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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Flash Thermal Diffusivity Measurements and Inspection of Additively Manufactured Ti-6Al-4V Specimens with Varying Process Parameters

Flash thermal diffusivity measurements were obtained on additively manufactured Ti-6Al-4V disk shaped specimens with various process parameters. For additively manufactured metal parts, processing parameters such as laser power and scanning speed are critical to ensure the desired microstructure. For this study, the laser powder bed fusion process parameters were changed at various angular sections on a 21 mm diameter and 3.0 mm thick disk. The measurement of thermal diffusivity was performed by fitting a 1-dimensional thermal model to the data pixel by pixel to produce an inspection image. The image revealed the detection of defects such as lack of fusion porosity and areas of aggregated porosity. The thermal diffusivity imagery was compared to immersion scan ultrasonic and X-ray computed tomography (CT) measurements for validation. Based on these results, additional samples were investigated using a single side thermal inspection technique to detect lack of fusion porosity and near surface voids.

thermal nondestructive evaluation↗
NASA NTRS2023

Flash Thermal Diffusivity Measurements and Inspection of Additively Manufactured Ti-6Al-4V Specimens with Varying Process Parameters

Flash thermal diffusivity measurements were obtained on additively manufactured Ti-6Al-4V disk shaped specimens with various process parameters. For additively manufactured metal parts, processing parameters such as laser power and scanning speed are critical to ensure the desired microstructure. For this study, the laser powder bed fusion process parameters were changed at various angular sections on a 21 mm diameter and 3.0 mm thick disk. The measurement of thermal diffusivity was performed by fitting a 1-dimensional thermal model to the data pixel by pixel to produce an inspection image. The image revealed the detection of defects such as lack of fusion porosity and areas of aggregated porosity. The thermal diffusivity imagery was compared to immersion scan ultrasonic and X-ray computed tomography (CT) measurements for validation. Based on these results, additional samples were investigated using a single side thermal inspection technique to detect lack of fusion porosity and near surface voids.

thermal nondestructive evaluation↗
NASA NTRS1984

The resonance lines of Hg II in IUE spectra of chemically peculiar stars

Twenty IUE images of chemically peculiar (CP) stars are analyzed to demonstrate that the previously detected Hg II overabundances in CP stars is real. Attention was focused on the Hg II resonance lines at 1650 and 1942 A. A total of eight stars were scanned and spectrum synthesis computations were performed to characterize the model atmospheres for each object. The 1942 A line was found to be insensitive to effective temperature, microturbulence and isotopic mixture influences, and therefore well-suited to abundance analyses. A non-LTE process was ruled out as a source of the Hg anomaly. Finally, it is suggested that diffusion-type processes be attributed to Hg enhancements in main sequences B stars.

Leckrone, D. S.↗
NASA NTRS1999

Nucleation, Growth, Annealing, and Coagulation of Refractory Oxides and Metals: Recent Experimental Progress and Applications to Astrophysical Systems

Starting with cooling, refractory vapors diluted in significant quantities of H and He there are four processes that most natural systems will undergo: nucleation, growth, annealing, and coagulation. Nucleation is the processes by which the first stable refractory nuclei form in the vapor. These are the seeds onto which the remaining vapors will condense during the growth stage. Solids of any composition will try to arrange themselves into the least energetic configuration, provided that there is sufficient energy available to support such processes as diffusion and the breaking of chemical bonds. There is a significant activation energy associated with the annealing process in refractory solids due to the relatively high energy of the chemical bonds in solids. The grains formed in most cosmochemical systems are extremely small and often tightly coupled to the gas. Because of their small physical cross sections coagulation may be a very slow process unless there is another driving force involved in addition to normal Brownian motion. In what follows we will briefly cover each of these four stages for refractory oxide and metal grains, although in inverse order.

Nuth, J. A.↗
NASA NTRS1986

Effects of thermal cycling on graphie-fiber-reinforced 6061 aluminum

Graphite-reinforced aluminum alloy metal-matrix composites are among materials being considered for structural components in dimensionally stable space structures. This application requires materials with low values of thermal expansions and high specific stiffnesses. They must remain stable during exposures to the space environment for periods extending to 20 years. The effects of thermal cycling on the thermal expansion behavior and mechanical properties of Thornel P100 graphite 6061 aluminum composites, as fabricated and after thermal processing to eliminate thermal strain hysteresis, have been investigated. Two groups of composites were studied: one was fabricated by hot roll bonding and the other by diffusion bonding. Processing significantly reduced strain hysteresis during thermal cycling in both groups and improved the ultimate tensile strength and modulus in the diffusion-bonded composites. Thermal cycling stabilized the as-fabricated composites by reducing the residual fabrication stress and increased the matrix strength by metallurgical aging. Thermal expansion behavior of both groups after processing was insensitive to thermal cycling. Data scatter was too large to determine effects of thermal cycling on the mechanical properties. The primary effects of processing and thermal cycling can be attributed to changes in the metallurgical condition and stress state of the matrix.

