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At least 595 records · Page 33

The NASA Earth Science Program and Small Satellites

Earth's changing environment impacts every aspect of life on our planet and climate change has profound implications on society. Studying Earth as a single complex system is essential to understanding the causes and consequences of climate change and other global environmental concerns. NASA's Earth Science Division (ESD) shapes an interdisciplinary view of Earth, exploring interactions among the atmosphere, oceans, ice sheets, land surface interior, and life itself. This enables scientists to measure global and climate changes and to inform decisions by Government, other organizations, and people in the United States and around the world. The data collected and results generated are accessible to other agencies and organizations to improve the products and services they provide, including air quality indices, disaster prediction and response, agricultural yield projections, and aviation safety. ESD's Flight Program provides the spacebased observing systems and supporting infrastructure for mission operations and scientific data processing and distribution that support NASA's Earth science research and modeling activities. The Flight Program currently has 21 operating Earth observing space missions, including the recently launched Global Precipitation Measurement (GPM) mission, the Orbiting Carbon Observatory-2 (OCO-2), the Soil Moisture Active Passive (SMAP) mission, and the International Space Station (ISS) RapidSCAT and Cloud-Aerosol Transport System (CATS) instruments. The ESD has 22 more missions and instruments planned for launch over the next decade. These include first and second tier missions from the 2007 Earth Science Decadal Survey, Climate Continuity missions to assure availability of key climate data sets, and small-sized competitively selected orbital missions and instrument missions of opportunity belonging to the Earth Venture (EV) Program. Small satellites (~500 kg or less) are critical contributors to these current and future satellite missions. Some examples are the aforementioned Orbiting Carbon Observatory-2 (OCO-2), the Gravity Recovery and Climate Experiment Follow On (GRACE FO), and the Cyclone Global Navigation Satellite System (CYGNSS) microsatellite constellation. Small satellites also support ESD in space validation and risk reduction of enabling technologies (components and systems). The status of the ESD Flight Program and the role of small satellites will be discussed.

Earth Science Prog & Small Sat↗

Dusty Environment Classification and Testing: Dust Mitigation Slide Cleaning Material Study

During the Apollo missions many mechanisms, equipment, and surfaces were contaminated by lunar dust and often negatively affected. The methods used to clear these devices of dust proved ineffective, which led to premature failure in some cases. Systems being designed for upcoming missions to the Moon will need to address the performance degradation risk of dust contamination. Surfaces at risk include thermal control surfaces, solar cells, camera and sensor optics, seals, metal joints and tools, and space suit assemblies. To improve state of the art dust mitigation approaches, the dust mitigation team at NASA Glenn Re-search Center (GRC) explored the effects imposed on substrates during cleaning activities in the presence of lunar dust. The Uniform Dust Deposition System (UDDS) was used to conduct a study of various cleaning techniques on different substrates. Test substrates and cleaning media were selected to represent a wide range of structural and functional materials. Substrates included orthofabric, thermal radiator coating, aluminum, quartz glass, silicone rubber, aluminized Mylar, and FEP. Cleaning materials included cloth wipes, tapes, a brush, and a pliable cleaner concept. Cleaning material / substrate pairs were rated on cleaning efficiency, substrate damage, cleaning material longevity, and ease of use. The best performing cleaning method varied based on application.

dust mitigation↗

Flow battery flow field having volume that is function of power parameter, time parameter and concentration parameter

A flow battery includes a cell that has first and second flow fields spaced apart from each other and an electrolyte separator layer. A supply/storage system is external of the cell and includes first and second vessels fluidly connected with the first and second flow fields, and first and second pumps configured to selectively move first and second fluid electrolytes between the vessels and the first and second flow fields. The flow fields each have an electrochemically active zone that is configured to receive flow of the fluid electrolytes. The electrochemically active zone has a total open volume that is a function of at least one of a power parameter of the flow battery, a time parameter of the pumps and a concentration parameter of the fluid electrolytes.

