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All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Soil, Groundwater, Surface Water, and Sediments of Kennedy Space Center, Florida: Background Chemical and Physical Characteristics

This study documented background chemical composition of soils, groundwater, surface; water, and sediments of Kennedy Space Center. Two hundred soil samples were collected, 20 each in 10 soil classes. Fifty-one groundwater wells were installed in 4 subaquifers of the Surficial Aquifer and sampled; there were 24 shallow, 16 intermediate, and 11 deep wells. Forty surface water and sediment samples were collected in major watershed basins. All samples were away from sites of known contamination. Samples were analyzed for organochlorine pesticides, aroclors, chlorinated herbicides, polycyclic aromatic hydrocarbons (PAH), total metals, and other parameters. All aroclors (6) were below detection in all media. Some organochlorine pesticides were detected at very low frequencies in soil, sediment, and surface water. Chlorinated herbicides were detected at very low frequencies in soil and sediments. PAH occurred in low frequencies in soiL, shallow groundwater, surface water, and sediments. Concentrations of some metals differed among soil classes, with subaquifers and depths, and among watershed basins for surface water but not sediments. Most of the variation in metal concentrations was natural, but agriculture had increased Cr, Cu, Mn, and Zn.

Shmalzer, Paul A.↗
NASA NTRS1999

The Confluence of Gangis and Eos Chasmas (5-12 deg S, 31-41 deg W): Geologic, Hydrologic, and Exobiologic Considerations for Landing Site at the East End of Valles Marineris

Over its 3,500 km length, Valles Marineris exhibits an enormous range of geologic and environmental diversity. At its western end, the canyon is dominated by the tectonic complex of Noctis Labyrinthus; while in the east it grades into an extensive region of chaos where scoured channels and streamlined islands provide evidence of catastrophic floods that spilled into the northern plains. In the central portion of the system, debris derived from the massive interior layered deposits of Candor and Ophir Chasmas spills into the central trough. In other areas, 6 km-deep exposures of Hesperian and Noachian-age canyon wall stratigraphy have collapsed in massive landslides that extend many tens of kilometers across the canyon floor. Ejecta from interior craters, aeolian sediments, and possible volcanics emanating from structurally controlled vents along the base of the scarps, further contribute to the canyon's geologic complexity. Following the initial rifting that gave birth to Valles Marineris, water appears to have been a principal agent in the canyon's geomorphic development an agent whose significance is given added weight by its potential role in both sustaining and preserving evidence of past life. In this regard, the interior layered deposits of Candor, Ophir, and Hebes Chasmas, have been identified as possible lucustrine sediments that may have been laid down in long-standing ice-covered lakes. The potential survival and growth of native organisms in such an environment, or in the aquifers whose disruption gave birth to the chaotic terrain and outflow channels to the north and east of the canyon, raises the possibility that fossil indicators of life may be present in the local sediment and rock. Because of the enormous distances over which these diverse environments occur, identifying a single landing site that maximizes the opportunity for scientific return is not a simple task. However, given the fluvial history and narrow geometry of the canyon, the presence of a single exit at its eastern end provides an opportunity for sampling that appears unequaled elsewhere in the system.

George, J. A.↗
NASA NTRS1994

The Search for Carbonates on Mars

Liquid water is presently unstable at the Martian surface, where the mean atmospheric pressure is 6 mbar (due to CO2) and the winter diurnal temperature ranges from 150 K at the pole to 220 K at the equator. Liquid water is widely regarded as a basic requirement for living systems, suggesting that life as we know it is not possible in present surface environments on Mars. However, life may survive within "oases" where liquid water is present. Potential oases on Mars include subsurface hydrothermal systems or deeply buried aquifers where chemoautolithotrophic microorganisms may exist. Potential metabolic strategies for primary production in such environments on Mars (and for the microbial mediation of geologic processes!) encompass the full range presently known for subsurface environments on the Earth (e.g. sulphate reduction, methanogenesis, acetogenesis, etc).

