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At least 595 records · Page 33

Analysis of mode-locked and intracavity frequency-doubled Nd:YAG laser

The paper presents analytical and computer studies of the CW mode-locked and intracavity frequency-doubled Nd:YAG laser which provide new insight into the operation, including the detuning behavior, of this type of laser. Computer solutions show that the steady-state pulse shape for this laser is much closer to a truncated cosine than to a Gaussian; there is little spectral broadening for on-resonance operation; and the chirp is negligible. This leads to a simplified analytical model carried out entirely in the time domain, with atomic linewidth effects ignored. Simple analytical results for on-resonance pulse shape, pulse width, signal intensity, and harmonic conversion efficiency in terms of basic laser parameters are derived from this model. A simplified physical description of the detuning behavior is also developed. Agreement is found with experimental studies showing that the pulsewidth decreases as the modulation frequency is detuned off resonance; the harmonic power output initially increases and then decreases; and the pulse shape develops a sharp-edged asymmetry of opposite sense for opposite signs of detuning.

Siegman, A. E.↗

Degenerate parametric down-conversion facilitated by exciton-plasmon polariton states in a nonlinear plasmonic cavity

Abstract We study the effect of degenerate parametric down-conversion (DPDC) in an ensemble of two-level quantum emitters (QEs) coupled via near-field interactions to a single surface plasmon (SP) mode of a nonlinear plasmonic cavity. For this purpose, we develop a quantum driven-dissipative model capturing non-equilibrium dynamics of the system in which incoherently pumped QEs have transition frequency tuned near the second-harmonic response of the SPs. Considering the strong coupling regime, i.e. the SP-QE interaction rate exceeds system dissipation rates, we find a critical SP-QE coupling attributed to the phase transition between normal and lasing steady states. Examining fluctuations above the system’s steady states, we predict new elementary excitations, namely, the exciton-plasmon polaritons formed by the two-SP quanta and single-exciton states of QEs. The contribution of two-SP quanta results in the linear scaling of the SP-QE interaction rate with the number of QEs,  o , as opposed to the  o -scaling known for the Dicke and Tavis–Cummings models. We further examine how SP-QE interaction scaling affects the polariton dispersions and power spectra in the vicinity of the critical coupling. For this purpose, we compare the calculation results assuming a finite ensemble of QEs and the model thermodynamic limit. The calculated power spectra predict an interplay of coherent photon emission by QEs near the second-harmonic frequency and correlated photon-pair emission at the fundamental frequency by the SPs (i.e. the photonic DPDC effect).

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Project 8 apparatus for cyclotron radiation emission spectroscopy with 83m Kr and tritium

Cyclotron Radiation Emission Spectroscopy (CRES) is a novel technique for the precise measurement of relativistic electron energy. This technique is being employed by the Project 8 collaboration for measuring a high-precision tritium beta decay spectrum to perform a frequency-based measurement of the neutrino mass. In this work, we describe the Project 8 Phase II apparatus, used for the detection of the CRES signal from the conversion electrons of 83m Kr and the first CRES measurement of the beta-decay spectrum of molecular tritium.

Neutrino detectors↗

Nonreciprocal Frequency Domain Beam Splitter

The canonical beam splitter—a fundamental building block of quantum optical systems—is a reciprocal element. It operates on forward- and backward-propagating modes in the same way, regardless of direction. The concept of nonreciprocal quantum photonic operations, by contrast, could be used to transform quantum states in a momentum- and direction-selective fashion. In this study, we demonstrate the basis for such a nonreciprocal transformation in the frequency domain through intermodal Bragg scattering four-wave mixing (BSFWM). Since the total number of idler and signal photons is conserved, the process can preserve coherence of quantum optical states, functioning as a nonreciprocal frequency beam splitter. We explore the origin of this nonreciprocity and find that the phase-matching requirements of intermodal BSFWM produce an enormous asymmetry ( 76 × ) in the conversion bandwidths for forward and backward configurations, yielding ~ 25 dB of nonreciprocal contrast over several hundred GHz. We also outline how the demonstrated efficiencies ( ~ 10 – 4 ) may be scaled to near-unity values with readily accessible powers and pumping configurations for applications in integrated quantum photonics.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Force-free Wave Interaction in Magnetar Magnetospheres: Computational Modeling in Axisymmetry

