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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Voltage cycling as a dynamic operation mode for high temperature electrolysis solid oxide cells

Solid Oxide Electrolysis Cells (SOECs) have emerged as a promising technology for the efficient production of H2 via high-temperature electrolysis. However, power input from dynamic energy sources remains a significant challenge for their long-term stability. It is important to analyze the tolerance of cells under dynamic operation conditions. This study focuses on evaluating the impact of voltage cycling on the performance and durability of electrode-supported SOECs. We explore the operational limits and degradation mechanisms of SOECs subjected to various voltage conditions and find that the cells have high tolerance for dynamic voltage. Voltage cycling between 1.3 V and 1.5 V for 9000 cycles does not damage the cell. Conversely, cycling to higher voltages (≥1.7 V) results in accelerated degradation. Advanced characterization is used to screen for various degradation modes post operation. Within the oxygen electrode, XRD and STEM EDS find compositional and phase evolution in all voltage cycled samples including increased decomposition of the air electrode resulting in cation migration. Microstructural analysis of the fuel electrode from nano-CT data shows minimal change throughout the sample set and no evidence of Ni migration, indicating the fuel electrode is stable and not impacted by cycling to higher voltages within the timeframe studied.

Zhu, Zhikuan↗
NASA NTRS2014

Detecting Change in Urban Areas at Continental Scales with MODIS Data

Urbanization is one of the most important components of global environmental change, yet most of what we know about urban areas is at the local scale. Remote sensing of urban expansion across large areas provides information on the spatial and temporal patterns of growth that are essential for understanding differences in socioeconomic and political factors that spur different forms of development, as well the social, environmental, and climatic impacts that result. However, mapping urban expansion globally is challenging: urban areas have a small footprint compared to other land cover types, their features are small, they are heterogeneous in both material composition and configuration, and the form and rates of new development are often highly variable across locations. Here we demonstrate a methodology for monitoring urban land expansion at continental to global scales using Moderate Resolution Imaging Spectroradiometer (MODIS) data. The new method focuses on resolving the spectral and temporal ambiguities between urban/non-urban land and stable/changed areas by: (1) spatially constraining the study extent to known locations of urban land; (2) integrating multitemporal data from multiple satellite data sources to classify c. 2010 urban extent; and (3) mapping newly built areas (2000-2010) within the 2010 urban land extent using a multi-temporal composite change detection approach based on MODIS 250 m annual maximum enhanced vegetation index (EVI). We test the method in 15 countries in East-Southeast Asia experiencing different rates and manifestations of urban expansion. A two-tiered accuracy assessment shows that the approach characterizes urban change across a variety of socioeconomic/political and ecological/climatic conditions with good accuracy (70-91% overall accuracy by country, 69-89% by biome). The 250 m EVI data not only improve the classification results, but are capable of distinguishing between change and no-change areas in urban areas. Over 80% of the error in the change detection can be related to definitional issues or error propagation, rather than algorithm error. As such, these methods hold great potential for routine monitoring of urban change, as well as for providing a consistent and up-to-date dataset on urban extent and expansion for a rapidly evolving region.

Urban areas↗
NASA NTRS2001

Alendronate and Resistive Exercise Countermeasures Against Bed Rest-Induced Bone Loss: Biochemical Markers of Bone and Calcium Metabolism

Weightlessness-induced bone loss must be counteracted to ensure crew health during extendedduration space missions. Studies were conducted to assess two bone loss countermeasures in a ground-based model: horizontal bed rest. Following a 3-wk ambulatory adaptation period, male and female subjects (aged 21-56 y) completed a 17-wk bed rest protocol. Subjects were assigned to one of three treatments: alendronate (ALEN; 10 mg/d, n=6), resistive exercise (RE; 1.5 h/d, 6 d/wk, n=8), or control (CN; no countermeasure, n=8). Dietary intake was adjusted to maintain body weight. Endocrine and biochemical indices were measured in blood and urine using standard laboratory methods. All data reported are expressed as percent change from individual pre-bedrest data. Serum calcium changed little during bed rest, and tended to decrease (4-8%) in ALEN subjects. In RE subjects, bone alkaline phosphatase and osteocalcin were increased >65 and >30%, respectively, during bed rest, while these were unchanged or decreased in ALEN and CN subjects. Urinary calcium was increased 50% in CN subjects, but was unchanged or decreased in both ALEN and RE groups. Urinary n-telopeptide excretion was increased 40-50% in CN and RE subjects, but decreased 20% in ALEN subjects. Pyridinium crosslink and deoxypyridinoline excretion were increased 20-50% during bed rest. These data suggest that RE countermeasures are effective at increasing markers of bone formation in an analog of weightlessness, while ALEN reduces markers of bone resorption. Counteracting the bone loss of space flight may require both pharmacologic and exercise countermeasures.

