. This speed is 10 and 15 times faster than has been reported for any alloy using ShAPE and friction stir back extrusion, respectively. Increasing the extrusion speed from 0.7 to 3.8 m/s resulted in using 68% less process energy at steady state. Microstructural analysis and tensile testing were performed on as-extruded tubes and tubes with a direct T5 heat treatment. Grain refinement from 65 µm to below 20 µm was observed. Growth of macroscale Mg 2 Si strengthening precipitates was not observed. ShAPE processing resulted in recrystallization, and extrusion speed was shown to influence final extrudate texture. Here, transmission electron microscopy analysis revealed that the as-extruded microstructure was free of nanoscale ß" strengthening precipitates. Nanoscale ß" was prominent in direct-aged (T5) ShAPE tubes, similar to a slightly over-aged conventional T6 microstructure. As-extruded tubes had ultimate tensile strengths on par with conventional T5 extrusions and approximately double the total elongation. Tubes that underwent a T5 heat treatment had yield and ultimate strengths averaging 198 and 234 MPa, respectively, with an average total elongation of 11%. The tensile test results are comparable to a conventional T6 heat treatment, but without the solutionization heat treatment step. Mechanical properties either remained flat or improved with increased extrusion speed, which suggests that ShAPE can be scaled up to an industrial process to create energy- and economically efficient high-strength extrusions.

36 MATERIALS SCIENCE↗