Smeltz, Andrew↗

Microgravity: A Teacher's Guide with Activities in Science, Mathematics, and Technology

Microgravity is the subject of this teacher's guide. This publication identifies the underlying mathematics, physics, and technology principles that apply to microgravity. The topics included in this publication are: 1) Microgravity Science Primer; 2) The Microgravity Environment of Orbiting Spacecraft; 3) Biotechnology; 4) Combustion Science; 5) Fluid Physics; 6) Fundamental Physics; and 7) Materials Science; 8) Microgravity Research and Exploration; and 9) Microgravity Science Space Flights. This publication also contains a glossary of selected terms.

Rogers, Melissa J.B.↗

Modification of the International Space Station USOS to Support Installation and Activation of the Node 3 Element

The International Space Station (ISS) program is nearing an assembly complete configuration with the addition of the final resource node module in early 2010. The Node 3 module will provide critical functionality in support of permanent long duration crews aboard ISS. The new module will permanently house the regenerative Environment Control and Life Support Systems (ECLSS) and will also provide important habitability functions such as waste management and exercise facilities. The ISS program has selected the Port side of the Node 1 "Unity" module as the permanent location for Node 3 which will necessitate architecture changes to provide the required interfaces. The USOS ECLSS fluid and ventilation systems, Internal Thermal Control Systems, and Avionics Systems require significant modifications in order to support Node 3 interfaces at the Node 1 Port location since it was not initially designed for that configuration. This paper outlines the design, development, certification, and implementation of these changes in support of ISS assembly complete.

Link, Dwight E., Jr.↗

Theoretical prediction of magnetic exchange coupling constants from broken-symmetry coupled cluster calculations

Exchange coupling constants ( J ) are fundamental to the understanding of spin spectra of magnetic systems. In this study, we investigate the broken-symmetry (BS) approaches of Noodleman and Yamaguchi in conjunction with coupled cluster (CC) methods to obtain exchange couplings. J values calculated from CC in this fashion converge smoothly toward the full configuration interaction result with increasing level of CC excitation. We compare this BS-CC scheme to the complementary equation-of-motion CC approach on a selection of bridged molecular cases and give results from a few other methodologies for context.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Kinetic Model for the Reduction of Cu II Sites by NO + NH 3 and Reoxidation of NH 3 -Solvated Cu I Sites by O 2 and NO in Cu-SSZ-13

In this work, a kinetic model is developed for the reduction of Cu II sites by NO + NH 3 and the reoxidation of NH 3 -solvated Cu I sites by O 2 and NO in Cu-SSZ-13. Fourier transform infrared (FTIR) spectroscopy and spatially resolved capillary inlet mass spectrometry (SpaciMS) measurements during transient reactor experiments are utilized to identify the rate parameters associated with NO + NH 3 RHC (reduction half-cycle), proposed to occur via two distinct pathways involving adsorbed NH 3 and gas-phase NH 3 . The resulting NO + NH 3 RHC model is validated using spatiotemporal N 2 measurements covering a wide range of temperatures (200–450 °C) and space velocities (53,000–640,000 h –1 ). N 2 O formation is observed and modeled during NO + NH 3 RHC, with quantitative validation under standard selective catalytic reduction (SCR) conditions. Experimentally measured enthalpic and entropic changes associated with O 2 adsorption on NH 3 -solvated Cu I (ZCu(NH 3 ) 2 ) complexes [ Kamasamudram, K. Catal. Today 2010 , 151 (3–4), 212-222], along with activation energies estimated computationally for the intercage diffusion of ZCu(NH 3 ) 2 complexes [ Paolucci, C. Science 2017 , 357 (6 354), 898-903], are incorporated into a mean field kinetic model for the low-temperature oxidation half-cycle (OHC). Significant NH 3 release is observed during the isothermal oxidation of Cu I sites, attributed to desorption of NH 3 ligands from NH 3 -solvated Cu II dimers (Z 2 Cu 2 (NH 3 ) 4 O 2 ). Reduction of these dimeric complexes leads to the consumption of one NO/Cu II , contradicting the expected reduction stoichiometry. Inclusion of a global Arrhenius rate for the NO titration of Z 2 Cu 2 (NH 3 ) 4 O 2 complexes provides accurate representations of standard SCR on reduced and oxidized catalysts, predicting transient NO and NH 3 consumption between 150 and 250 °C as a function of hydrothermal aging. Deactivation of low-temperature standard SCR by NH 3 is observed at high NH 3 pressures, modeled via the formation of superoxo amino (ZCu(NH 3 ) 3 OO*) complexes during NH 3 titration of Z 2 Cu 2 (NH 3 ) 4 O 2 complexes [ Negri, C. J. Am. Chem. Soc. 2020 , 142 (37), 15884-15896]. The redox kinetic model presented here provides a foundational description of active site redox during low-temperature standard SCR, combining the recent kinetic, spectroscopic, and computational findings on the mechanism of standard SCR over Cu-SSZ-13.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Space station proximity operations and window design