Abstract Crustal quakes of highly magnetized neutron stars can disrupt their magnetospheres, triggering energetic phenomena like X-ray and fast radio bursts. Understanding plasma wave dynamics in these extreme environments is vital for predicting energy transport across scales to the radiation length. This study models relativistic plasma wave interaction in magnetar magnetospheres with force-free electrodynamics simulations. For propagation along curved magnetic field lines, we observe the continuous conversion of Alfvén waves to fast magnetosonic (FMS) waves. The conversion efficiency can be up to three times higher when counter-propagating Alfvén waves interact in the equatorial region. Alfvén waves generate FMS waves of twice their frequency during their first crossing of the magnetosphere. After the initial transient burst of FMS waves, Alfvén waves convert to FMS waves periodically, generating variations on timescales of the magnetospheric Alfvén wave crossing time. This decaying FMS wave tail carries a significant portion (half) of the total energy emitted. Plastic damping of “bouncing” Alfvén waves by the magnetar crust has minimal impact on the FMS efficiency. We discuss the implications of the identified wave phenomena for magnetar observations. Outgoing FMS waves can develop electric zones, potential sources of coherent radiation. Long wavelength FMS waves could generate FRBs through reconnection beyond the light cylinder.

Astronomy & Astrophysics↗

Characteristics of a Josephson junction harmonic mixer with external pumping

Numerical calculations are carried out on harmonic mixing with an externally pumped Josephson junction. Bias conditions for optimum conversion efficiency are studied for a variety of junction parameters. The predicted noise temperature for harmonic mixing is compared with that for fundamental mixing at the same signal frequency.

Taur, Y.↗

ATS-6 satellite radio beacon measurements at Ootacamund, India

ATS-6 radio beacon measurements of modulation phase and Faraday rotation made at Ootacamund, India in 1975-1976 are discussed with emphasis on the measurement and analysis errors. The modulation-phase errors are insensitive to the geomagnetic field and provide an accurate determination of the total columnar electron content. Comparison of modulation-phase measurements at different frequencies shows a minor sensitivity to the ATS-6 pitch angle. For the low geomagnetic latitude and nearly transverse propagation conditions of Ootacamund, the use of a fixed conversion coefficient gives an unreliable Faraday content. However, the Faraday rotation measurements may be used to determine the shape factor F, which provides information about the electron density height profile.

Davies, K.↗

SAW-Modulated Image Device

Imaging device uses surface-acoustic-wave (SAW) charge transfer for image readout. Spatial resolution of image changed electronically by changing frequency of applied signal. Surface acoustic waves create traveling longitudinal electric fields. These fields create potential wells that carry along stored charges. Charges injected into wells by photoelectric conversion when light strikes device.

Benz, H. F.↗

Multimegawatt dynamic NEP PMAD study

The National Aeronautics and Space Administration Lewis Research Center (NASA LeRC) is developing a FORTRAN-based model of a complete nuclear electric propulsion (NEP) vehicle to be used for piloted or cargo missions to the Moon or Mars. The proposed vehicle will use either a Brayton or K-Rankine power conversion cycle, and either ion or magnetoplasmadynamic (MPD) thrusters. In support of this effort, Rocketdyne evaluated various power management and distribution (PMAD) approaches and selected a low-frequency design that is based on the direct use of the alternator voltage and frequency for power transmission. This approach was compared with dc and high-frequency ac designs, and selected on the basis of mass, efficiency, and qualitative assessment of power quality, reliability and development costs. This low-frequency architecture will be used as the reference in future NEP PMAD studies and for the subsequent FORTRAN model development.