Dries, G. A.↗
DOE OSTI2023

Coupled chemo-mechanical modeling of point-defect diffusion in a crystal plasticity fast Fourier transform framework

Below the yield strength and at moderate-to-high homologous temperatures, the inelastic deformation of metals is mostly governed/rate-controlled by vacancy diffusion-mediated processes. As a function of grain size, stress, temperature and dislocation content, vacancies (or atoms) can adopt preferential diffusion paths across grain interiors, along grain boundaries, or towards and along dislocations, resulting in climb and self-climb. In the steady state and under constant load, grain boundary and grain bulk vacancy diffusion-mediated plasticity have been described in seminal works by Coble and by Nabarro and Herring, respectively. Yet, the interplay between all aforementioned potential diffusion pathways has not been comprehensively mapped. This work presents a thermodynamically-consistent full-field model integrated within a voxel-based elasto-viscoplastic fast Fourier transform framework, which considers the coupling between the diffusion-mediated plasticity mechanisms. In the proposed approach, the kinetics and kinematics of plastic deformation due to vacancy diffusion along grain boundaries and grain bulk, as well as the exchange between grain boundaries and bulk are described explicitly. A homogenization approach at the voxel level is further introduced to simultaneously consider bulk and grain boundary diffusion in a numerically efficient fashion. The new formulation predicts the expected strain rate dependencies and the scaling of the steady-state creep rate with respect to grain size, temperature, and stress. Finally, the model predicts the transition from grain bulk to grain boundary-dominated diffusion with reduction in grain size, a significant step towards capturing transitions in deformation behavior without any phenomenological or ad-hoc adjustments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Explaining persistent incomplete mixing in multicomponent reactive transport with Eulerian stochastic model

We present an Eulerian stochastic advection–diffusion–reaction (SADR) model and use it to explain incomplete mixing typically observed in transport experiments with bimolecular reactions. Unlike traditional advection– dispersion–reaction (ADR) models, the SADR model describes mechanical and diffusive mixing as two separate processes. In the SADR model, mechanical mixing is driven by random advective velocity whose variance is given by the coefficient of mechanical dispersion. The diffusive mixing is modeled as a Fickian diffusion process with the effective diffusion coefficient. We demonstrate that the sum of the two coefficients is equal to the dispersion coefficient, but only the effective diffusion coefficient contributes to the mixing-controlled reactions. We use experimental results of Gramling et al. * * to show that for transport and bimolecular reactions in porous media, the SADR model is significantly more accurate than the ADR model, which overestimates the concentration of the reaction product by as much as 60%. We also show that the SADR model predicts an experimentally observed bell- shaped spatial distribution of the reactive product concentration, while the ADR model results in a concentration distribution with an unphysical kink.

Bimolecular reactions, incomplete mixing, Stochast↗
DOE OSTI2022

A reaction–diffusion model for grayscale digital light processing 3D printing

We report that digital light processing (DLP) 3D printing is an additive manufacturing process that utilizes light patterns to photopolymerize a liquid resin into a solid. Due to the accuracy of modern digital micromirror devices (DMD) and recent advances in resin chemistry, it is now possible to create functionally graded structures using different light intensity values, also known as grayscale DLP (g-DLP). Different intensities of light lead to differences in the polymer crosslinking density after curing, which ultimately produces a part with gradients of material properties. However, g-DLP is a complicated process. First, the DLP printing is a highly coupled chemical and physical process that involves light propagation, chemical reactions, species diffusion, heat transfer, volume shrinkage, and changes in mechanical behaviors of the curing resin. Second, in g-DLP, light gradients create strong in plane gradients of chemical species concentrations in the curing liquid resin due to the strong dependence of light intensity on the rate of monomer crosslinking. Furthermore, light gradients through the depth create concentration gradients due to the degree of cure dependent light absorption and the use of photoabsorbers. These complex physical features of the printing process must be understood in order to properly control printing parameters such as light exposure time, printing speed, and grayscale variations to achieve accurate mechanical properties. In this paper, a photopolymerization reaction–diffusion model is developed and used in conjunction with experiments to investigate the coupled effects of light propagation, chemical reaction rates, and species diffusion during g-DLP 3D printing. The model is implemented numerically utilizing the finite difference method and simulation results are compared to experimental findings of simple printed structures. The agreement between experimental and model predictions of simple quantities of interest, such as geometric feature sizes, shows that the model can capture the overcure due to free-radical and other species diffusion during printing when grayscale patterns are employed. This model lays the groundwork for future extensions that can incorporate more complex coupled physics such as heat transfer, volume shrinkage, and material property evolution, which are critically important in utilizing g-DLP 3D printing for the fabrication of high-performance parts which excellent geometric and material property tolerances.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Joints in fiber-reinforced aluminum alloys