On-orbit proximity operations (PROX-OPS) consist of all extravehicular activity (EVA) within 1 km of the space station. Because of the potentially large variety of PROX-OPS, very careful planning for space station windows is called for and must consider a great many human factors. The following topics are discussed: (1) basic window design philosophy and assumptions; (2) the concept of the local horizontal - local vertical on-orbit; (3) window linear dimensions; (4) selected anthropomorphic considerations; (5) displays and controls relative to windows; and (6) full window assembly replacement.

Haines, Richard F.↗

A movable mass control system to detumble a disabled space vehicle

An internal autonomous control system to either completely detumble a spacecraft or lessen the tumbling motions until the rescue craft arrives is discussed. Such a device would become active upon loss of control. The development of a movable mass control system to convert the tumbling motions of a disabled vehicle into simple spin is presented. A simple spin state would greatly facilitate crew evacuation and final despinning by an external means. The system moves a control mass, according to a selected control law, in the acceleration environment created by the tumbling motion. By moving the mass properly, the rotational kinetic energy of the system may be increased or decreased creating simple spin states about the minimum or maximum moment of inertia axis, respectively. The control system is designed for the latter case due to its associated stability in the presence of perturbing forces.

Edwards, T. L.↗

Space reactor power 1986 - A year of choices and transition

Both the SP-100 and Multimegawatt programs have made significant progress over the last year and that progress is the focus of this paper. In the SP-100 program the thermoelectric energy conversion concept powered by a compact, high-temperature, lithium-cooled, uranium-nitride-fueled fast spectrum reactor was selected for engineering development and ground demonstration testing at an electrical power level of 300 kilowatts. In the Multimegawatt program, activities moved from the planning phase into one of technology development and assessment with attendant preliminary definition and evaluation of power concepts against requirements of the Strategic Defense Initiative.

Wiley, R. L.↗

XXL-HSC: An updated catalogue of high-redshift ( z ≥ 3.5) X-ray AGN in the XMM-XXL northern field

X-rays offer a reliable method to identify active galactic nuclei (AGNs). However, in the high-redshift Universe, X-ray AGNs are poorly sampled due to their relatively low space density and the small areas covered by X-ray surveys. In addition to wide-area X-ray surveys, it is important to have deep optical data in order to locate the optical counterparts and determine their redshifts. Here, in this work, we built a high-redshift (z ≥ 3.5) X-ray-selected AGN sample in the XMM-XXL northern field using the most updated [0.5–2 keV] catalogue along with a plethora of new spectroscopic and multi-wavelength catalogues, including the deep optical Subaru Hyper Suprime-Cam (HSC) data, reaching magnitude limits i ~ 26 mag. We selected all the spectroscopically confirmed AGN and complement this sample with high-redshift candidates that are HSC g- and r-band dropouts. To confirm the dropouts, we derived their photometric redshifts using spectral energy distribution techniques. We obtained a sample of 54 high-z sources (28 with spec-z), the largest in this field so far (almost three times larger than in previous studies), and we estimated the possible contamination and completeness. We calculated the number counts (log N-log S) in different redshift bins and compared our results with previous studies and models. We provide the strongest high-redshift AGN constraints yet at bright fluxes (f 0.5 – 2 keV > 10 –15 erg s –1 cm –2 ). The samples of z ≥ 3.5, z ≥ 4, and z ≥ 5 are in agreement with an exponential decline model similar to that witnessed at optical wavelengths. Our work emphasises the importance of using wide-area X-ray surveys with deep optical data to uncover high-redshift AGNs.