Metcalf, Kenneth J.↗

Hyperspectral Microwave Atmospheric Sounder (HyMAS) Architecture and Design Accommodations

The Hyperspectral Microwave Atmospheric Sounder (HyMAS) is being developed at Lincoln Laboratories and accommodated by the Goddard Space Flight Center for a flight opportunity on a NASA research aircraft. The term "hyperspectral microwave" is used to indicate an all-weather sounding that performs equivalent to hyperspectral infrared sounders in clear air with vertical resolution of approximately 1 km. Deploying the HyMAS equipped scanhead with the existing Conical Scanning Microwave Imaging Radiometer (CoSMIR) shortens the path to a flight demonstration. Hyperspectral microwave is achieved through the use of independent RF antennas that sample the volume of the Earth s atmosphere through various levels of frequencies, thereby producing a set of dense, spaced vertical weighting functions. The simulations proposed for HyMAS 118/183-GHz system should yield surface precipitation rate and water path retrievals for small hail, soft hail, or snow pellets, snow, rainwater, etc. with accuracies comparable to those of the Advanced Technology Microwave Sounder. Further improvements in retrieval methodology (for example, polarization exploitation) are expected. The CoSMIR instrument is a packaging concept re-used on HyMAS to ease the integration features of the scanhead. The HyMAS scanhead will include an ultra-compact Intermediate Frequency Processor (IFP) module that is mounted inside the door to improve thermal management. The IFP is fabricated with materials made of Low-Temperature Co-fired Ceramic (LTCC) technology integrated with detectors, amplifiers, A/D conversion and data aggregation. The IFP will put out 52 channels of 16 bit data comprised of 4-9 channel data streams for temperature profiles and 2-8 channel streams for water vapor. With the limited volume of the existing CoSMIR scanhead and new HyMAS front end components, the HyMAS team at Goddard began preliminary layout work inside the new drum. Importing and re-using models of the shell, the scan head computer, and the slip rings developed for CoSMIR was the starting point. The next step was to modify the antenna faceplate to accommodate the dimensions of the three dual polarization Gaussian Optics Antenna (GOA) assemblies. Two mechanical concepts for the core technology, the hyperspectral IFP, were captured in a design tradeoff. Connector models considered minimum bend radii for the IFP analog connectors. Hyperspectral imaging is accomplished by strategically using a short wavelength intermediate frequency of 18-29 GHz, and thus reducing the size of components in the connection of the front end to the IFP. The SMK (2.92mm) Series connector will lay near the hinge line to minimize its flexing. The digital output of the IFP will use a Serial Peripheral Interface (SPI) that must be accommodated by the scan head computer. To make that computer more reliable, maintainable, and forward compatible with the 52 HyMAS channels, a testbed of the scan head, calibration, and archive computers and the PIC24 microprocessor that resides on the IFP is in development. The computers will be programmed using a new framework application called Interoperable Remote Component (IRC). This software allows flexibility to program computers that communicate with each other and can adapt easily to the emerging HyMAS requirements for data format, algorithms, and graphical user interface (GUI). It is expected that the CoSMIR instrument will cut over to the IRC after it is adapted on an updated CoSMIR testbed.

Hilliard, Lawrence↗

Integrated frequency-modulated optical parametric oscillator

Optical frequency combs have revolutionized precision measurement, time-keeping, and molecular spectroscopy. A substantial effort has developed around "microcombs": integrating comb-generating technologies into compact, reliable photonic platforms. Current approaches for generating these microcombs involve either the electro-optic (EO) or Kerr mechanisms. Despite rapid progress, maintaining high efficiency and wide bandwidth remains challenging. Here, we introduce a new class of microcomb -- an integrated optical frequency comb generator that combines electro-optics and parametric amplification to yield a frequency-modulated optical parametric oscillator (FM-OPO). In stark contrast to EO and Kerr combs, the FM-OPO microcomb does not form pulses but maintains operational simplicity and highly efficient pump power utilization with an output resembling a frequency-modulated laser. We outline the working principles of FM-OPO and demonstrate them by fabricating the complete optical system in thin-film lithium niobate (LNOI). We measure pump to comb internal conversion efficiency exceeding 93% (34% out-coupled) over a nearly flat-top spectral distribution spanning approximately 1,000 modes (approximately 6 THz). Compared to an EO comb, the cavity dispersion rather than loss determines the FM-OPO bandwidth, enabling broadband combs with a smaller RF modulation power. The FM-OPO microcomb, with its robust operational dynamics, high efficiency, and large bandwidth, contributes a new approach to the field of microcombs and promises to herald an era of miniaturized precision measurement, and spectroscopy tools to accelerate advancements in metrology, spectroscopy, telecommunications, sensing, and computing.

