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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2018

Use of Open Networks and Delay-Tolerant Protocol to Decrease WAN Latency of EOS near Real-Time Data

Since 1999, NASA's Earth Observing System Data Operations System (EDOS) project at Goddard Space Flight Center (GSFC) has provided high-rate data capture, level zero processing, and product distribution services for a majority of NASA's EOS (Earth Observing System) high-rate missions, including Terra, Aqua, Aura, ICESat, EO-1, SMAP, and OCO-2. EDOS high-rate science and engineering (150-300 Mbps) data-driven capture systems are deployed at 7 worldwide ground stations which are connected via both private (closed) and public (open) wide area networks (WANs) to the centralized EDOS Level Zero Processing Facility (LZPF) located at GSFC, where the data is processed and Level 0 products are distributed to users worldwide. All data transferred over the open networks to GSFC traverse an IPSec tunnel, providing the same level of security as a VPN connection. EDOS produces both time-based and near real-time products (session-based). Near real-time data products are produced from a single ground station contact; time-based products are produced from multiple ground station contacts. EDOS is the primary supplier of EOS Level 0 data to the NASA near real-time user community known as the Land, Atmosphere Near real-time Capability for EOS (LANCE). For the past few years, EDOS has streamlined its systems to reduce WAN latency for near real-time data delivery, including implementing Quality of Service (QoS), expanding closed network bandwidth, adding open network connections with more bandwidth, and implementing a delay-tolerant protocol to mitigate long round-trip times to remote ground stations.

Delay-Tolerant Protocol↗

DOE OSTI2025

Could the chemical industry mitigate rapid global cooling from a catastrophic volcanic eruption?

Abstract Estimates based on historical data place the probability of a catastrophic volcanic eruption in the next 100 years at around one in six. Large volcanic eruptions can lead to significant global cooling for 2–4 years, with potentially devastating impacts on global agriculture. In principle, the negative impacts of volcano‐induced cooling could be reduced by deliberate emission of short‐lived chemicals with high greenhouse gas intensity into the atmosphere. This article examines the physical feasibility of this concept for a wide range of short‐lived climate pollutants, using the global chemical industry for context. Deliberate emission of any known chemical species would require gigatons of material, which would have to be produced and stored far in advance of the volcanic event. The cost of this undertaking would be immense. In addition to these daunting logistical challenges, a range of other uncertainties and complications associated with this concept are discussed.

Sholl, David S. [University of Tennessee‐Oak Ridge↗

NASA NTRS2012

Characterization Approaches to Place Invariant Sites on SI-Traceable Scales

The effort to understand the Earth's climate system requires a complete integration of remote sensing imager data across time and multiple countries. Such an integration necessarily requires ensuring inter-consistency between multiple sensors to create the data sets needed to understand the climate system. Past efforts at inter-consistency have forced agreement between two sensors using sources that are viewed by both sensors at nearly the same time, and thus tend to be near polar regions over snow and ice. The current work describes a method that would provide an absolute radiometric calibration of a sensor rather than an inter-consistency of a sensor relative to another. The approach also relies on defensible error budgets that eventually provides a cross comparison of sensors without systematic errors. The basis of the technique is a model-based, SI-traceable prediction of at-sensor radiance over selected sites. The predicted radiance would be valid for arbitrary view and illumination angles and for any date of interest that is dominated by clear-sky conditions. The effort effectively works to characterize the sites as sources with known top-of-atmosphere radiance allowing accurate intercomparison of sensor data that without the need for coincident views. Data from the Advanced Spaceborne Thermal Emission and Reflection and Radiometer (ASTER), Enhanced Thematic Mapper Plus (ETM+), and Moderate Resolution Imaging Spectroradiometer (MODIS) are used to demonstrate the difficulties of cross calibration as applied to current sensors. Special attention is given to the differences caused in the cross-comparison of sensors in radiance space as opposed to reflectance space. The radiance comparisons lead to significant differences created by the specific solar model used for each sensor. The paper also proposes methods to mitigate the largest error sources in future systems. The results from these historical intercomparisons provide the basis for a set of recommendations to ensure future SI-traceable cross calibration using future missions such as CLARREO and TRUTHS. The paper describes a proposed approach that relies on model-based, SI-traceable predictions of at-sensor radiance over selected sites. The predicted radiance would be valid for arbitrary view and illumination angles and for any date of interest that is dominated by clear-sky conditions. The basis of the method is highly accurate measurements of at-sensor radiance of sufficient quality to understand the spectral and BRDF characteristics of the site and sufficient historical data to develop an understanding of temporal effects from changing surface and atmospheric conditions.