Problems of joining involving structural components made of aluminum alloys with boron-fiber reinforcements are discussed, giving attention to a diffusion-welding process. The tension characteristics and weight factors in the case of various types of welded joints are considered. Diffusion-welding equipment used in the experimental investigation is described. The strength characteristics obtained in various cases of weld and component design are examined, taking into account static and dynamic stresses.

Gerber, K.↗
DOE OSTI2017

The Effects of Interplanetary Transport in the Event-intergrated Solar Energetic Particle Spectra

Previous investigations on the energy spectra of solar energetic particle (SEP) events revealed that the energy spectra observed at 1 au often show double power laws with break energies from one to tens of MeV/nuc. In order to determine whether the double power-law features result from the SEP source or the interplanetary transport process from the Sun to 1 au, we separately analyze the SEP spectra in the decay phase, during which the transport effect is minimum. In this paper, we reported three events observed by the Interplanetary Monitory Platform 8 spacecraft, which occurred on 1977 September 19, November 22, and 1979 March 1. For the first two events, the event-integrated spectra of protons possess double power-law profiles with break energies in a range of several MeV to tens of MeV, while the spectra integrated in the decay (reservoir) phase yield single power laws. Moreover, a general trend from a double power law at the rising phase to a single power law at the decay phase is observed. For the third event, both the event-integrated and the reservoir spectra show double power-law features. However, the difference between the low- and high-energy power-law indices is smaller for the reservoir spectrum than the event-integrated spectrum. These features were reproduced by solving the 1D diffusion equation analytically and we suggest that the transport process, especially the diffusion process, plays an important role in breaking the energy spectra.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Quantal diffusion approach for multinucleon transfer processes in the 58,64 Ni + 208 Pb reactions: Toward the production of unknown neutron-rich nuclei

In recent years, substantial efforts have been made for the study of multinucleon transfer reactions at energies around the Coulomb barrier both experimentally and theoretically, aiming at the production of unknown neutron-rich heavy nuclei. It is crucial to provide reliable theoretical predictions based on microscopic theories with sufficient predictive power. Purpose: This article aims to clarify the applicability of the quantal diffusion approach based on the stochastic mean-field (SMF) theory for multinucleon transfer processes. Isotope production cross sections are evaluated for the reactions of 64 Ni + 208 Pb at E c.m. = 268 MeV and 58 Ni + 208 Pb at E c.m. = 270 MeV and are compared with available experimental data. Methods: Three-dimensional time-dependent Hartree-Fock (TDHF) calculations are carried out for a range of initial orbital angular momenta with Skyrme SLy4d functional. Quantal diffusion equations, derived based on the SMF theory, for variances and covariance of neutron and proton numbers of reaction products are solved, with microscopic drift and diffusion coefficients obtained from time evolution of occupied single-particle orbitals in TDHF. Secondary de-excitation processes, both particle evaporation and fission, are simulated by a statistical compound-nucleus de-excitation model, gemini++. Dynamics of a fast isospin equilibration process followed by a slow drift toward the mass symmetry are commonly observed, as expected. Various reaction outcomes are evaluated, including average mass and charge numbers of reaction products, total kinetic energy loss (TKEL), scattering angle, contact time, and production cross sections for primary and secondary products. By comparing with the experimental data, we find that SMF and TDHF quantitatively reproduce experimental data for few-nucleon-transfer channels around the average values. In contrast, for many-nucleon-transfer channels, we find that the SMF approach provides much better description of the experimentally measured isotopic distributions. The results underline the importance of beyond-mean-field effects, especially one-body (mean-field) fluctuations and correlations, in describing multinucleon transfer processes. Moreover, through a combined analysis of SMF with a statistical model, gemini++, we find a significant contribution of transfer-induced fission, which is consistent with the experimental observation. In some cases, the SMF approach overestimates the isotopic width, requiring further improvements of the theoretical description. Possible ways to improve the description are discussed. The SMF approach is designed to describe the quantum many-body problem according to an ensemble of mean-field trajectories, taking into account part of many-body correlations in the description. As it requires feasible computational costs comparable to the ordinary TDHF approach, together with further model improvements, it will be a promising tool in the search for optimal reaction conditions to produce yet-unknown neutron-rich heavy nuclei through the multinucleon transfer reaction.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS2004