42 ENGINEERING↗

Electron-Donating para -Substituent (X) Enhances the Water Oxidation Activity of the Catalyst Ru(4'-X-terpyridine)(phenanthroline-SO 3 ) +

Recently, our group has developed a Ru-based water oxidation catalyst (WOC) with pendant sulfonate (1, Ru(4'-X-terpyridine)(phenanthroline-SO 3 )OTf (X = H, 1a) that shows high activity under both sacrificial oxidant (CAN, Ce(NH 4 ) 2 (NO 3 ) 6 , Ce IV ) and electrocatalytic conditions, in both acidic and neutral media. Here, we demonstrate that the functionalization of the 4'-X-terpyridine ligand with an electron-donating substituent X = OEt (1b) makes potentials of Ru II /Ru III redox catalysis more negative, whereas when X = NO 2 (1c) and CF 3 (1d), potentials are more positive. For 1b, full conversion of the sacrificial oxidant Ce IV occurred in 0.4 h (7 h for 1a), with an initial rate of 2.07 μmol O 2 s –1 and a turnover frequency of 7.6 s –1 , which is 30-fold faster than that for 1a at [cat] 0 = 20 μM. Under electrocatalytic conditions, water oxidation by 1b is three times faster than that by the parent catalyst 1a at close to the same potential. Extensive computations have identified differences in the initial PCET steps of the water oxidation by catalysts 1a, 1b, and 1d, and demonstrated the increased probability of the O 2 formation via the oxide relay pathway in the order 1b< 1a < 1d.

14 SOLAR ENERGY↗

Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn/anti Isomerization

α-Diimine palladium complexes incorporating phenanthryl- and 6,7-dimethylphenanthrylimino groups have been synthesized and characterized. The (diimine)PdMeCl complexes prepared from 2,3-butanedione and acenaphthenequinone bearing the unsubstituted phenanthrylimino groups, 12a and 14a, respectively, exist as a mixture syn and anti isomers in a ca. 1:1 ratio. Separation and X-ray diffraction analysis of 14a-syn and 14a-anti isomers confirms the syn/anti assignments. The barrier to interconversion of 14a-syn and 14a-anti via ligand rotation, ΔG ‡ , was found to be 25.5 kcal/mol. The corresponding (diimine)PdMeCl complex prepared from acenaphthenequinone and incorporating the 6,7-dimethylphenanthrylimino group exists solely as the anti isomer, 14b, due to steric crowding which destabilizes the syn isomer. Analogous (diimine)NiBr2 complexes were prepared from 2,3-butanedione incorporating the phenanthrylimino group, 16a, and the 6,7-dimethylphenanthrylimino group, 16b. Nickel-catalyzed polymerizations of ethylene were carried out by activation of the dibromide complexes 16a and 16b using various aluminum alkyl activators. Complex 16a yields a bimodal distribution polymer, the low molecular weight fraction originating from the syn isomer and the high molecular weight fraction arising from the anti isomer. Polymerizations carried out by 16b yield only high molecular weight polymers with monomodal distributions due to the existence of a single isomer (anti) as the active catalyst. All polymers are linear or nearly so. All catalysts are highly active but catalysts derived from 16b are somewhat more active than 16a and exhibit turnover frequencies general over 10 6 and up to 5 × 10 6 per hour (40 °C, 27.2 atm ethylene, 15 min). Here, active palladium ethylene oligomerization catalysts were generated by conversion of the neutral methyl chloride complexes 14a and 14b to the cationic nitrile complexes 15a and 15b via halide abstraction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Role of the North Atlantic Oscillation for Projections of Winter Mean Precipitation in Europe

Climate models generally project an increase in the winter North Atlantic Oscillation (NAO) index under a future high-emissions scenario, alongside an increase in winter precipitation in northern Europe and a decrease in southern Europe. The extent to which future forced NAO trends are important for European winter precipitation trends and their uncertainty remains unclear. We show using the Multimodel Large Ensemble Archive that the NAO plays a small role in northern European mean winter precipitation projections for 2080–2099. Conversely, half of the model uncertainty in southern European mean winter precipitation projections is potentially reducible through improved understanding of the NAO projections. Extreme positive NAO winters increase in frequency in most models as a consequence of mean NAO changes. These extremes also have more severe future precipitation impacts, largely because of mean precipitation changes. This has implications for future resilience to extreme positive NAO winters, which frequently have severe societal impacts.