79 ASTRONOMY AND ASTROPHYSICS↗

A First-Principles Approach to Modeling Surface Site Stabilities on Multimetallic Catalysts

The study of multimetallic alloys and the multitude of possible surface compositions have sparked a tremendous interest in engineering low-cost materials with high activity and selectivity in heterogeneous catalysis. Multimetallic systems provide complementary functionalities and an unprecedented tunability when designing catalyst formulations. However, due to their immense structural and compositional complexity, the investigation and identification of an optimal catalyst is a tedious and time-consuming process, both experimentally and theoretically. Therefore, theoretical design principles are highly desirable to accelerate the screening of catalyst structures across the vast compositional space. In this paper, we introduce a simple and general model for predicting the site stability of multimetallic surfaces and nanoparticles, which is based on physical principles. The model requires only a small set of density functional theory (DFT) calculations of metal atom binding energies on monometallic and dilute alloy surface slabs to optimize the parameters in the simple model. The resulting model allows for the quantification of the stability of any particular atom site in any conceivable chemical environment across a wide range of morphologies, sizes, and arrangements by interpolating the derived parameters from a monometallic system to a completely diluted alloyed system. Herein, we demonstrate the robustness of the model across an extensive data set of transition metal alloy surfaces and 147-atoms cuboctahedral nanoparticles (NPs) composed of IrRhRu and PtPdRu. In conclusion, our approach yields mean absolute errors of ≈0.15 (IrRhRu), 0.20 (PtPdRu), 0.19 (IrRhRu NP), and 0.26 (PtPdRu NP) eV relative to site binding energies calculated using DFT.

36 MATERIALS SCIENCE↗

Lunar International Science Coordination/Calibration Targets

A new era of international lunar exploration has begun and will expand over the next four years with data acquired from at least four sophisticated remote sensing missions: KAGUYA (SELENE) [Japan], Chang'E [China], Chandrayaan-l [India], and LRO [United States]. It is recognized that this combined activity at the Moon with modern sophisticated sensors wi II provide unprecedented new information about the Moon and will dramatically improve our understanding of Earth's nearest neighbor. It is anticipated that the blooming of scientific exploration of the Moon by nations involved in space activities will seed and foster peaceful international coordination and cooperation that will benefit all. Summarized here are eight Lunar International Science Coordination/Calibration Targets (L-ISCT) that are intended to a) allow cross-calibration of diverse multi-national instruments and b) provide a focus for training young scientists about a range of lunar science issues. The targets, discussed at several scientific forums, were selected for coordinated science and instrument calibration of orbital data. All instrument teams are encouraged to participate in a coordinated activity of early-release data that will improve calibration and validation of data across independent and diverse instruments.

