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At least 595 records · Page 33

Capacity decline of ambient temperature secondary Li-TiS2 cells

The main objective of the study described was to identify the causes responsible for the capacity losses observed during cycling of secondary Li-TiS2 cells. Experimental Li-TiS2 cells were fabricated and tested for their cycle life performance. The open circuit voltage of the cells was monitored during the rest period between the charging and discharging. The polarization at the Li and TiS2 electrodes was also monitored during cycling. Cycled cells were disassembled and the cathodes were analyzed by various analytical techniques. The results of the study indicate that the observed capacity loss is almost entirely due to the increased polarization of the TiS2 electrode with cycling. The electrolyte was found to degrade during cycling and the degradation products were found to deposit at the TiS2 electrode, which probably lead to the higher polarization.

Subbarao, S.↗

Nature of buoyancy-driven flows in a reduced-gravity environment

The role of buoyancy-driven convection in reduced-gravity environments has been emphasized. It is shown that for some materials-processing experiments the values of the fundamental dimensionless parameters such as Gr or Ra are shifted from the very large (ground-based values) to moderately large (space-based values). As a consequence, in cases where approximate analytical solutions are desired, the accuracy of the usual asymptotic (boundary-layer) analysis in which infinitely large parametric ranges are assumed is reduced. Approximate analytical techniques for refinement of the asymptotic solutions are identified that will extend the accuracy to the moderately large parametric ranges associated with space-based processing.

Kassemi, Siavash A.↗

Synthesis and characterization of fine grain diamond films

A fine grain diamond film has been developed by microwave plasma assisted chemical vapor deposition. Various analytical techniques, including Rutherford backscattering, proton recoil analysis, Raman spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. The grain size of the film was determined from bright and dark field electron micrographs, and found to be 200-1000 A. The films exhibited good optical transmission between 2.5 and 10 microns, with a calculated absorption coefficient of 490/cm. The friction coefficients of this film were found to be 0.035 and 0.030 at dry nitrogen and humid air environments, respectively, and the films had low wear rates.

Wu, Richard L. C.↗

Algorithms for real-time fault detection of the Space Shuttle Main Engine

This paper reports on the results of a program to develop and demonstrate concepts related to a realtime health management system (HMS) for the Space Shuttle Main Engine (SSME). An HMS framework was developed on the basis of a top-down analysis of the current rocket engine failure modes and the engine monitoring requirements. One result of Phase I of this program was the identification of algorithmic approaches for detecting failures of the SSME. Three different analytical techniques were developed which demonstrated the capability to detect failures significantly earlier than the existing redlines. Based on promising initial results, Phase II of the program was initiated to further validate and refine the fault detection strategy on a large data base of 140 SSME test firings, and implement the resultant algorithms in real time. The paper begins with an overview of the refined algorithms used to detect failures during SSME start-up and main-stage operation. Results of testing these algorithms on a data base of nominal and off-nominal SSME test firings is discussed. The paper concludes with a discussion of the performance of the algorithms operating on a real-time computer system.

Ruiz, C. A.↗

X-Ray And Acoustic Measurements Yield Stiffnesses

Analytical technique combines ultrasonic scanning measurements of local velocity of sound in specimen of material with x-ray computed tomographic measurements of local mass density to compute local stiffness of material. Stiffnesses at various locations in specimen then used in finite-element mathematical model of elastic behavior of specimen to compute local stresses, local strains, and overall deformations. Technique enhances value of quantitative nondestructive x-ray and ultrasonic measurements. Especially useful in characterization of carbon/carbon composites and other advanced materials not homogeneous and for which customary simplifying assumption of constant density and/or constant stiffness not valid.

Madaras, Eric Irvine↗

Low level measurements of atmospheric DMS, H2S, and SO2 for GTE/CITE-3

This project involved the measurement of atmospheric dimethylsulfide (DMS) and hydrogen sulfide (H2S) as part of the GTE/CITE-3 instrument intercomparison program. The two instruments were adapted for use on the NASA Electra aircraft and participated in all phases of the mission. This included ground-based measurements of NIST-provided standard gases and a series of airborne missions over the Western Atlantic Ocean. Analytical techniques used are described and the results are summarized.

