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At least 595 records · Page 33

Wear and interfacial transport of material

Bonding across the interface for two solids in contact and the subsequent transfer of material from one surface to another is a direct result of the interfacial bonds being stronger than the cohesive bonds in either of the two solids. Surface tools such as LEED, Auger emission spectroscopy, field ion microscopy, and the atom probe are used to examine adhesive contacts and to determine the direction, nature, quantity of material transfer and properties of the solids which effect transfer and wear. The electronic nature, cohesive binding energies, surface structure, lattice disregistry and distribution of species in surface layers are all found to effect adhesion and transfer or transport for clean surfaces in solid state contact. The influence of adsorbed and reacted surface films from fractions of a monolayer to multilayer reactive films are considered. It is shown that even fractions of a monolayer of surface active species such as oxygen and sulfur can markedly inhibit adhesion and transport.

Buckley, D. H.↗

Space shuttle SRM development

The successful static testing of the fourth Space Shuttle Solid Rocket Motor (SRM) is described. Transportation and support equipment concepts and component reusability are demonstrated. The evolution of the SRM transportation support equipment and special test equipment designs are reviewed, and development activities are discussed. Handling and processing aspects of large, heavy components are reviewed briefly.

Adams, I. C.↗

Aircraft fire safety research

During the past 15 years, very significant progress has been made toward enhancing aircraft fire safety in both normal and hostile (combat) operational environments. Most of the major aspects of the aircraft fire safety problem are touched upon here. The technology of aircraft fire protection, although not directly applicable in all cases to spacecraft fire scenarios, nevertheless does provide a solid foundation to build upon. This is particularly true of the extensive research and testing pertaining to aircraft interior fire safety and to onboard inert gas generation systems, both of which are still active areas of investigation.

Botteri, Benito P.↗

Fundamentals of tribology at the atomic level

Tribology, the science and engineering of solid surfaces in moving contact, is a field that encompasses many disciplines: solid state physics, chemistry, materials science, and mechanical engineering. In spite of the practical importance and maturity of the field, the fundamental understanding of basic phenomena has only recently been attacked. An attempt to define some of these problems and indicate some profitable directions for future research is presented. There are three broad classifications: (1) fluid properties (compression, rheology, additives and particulates); (2) material properties of the solids (deformation, defect formation and energy loss mechanisms); and (3) interfacial properties (adhesion, friction chemical reactions, and boundary films). Research in the categories has traditionally been approached by considering macroscopic material properties. Recent activity has shown that some issues can be approached at the atomic level: the atoms in the materials can be manipulated both experimentally and theoretically, and can produce results related to macroscopic phenomena.

Ferrante, John↗

Development of a unique polyurethane primer/topcoat

USBI Company, a Division of Pratt & Whitney Government Engines and Space Propulsion, is involved in corrosion and environmental research and development activities both at their headquarters in Huntsville, Alabama and their Florida Operations at Kennedy Space Center, Florida. The programs involve the development of environmentally compatible materials that improve the corrosion protection of expensive Solid Rocket Boosters (SRB) that are part of the Space Shuttle systems developed and managed by Marshall Space Flight Center in Huntsville, Alabama. Coatings For Industry, a paint manufacturer in Souderton, PA helped formulate and produce the first lot of BOOSTERCOAT paint. High strength aluminum aerospace flight hardware exposed to harsh seacoast environments and seawater immersion presently uses high volatile organic compound (VOC) chromated and lead bearing primers and epoxy topcoats for corrosion protection. Epoxy paint tends to be brittle and has relatively low ultraviolet (UV) exposure resistance. A unique, environmentally compatible, non-leaded/non-chromated, low VOC polyurethane single coat (primer/topcoat) trade named BOOSTERCOAT has been developed for excellent corrosion protection, flexibility, adhesion, chemical and solvent resistance properties. This report will discuss the development of BOOSTERCOAT and the potential opportunities for commercial use in the energy, transportation, chemical, maritime, structural fields.

Novak, Howard L.↗

High Redshift Quasars

The report for this period includes three papers: 'Associated Absorption at Low and High Redshift'; 'Strong X-ray Absorption in a Broad Absorption Line Quasar: PHL5200'; and 'ASCA and ROSAT X-ray Spectra of High-Redshift Radio-Loud Quasars'. The first gives examples from both low and high redshift for combining information on absorbing material in active galactic nuclei from both x-ray and the UV. The second presents ASCA observations of the z = 1.98 prototype broad absorption line quasar (BALQSO): PHL 5200, detected with both the solid-state imaging spectrometers and the gas imaging spectometers. The third paper presents results on the x-ray properties of 9 high-redshift radio-loud quasars observed by ASCA and ROSAT, including ASCA observations of S5 0014+81 (z = 3.38) and S5 0836+71 (z = 2.17) and ROSAT observations of PKS 2126-158.

