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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Evaluation of the smoke density chamber as an apparatus for fire toxicity screening tests

The smoke density chamber is perhaps the most widely used apparatus for smoke measurements. Because of its availability, it has been proposed as an apparatus for evaluating fire toxicity. The standard apparatus and procedure were not found suitable for toxicity screening tests using laboratory animals, because not enough materials of interest produced animal mortality or even incapacitation under standard test conditions. With modifications, the chamber offers greater promise as a screening tool, but other tests specifically designed to measure relative toxicity may be more cost-effective. Where one-dimensional heat flux is a requirement, the chamber is the most suitable apparatus available. It should be improved in regard to visibility of animals and ease of cleaning.

Hilado, C. J.↗
NASA NTRS1988

Orbiter Motion - Microgravity and pointing

The Orbiter Motion section of the Environet Data Base deals with the acceleration and pointing environment on the Space Shuttle Orbiter. This paper presents a discussion of the contents of this section, how to effectively use the material, and plans for further development and modification of the material. Topics covered in the section include types of disturbance forces, terminology, instrumentation, and sources of motion. The sources of motion are further classified as gravity-gradient, aerodynamic drag, thrusting events, crew motion, and machinery motion. Acceleration levels given are the results of direct measurement and also calculation from known force levels. Where appropriate, power spectral density has been used to evaluate frequency content of the acceleration time history. The pointing accuracy of the Orbiter and instruments carried by the Orbiter for fine pointing is also given.

Schwaniger, Arthur J., Jr.↗
NASA NTRS1994

Toward unbiased determination of the redshift evolution of Lyman-alpha forest clouds

The possibility of using D(sub A), the mean depression of a quasar spectrum due to Ly-alpha forest absorption, to study the number density evolution of the Ly-alpha forest clouds is examined in some detail. Current D(sub A) measurements are made against a continuum that is a power-law extrapolation from the continuum longward of Ly-alpha emission. Compared to the line-counting approach, the D(sub A)-method has the advantage that the D(sub A) measurements are not affected by line-blending effects. However, we find using low-redshift quasar spectra obtained with the Hubble Space Telescope (HST), where the true continuum in the Ly-alpha forest can be estimated fairly reliably because of the much lower density of the Ly-alpha forest lines, that the extrapolated continuum often deviates systematically from the true continuum in the forest region. Such systematic continuum errors introduce large errors in the D(sub A) measurements. The current D(sub A) measurements may also be significantly biased by the possible presence of the Gunn-Peterson absorption. We propose a modification to the existing D(sub A)-method, namely, to measure D(sub A) against a locally established continuum in the Ly-alpha forest. Under conditions that the quasar spectrum has good resolution and S/N to allow for a reliable estimate of the local continuum in the Ly-alpha forest, the modified D(sub A) measurements should be largely free of the systematic uncertainties suffered by the existing D(sub A) measurements. We also introduce a formalism based on the work of Zuo (1993) to simplify the application of the D(sub A)-method(s) to real data. We discuss the merits and limitations of the modified D(sub A)-method, and conclude that it is a useful alternative. Our findings that the extrapolated continuum from longward of Ly-alpha emission often deviates systematically from the true continuum in the Ly-alpha forest present a major problem in the study of the Gunn-Peterson absorption.

Lu, Limin↗
DOE OSTI2023

Irradiation damage reduces alloy corrosion rate via oxide space charge compensation effects

Radiation effects in materials often compound and accelerate other detrimental phenomena such as embrittlement, oxidation and creep. However, irradiation can also decrease the oxidation rate, for instance with ZrNb alloys nuclear fuel cladding. In this study, we rationalize this observation on Zr-0.5Nb alloy by introducing a mechanism based on oxide space charge modification, resulting from irradiation enhanced Nb clustering. Here, this mechanism is investigated using a multiscale approach: from the macroscale, to determine post-irradiation oxidation kinetics, to the atomic scale, using in-situ atom probe tomography sample oxidation, to observe elemental solute redistribution across the oxide/metal interface. The mechanism is further supported by high resolution transmission electron microscopy characterization and density functional theory calculations. A point defect model is proposed to account for oxide space charge effects and their changes under irradiation. This integrated, multiscale experimental and modeling approach challenges the current paradigm on irradiation effects and how they can potentially improve materials performance in extreme environments.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Dynamic compression effects of H 2 ⁡O in a dynamic diamond anvil cell: Origin of metastable ice VII and its crystal growth kinetics