Thome, Kurtis↗

DOE OSTI2022

Viewing convection as a solar farm phenomenon broadens modern power predictions for solar photovoltaics

We report heat mitigation for large-scale solar photovoltaic (PV) arrays is crucial to extend lifetime and energy harvesting capacity. PV module temperature is dependent on site-specific farm geometry, yet common predictions consider panel-scale and environmental factors only. Here, we characterize convective cooling in diverse PV array designs, capturing combined effects of spatial and atmospheric variation on panel temperature and production. Parameters, including row spacing, panel inclination, module height, and wind velocity, are explored through wind tunnel experiments, high-resolution numerical simulations, and operating field data. A length scale based on fractal lacunarity encapsulates all aspects of arrangement (angle, height, etc.) in a single value. When applied to the Reynolds number Re within the canonical Nusselt number heat transfer correlation, lacunarity reveals a relationship between convection and farm-specific geometry. This correlation can be applied to existing and forthcoming array designs to optimize convective cooling, ultimately increasing production and PV cell life.

14 SOLAR ENERGY↗

NASA NTRS2007

Influences of Local Sea-Surface Temperatures and Large-scale Dynamics on Monthly Precipitation Inferred from Two 10-year GCM-Simulations

Two parallel sets of 10-year long: January 1, 1982 to December 31, 1991, simulations were made with the finite volume General Circulation Model (fvGCM) in which the model integrations were forced with prescribed sea-surface temperature fields (SSTs) available as two separate SST-datasets. One dataset contained naturally varying monthly SSTs for the chosen period, and the oth& had the 12-monthly mean SSTs for the same period. Plots of evaporation, precipitation, and atmosphere-column moisture convergence, binned by l C SST intervals show that except for the tropics, the precipitation is more strongly constrained by large-scale dynamics as opposed to local SST. Binning data by SST naturally provided an ensemble average of data contributed from disparate locations with same SST; such averages could be expected to mitigate all location related influences. However, the plots revealed: i) evaporation, vertical velocity, and precipitation are very robust and remarkably similar for each of the two simulations and even for the data from 1987-ENSO-year simulation; ii) while the evaporation increased monotonically with SST up to about 27 C, the precipitation did not; iii) precipitation correlated much better with the column vertical velocity as opposed to SST suggesting that the influence of dynamical circulation including non-local SSTs is stronger than local-SSTs. The precipitation fields were doubly binned with respect to SST and boundary-layer mass and/or moisture convergence. The analysis discerned the rate of change of precipitation with local SST as a sum of partial derivative of precipitation with local SST plus partial derivative of precipitation with boundary layer moisture convergence multiplied by the rate of change of boundary-layer moisture convergence with SST (see Eqn. 3 of Section 4.5). This analysis is mathematically rigorous as well as provides a quantitative measure of the influence of local SST on the local precipitation. The results were recast to examine the dependence of local rainfall on local SSTs; it was discernible only in the tropics. Our methodology can be used for computing relationship between any forcing function and its effect(s) on a chosen field.