Smith, Scott M.↗
DOE OSTI2023

PRO-X Research Reactor Database Status

The PRO-X Research Reactor Database is a functioning tool that can be used to quickly view attributes of past, current, and future research reactors. It contains all data found in the IAEA Research Reactor Database and entries generated from the M3 fuel conversion program. Additionally, it can be downloaded to any computer with the ability to run Microsoft ACCESS. Several research reactor attributes visible to the user have a limited amount of information, much of which is available and vetted for entry into the database. However, the necessary resources have not been allocated to add this information to the data tables. A change management system has also been developed to track changes to the database. This would need to be incorporated into the database program prior to data table modification in order to ensure proper management of the changes.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1998

Analysis of Daily, Seasonal, and Interannual Changes in Hofsjokull Ice Cap, Iceland, using Satellite Data

Analysis of a time series of European Remote Sensing Satellite (ERS)-1 and -2, RADARSAT ScanSAR synthetic aperture radar (SAR) and Landsat images from 1973 to 1998, shows daily to interannual changes in Hofsjokull, a 923 sq km ice cap in central Iceland. A digital elevation model of Hofsjokull was constructed using interferometry, and then SAR backscatter coefficient (d) was plotted with elevation, and air temperature along a transect across the ice cap. Most of the a' changes measured along the transect are caused by a change in the state (frozen or thawed) of the surficial snow or ice when air temperature rises above or below about -5 to O C. Seasonal (sigma)deg patterns are identified in a 4-year time series of 57 ERS-1 and -2 images. In addition, June 1997 ScanSAR images display rapid changes in brightness that are tied closely to daily meteorological events. SAR and Landsat data were also used to measure changes in the areal extent of Hofsjokull, from 1973 to 1997, and to locate (sigma)deg and reflectance boundaries that relate to the glacier facies. Late-summer 1997 (sigma)deg and reflectance boundaries agree and are coincident with the approximate location of the fim line, and the January 1998 position of the equilibrium line as determined from ERS-2 data.

Hall, D. K.↗
NASA NTRS1997

Workshop on Strategies for Calibration and Validation of Global Change Measurements

The Committee on Environment and Natural Resources (CENR) Task Force on Observations and Data Management hosted a Global Change Calibration/Validation Workshop on May 10-12, 1995, in Arlington, Virginia. This Workshop was convened by Robert Schiffer of NASA Headquarters in Washington, D.C., for the CENR Secretariat with a view toward assessing and documenting lessons learned in the calibration and validation of large-scale, long-term data sets in land, ocean, and atmospheric research programs. The National Aeronautics and Space Administration (NASA)/Goddard Space Flight Center (GSFC) hosted the meeting on behalf of the Committee on Earth Observation Satellites (CEOS)/Working Group on Calibration/walidation, the Global Change Observing System (GCOS), and the U. S. CENR. A meeting of experts from the international scientific community was brought together to develop recommendations for calibration and validation of global change data sets taken from instrument series and across generations of instruments and technologies. Forty-nine scientists from nine countries participated. The U. S., Canada, United Kingdom, France, Germany, Japan, Switzerland, Russia, and Kenya were represented.

Guenther, Bruce↗
DOE OSTI2026

Ultrafast Laser Welding and Terahertz Time-domain Spectroscopy of Soda Lime Silicate Glass

Joining and welding techniques of similar and dissimilar materials have reached their limits due to the inflexibility of adapting dielectric materials, e.g., glasses and ceramics, reproducibility for transparent materials, and cycle process time. The ability to join pieces of glasses using laser irradiation allows rapid processing of vacuum insulating glass (VIG) for a widening range of commercial energy-efficient applications. We have used a 1064-nm laser wavelength with 15 picoseconds pulse width and a 155-kHz repetition rate to weld commercial plate glass pieces. The welded samples were characterized via x-ray fluorescence (XRF), time-of-flight secondary ion mass spectrometry (TOF–SIMS), polarimetry, and terahertz time-domain spectroscopy (THz-TDS) to determine the integrity of the weld and chemical changes in the welded areas. Our data shows no significant changes in glass chemistry and structure on average over nano- to micro-scales occurred from the welding process within the limits of the characterization tools. Our results demonstrate successful welding of glass plates without significant changes in the glass chemistry, structure, or properties in the laser-modified region or strains in the bulk glass.