We report on the structural verification of metastable ice VII solidifying in the phase space of ice VI at 1.80 GPa at room temperature. Using time-resolved (TR) x-ray diffraction and TR ruby luminescence paired with high-speed microphotography utilizing a dynamic diamond anvil cell, an initial compression rate range from 0.12 to 95.84 GPa/s was explored. The solidification pressure of metastable ice VII has a potential sigmoidal dependence upon compression rate with a turnover compression rate of ∼80 GPa/s. The preferred crystallization of ice VII in the stability field of ice VI is due to the increased nucleation rate of ice VII over ice VI at 1.77 GPa that is driven by the surface energy difference between the liquid and solid phases along with the change in Gibbs free energy of solidification. The dynamic pressure-volume–compression behaviors of ice phases (VI and VII) show a lattice stiffening in both phases, especially during the compression loading. It is also found that the compression rate greatly affects the solid-solid phase transition between ice VI and VII but does not affect the liquid-solid transition between water and ice VI as much. Lastly, a third phase transition was found to occur after metastable ice VII transforms into high-density amorphous (HDA) ice, which could be a disordered hydrogen-bonded network configuration of ice VII forming out of HDA ice facilitated by the decoupling of the oxygen movement and reorientation of the H 2⁡ O molecule. These results demonstrate the complexity of a seemingly simple molecule H 2⁡ O, how it can readily change its static properties with the modification of (de)compression rate, and highlight the need to use multiple TR structural and spectroscopic probes at higher time resolutions to realize the most comprehensive understanding.

Chemical bonding↗
NASA NTRS1975

Preliminary estimates of operating costs for lighter than air transports

Presented is a preliminary set of operating cost relationships for airship transports. The starting point for the development of the relationships is the direct operating cost formulae and the indirect operating cost categories commonly used for estimating costs of heavier than air commercial transports. Modifications are made to the relationships to account for the unique features of airships. To illustrate the cost estimating method, the operating costs of selected airship cargo transports are computed. Conventional fully buoyant and hybrid semi-buoyant systems are investigated for a variety of speeds, payloads, ranges, and altitudes. Comparisons are made with aircraft transports for a range of cargo densities.

Smith, C. L.↗
NASA NTRS1975

Preliminary estimates of operating costs for lighter than air transports

A preliminary set of operating cost relationships are presented for airship transports. The starting point for the development of the relationships is the direct operating cost formulae and the indirect operating cost categories commonly used for estimating costs of heavier than air commercial transports. Modifications are made to the relationships to account for the unique features of airships. To illustrate the cost estimating method, the operating costs of selected airship cargo transports are computed. Conventional fully buoyant and hybrid semi-buoyant systems are investigated for a variety of speeds, payloads, ranges, and altitudes. Comparisons are made with aircraft transports for a range of cargo densities.

Smith, C. L.↗
NASA NTRS1977

Synchrotron emissivity near the electron cyclotron and upper hybrid frequencies

The spontaneous synchrotron emissivity from a high density, weakly relativistic plasma in thermal equilibrium is discussed. Thermal effects on the dielectric polarization of the plasma are included in the analysis, and the result is compared with computations of the emissivity based upon the cold plasma approximation. A numerical analysis is performed for frequencies in the vicinity of both the electron cyclotron frequency and the upper hybrid resonance. Significant modifications to the synchrotron emissivity in the cold plasma approximation are found in both of these frequency regimes.

Freund, H. P.↗
NASA NTRS1987

The theory of ionospheric focused heating

Ionospheric modification by high power radio waves and by chemical releases are combined in a theoretical study of ionospheric focused heating. The release of materials which promote electron-ion recombination creates a hole in the bottomside ionosphere. The ionospheric hole focuses high power radio waves from a ground-based transmitter to give a 20 dB or greater enhancement in power density. The intense radio beam excites atomic oxygen by collisions with accelerated electrons. Airglow from the excited oxygen provides a visible trace of the focused beam. The large increase in the intensity of the radio beam stimulates new wave-plasma interactions. Numerical simulations show that the threshold for the two-plasmon decay instability is exceeded. The interaction of the pump electromagnetic wave with the backward plasmon produces a scattered electromagnetic wave at 3/2 the pump frequency. The scattered wave provides a unique signature of the two-plasmon decay process for ground-based detection.