Sud, Y. C.↗

NASA NTRS2020

Toward More Realistic Simulation and Prediction of Dust Storms on Mars

Major (regional and global)dust storms dominate weather and climate variability on present-day Mars. Absorption and scattering of visible and IR radiation by dust strongly affect the thermal state of the thin Mars atmosphere, while dust provides condensation nuclei for water and CO2 cloud particles, which also affect radiative fluxes. Global dust storms (GDS) occur ~three times per Mars decade and to date have been observed in only northern fall and winter,when the global circulation is strongest. Tenfold increases in column dust opacity are typical during GDS, with intense vertical motions transporting dust to far higher altitudes than usual. The key processes and feedbacks that produce GDS remain poorly understood, hence current atmospheric models fail to self-consistently simulate observed dust storm activity. This means we have no predictive capability for when GDS may occur, either now or in Mars’s past. And crucially, due to the huge impact of GDS on the atmosphere and surface, our lack of ability to simulate realistic dust storms has major implications for Mars science and exploration: from understanding the present climate (§2.1),to modeling past climates and water cycles (§2.2), to exploring how wind, water, and dust cycles varied over time to interpret geology and assess potential habitability(§2.3), to quantifying and mitigating risks posed to Mars missions (§2.4)

Claire E Newman↗

NASA NTRS2000

Mate and Dart: An Instrument Package for Characterizing Solar Energy and Atmospheric Dust on Mars

The MATE (Mars Array Technology Experiment) and DART (Dust Accumulation and Removal Test) instruments were developed to fly as part of the Mars ISPP Precursor (MIP) experiment on the (now postponed) Mars-2001 Surveyor Lander. MATE characterizes the solar energy reaching the surface of Mars, and measures the performance and degradation of solar cells under Martian conditions. DART characterizes the dust environment of Mars, measures the effect of settled dust on solar arrays, and investigates methods to mitigate power loss due to dust accumulation.

Landis, Geoffrey A.↗

DOE OSTI2020

Conifer water use patterns in the East River Watershed, Colorado US, based on stable water isotopes and cellulose isotopes

This data package contains a series of datasets aimed at understanding the seasonal origins of water used by the dominant conifer species, Abies lasiocarpa and Picea engelmannii, in the East River Watershed. There is a distinct difference in the stable isotopic ratio of summer rain and snowpack and thus by tracking the isotopic ratio of the xylem water in trees, it is possible to separate when a tree is using snow vs. summer rain. Following typical protocols, we sampled and extracted water from soils in the "Research Meadow" near Gothic, CO within the East River Watershed through the 2016 growing season. The stable isotopic ratio of these waters were then measured. Using values of the isotopic ratio of precipitation and snowpack from that season, we develop a mixing model to show how the trees transitioned from use of snowpack to summer in late July. We extended the information on the seasonal origins of water from 2016 back until 1980 by using measurements of the isotopic ratio of cellulose from trees in the Research Meadow. The isotopic ratio of tree ring cellulose records a signal both of the Vapor Pressure Deficit at the leaf-atmosphere boundary and also the source water for the trees. We concluded from this extended analysis that the trees underwent transitions between periods where snow was the dominant water source and summer rain was the dominant water source. More details on this analysis can be found in the publication: Persistence and Plasticity in Conifer Water Use Strategies. JGR Biogeoscience. DOI 10.1029/2018JG004845. The dataset specifically includes stable isotope measurements of xylem and soil water for Spruce and Fir trees at the Rocky Mountain Biological Lab's Research Meadow as well as snowpack and precipitation stable isotopes from nearby National Atmospheric Deposition Program sites. Associated meteorological data is included, which is needed to understand the source water for the trees based on the cellulose measurements.This dataset was updated in June 2021 also include intra-ring measurements of the d18O and d13C of cellulose these same species of trees at the Ziegler Reservoir site in Snowmass, CO. These are listed as files: "Interglaciald18OCellulose.csv", "Interglaciald13OCellulose.csv" and "Modernd13CCellulose.csv". The intent of these measurements was to assess whether common conifers (abies and picea) had undergone ecophysiological or ecohydrological changes during the last period in Earth's history was warmer than today, i.e. the last Interglacial (116,000 to 130,000 years ago). This site was chosen because it is a location where subfossil wood from this critical warm period was discovered. We measured the d18O and d13C of the subfossil trees following the same protocol as the modern samples which included chemical extraction of cellulose and isotope ratio mass spectrometry. We found that the trees showed little difference in water use efficiency but utilized more summer rain during the interglacial period. This analysis and detailed methods are provided in the following manuscript: Wetter summers mitigated temperature stress on Rocky Mountain forests during the last interglacial warm period which is in revision at GRL but is available as a preprint here: 10.1002/essoar.10506740.2