Saltzman, Eric↗

Reliable fusion of control and sensing in intelligent machines

Although robotics research has produced a wealth of sophisticated control and sensing algorithms, very little research has been aimed at reliably combining these control and sensing strategies so that a specific task can be executed. To improve the reliability of robotic systems, analytic techniques are developed for calculating the probability that a particular combination of control and sensing algorithms will satisfy the required specifications. The probability can then be used to assess the reliability of the design. An entropy formulation is first used to quickly eliminate designs not capable of meeting the specifications. Next, a framework for analyzing reliability based on the first order second moment methods of structural engineering is proposed. To ensure performance over an interval of time, lower bounds on the reliability of meeting a set of quadratic specifications with a Gaussian discrete time invariant control system are derived. A case study analyzing visual positioning in robotic system is considered. The reliability of meeting timing and positioning specifications in the presence of camera pixel truncation, forward and inverse kinematic errors, and Gaussian joint measurement noise is determined. This information is used to select a visual sensing strategy, a kinematic algorithm, and a discrete compensator capable of accomplishing the desired task. Simulation results using PUMA 560 kinematic and dynamic characteristics are presented.

Mcinroy, John E.↗

Thruster configurations for maneuvering heavy payloads

The Cargo Transfer Vehicle (CTV) will be required to perform six degree of freedom (6 DOF) maneuvers while carrying a wide range of payloads varying from 100,000 lbm to no payload. The current baseline design configuration for the CTV uses a forward propulsion module (FPM) mounted in front of the payload with the CTV behind the payload so that the center of gravity (CG) of the combined stack is centered between the thruster sets. This allows for efficient rotations and translations of heavy payloads in all directions; however, the FPM is a costly item, so it is desirable to find design solutions that do not require the FPM. This presentation provides an overview of the analysis of the FPM requirements for the CTV. In this study, only the reaction control system (RCS) thruster configurations are considered for 6 DOF maneuvers of various CTV cargo configurations. An important output of this study are the viable alternative thruster configurations that eliminate the need for the FPM. Initial results were derived using analytical techniques and simulation analysis tools. Results from the preliminary analysis were validated using our 6 DOF simulation.

Tsugawa, Roy K.↗

Radiative transfer models

The purpose of this work was to assist with the development of analytical techniques for the interpretation of infrared observations. We have done the following: (1) helped to develop models for continuum absorption calculations for water vapor in the far infrared spectral region; (2) worked on models for pressure-induced absorption for O2 and N2 and their comparison with available observations; and (3) developed preliminary studies of non-local thermal equilibrium effects in the upper stratosphere and mesosphere for infrared gases. These new techniques were employed for analysis of balloon-borne far infrared data by a group at the Harvard-Smithsonian Center for Astrophysics. The empirical continuum absorption model for water vapor in the far infrared spectral region and the pressure-induced N2 absorption model were found to give satisfactory results in the retrieval of the mixing ratios of a number of stratospheric trace constituents from balloon-borne far infrared observations.

Horwitz, James L.↗

Thruster configurations for maneuvering heavy payloads

The cargo transfer vehicle (CTV) will be required to perform six degree of freedom (6DOF) maneuvers while carrying a wide range of payloads varying from 100,000 lbm to no payload. The current baseline design configuration for the CTV uses a forward propulsion module (FPM) mounted in front of the payload and the CTV behind the payload so that the center of gravity (CG) of the combined stack is contained between the thruster sets. This allows for efficient rotation and translations of heavy payloads in all directions; however, the FPM is a costly item, so it is desirable to find design solutions which do not require the FPM. This presentation provides an overview of the work performed in analyzing the FPM requirements for the CTV. Specifically, key issues related to thruster configuration requirements for operating the CTV without the FPM, throughout the 100,000 lbm payload to no payload range, will be highlighted. In this study, only the reaction control system (RCS) thruster configurations are considered and the orbit adjust engines are not addressed. An important output of this study is the viable alternative thruster configurations which eliminate the need for the FPM. Initial results were derived using analytical techniques and simulation analysis tools. Results from the preliminary analysis were used as inputs for our 6DOF simulation. The 6DOF simulation was used to validate our design guidelines and to verify the performance of the thruster configurations.