Farmer, Jack D.↗
NASA NTRS2001

Abiotic Versus Biotic Weathering Of Olivine As Possible Biosignatures

We are investigating the weathering of silicate minerals by both purely inorganic, and biologically mediated processes using field-emission scanning electron microscopy (FESEM) and energy dispersive x-ray spectroscopy (EDS). By resolving surface textures and chemical compositions of weathered surfaces at the sub-micron scale we hope to be able to distinguish abiotic from biotic weathering processes and so establish a new biosignature applicable to the study of astromaterials including but not limited to the Martian meteorites. Sterilized olivine grains (San Carlos, Arizona) no more than 1-2 mm in their longest dimension were optically assayed to be uniform in color and free of inclusions were selected as weathering subjects. Prior to all experiments surface morphologies and Fe/Mg ratios were determined for each grain using FE-SEM and EDS. Experiments were divided into two categories abiotic and biotic and were compared with "naturally" weathered samples. For the preliminary experiments, two trials (open and closed to the ambient laboratory environment) were performed under abiotic conditions, and three trials under biotic conditions (control, day 1 and day 2). The open system abiotic trials used sterile grains heated at 98 C and 200 C for both 24 and 48 hours in 1L double distilled de-ionized water. The closed system abiotic trials were conducted under the same conditions but in a sealed two layer steel/Teflon "bomb" apparatus. The biotic trials used sterile grains mounted in a flow-through device attached to a wellhead on the Columbia River aquifer. Several discolored, altered, grains were selected to document "natural" weathering surface textures for comparison with the experimental samples. Preliminary results indicate there are qualitative differences in weathered surface textures among all the designed experiments. The olivine grains in abiotic trials displayed etching, pitting, denticulate margins, dissolution and clay formation. The scale of the features ranged from tens to a few microns with textures that remained relatively sharp and were crystallographically controlled. These results were comparable to that observed in the "naturally" weathered comparison/reference grains. Chemical analysis by EDS indicates these textures correlated with the relative loss of Mg and Fe cations by diffusional processes. In contrast the biotic results indicated changes in the etching patterns on the scale of hundreds of nm, which are neither sharp nor crystallographically controlled (nanoetching). Organisms, organic debris and/or extracellular polymeric substances (biofilm) were often in close proximity or direct contact with the nanoetching. While there are many poorly constrained variables in natural weathering experiments to contend with, such as the time scale, the chemistry of the fluids and degree of biologic participation, some preliminary observations can be made: (1) certain distinct surface textures appear correlated with the specific processes giving rise to these textures; (2) the process of diffusing cations can produce many similar styles of surface textural changes; and (3) the main difference between abiotic and biotically produced weathering is the scale (microns versus nanometers) and the style (crystallographically versus noncrystallographically controlled) of the textural features. Further investigation into nanosize scale surface textures should attempt to quantify both textures and chemical changes of the role of microorganisms in the weathering of silicates. Additional experiments addressing nanoscale textures of shock features for comparison with the current data set.

Longazo, Teresa G.↗
NASA NTRS2001

The Evolution of the Martian Hydrosphere: Implications for the Fate of a Primordial Ocean and the Current State of the Northern Plains

In this paper we consider the hydraulic and thermal conditions that gave rise to the elevated source regions of the Late Hesperian outflow channels and explore their implications for the evolution of the Martian hydrosphere. We find that if the outflow channel floodwaters were derived from a subpermafrost aquifer, then it implies that, throughout the planet's first billion years of evolution, as much as one third of its surface was covered by standing bodies of water and ice. Following the development of the global dichotomy, the bulk of this water would have existed as an ice-covered ocean in the northern plains. We demonstrate that the progressive crustal assimilation of this early surface reservoir of H2O (punctuated by possible episodes of less extensive flooding) was a natural consequence of the planet's subsequent climatic and geothermal evolution-potentially cycling the equivalent of a km-deep global ocean of water through the atmosphere and subsurface every approx. 10(exp 9) years. In response to the long-term decline in planetary heat flow, the progressive coldtrapping of H2O into the growing cryosphere is expected to have significantly depleted the original inventory of groundwater-a development that could well explain the apparent decline in outflow channel activity observed during the Amazonian. Although primarily a theoretical analysis, our findings appear remarkably consistent with the geomorphic and topographic evidence that Mars once possessed a primordial ocean and that a substantial relic of that body continues to survive as massive ice deposits within the northern plains. Confirmation of the presence of such deposits, combined with the potential detection of a global-scale groundwater system, would provide persuasive support for the validity of this analysis.