Elvis, Martin S.↗

SEP Mission to Titan NEXT Aerocapture In-Space Propulsion (Quicktime Movie)

The ion thruster is one of the most promising solar electric propulsion (SEP) technologies to support future Outer Planet missions (place provided link below here) for NASA's Office of Space Science. Typically, ion thrusters are used in high Isp- low thrust applications that require long lifetimes, as well as, higher efficiency over state-of-the-art chemical propulsion systems.Today, the standard for ion thrusters is the SEP Technology Application Readiness (NSTAR) thruster. Jet Propulsion Laboratory's (JPL's) extended life test (ELT) of the DS 1 flight spare NSTAR thruster began in October 1998. This test successfully demonstrated lifetime of the NSTAR flight spare thruster, which will provide a solid basis for selection of ion thrusters for future Code S missions. The NSTAR ELT was concluded on June 30,2003 after 30,352 hours. The purpose of the Next Generation Ion (NGI) activities is to advance Ion propulsion system technologies through the development of NASA's Evolutionary Xenon Thruster (NEXT). The goal of NEXT is to more than double the power capability and lifetime throughput (the total amount of propellant which can be processed) while increasing the Isp by 30% and the thrust by 120%.

Baggett, Randy↗

Meteoritic Carbonates - The Key to Sampling Extraterrestrial Fluids?

Fluid inclusions are naturally occurring mineral features that preserve trapped fluid phases inside a solid phase. These cavities exist as a closed system, recording the environmental conditions present during entrapment – both physical and chemical. As a result, fluid inclusions are great candidates for directly studying past fluid activity on extraterrestrial bodies within the Solar System. On Earth, fluid inclusions are abundant as they occur within numerous host minerals. They are a powerful tool for accurately and directly understanding the driving processes in various geological environments. In contrast, extraterrestrial fluid inclusions have only been positively identified on three separate occasions within host materials ranging from ordinary chondrites to C/B-type asteroid mission return samples. The possibility of directly studying the fluids involved in aqueous alteration and accurately constraining their heliocentric distances drives the hunt for these elusive capsules. Our goals are to locate new fluid inclusion candidates (hereon referred to as candidates) and assess whether fluid inclusions are a common feature within meteoritic carbonates and why they may have eluded detection for so long. We also aim to characterize the host grain’s mineralogical properties and assess the potentially preferential conditions for fluid entrapment on the asteroid parent body.

P A B Krizan↗

Reaction between nitric oxide and ozone in solid nitrogen

Nitrogen dioxide, NO2, is produced when nitric oxide, NO, and ozone, O3, are suspended in a nitrogen matrix at 11-20 K. The NO2 is formed with first-order kinetics, a 12 K rate constant of (1.4 + or - 0.2) x 0.00001/sec, and an apparent activation energy of 106 + or - 10 cal/mol. Isotopic labeling, variation of concentrations, and cold shield experiments show that the growth of NO2 is due to reaction between ozone molecules and NO monomers, and that the reaction is neither infrared-induced nor does it seem to be a heavy atom tunneling process. Reaction is attributed to nearest-neighbor NO.O3 pairs probably held in a specific orientational relationship that affects the kinetic behavior. When the temperature is raised, more such reactive pairs are generated, presumably by local diffusion. Possible mechanisms are discussed.

Lucas, D.↗

Electromotive force measurements on cells involving beta-alumina solid electrolyte

Open-circuit emf measurements have been made to demonstrate that a two-phase, polycrystalline mixture of beta-alumina and alpha-alumina could be used as a solid electrolyte in galvanic cells with reversible electrodes fixing oxygen or aluminum chemical potentials. These measurements indicate that such a two-phase solid electrolyte may be used to monitor oxygen chemical potentials as low as that corresponding to Al and Al2O3 coexistence (potentials of about 10 to the minus 47th power atm at 1000 K). The activity of Na2O in beta-alumina in coexistence with alpha-alumina was also determined by emf measurements.

Choudhury, N. S.↗

Kinetics and transport at AMTEC electrodes. II - Temperature dependence of the interfacial impedance of Na(g)/porous Mo/Na-Beta-double prime alumina

The exchange current, transfer coefficient, mass-transport parameters, and electrode capacitance at the Na(g)/porous Mo/Na-Beta-double prime alumina solid electrolyte (BASE) phase boundary have been evaluated from 740 to 1220 K. The transfer coefficient exhibits a value close to 0.5 and the exchange current is dominated by collision frequency, with no significant activation energy. Since the porous Mp-electrode adopts a fairly regular microstructure on the BASE surface, the magnitude of the exchange current of mature electrodes directly depends on the actual contact zone of the porous metal film with the BASE ceramic, and decreases slightly as grain growth occurs. The exchange currents and the mass-transport parameters derived for very porous, thin Mo electrodes indicate that the charge-transfer reaction occurs at a small fraction of the interface. High-frequency limiting capacitance and resistance values due to the interface show potential dependence and a value on the order of 1 F/sq m and 0.1-1.0 Ohm-sq cm.