Matthies, Kathleen [ORNL] (ORCID:0009000213135441)↗
DOE OSTI2022

Monitoring Offshore CO 2 Sequestration Using Marine CSEM Methods; Constraints Inferred from Field- and Laboratory-Based Gas Hydrate Studies

Offshore geological sequestration of CO 2 offers a viable approach for reducing greenhouse gas emissions into the atmosphere. Strategies include injection of CO 2 into the deep-ocean or ocean-floor sediments, whereby depending on pressure–temperature conditions, CO 2 can be trapped physically, gravitationally, or converted to CO 2 hydrate. Energy-driven research continues to also advance CO 2 -for-CH 4 replacement strategies in the gas hydrate stability zone (GHSZ), producing methane for natural gas needs while sequestering CO 2 . In all cases, safe storage of CO 2 requires reliable monitoring of the targeted CO 2 injection sites and the integrity of the repository over time, including possible leakage. Electromagnetic technologies used for oil and gas exploration, sensitive to electrical conductivity, have long been considered an optimal monitoring method, as CO 2 , similar to hydrocarbons, typically exhibits lower conductivity than the surrounding medium. We apply 3D controlled-source electromagnetic (CSEM) forward modeling code to simulate an evolving CO 2 reservoir in deep-ocean sediments, demonstrating sufficient sensitivity and resolution of CSEM data to detect reservoir changes even before sophisticated inversion of data. Laboratory measurements place further constraints on evaluating certain systems within the GHSZ; notably, CO 2 hydrate is measurably weaker than methane hydrate, and >1 order of magnitude more conductive, properties that may affect site selection, stability, and modeling considerations.

58 GEOSCIENCES↗
DOE OSTI2023

Data from "The Influence of Climate Change on Flooding and Social Inequalities from Remnants of Hurricane Ida"

Previous research has demonstrated that tropical cyclone-related precipitation and flooding have been increased by anthropogenic global warming. Our work aims to quantify the contribution of climate change to the deadly flooding from the remnants of Hurricane Ida (2021) and its impact on human society. We developed an analysis framework that combines lessons from climate change attribution science, two-dimensional hydrodynamic modeling, and flood impact evaluation, including a social inequality index, to estimate remnants of Ida flooding and consequences responding to current (locally 1°C warmer) and future (another 1°C warmer) climate change. We find that an additional quarter to a half million people were exposed to flooding due to current and future climate change. The human influence on flood impacts was larger with deeper flood water depth (≥ 1 m) than with shallow depths. Socially vulnerable populations were found to be disproportionately more affected, and climate change exacerbates this inequality

Climate Change↗
NASA NTRS1981

Geological and geothermal investigations for HCMM-derived data

An attempt was made to match HCMM- and U2HCMR-derived temperature data over two test sites of very local size to similar data collected in the field at nearly the same times. Results indicate that HCMM investigations using resolutions cells of 500 m or so are best conducted with areally-extensive sites, rather than point observations. The excellent quality day-VIS imagery is particularly useful for lineament studies, as is the DELTA-T imagery. Attempts to register the ground observed temperatures (even for 0.5 sq mile targets) were unsuccessful due to excessive pixel-to-pixel noise on the HCMM data. Several computer models were explored and related to thermal parameter value changes with observed data. Unless quite complex models, with many parameters which can be observed (perhaps not even measured (perhaps not even measured) only under remote sensing conditions (e.g., roughness, wind shear, etc) are used, the model outputs do not match the observed data. Empirical relationship may be most readily studied.

Lyon, R. J. P.↗
NASA NTRS1975

Electrostatic field changes and recovery curves produced by Florida lightning

Preliminary data on electric field changes produced by cloud-to-ground lightning and the subsequent field recoveries are presented. Both single-station and multiple-station observations were made. There is large variation in the data: total charge transfers range from 10 to 30 C and beyond, electric-field recovery times vary by a factor of 2 or more, and initial charge heights occur over a large interval. Only distance and angle dependencies are somewhat predictable, and then only in a few cases. Thus the field recovery mechanism is not a simple one.

Jacobson, E. A.↗
NASA NTRS1991

Satellite orbit considerations for a global change technology architecture trade study

A study was conducted to determine satellite orbits for earth observation missions aimed at obtaining data for assessing data global climate change. A multisatellite system is required to meet the scientific requirements for temporal coverage over the globe. The best system consists of four sun-synchronous satellites equally spaced in local time of equatorial crossing. This system can obtain data every three hours for all regions. Several other satellite systems consisting of combinations of sun-synchronous orbits and either the Space Station Freedom or a mid-altitude equatorial satellite can provide three to six hour temporal coverage, which is sufficient for measuring many of the parameters required for the global change monitoring mission. Geosynchronous satellites are required to study atmospheric and surface processes involving variations on the order of a few minutes to an hour. One or two geosynchronous satellites can be relocated in longitude to study processes over selected regions of earth.

Harrison, Edwin F.↗