Tsugawa, Roy K.↗

The properties of and analytical methods for detection of LiOH and Li2CO3

Lithium hydroxide (LiOH) is used as a CO2 absorbent in the Shuttle Extravehicular Mobility Unit (EMU) Portable Life Support System (PLSS). The first objective was to survey parameters that may be used to indicate conversion of LiOH to Li2CO3, and compile a list of all possible properties, including physical, chemical, structural, and electrical, that may serve to indicate the occurrence of reaction. These properties were compiled for the reactant (LiOH), the intermediate monohydrate compound (LiOH.H2O), and the final product (Li2CO3). The second objective was to survey measurement and analytical techniques which may be used in conjunction with each of the properties identified above, to determine the extent of conversion of LiOH to Li2CO3. Both real-time and post-run techniques were of interest. The techniques were also evaluated in terms of complexity, technology readiness, materials/equipment availability, and cost, where possible.

Selvaduray, Guna↗

The two-point correlation function of randomly distributed Lyman alpha clouds

It is often assumed that Ly-alpha forest clouds are randomly distributed, intergalactic objects that are highly ionized by the UV background produced by quasars. If these assumptions are true, fluctuations in the UV background should produce a nonzero two point correlation function in the Ly-alpha forest. This effect, which is really just a generalization of the proximity effect, is more significant at high redshift (z is approximately 3-4) because the mean free path for UV photons is smaller there, and the fluctuations correspondingly larger. This effect was studied using both the semi-analytic techniques of Zuo's recent papers and Monte Carlo simulations. The correlation function is expected to have a small yet potentially measurable amplitude that is consistent with current upper limits. Furthermore, the signature of this effect is distinctive because the nonzero correlation function extends over the photon mean free path, which is larger than the expected scale of large-scale structure. Observations or upper limits on this effect could provide information about the source of the ionizing background at high redshifts and the nature of the Ly-alpha forest clouds.

Fardal, Mark A.↗

Hypervelocity impact survivability experiments for carbonaceous impactors

We performed a series of hypervelocity impact experiments using carbon-bearing impactors (diamond, graphite, fullerenes, phthalic acid crystals, and Murchison meteorite) into Al plate at velocities between 4.2 and 6.1 km/s. These tests were made to do the following: (1) determine the survivability of carbon forms and organize molecules in low hypervelocity impact; (2) characterize carbonaceous impactor residues; and (3) determine whether or not fullerenes could form from carbonaceous impactors, under our experimental conditions, or survive as impactors. An analytical protocol of field emission SEM imagery, SEM-EDX, laser Raman spectroscopy, single and 2-stage laser mass spectrometry, and laser induced fluorescence (LIF) found the following: (1) diamonds did not survive impact at 4.8 km/s, but were transformed into various forms of disordered graphite; (2) intact, well-ordered graphite impactors did survive impact at 5.9 km/sec, but were only found in the crater bottom centers; the degree of impact-induced disorder in the graphite increases outward (walls, rims, ejecta); (3) phthalic acid crystals were destroyed on impact (at 4.2 km/s, although a large proportion of phthalic acid molecules did survive impact); (4) fullerenes did not form as products of carbonaceous impactors (5.9 - 6.1 km/s, fullerene impactor molecules mostly survived impact at 5.9 km/s; and (5) two Murchison meteorite samples (launched at 4.8 and 5.9 km/s) show preservation of some higher mass polycyclic aromatic hydrocarbons (PAHs) compared with the non-impacted sample. Each impactor type shows unique impactor residue morphologies produced at a given impact velocity. An expanded methodology is presented to announce relatively new analytical techniques together with innovative modifications to other methods that can be used to characterize small impact residues in LDEF craters, in addition to other acquired extraterrestrial samples.