Chlorine stable isotopes in sedimentary systems: does size matter?

Stable isotope abundances vary because of size differences. The chlorine stable isotope system was one of the first described theoretically, but had a slow, disappointment strewn development, relative to other elements. Method improvement gave only small, but significant, differences in compositions of geological materials. Eventually, brines and groundwater chlorides gave larger differences. Physical processes like diffusion and adsorption, probably are the main controls of groundwater compositions. Recent work on anthropogenic groundwater contaminants shows variations resulting from manufacturing processes; implying possibilities of tracing sources.

chlorine stable isotopes↗
DOE OSTI2019

Effect of Sulfide Concentration on the Corrosion and Cavitation Erosion Behavior of a Manganese-Aluminum Bronze in 3.5% NaCl Solution

The effect of sulfide concentration on the corrosion and cavitation erosion behavior of a cast manganese-aluminum bronze (MAB) alloy in 3.5% NaCl solution was investigated. The electrochemical results showed that when the sulfide concentration exceeded 50 ppm, hydrogen evolution reaction dominated the cathodic process because of the very negative corrosion potential of MAB, and the formation of a copper sulfide film on MAB was a diffusion-controlled process. The mass loss rate of MAB after longer-term immersion was ordered by the sulfide concentration as: 20/50 ppm > 100 ppm > zero > 200 ppm. In the 200 ppm sulfide solution, the mass loss rate of MAB was the lowest, because of the formation of a thin and homogeneous copper sulfide film. In the other sulfide solutions, the formation of a less-protective film with both oxides and sulfides resulted in higher mass loss rate of MAB. Moreover, selective phase corrosion occurred at the β and κ phases in solutions with sulfide addition less than 100 ppm. For all solutions, it was the mechanical attack that dominated cavitation erosion degradation. The cavitation erosion–corrosion synergy was lower in high sulfide solutions, because the corrosion products on MAB could reduce the mechanical impact under cavitation erosion.

36 MATERIALS SCIENCE↗
NASA NTRS2008

Magnetotail Current Sheet Thinning and Magnetic Reconnection Dynamics in Global Modeling of Substorms

Magnetotail current sheet thinning and magnetic reconnection are key elements of magnetospheric substorms. We utilized the global MHD model BATS-R-US with Adaptive Mesh Refinement developed at the University of Michigan to investigate the formation and dynamic evolution of the magnetotail thin current sheet. The BATSRUS adaptive grid structure allows resolving magnetotail regions with increased current density up to ion kinetic scales. We investigated dynamics of magnetotail current sheet thinning in response to southwards IMF turning. Gradual slow current sheet thinning during the early growth phase become exponentially fast during the last few minutes prior to nightside reconnection onset. The later stage of current sheet thinning is accompanied by earthward flows and rapid suppression of normal magnetic field component $B-z$. Current sheet thinning set the stage for near-earth magnetic reconnection. In collisionless magnetospheric plasma, the primary mechanism controlling the dissipation in the vicinity of the reconnection site is non-gyrotropic effects with spatial scales comparable with the particle Larmor radius. One of the major challenges in global MHD modeling of the magnetotail magnetic reconnection is to reproduce fast reconnection rates typically observed in smallscale kinetic simulations. Bursts of fast reconnection cause fast magnetic field reconfiguration typical for magnetospheric substorms. To incorporate nongyritropic effects in diffusion regions we developed an algorithm to search for magnetotail reconnection sites, specifically where the magnetic field components perpendicular to the local current direction approaches zero and form an X-type configuration. Spatial scales of the diffusion region and magnitude of the reconnection electric field are calculated self-consistently using MHD plasma and field parameters in the vicinity of the reconnection site. The location of the reconnection sites and spatial scales of the diffusion region are updated during the simulations. Such an approach allows quantifying the interaction between large-scale global magnetospheric dynamics and microphysical processes in diffusion regions localized near reconnection sites. To clarify the role of smallscale non-MHD effects in diffusion region on the global magnetospheric dynamic and to test different models of dissipation we perform simulations with steady southward IMF driving of the magnetosphere.