Bernhardt, P. A.↗
NASA NTRS2019

The SMAP and Copernicus Sentinel 1A/B Microwave Active-Passive High Resolution Surface Soil Moisture Product and Its Applications

SMAP project released a new enhanced high-resolution (3km and 1 km) soil moisture active-passive product. This product is obtained by combining the SMAP radiometer data and the Sentinel-1A and -1B Synthetic Aperture Radar (SAR) data. The approach used for this product draws heavily from the heritage SMAP active-passive algorithm. Modifications in the SMAP active-passive algorithm are done to accommodate the Copernicus Program's Sentinel-1A and -1B multi-angular C-band SAR data. Assessment of the SMAP and Sentinel active-passive algorithm has been conducted and results show feasibility of estimating surface soil moisture at high-resolution in regions with low vegetation density (~< 3 kg/sq.m). A new version of this product is released to public in May 2018. This high resolution (3 km and 1 km) soil moisture product with reasonable accuracy of 0.05 m3/m3 is useful for agriculture, flood mapping, watershed/rangeland management, and ecological/hydrological applications.

microwave remote sensing↗
DOE OSTI2025

Introducing metal–sulfur active sites in metal–organic frameworks via post-synthetic modification for hydrogenation catalysis

Metal–sulfur active sites play a central role in catalytic processes such as hydrogenation and dehydrogenation, yet the majority of active sites in these compounds reside on the surfaces and edges of catalyst particles, limiting overall efficiency. Here we present a strategy to embed metal–sulfur active sites into metal–organic frameworks (MOFs) by converting bridging or terminal chloride ligands into hydroxide and subsequently into sulfide groups through post-synthetic modification. We apply this method to two representative MOF families: one featuring one-dimensional metal–chloride chains and another containing discrete multinuclear metal clusters. Crystallographic and spectroscopic analyses confirm structural integrity and sulfide incorporation, and the transformation is monitored by in situ total scattering methods. The sulfided MOFs display enhanced catalytic activity in the selective hydrogenation of nitroarenes using molecular hydrogen. Density functional theory calculations indicate that sulfur incorporation promotes homolytic metal–ligand bond cleavage and facilitates H 2 activation. This work establishes an approach to construct MOFs featuring accessible metal–sulfide sites.

Catalyst synthesis↗
DOE OSTI2023

Elucidating Primary Degradation Mechanisms in High-Cycling-Capacity, Compositionally Tunable High-Entropy Hydrides

The hydrogen sorption properties of single-phase bcc (TiVNb) 100–x Cr x alloys (x = 0–35) are reported. All alloys absorb hydrogen quickly at 25 °C, forming fcc hydrides with storage capacity depending on the Cr content. Here, a thermodynamic destabilization of the fcc hydride is observed with increasing Cr concentration, which agrees well with previous compositional machine learning models for metal hydride thermodynamics. The steric effect or repulsive interactions between Cr–H might be responsible for this behavior. The cycling performances of the TiVNbCr alloy show an initial decrease in capacity, which cannot be explained by a structural change. Pair distribution function analysis of the total X-ray scattering on the first and last cycled hydrides demonstrated an average random fcc structure without lattice distortion at short-range order. If the as-cast alloy contains a very low density of defects, the first hydrogen absorption introduces dislocations and vacancies that cumulate into small vacancy clusters, as revealed by positron annihilation spectroscopy. Finally, the main reason for the capacity drop seems to be due to dislocations formed during cycling, while the presence of vacancy clusters might be related to the lattice relaxation. Having identified the major contribution to the capacity loss, compositional modifications to the TiVNbCr system can now be explored that minimize defect formation and maximize material cycling performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Post-Modification of Crystalline Peptoid Nanomembranes with Active Nanoparticles for Efficient Photooxidation of a Mustard Gas Simulant

Peptoids (or poly-N-substituted glycines) hold immense potential for assembling into hierarchically structured functional materials via controlled molecular interactions. To create self-assembled materials with tailored functionalities, peptoid sequences are often conjugated with reactive or recognition motifs to enable applications including specific binding, biomimetic catalysis, and fluorescence imaging. However, the direct integration of bulky functional motifs into peptoid sequences can disrupt assembly processes and structural outcomes. Herein, we present a post-modification strategy for functionalizing pre-formed 2D crystalline assemblies. Through introducing clickable active sites, such as azide, alkyne, or thiol groups into a peptoid sequence, site-specific conjugation is achieved post-assembly via efficient “click”-type reactions. This strategy enables the ordered alignment of functional groups and gold nanoparticles (Au NPs) on the surface of 2D peptoid nanomaterials with controlled density, while preserving their high crystallinity and structural integrity. Furthermore, we demonstrated that nanomembranes functionalized with both Au NPs and porphyrins enhance the efficiency and selectivity of the photooxidation of 2-chloroethyl ethyl sulfide, a simulant of sulfur mustard. This innovative strategy lays the groundwork for advancing peptoid-based functional materials across diverse applications, from catalysis to biomedicine.