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

UNCERTAINTY-AWARE DEEP LEARNING FRAMEWORK FOR FORECASTING COASTAL WATER LEVEL IN VIRGINIA BEACH

Coastal areas like Virginia Beach, USA, are increasingly vulnerable to flooding. To mitigate the impact of flooding, it is crucial for the City of Virginia Beach to have reliable 72-hour-ahead (3 days) forecasts of water levels at key gauge locations. To support this effort, several sensors have been installed throughout the city to monitor water levels and other environmental parameters such as wind speed, precipitation, and atmospheric pressure. Leveraging sensor data from one of these locations, we developed an uncertainty-aware deep learning model to forecast water levels. We employed deep quantile regression (DQR) to quantify variability in the predictions and examined the performance of three different model architectures. In addition to exclusively including historical data, we investigated the improvement wind forecasts provide to the accuracy of 72-hour-ahead water level predictions. The results show a twelvefold improvement in the flood forecast for a real flooding event.

Hasan, Mahmud [Thomas Jefferson National Accelerat↗

NASA NTRS2004

Toward a Global Map of Raindrop Size Distributions: Rain-Type Classification and Its Implications for Validating Global Rainfall Products - Part 1

Variability in the global distribution of precipitation is recognized as a key element in assessing the impact of climate change for life on earth. The response of precipitation to climate forcings is, however, poorly understood because of discrepancies in the magnitude and sign of climatic trends in satellite-based rainfall estimates. Quantifying and ultimately removing these biases is critical for studying the response of the hydrologic cycle to climate change. In addition, estimates of random errors owing to variability in algorithm assumptions on local spatial and temporal scales are critical for establishing how strongly their products should be weighted in data assimilation or model validation applications and for assigning a level of confidence to climate trends diagnosed from the data. This paper explores the potential for refining assumed drop size distributions (DSDs) in global radar rainfall algorithms by establishing a link between satellite observables and information gleaned from regional validation experiments where polarimetric radar, Doppler radar, and disdrometer measurements can be used to infer raindrop size distributions. By virtue of the limited information available in the satellite retrieval framework, the current method deviates from approaches adopted in the ground-based radar community that attempt to relate microphysical processes and resultant DSDs to local meteorological conditions. Instead, the technique exploits the fact that different microphysical pathways for rainfall production are likely to lead to differences in both the DSD of the resulting raindrops and the three-dimensional structure of associated radar reflectivity profiles. Objective rain-type classification based on the complete three-dimensional structure of observed reflectivity profiles is found to partially mitigate random and systematic errors in DSDs implied by differential reflectivity measurements. In particular, it is shown that vertical and horizontal reflectivity structure obtained from spaceborne radar can be used to reproduce significant differences in Z(sub dr) between the easterly and westerly climate regimes observed in the Tropical Rainfall Measuring Mission Large-scale Biosphere-Atmosphere (TRMM-LBA) field experiment as well as the even larger differences between Amazonian rainfall and that observed in eastern Colorado. As such, the technique offers a potential methodology for placing locally observed DSD information into a global framework.