Head, J. W.↗

Early Transition and Use of VIIRS and GOES-R Products by NWS Forecast Offices

The Visible Infrared Imaging Radiometer Suite (VIIRS) on the NPOESS Preparatory Project (NPP) satellite, part of the Joint Polar Satellite System (JPSS), and the ABI and GLM sensors scheduled for the GOES-R geostationary satellite will bring advanced observing capabilities to the operational weather community. The NASA Short-term Prediction Research and Transition (SPoRT) project at Marshall Space Flight Center has been facilitating the use of real-time experimental and research satellite data by NWS Weather Forecast Offices (WFOs) for a number of years to demonstrate the planned capabilities of future sensors to address particular forecast challenges through improve situational awareness and short-term weather forecasts. For the NOAA GOES-R Proving Ground (PG) activity, SPoRT is developing and disseminating selected GOES-R proxy products to collaborating WFOs and National Centers. SPoRT developed the a pseudo-Geostationary Lightning Mapper product and helped in the transition of the Algorithm Working Group (AWG) Convective Initiation (CI) proxy product for the Hazardous Weather Testbed (HWT) Spring Experiment,. Along with its partner WFOs, SPoRT is evaluating MODIS/GOES Hybrid products, which brings ABI-like data sets from existing NASA instrumentation in front of the forecaster for everyday use. The Hybrid uses near real-time MODIS imagery to demonstrate future ABI capabilities, while utilizing standard GOES imagery to provide the temporal frequency of geostationary imagery expected by operational forecasters. In addition, SPoRT is collaborating with the GOES-R hydrology AWG to transition a baseline proxy product for rainfall rate / quantitative precipitation estimate (QPE) to the OCONUS regions. For VIIRS, SPoRT is demonstrating multispectral observing capabilities and the utility of low-light channels not previously available on operational weather satellites to address a variety of weather forecast challenges. This presentation will discuss the results of transitioning these products to collaborating WFOs throughout the country.

Fuell, Kevin K.↗

Users Guide for the Anvil Threat Corridor Forecast Tool V1.7.0 for AWIPS

The Applied Meteorology Unit (AMU) originally developed the Anvil Threat Sector Tool for the Meteorological Interactive Data Display System (MIDDS) and delivered the capability in three phases beginning with a feasibility study in 2000 and delivering the operational final product in December 2003. This tool is currently used operationally by the 45th Weather Squadron (45 WS) Launch Weather Officers (LWO) and Spaceflight Meteorology Group (SMG) forecasters. Phase I of the task established the technical feasibility of developing an objective, observations-based tool for short-range anvil forecasting. The AMU was subsequently tasked to develop short-term anvil forecasting tools to improve predictions of the threat of triggered lightning to space launch and landing vehicles. Under the Phase II effort, the AMU developed a nowcasting anvil threat sector tool, which provided the user with a threat sector based on the most current radiosonde upper wind data from a co-located or upstream station. The Phase II Anvil Threat Sector Tool computes the average wind speed and direction in the layer between 300 and 150 mb from the latest radiosonde for a user-designated station. The following threat sector properties are consistent with the propagation and lifetime characteristics of thunderstorm anvil clouds observed over Florida and its coastal waters (Short et al. 2002): a) 20 n mi standoff circle, b) 30 degree sector width, c) Orientation given by 300 to 150 mb average wind direction, d) 1-, 2-, and 3- hour arcs in upwind direction, and e) Arc distances given by 300 to 150 mb average wind speed. Figure 1 is an example of the MIDDS Anvil Threat Sector tool overlaid on a visible satellite image at 2132 UTC 13 May 2001. Space Launch Complex 39A was selected as the center point and the Anvil Threat Sector was determined from upper-level wind data at 1500 UTC in the preconvective environment. Narrow thunderstorm anvil clouds extend from central Florida to the space launch and landing facilities at the Kennedy Space Center (KSC) and Cape Canaveral Air Force Station (CCAFS) and beyond. The anvil clouds were generated around 1930 UTC (1430 EDT) by thunderstorm activity over central Florida and transported 90 n mi east-northeastward within 2 hours, as diagnosed by the anvil forecast tool. Phase III, delivered in February 2003, built upon the results of Phase II by enhancing the Anvil Threat Sector Tool with the capability to use national model forecast winds for depiction of potential anvil lengths and orientations over the KSC/CCAFS area with lead times from 3 through 168 hours (7 days). In September 2003, AMU customers requested the capability to use data from the KSC 50 MHz Doppler Radar Wind Profiler (DRWP) in the Anvil Threat Sector Tool and this capability was delivered by the AMU in December 2003. In March 2005, the AMU was tasked to migrate the MIDDS Anvil Threat Sector Tool capabilities onto the Advanced Weather Interactive Processing System (AWIPS) as the Anvil Threat Corridor Forecast Tool.