Kuznetsova, M. M.↗
DOE OSTI2017

The Great Solar Active Region NOAA 12192: Helicity Transport, Filament Formation, and Impact on the Polar Field

The solar active region (AR), NOAA 12192, appeared in 2014 October as the largest AR in 24 years. Here we examine the counterintuitive nature of two diffusion-driven processes in the region: the role of helicity buildup in the formation of a major filament, and the relationship between the effects of supergranular diffusion and meridional flow on the AR and on the polar field. Quantitatively, calculations of current helicity and magnetic twist from Helioseismic and Magnetic Imager (HMI) vector magnetograms indicate that, though AR 12192 emerged with negative helicity, positive helicity from subsequent flux emergence, consistent with the hemispheric sign-preference of helicity, increased over time within large-scale, weak-field regions such as those near the polarity inversion line (PIL). Morphologically, Atmospheric Imaging Assembly observations of filament barbs, sigmoidal patterns, and bases of Fe xii stalks initially exhibited signatures of negative helicity, and the long filament that subsequently formed had a strong positive helicity consistent with the helicity buildup along the PIL. We find from full-disk HMI magnetograms that AR 12192's leading positive flux was initially closer to the equator but, owing either to the region’s magnetic surroundings or to its asymmetric flux density distribution, was transported poleward more quickly on average than its trailing negative flux, contrary to the canonical pattern of bipole flux transport. This behavior caused the AR to have a smaller effect on the polar fields than expected and enabled the formation of the very long neutral line where the filament formed.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1983

Numerical solution of the problem of flame propagation by the use of the random element method

A numerical, grid-free algorithm is presented for one-dimensional reaction-diffusion model of laminar flame propagation in premixed gases. It is based on the random element method we developed for the analysis of diffusional processes. The effect of combustion is taken into account by applying the principle of fractional steps to separate the process of diffusion, modeled by the random walk of computational elements, from the exothermic effects of chemical reaction, monitoring their strength. The validity of the algorithm is demonstrated by application to flame propagation problems for which exact solutions exist. The flame speed evaluated by its use oscillates around the exact value at a relatively small amplitude, while the temperature and species concentration profiles are self-correcting in their convergence to the exact solution. A satisfactory resolution is obtained by the use of quite a small number of computational elements which automatically adjust their distribution of fit sharp gradients.

Ghoniem, A. F.↗
NASA NTRS1991

Diffusion of water in rhyolitic glasses

The process of water diffusion in 11 natural rhyolitic glasses was considered using the results of measurements by FTIR spectroscopy of concentration profiles of both H2O and OH at different temperatures. The diffusion coefficients of H2O and OH, D(H2O) and D(OH), respectively, were calculated from concentration profiles. Results indicate that, at 400-530 C, the value of D(OH) is negligible compared to that of D(H2O), and that OH does not contribute significantly to the diffusion of total water even at water concentrations as low as 0.2 percent, which is minute compared to that of OH. In the activation energy vs radius plot, the D(H2O) followed the same trend as that of noble gases.

Zhang, Youxue↗
DOE OSTI2019

Effect of Primary Carbides on the Sharpness of Kitchen Knives Made of 8Cr13MoV Steel

Although there are many primary carbides in the cutting edge of knives made of high-carbon martensitic steel, the effect of primary carbides on the sharpness of knives has not been clarified. In this paper, the evolution of primary carbides during the production process of 8Cr13MoV steel was presented. The effect of size and amount of primary carbides on the sharpness of knives was studied via employing rolling forging and diffusion annealing process, respectively. Results indicated that primary carbides easily fell off from cutting edge during cutting process, which would decrease the wear resistance of knives. The refinement of primary carbides could not only improve the wear resistance of cutting edge, but also weaken the fluctuation of sharpness during the service process of knives. By decreasing the amount of primary carbides, the wear resistance of knives would increase effectively, which improved the cutting performance effectively. Reducing the amount of primary carbides and refining the primary carbides in cutting edge were both effective ways to improve the sharpness of knives.

36 MATERIALS SCIENCE↗