L'Ecuyer, Tristan S.↗

NASA NTRS2022

Separating Propulsive Mass and Energy for Space Applications

Initially and traditionally, space access and in-space propulsion utilized combustion and expulsion of chemical “fuels” carried on board, with performance governed by the rocket equation. These chemicals produced energy, and after combustion, constituted the propulsive mass/momentum. The best such chemicals in terms of Isp that are deemed safe engineering/mission wise are hydrogen and oxygen, producing some 450 seconds of Isp. There are more reactive chemicals, such as fluorine, which have higher Isp, but also have serious safety issues. Propulsion in atmospheres can ingest atmospheric constituents (aka “airbreathing propulsion”) which provide additional propulsive mass when heated and a component of the combustion/energy generation process. This utilization of non-stored/carried propulsive mass provides partial separation of propulsive mass and energy and produces higher Isp. The other approach to separating propulsive mass and energy is to, either on board or added from offboard, supply additional energy, such as from nuclear or solar sources. This is the approach for fission nuclear thermal and electric propulsion, which can provide an Isp in excess of 800 seconds of Isp. Other processes or in addition to thermal expansion, such as electro-magnetics, can be employed to increase exit velocity and Isp. Separating propulsive mass and energy for space faring is commonly referred to as a means to circumvent the rocket equation and is capable of producing major benefits for the development of commercial deep space and space faring in general including affordable fast transits to mitigate the human health impacts of galactic cosmic radiation (GCR) and microG. The key to higher than chemical Isp, beyond H2-O2, and beyond the radiated energy and systems limitations of solar for space faring, is a light weight, high energy density source, either on board or via utilization of energy beaming to the vehicle. Traditional energy sources include chemical, heat, electrics, mechanical, photons, and nuclear. Propulsive mass can be carried on board, sourced beyond the surface of Earth via in-situ resource utilization (ISRU), and includes harvesting from atmospheres. High Isp via electromagnetic related propulsive mass acceleration requires sufficient ionization and conductivity. The major metrics for space propulsion are costs, safety, Isp, weight, and thrust level, the latter dependent upon mission requirements. High thrust for human missions is needed to reduce time exposed to radiation and microG and high thrust is required for space access. Costs of space access are reducing via reusability, printing manufacture, and robotization of manufacturing and operation. Chemical rockets provide high thrust from the expansion of the heated mass constituents at high mass flow. The other high thrust propulsion approach is magnetohydrodynamics (MHD), which, in addition to high thrust, has a high Isp of over 2,000 seconds of Isp. The VASIMIR engine offers some 5,000 seconds of Isp at high thrust [ref. 3]. Electric propulsion cycles are capable of Isp much higher than that but at low thrust levels using available energy sources. With cost as a major metric, reusable rockets and improved manufacturing and operations are rapidly greatly lowering the costs of space access, which could provide/supply in space fuel depots and affordable chemical propulsion for the desired human fast transits (e.g., some 200-day round trips to Mars). The other option for fast transits is VASIMIR, given a nuclear on-board energy source that has the requisite many megawatts of power and an alpha, kgs of weight/kW of energy produced, on the order of one (i.e., a light weight, high energy density energy source). The purpose of this report is to examine the options beyond traditional rocket engines, where propulsive mass and energy are combined, specifically the separation of propulsive mass and energy. This report considers the spectrum of advanced energetics, sources of propulsive mass, conductivity enhancement approaches, energy beaming possibilities, and candidate propulsion cycles. Suggestions are made for various combinatorial, system level, beyond traditional combustion rocket, space propulsion approaches for human deep space missions given the changing conditions of increased knowledge of deep space resources for ISRU, revolutionary energetics, and technology advancements writ large.

Dennis M. Bushnell↗

NASA NTRS2014

Mechanisms and Observations of Coronal Dimming for the 2010 August 7 Event

Coronal dimming of extreme ultraviolet (EUV) emission has the potential to be a useful forecaster of coronal mass ejections (CMEs). As emitting material leaves the corona, a temporary void is left behind which can be observed in spectral images and irradiance measurements. The velocity and mass of the CMEs should impact the character of those observations. However, other physical processes can confuse the observations. We describe these processes and the expected observational signature, with special emphasis placed on the differences. We then apply this understanding to a coronal dimming event with an associated CME that occurred on 2010 August 7. Data from the Solar Dynamics Observatory's (SDO) Atmospheric Imaging Assembly (AIA) and EUV Variability Experiment (EVE) are used for observations of the dimming, while the Solar and Heliospheric Observatory's (SoHO) Large Angle and Spectrometric Coronagraph (LASCO) and the Solar Terrestrial Relations Observatory's (STEREO) COR1 and COR2 are used to obtain velocity and mass estimates for the associated CME. We develop a technique for mitigating temperature effects in coronal dimming from full-disk irradiance measurements taken by EVE. We find that for this event, nearly 100% of the dimming is due to mass loss in the corona.