Bauman, William H., III↗

Advanced Material Options for the Portable Life Support System

Meeting an aggressive mass requirement is a challenge for new space suit development efforts, including that of the Exploration Extravehicular Mobility Unit Portable Life Support System (PLSS) government reference design. To reduce overall system mass, titanium was selected as the primary metal for the PLSS backplate and thermal loop. However, galvanically compatible metals (Hastelloy, Inconel, Monel) have relatively high densities and require further design complexities such as coatings and more challenging manufacturing. Efforts to reduce the mass of the government reference design for an International Space Station (ISS) or lunar mission were halted due to the government’s transition to a commercial Extravehicular Activity (EVA) services approach, but research was conducted into methodologies for mass savings using advanced materials. With the advent of a lunar Artemis mission and potential for future Mars missions, mass becomes a more critical driver going forward. Therefore, alternative materials and processes must be considered to fully close the mass requirement. There are many new materials and processes that can be considered; however, considerations must be made to ensure galvanic compatibility, radiation concerns for sensitive electronics, vacuum compatibility, tight tolerances, fluid compatibility with oxygen and water, and thread insert options. Individual PLSS components may have different requirements and need to be considered separately for reducing overall mass. This report will touch on comparisons between advanced materials, focusing on composites, additive manufacturing, and plastics. It will also address the different processes that may need to be applied when using these materials in the harsh environment of space. Lastly, it will look at specific components and make recommendations for options to reduce the mass of each one.

Ryan Ogilvie↗

Advanced Material Options for the Portable Life Support System (PLSS)

Meeting an aggressive mass requirement is a challenge for new space suit development efforts, including that of the Exploration Extravehicular Mobility Unit Portable Life Support System (PLSS) government reference design. To reduce overall system mass, titanium was selected as the primary metal for the PLSS backplate and thermal loop. However, galvanically compatible metals (Hastelloy, Inconel, Monel) have relatively high densities and require further design complexities such as coatings and more challenging manufacturing. Efforts to reduce the mass of the government reference design for an International Space Station (ISS) or lunar mission were halted due to the government’s transition to a commercial Extravehicular Activity (EVA) services approach, but research was conducted into methodologies for mass savings using advanced materials. With the advent of a lunar Artemis mission and potential for future Mars missions, mass becomes a more critical driver going forward. Therefore, alternative materials and processes must be considered to fully close the mass requirement. There are many new materials and processes that can be considered; however, considerations must be made to ensure galvanic compatibility, radiation concerns for sensitive electronics, vacuum compatibility, tight tolerances, fluid compatibility with oxygen and water, and thread insert options. Individual PLSS components may have different requirements and need to be considered separately for reducing overall mass. This report will touch on comparisons between advanced materials, focusing on composites, additive manufacturing, and plastics. It will also address the different processes that may need to be applied when using these materials in the harsh environment of space. Lastly, it will look at specific components and make recommendations for options to reduce the mass of each one.

Ryan Ogilvie↗

Comparison of CCM- and CRM-Based Boost Parallel Active Power Decoupler for PV Microinverter

Single-phase inverter or rectifier systems often make use of an active power decoupler (APD) to balance the mismatch between constant dc power and fluctuating ac power. This article deals with the comparison of continuous conduction mode (CCM) and critical conduction mode (CRM) operation-based design of a parallel boost-type APD for photovoltaic microinverter applications. From a design perspective, multiobjective analysis of efficiency, volume, and cost is explored within a decision space including planar inductors, gallium nitride based devices, film capacitors, switching frequency, and modulation (CCM vs. CRM). The theoretical study analyzes all possible design configurations within CCM and CRM and identifies Pareto-optimal designs, from which the selected CRM design can achieve reduced system volume and lower cost with the use of smaller inductor core, while operating with similar California Energy Commission efficiency drop as the selected CCM design. From a control perspective, a pulsewidth modulation based control strategy is proposed to implement closed-loop CRM modulation that does not rely on zero-crossing detection. Furthermore, closed-loop systems are designed for the optimal CCM and CRM realizations, and the final system characteristics are compared. Experimental results, obtained using two separate 40-V, 400-W hardware prototypes for CCM and CRM, are presented to verify the analyses.

42 ENGINEERING↗