Bunch, T. E.↗

A micromechanics-based strength prediction methodology for notched metal-matrix composites

An analytical micromechanics-based strength prediction methodology was developed to predict failure of notched metal matrix composites. The stress-strain behavior and notched strength of two metal matrix composites, boron/aluminum (B/Al) and silicon-carbide/titanium (SCS-6/Ti-15-3), were predicted. The prediction methodology combines analytical techniques ranging from a three-dimensional finite element analysis of a notched specimen to a micromechanical model of a single fiber. In the B/Al laminates, a fiber failure criteria based on the axial and shear stress in the fiber accurately predicted laminate failure for a variety of layups and notch-length to specimen-width ratios with both circular holes and sharp notches when matrix plasticity was included in the analysis. For the SCS-6/Ti-15-3 laminates, a fiber failure based on the axial stress in the fiber correlated well with experimental results for static and postfatigue residual strengths when fiber matrix debonding and matrix cracking were included in the analysis. The micromechanics-based strength prediction methodology offers a direct approach to strength prediction by modeling behavior and damage on a constituent level, thus, explicitly including matrix nonlinearity, fiber matrix debonding, and matrix cracking.

Bigelow, C. A.↗

Tribological evaluation and analysis of coating materials

A physical characterization of coating materials by analytical techniques such as XPS, AES, ellipsometry, and nuclear reaction analysis can contribute to the understanding of adhesion and friction of the coatings and can partially predict the tribological properties of the coatings. This two-part paper describes the tribological properties and physical characteristics of (1) diamondlike carbon (DLC) films and (2) silicon nitride (SiN(x)) films. Emphasis is to relate plasma deposition conditions to the film chemistry and composition and to the adhesion and friction of the films. With the DLC films, the higher the plasma deposition power, the less the hydrogen concentration and the greater the film density and the hardness. The friction behavior of DLC films deposited at higher deposition powers (200 to 300 W) is similar to that of bulk diamond. Even in a vacuum, the DLC films effectively lubricate ceramic surfaces (Si3N4) at temperatures to 500 C. With SiN(x) films, the silicon to nitrogen ratios and the amount of amorphous silicon depend on deposition frequency. The presence of rich amorphous silicon in the high-frequency plasma-deposited SiN(x) films increases their adhesion and friction above 500 C in vacuum.

Miyoshi, Kazuhisa↗

On panel flutter and divergence of infinitely long unstiffened and ring-stiffened thin-walled circular cylinders

A preliminary theoretical investigation of the panel flutter and divergence of infinitely long, unstiffened and ring-stiffened thin-walled circular cylinders is described. Linearized unsteady potential-flow theory is utilized in conjunction with Donnell's cylinder theory to obtain equilibrium equations for panel flutter. Where necessary, a simplified version of Flugge's cylinder theory is used to obtain greater accuracy. By applying Nyquist diagram techniques, analytical criteria for the location of stability boundaries are derived. A limited number of computed results are presented.

Leonard, Robert W↗

Thermal History Of PMRs Via Pyrolysis-Gas Chromatography

Pyrolysis-gas chromatography (PY-GC) useful as analytical technique to determine extents of cure or postcure of PMR-15 polyimides and to lesser extent, cumulative thermal histories of PMR-15 polyimides exposed to high temperatures. Also applicable for same purposes to other PMR polyimides and to composite materials containing PMR polyimides. Valuable in reducing costs and promoting safety in aircraft industry by helping to identify improperly cured or postcured PMR-15 composite engine and airframe components and helping to identify composite parts nearing ends of their useful lives.

Gluyas, Richard E.↗

Looking ahead in systems engineering

Five areas that are discussed in this paper are: (1) the technological characteristics of systems engineering; (2) the analytical techniques that are giving modern systems work its capability and power; (3) the management, economics, and effectiveness dimensions that now frame the modern systems field; (4) systems engineering's future impact upon automation, computerization and managerial decision-making in industry - and upon aerospace and weapons systems in government and the military; and (5) modern systems engineering's partnership with modern quality control and reliability.

Feigenbaum, Donald S.↗