Solar↗

DOE OSTI2025

Role of Mg:Al ratio and Pt promotion on mitigating the deactivation of Ni-based methane steam reforming catalysts

Ni-based catalysts for CH 4 steam reforming require fine-tuning to withstand deactivation under dynamic operation conditions relevant to emerging H 2 -driven technologies. This study investigates the impact of the Mg:Al ratio and Pt presence in catalyst composition on the activity and stability of industrially relevant Ni-based mono- and bimetallic catalysts during simulated daily start-up and shut-down cycles in various gas atmospheres. The evolution of the catalyst structure during extensive testing procedures was investigated in detail by complementary electron microscopy, in situ/operando XAS and XRD. The results obtained revealed that catalyst deactivation is promoted at high Mg:Al ratios and especially affects the monometallic catalysts. By converting CH 4 at lower temperatures, Pt regulates the extent of Ni oxidation and its incorporation into MgO lattice. Further prevention of catalyst deactivation was achieved by optimizing the reactor shut-down procedure to minimize the simultaneous exposure to high temperatures and H 2 O vapors. By flushing the reactor with N 2 only around the reaction extinction temperature, a fraction of Ni species is maintained in metallic state, which is beneficial for the long-term activity and reaction operation economy.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

From peak to plummet: impending decline of the warm Arctic-cold continents phenomenon

Abstract This study assesses the projected trajectory of Warm Arctic-Cold Continent (WACC) events in East Asia and North America through large ensemble simulation for the upcoming decades. It analyses the evolution of the geographical boundaries of threshold cold temperatures, revealing a significant northward shift as a sign of global warming’s impact on the southward advancement of Arctic cold air. While validating the intensification of the WACC phenomenon until the 2020 s, echoing earlier studies, the findings indicate a marked decrease beginning in the 2030s. If warming is not curbed, this shift suggests a critical modification in the WACC pattern, prompting a re-evaluation of existing theories and models for extreme winter weather events. The results have major implications, spurring communities impacted by WACC to anticipate future changes and encouraging the climate forecasting community to update conceptual models for improved adaptation and mitigation approaches.

Meteorology & Atmospheric Sciences↗

NASA NTRS2001

DART: Instrument Package Developed for Investigating Atmospheric Dust on Mars

Mars' dust-filled atmosphere could be a significant problem for photovoltaic array operation during long missions on the surface of Mars. Measurements made by Pathfinder showed a 0.3-percent loss of solar array performance per day due to dust obscuration. Thus, dust deposition is the limiting factor in the lifetime of solar arrays for Martian power systems, and developing design tools to mitigate this deposition is important for long missions.

Landis, Geoffrey A.↗

NASA NTRSDate not supplied

NASA’s Earth System Observatory Formulation Overview

NASA’s Earth System Observatory (ESO) is an array of Earth-focused, interconnected satellite missions focused on five core study areas: Surface Biology and Geology, Mass Change, Aerosols, Surface Deformation and Change, and Clouds, Convection, and Precipitation. Observatory development follows recommendations from the National Academies of Sciences, Engineering and Medicine’s 2017 Earth Science Decadal Survey. Data gathered by ESO missions will provide actionable science to inform decisions related to climate change, disaster mitigation, and wildfires, improve real-time agricultural processes, and many other applications. Targeting launch dates in the late 2020s and early 2030s, each ESO satellite will deliver valuable information, but by working together as a single observatory system, their combined data and imagery will provide the global community with a 4D, holistic view of Earth, from bedrock to atmosphere. The ESO is also building on the legacy of international collaboration in Earth science, with initial participation and collaboration on these missions across space agency partners, including the Japanese Aerospace Exploration Agency (JAXA), Centre National D'Etudes Spatiales (CNES), Canadian Space Agency (CSA), Deutsches Zentrum für Luft- und Raumfahrt (DLR), and Agenzia Spaziale Italiana (ASI). This paper provides an overview of ESO, as well as an update on ESO missions currently in formulation – the Atmosphere Observing System, Mass Change, and Surface Biology and Geology elements – including current mission architectures, international partner collaboration, science community engagement, and applications efforts, as well as how NASA and its partners will make ESO data accessible to users all over the world.