Clifford, Stephen M.↗
NASA NTRS2003

Life in the Ice

The current Martian surface environment is extremely hostile to any known form of life. The combination of subfreezing temperature, low atmospheric pressure and high ultraviolet flux, combined with desiccated and possibly oxidizing soil, could destroy even the hardiest microorganisms. The Viking biology experiments are generally interpreted to indicate that the surface of Mars is currently devoid of life and organic molecules at the part-per-billion level. Speculation on the possibility of extant or preserved microbial life on Mars thus centers on refuges in some manner protected from the current surface environment, either in space or time. Terrestrial analogs include hydrothermal systems, lakes, caves and subsurface aquifers as well as more clement conditions in the distant past. We are examining the evidence for microbiology in Earth's glaciated polar regions as analogs to the polar caps of Mars. This research concerns the detection of microorganisms or their preserved remains at the surface and within polar glacial ice.

C C Allen↗
NASA NTRS2003

Melting of the Martian Permafrost by Hydrothermal Convection Associated with Magmatic Intrusion

Many surface features on Mars are closely connected with the subsurface permafrost layer. The polygonal fractures and the possible thermokarsts are observed on the martian surface and they are analogous to the terrestrial features located on the permafrost. The rampart and/or fluidized ejecta morphology of martian craters is indicative of subsurface volatiles. Mars should stock much water in a form of ground ice. The suspected fluvial features on Mars would suggest water (or its mixture), which is coming from the subsurface aquifer or the ground ice. Such a martian hydrothermal system has been the alternative idea to the assumption of precipitation for forming observed fluvial-like features on Mars. The outflow channels, in particular, have characteristics unique to water erosion and clearly indicates the surface runoff of huge amount of water, which usual precipitations could not supply. The outflow channels potentially suggest the pre-existence of a substantial amount of liquid water very close to the martian surface to cause a large flood. The idea of supplying such massive liquid water near the ground might be still controversial, however, from many observational facts, we assume that the igneous melting of the martian permafrost layer should have played a significant role. We have numerically simulated the generation of meltwater and are proposing a consistent scenario of forming the outflow channels as well as the headwater regions; chaotic terrains.

Y Ogawa↗
NASA NTRS2003

A Case for Hydrothermal Gray Hematite in Aram Chaos

The Thermal Emission Spectrometer (TES) on Mars Global Surveyor has detected deposits of coarsegrained, gray crystalline hematite in Sinus Meridiani, Aram Chaos, and Vallis Marineris [1]. Detailed features in the hematite spectral signature of the Sinus Meridiani region show that the spectrum is consistent with emission dominated by crystal c-faces of hematite, implying that the hematite is specular [2]. Gray specular hematite (also known as specularite ) is a particular gray crystalline form that has intergrown, hexagonal plates with a silvery metallic luster. We believe that the key to the origin of specularite is that it requires crystallization at temperatures in excess of about 100 C. In reviewing the occurrence of gray hematite on Earth, we find no exceptions to this warm temperature requirement [3]. Thermal crystallization on Mars could occur (1) as diagenesis at a depth of a few kilometers of sediments originally formed in lowtemperature waters, or (2) as direct precipitation from hydrothermal solution. Aram Chaos has unique chaotic terrain that offers more clues to the formation of the hematite than the relatively featureless flat terrain (as seen from orbit) of Sinus Meridiani. Aram Chaos provides the opportunity to look at a combination of TES data, Mars Orbiter Camera images, and Mars Orbiter Laser Altimeter (MOLA) topography. This combination of data suggests that high concentrations of hematite were formed in planar strata and have since been exposed by erosion of an overlying light-toned, caprock. Lesser concentrations of hematite are found adjacent to these strata at lower elevations, which we interpret as perhaps a lag deposit. The topography and the collapsed nature of the chaotic terrain favor a hydrothermally charged aquifer as the original setting where the hematite formed. An alternative sedimentary origin requires post-depositional burial to a depth of ~3-5 km to induce thermally driven recrystallization of fine-grained iron oxides to coarse-grained hematite.