Chemistry↗
DOE OSTI2025

Systematic Bandgap Engineering of a 2D Organic–Inorganic Chalcogenide Semiconductor via Ligand Modification

Hybrid organic–inorganic semiconductors present new opportunities for optoelectronic materials design not available in all-organic or all-inorganic materials. One example is silver phenylselenide (AgSePh) – or “mithrene” – a blue-emitting 2D organic–inorganic semiconductor exhibiting strong optical and electronic anisotropy. Here, we show that the bandgap of mithrene can be systematically tuned by introducing electron-donating and electron-withdrawing groups to the phenyl ligands. We synthesized nine mithrene variants, eight of which formed 2D van der Waals crystals analogous to those of AgSePh. Density functional theory calculations reveal that these 2D mithrene variants are direct-gap or nearly direct gap semiconductors. Furthermore, we identify correlations between the optical gap and three experimental observables – the Hammett constant, 77 Se chemical shift, and selenium partial charge – offering predictive power for bandgap tuning. These findings highlight new opportunities for applying the tools of chemical synthesis to semiconductor materials design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

The Davis–Chandrasekhar–Fermi method revisited

ABSTRACT Despite the rich observational results on interstellar magnetic fields in star-forming regions, it is still unclear how dynamically significant the magnetic fields are at varying physical scales, because direct measurement of the field strength is observationally difficult. The Davis–Chandrasekhar–Fermi (DCF) method has been the most commonly used method to estimate the magnetic field strength from polarization data. It is based on the assumption that gas turbulent motion is the driving source of field distortion via linear Alfvén waves. In this work, using MHD simulations of star-forming clouds, we test the validity of the assumption underlying the DCF method by examining its accuracy in the real 3D space. Our results suggest that the DCF relation between turbulent kinetic energy and magnetic energy fluctuation should be treated as a statistical result instead of a local property. We then develop and investigate several modifications to the original DCF method using synthetic observations, and propose new recipes to improve the accuracy of DCF-derived magnetic field strength. We further note that the biggest uncertainty in the DCF analysis may come from the linewidth measurement instead of the polarization observation, especially since the line-of-sight gas velocity can be used to estimate the gas volume density, another critical parameter in the DCF method.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Bottomonium suppression from the three-loop QCD potential

We compute the suppression of bottomonium in the quark-gluon plasma using the three-loop QCD static potential. The potential describes the spin-averaged bottomonium spectrum below threshold with a less than 1% error. Within potential nonrelativistic quantum chromodynamics and an open quantum systems framework, we compute the evolution of the bottomonium density matrix. The values of the quarkonium transport coefficients are obtained from lattice QCD measurements of the bottomonium in-medium width and thermal mass shift; we additionally include for the first time a vacuum contribution to the dispersive coefficient γ . Using the three-loop potential and the values of the heavy quarkonium transport coefficients, we find that the resulting bottomonium nuclear modification factor is consistent with experimental observations, while at the same time reproducing the lattice measurements of the in-medium width. Published by the American Physical Society 2024

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1987

An analytical and experimental investigation of resistojet plumes

As a part of the electrothermal propulsion plume research program at the NASA Lewis Research Center, efforts have been initiated to analytically and experimentally investigate the plumes of resistojet thrusters. The method of G.A. Simons for the prediction of rocket exhaust plumes is developed for the resistojet. Modifications are made to the source flow equations to account for the increased effects of the relatively large nozzle boundary layer. Additionally, preliminary mass flux measurements of a laboratory resistojet using CO2 propellant at 298 K have been obtained with a cryogenically cooled quartz crystal microbalance (QCM). There is qualitative agreement between analysis and experiment, at least in terms of the overall number density shape functions in the forward flux region.

Zana, L. M.↗
NASA NTRS1987

An analytical and experimental investigation of resistojet plumes

As a part of the electrothermal propulsion plume research program at the NASA Lewis Research Center, efforts have been initiated to analytically and experimentally investigate the plumes of resistojet thrusters. The method of Simons for the prediction of rocket exhaust plumes is developed for the resistojet. Modifications are made to the source flow equations to account for the increased effects of the relatively large nozzle boundary layer. Additionally, preliminary mass flux measurements of a laboratory resistojet using CO2 propellant at 298 K have been obtained with a cryogenically cooled quartz crystal microbalance (QCM). There is qualitative agreement between analysis and experiment, at least in terms of the overall number density shape functions in the forward flux region.

Zana, Lynnette M.↗