NASA Earth Science↗

NASA NTRSDate not supplied

Moon to Mars (M2M): Exploration Atmosphere

As humans leave the bounds of Earth to explore the lunar surface and beyond, crew will don extravehicular activity (EVA) suits to learn more about these extraterrestrial environments, establish sustained presence, and perform needed upgrades and maintenance to their space vehicle and habitation systems. Spacefaring vehicle and habitation design will need to support these EVA excursions while ensuring crew health and safety. A crucial technological design advancement towards this goal is the use of a lower pressure exploration atmosphere (EA) that enables high efficiency EVA, rather than the sea level atmosphere of 14.7 psia, 21% oxygen (O 2 ) found on the International Space Station, Shuttle, and most other Russian and Chinese space vehicles and stations. Early space vehicles (Mercury through Apollo Programs) used a 5 psia, 100% O 2 environment, which eliminated the need for pre-EVA denitrogenation protocols, simplified the life support system to a single gas, and saved structural mass. For longer duration missions (Skylab), a diluent gas was added, changing the atmosphere to 5 psia, 70-74% O 2 to prevent atelectasis while remaining normoxic. As in-flight science became a top priority, Shuttle and ISS atmospheres were chosen to operate at sea level allowing for simpler ground-based study control conditions. Consequently this led to long pre-EVA denitrogenation protocols involving up to 4 hours of O 2 prebreathe because the EVA suit still operated at a low pressure of 4.3 psid. To increase operational efficiency, the Shuttle was retroactively certified to operate using 10.2 psia, 26.5% O 2 , reducing O 2 prebreathe time to 40-75 min. Current plans for M2M habitats on the Lunar surface require EVA, thus EA recommendation became 8 psia and 32% O 2 but was revised to 8.2 psia and 34% O 2 to decrease hypoxia exposure. Unfortunately, the benefits of EA in support of safe and efficient EVAs comes with the challenge of fire management in a higher-than-normal O 2 % environment. Although known for decades, the recommended forward work to address fire management has only recently begun. Current flammability tests include examining material propagation and ignition sources as well as fire mitigation processes to better understand these properties for proposed new EA environments. Fire safety, DCS risk, and mission design all contribute to the multifaceted parameters of EA. Thus while it is clear that EA is required to achieve the goals of future exploratory space missions, final specifications are still being evaluated for optimizing crew health and safety.

space atmosphere↗

DOE OSTI2020

Carbon Utilization: Electrochemical Approach Using Novel Catalyst and System Integration

The environmental footprint from power generation can be mitigated by capturing emitted carbon dioxide (CO2) and converting it to value-added fuel sources. A multitude of different fuels can be produced from CO2 depending on the chemical reaction catalysts. Typically, these pathways can be developed electrochemically, or through hydrogenation. In recent years the electrochemical reduction of CO2 has grown exponentially, as it has shown potential to decrease atmospheric pollution and provide an additional means of on-demand electricity storage. Formic acid (FA) in particular has industrial applications such as in fuel cells or as a hydrogen storage medium, and requires a lower thermodynamic energy input than any other fuel produced for electrochemical CO2 reduction. However, product selectivity remains a challenge for conventional electrocatalysts, making FA production efficiencies above 50% difficult. To address the challenge of catalytic selectivity, UK CAER employs enzymatic catalysts to facilitate the FA production and minimize unwanted byproducts. Our process couples the catalyst with a charge mediator which is necessary to shuttle electrons, and an electrolyte pH buffer to prevent the catalyst from degrading. Presently, production efficiencies have approached 60% at a rate of over 10 mM FA/hour. System design considerations (flow rate, bulk volume) will also be discussed.

01 COAL, LIGNITE, AND PEAT↗