D C Catling↗
NASA NTRS2003

Physical Characteristics, Geologic Setting, and Possible Formation Processes of Spring Deposits on Mars Based on Terrestrial Analogs

Spring formation is a predicted consequence of the interaction of former Martian aquifers with structures common to Mars, including basin margins, Tharsis structures, and other structural deformation characteristics. The arid environment and high abundance of water soluble compounds in the crust will have likewise encouraged spring deposit formation at spring sites. Such spring deposits may be recognized from morphological criteria if the characteristics of formation and preservation are understood. An important first step in the current Mars exploration strategy [10] is the detection of sites where there is evidence for past or present near-surface water on Mars. This study evaluates the large-scale morphology of spring deposits and the physical processes of their formation, growth, and evolution in terms that relate to (1) their identification in image data, (2) their formation, evolution, and preservation in the environment of Mars, and (3) their potential as sites of long-term or late stage shallow groundwater emergence at the surface of Mars.

L S Crumpler↗
NASA NTRS2003

Detecting Near-Surface Water and Hydrate Minerals on Mars from a Rover, Penetrator, or Borehole: The HYDRA Instrument

One of the major goals of near term NASA Mars exploration is to identify exact locations of near-surface water or hydrated minerals on Mars. Evidence for the existence of recent nearsurface water on Mars underscores the need for developing instrumentation that can identify water or hydrated minerals very near the surface. Further encouraging evidence of surface and near-surface water and hydrate minerals on Mars comes from neutron spectrometer measurements aboard Mars Odyssey. Preliminary results show very large regions of high hydrogen content poleward of 60 deg. latitude, as well as interesting features closer to the equator. However, spatial resolution from orbit is very poor, approx. 400 km. The next logical step is to use in-situ or near-surface investigations to map in detail some of the most interesting features. Relatively simple instrumentation based on He-3 gas proportional counters were shown to be highly successful on the Lunar Prospector mission in identifying even low levels of enhanced hydrogen abundances. Here we discuss HYDRA, a water- and hydrate-sensing instrument currently being developed under the NASA Mars Instrument Development Program (MIDP). HYDRA is based on Lunar Prospector technology, and is intended as a rover body-mounted instrument, or an instrument on an aerobot, penetrator, hard lander on the surface of Mars, or for borehole stratigraphy applications. Our proposed instrument would be ideal for such platforms as it would be small (less than 7 cm diameter by 10 cm long), low mass (less than 500 g), low power (less than 1W), and have a low data volume per measurement. We use neutron spectrometry (a) because of its proven ability to uniquely detect and quantify hydrogen abundance, and (b) because the resources required by this approach (weight, power, size, telemetry bandwidth, and measurement time) are extremely low. This compact neutron spectrometer package, comprised of two small He-3 gas proportional counters, offers superior sensitivity, extensive flight heritage, and inherent ruggedness. These tubes have survived approx. 1500 g's of acceleration in penetrator tests. In a landed application, HYDRA would help address many topics of interest to the Mars Exploration and Astrobiology communities: (a) nature and origin of stratified deposits; (b) water cycle(s) and temporal changes; (c) early water oceans, aquifers, precipitation; (d) current extent/location/state of water; (e) polar cap processes and temporal changes; (f) where extremeophiles could survive on Mars; (g) paleoclimate surface signatures and modeling; (h) strategies for future Mars exploration.

R C Elphic↗
NASA NTRS2003

Electrically Conducting, Ca-Rich Brines, Rather Than Water, Expected in the Martian Subsurface

If Mars ever possessed a salty liquid hydrosphere, which later partly evaporated and froze down, then any aqueous fluids left near the surface could have evolved to become dense eutectic brines. Eutectic brines, by definition, are the last to freeze and the first to melt. If CaC12-rich, such brines can remain liquid until temperatures below 220 K, close to the average surface temperature of Mars. In the Martian subsurface, in intimate contact with the Ca-rich basaltic regolith, NaC1-rich early brines should have reacted to become Ca-rich. Fractional crystallization (freezing) and partial melting would also drive brines toward CaC12-rich compositions. In other words, eutectic brine compositions could be present in the shallow subsurface of Mars, for the same reasons that eutectic magma compositions are common on Earth. Don Juan Pond, Antarctica, a CaC12-rich eutectic brine, provides a possible terrestrial analog, particularly because it is fed from a basaltic aquifer. Owing to their relative density and fluid nature, brines in the Martian regolith should eventually become sandwiched between ice above and salts beneath. A thawing brine sandwich provides one explanation (among many) for the young gullies recently attributed to seepage of liquid water on Mars. Whether or not brine seepage explains the gullies phenomenon, dense, CaC12-rich brines are to be expected in the deep subsurface of Mars, although they might be somewhat diluted (temperatures permitting) and of variable salt composition. In any case, they should be good conductors of electricity.