54 ENVIRONMENTAL SCIENCES↗

Limitation of 3547 to 1182 A conversion efficiency in Xe

It is found that the 3547 to 1182 A conversion efficiency in Xe-Ar mixtures is limited to about 0.9% by Kerr-induced dispersion. The primary effect is felt to be produced by a mixed-frequency Kerr nonlinearity which changes the index of refraction at 1182 A in the presence of large power densities at 3547 A, affecting phase matching. It is suggested that a Xe-Mg-Ar mixture compensates for the Kerr-induced dispersion and permits increased efficiencies.

Zych, L. J.↗

On-board demux/demod

To make satellite channels cost competitive with optical cables, the use of small, inexpensive earth stations with reduced antenna size and high powered amplifier (HPA) power will be needed. This will necessitate the use of high e.i.r.p. and gain-to-noise temperature ratio (G/T) multibeam satellites. For a multibeam satellite, onboard switching is required in order to maintain the needed connectivity between beams. This switching function can be realized by either an receive frequency (RF) or a baseband unit. The baseband switching approach has the additional advantage of decoupling the up-link and down-link, thus enabling rate and format conversion as well as improving the link performance. A baseband switching satellite requires the demultiplexing and demodulation of the up-link carriers before they can be switched to their assigned down-link beams. Principles of operation, design and implementation issues of such an onboard demultiplexer/demodulator (bulk demodulator) that was recently built at COMSAT Labs. are discussed.

Sayegh, S.↗

Comparative Analysis of Pendulum and Flywheel Power Take-Off Mechanisms for Wave Energy Conversion

Here, this study compares three power-take-off (PTO) mechanisms for wave energy converters—a flywheel -type pitch resonator and two pendulum variants (normal and inverted)—all designed to fit within a fixed envelope. Performance is assessed via linear frequency-domain models and bi-conjugate impedance matching under a representative sea state. The inverted-pendulum PTO achieves 27.9% of the incident wave energy, versus 16.5% for the normal pendulum and 4.2% for the flywheel—that is, 6.6 × and 3.9 × improvements, respectively. These gains arise because pendulum-based systems generate higher torque for a given buoy motion and maintain impedance matching across a wider frequency band. Parametric studies of mass, pendulum arm length, spring stiffness, generator friction, and motor constant quantify the impact of key design choices on power output. By locating the pendulum pivot near the buoy's center of gravity and positioning the center of rotation below the COG, surge–pitch coupling is improved and energy transfer is further boosted.

Keow, Alicia Li Jen [Sandia National Laboratories ↗

Assessing the complex influences of water management on hydrological drought characteristics in Texas

The state of Texas in the United States is highly susceptible to drought. Its major rivers are subject to extensive water management (WM) activities in order to sustain multisectoral water demands, particularly during drought conditions. However, the impact of WM on the propagation dynamics and characteristics of hydrological drought (HD) in Texas remains unclear. To fill this gap, this study quantifies the influence of WM across 32 streamflow gauges along the mainstems of seven major rivers in Texas by comparing a variety of drought metrics under natural and managed conditions. Notably, we leveraged an extensive, naturalized streamflow dataset constructed by the Texas Commission on Environmental Quality, paired with gauge observations of managed conditions. Results indicate that at the multi-decadal scale, WM significantly reduced HD frequency across all seven rivers and at 81% of the gauges analyzed. Additionally, it increased the response timescale of HD across Texas’ major rivers by a median of 2.5 months. Conversely, the average-event duration and severity increased in most locations. Temporal analysis reveals that the WM impact on HD varied seasonally, with attenuation effects during mid-summer and early fall and intensification effects during late winter and spring. Additionally, WM was found to greatly increase the spatial variability of HD characteristics across the region. These findings emphasize the complexity of WM effects on HD and the necessity for nuanced strategies in managing HD under WM influences.

54 ENVIRONMENTAL SCIENCES↗