Burt, D. M.↗
NASA NTRS2003

Mound Spring Complexes in Central Australia: An Analog for Martian Groundwater Fed Outflow Channels?

The arid inland of Australia contains a diversity of landscapes and landscape processes, often of great antiquity, extending back to the Mesozoic and Paleozoic. The potential of this landscape as a source of Mars analogs has, however, been little explored. The few examples studied so far include radiation-tolerant microbes in thermal springs and hematite-silica hydrothermal alteration near Arkaroola in the Finders Ranges, and aeolian landforms at Gurra Gurra water hole the north east of Arkaroola. Further Australian Mars analog studies were provided by the studies of Bourke and Zimbelman of the paleoflood record of the Todd and Hale Rivers in central Australia. To facilitate study of such analogues, Mars Society Australia has embarked on a project to construct a Mars Analog Research Station near Arkaroola. The international scientific community will soon have the opportunity to participate in Mars analog studies in central Australia utilizing this facility. An area of considerable Mars analog potential is the mound spring complexes that occur at the margins of the Great Artesian Basin (GAB) which underlies 22% of the Australian continent and covers 1.7 million km2. The mound springs are formed when ground water flows to a topographic low, and subsurface strata dips up causing a hydrological head at the surface. Minerals precipitated at the spring discharge zone form low mesas or "mounds", the height of which are controlled by the hydrological head. This paper describes the Dalhousie Mound Spring Complex (DMC) in the northern part of South Australia (Figure 1), and its potential as a Mars analog. Hydrogeology: The DMC consists of a cluster of more than 60 active springs formed by natural discharge from the GAB). Total measured discharge from the GAB is 1.74 GL per day, estimated unfocussed natural leakage through the aquaclude is thought be approximately equal to this figure. Some 54 ML per day are currently discharged by the DMC, 3% of the measured total. The discharged artesian waters are of low to moderate salinity (700 - 9400 ppm), near neutral pH (6.8-7.3) and warm (20-46 C). The elevated temperatures are due to passage of the groundwater through deeply buried (up to 3 km) aquifers in an region of high heat flow, rather than magmatic heating. The waters also contain high levels of dissolved iron and H2S and less than 1 ppm dissolved oxygen. The water is carried in the Late Jurassic Algebuckina Sandstone beneath the aquaclude of the Bulldog Shale. It is brought near the surface by the mid-Cenozoic Dalhousie anticline and the ground water flow focused along a series of faults that breach the anticline's crest.

Clarke, J. D. A.↗
NASA NTRS2004

Mangala Valles, Mars: Investigations of the Source of Flood Water and Early Stages of Flooding

Mangala Valles, an approx. 900 km long north-south trending outflow channel located southwest of the Tharsis rise, extends northward from one of the Memnonia Fossae graben across the southern highlands, terminating at the dichotomy boundary. Previous Viking-based analyses suggest that the water that carved the channel was expelled from the graben, possibly during two distinct flood events, one in the Late Hesperian and one in the Latest Hesperian/Early Amazonian. The mechanism by which the water was transported to the graben, and ultimately to the surface remained ambiguous, although two general scenarios were proposed: melting of near surface ground ice via nearby Tharsis lava flows, and tapping of a near surface aquifer via faulting associated with the graben. Here we use MOLA altimetric data and MOC and THEMIS images to reexamine Mangala Valles and the surrounding region. Further, we develop a new model for the production and transport of the floodwater.

Ghatan, Gil J.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Astrobiology: Analogs and Applications to the Search for Life

The session "Astrobiology: Analogs and Applications to the Search for Life" included the folowing reports:The Search for Life on Mars Using Macroscopically Visible Microbial Mats (Stromatolites) in 3.5/3.3 Ga Cherts from the Pilbara in Australia and Barberton in South Africa as Analogues; Life in a Mars Analog: Microbial Activity Associated with Carbonate Cemented Lava Breccias from NW Spitsbergen; Groundwater-fed Iron-rich Microbial Mats in a Freshwater Creek: Growth Cycles and Fossilization Potential of Microbial Features; Episodic Fossilization of Microorganisms on an Annual Timescale in an Anthropogenically Modified Natural Environment: Geochemical Controls and Implications for Astrobiology; Proterozoic Microfossils and Their Implications for Recognizing Life on Mars; Microbial Alteration of Volcanic Glass in Modern and Ancient Oceanic Crust as a Proxy for Studies of Extraterrestrial Material ; Olivine Alteration on Earth and Mars; Searching for an Acidic Aquifer in the R!o Tinto Basin. First Geobiology Results of MARTE Project; In-Field Testing of Life Detection Instruments and Protocols in a Mars Analogue Arctic Environment; Habitability of the Shallow Subsurface on Mars: Clues from the Meteorites; Mars Analog Rio Tinto Experiment (MARTE): 2003 Drilling Campaign to Search for a Subsurface Biosphere at Rio Tinto Spain; Characterization of the Organic Matter in an Archean Chert (Warrawoona, Australia); and The Solfatara Crater, Italy: Characterization of Hydrothermal Deposits, Biosignatures and Their Astrobiological Implication.

Lunar and Planetary Institute↗
NASA NTRS2004

Ancient Giant Basin/Aquifer System in the Arabia Region, Mars

Ancient geologic/hydrologic phenomena on Mars observed through the magnetic data [1,2] provide windows to the ancient past through the younger Argyre and Hellas impacts [e.g., 3,4], the northern plains basement [5], and the Tharsis and Elysium magmatic complexes (recently referred to as superplumes [6,7]). These signatures, coupled with highly degraded macrostructures (tectonic features that are tens to thousands of km-long [8]), reflect an energetic planet during its embryonic development (.5 Ga or so of activity) with an active dynamo and magnetosphere [1,2,6]. One such window into the ancient past occurs northwest of the Hellas impact basin in Arabia Terra. Arabia Terra is one of the few water-rich equatorial regions of Mars, as indicated through impact crater [9] and elemental [10,11] information. This region records many unique traits, including stratigraphy, topography, cratering record, structural character, geomorphology, and geophysical, elemental, albedo, and thermal inertia signatures. We interpret these to collectively indicate a possible ancient giant impact basin that later became an important aquifer, as it provided yet another source of water for the formation of putative water bodies that occupied the northern plains [12,13] and addresses possible water-related characteristics that may be observed at the Opportunity landing site. This basin is antipodal to Tharsis and estimated to be at least 3,000 km in diameter.

Dohm, James M.↗
NASA NTRS2003

The Ability to Probe the Martian Polar Subsurface Via Ground-penetrating Radar

Ground-penetrating radar (GPR) offers the exciting possibility of remote sensing below the Martian surface for trapped aquifers. A GPR is currently heading to Mars onboard Mars Express (MEX) and a GPR is in consideration to be onboard Mars Reconnaissance Orbiter (MRO) in 2005. While such orbital systems offer great potential for polar stratigraphy studies, their ability to penetrate deep into the Martian polar ice is a function of both the intervening ionospheric density and the overlying ground ice conductivity. The influence of both signal-altering layers will be discussed. Polar Ice and Water: Clifford1,2 has suggested

Farrell, W. M.↗
NASA NTRS1998

Hydrogen consumption by methanogens on the early Earth

It is possible that the first autotroph used chemical energy rather than light. This could have been the main source of primary production after the initial inventory of abiotic organic material had been depleted. The electron acceptor most readily available for use by this first chemoautotroph would have been CO2. The most abundant electron donor may have been H2 that would have been outgassing from volcanoes at a rate estimated to be as large as 10(12) moles yr-1, as well as from photo-oxidation of Fe+2. We report here that certain methanogens will consume H2 down to partial pressures as low as 4 Pa (4 x 10(-5) atm) with CO2 as the sole carbon source at a rate of 0.7 ng H2 min-1 microgram-1 cell protein. The lower limit of pH2 for growth of methanogens can be understood on the basis that the pH2 needs to be high enough for one ATP to be synthesized per CO2 reduced. The pH2 values needed for growth measured here are consistent with those measured by Stevens and McKinley for growth of methanogens in deep basalt aquifers. H2-consuming autotrophs are likely to have had a profound effect on the chemistry of the early atmosphere and to have been a dominant sink for H2 on the early Earth after life began rather than escape from the Earth's atmosphere to space.

Non-NASA Center↗