Williams, R. M.↗

Sensors and sensor systems for guidance and navigation II; Proceedings of the Meeting, Orlando, FL, Apr. 22, 23, 1992

Topics discussed in this volume include aircraft guidance and navigation, optics for visual guidance of aircraft, spacecraft and missile guidance and navigation, lidar and ladar systems, microdevices, gyroscopes, cockpit displays, and automotive displays. Papers are presented on optical processing for range and attitude determination, aircraft collision avoidance using a statistical decision theory, a scanning laser aircraft surveillance system for carrier flight operations, star sensor simulation for astroinertial guidance and navigation, autonomous millimeter-wave radar guidance systems, and a 1.32-micron long-range solid state imaging ladar. Attention is also given to a microfabricated magnetometer using Young's modulus changes in magnetoelastic materials, an integrated microgyroscope, a pulsed diode ring laser gyroscope, self-scanned polysilicon active-matrix liquid-crystal displays, the history and development of coated contrast enhancement filters for cockpit displays, and the effect of the display configuration on the attentional sampling performance.

Welch, Sharon S.↗

Stealth Plumes on Io

We suggest that Io's eruptive activity may include a class of previously undetected SO2 geysers. The thermodynamic models for the eruptive plumes discovered by Voyager 'involve low to moderate entropy SO2 eruptions. The resulting plumes are a mixture of solid and gas which emerge from the vent and follow essentially ballistic trajectories. We show that intrusion of silicate magma into buried SO2 deposits can create the required conditions for high entropy eruptions which proceed entirely in the vapor phase. These purely gaseous plumes would have been invisible to Voyager's instruments. Hence, we call them "stealth" plumes. Such eruptions could explain the "patchy" SO2 atmosphere inferred from recent UV and micro-wave spectral observations. The magma intrusion rate required to support the required gas production for these plumes is a negligible fraction of estimated global magma intrusion rates.

Johnson, T. V.↗

Lunar and Planetary Science XXXV: Terrestrial Planets: Building Blocks and Differentiation

The session "Terrestrial Planets: Building Blocks and Differentiation: included the following topics:Magnesium Isotopes in the Earth, Moon, Mars, and Pallasite Parent Body: High-Precision Analysis of Olivine by Laser-Ablation Multi-Collector ICPMS; Meteoritic Constraints on Collision Rates in the Primordial Asteroid Belt and Its Origin; New Constraints on the Origin of the Highly Siderophile Elements in the Earth's Upper Mantle; Further Lu-Hf and Sm-Nd Isotopic Data on Planetary Materials and Consequences for Planetary Differentiation; A Deep Lunar Magma Ocean Based on Neodymium, Strontium and Hafnium Isotope Mass Balance Partial Resetting on Hf-W System by Giant Impacts; On the Problem of Metal-Silicate Equilibration During Planet Formation: Significance for Hf-W Chronometry ; Solid Metal-Liquid Metal Partitioning of Pt, Re, and Os: The Effect of Carbon; Siderophile Element Abundances in Fe-S-Ni-O Melts Segregated from Partially Molten Ordinary Chondrite Under Dynamic Conditions; Activity Coefficients of Silicon in Iron-Nickel Alloys: Experimental Determination and Relevance for Planetary Differentiation; Reinvestigation of the Ni and Co Metal-Silicate Partitioning; Metal/Silicate Paritioning of P, Ga, and W at High Pressures and Temperatures: Dependence on Silicate Melt Composition; and Closure of the Fe-S-Si Liquid Miscibility Gap at High Pressure and Its Implications for Planetary Core Formation.

Source record↗

Accurate Realization of GPS Vertical Global Reference Frame

The few millimeter per year level accuracy of radial global velocity estimates with the Global Positioning System (GPS) is at least an order of magnitude poorer than the accuracy of horizontal global motions. An improvement in the accuracy of radial global velocities would have a very positive impact on a number of geophysical studies of current general interest such as global sea-level and climate change, coastal hazards, glacial isostatic adjustment, atmospheric and oceanic loading, glaciology and ice mass variability, tectonic deformation and volcanic inflation, and geoid variability. The goal of this project is to improve our current understanding of GPS error sources associated with estimates of radial velocities at global scales. GPS error sources relevant to this project can be classified in two broad categories: (1) those related to the analysis of the GPS phase observable, and (2) those related to the combination of the positions and velocities of a set of globally distributed stations as determined from the analysis of GPS data important aspect in the first category include the effect on vertical rate estimates due to standard analysis choices, such as orbit modeling, network geometry, ambiguity resolution, as well as errors in models (or simply the lack of models) for clocks, multipath, phase-center variations, atmosphere, and solid-Earth tides. The second category includes the possible methods of combining and defining terrestrial reference flames for determining vertical velocities in a global scale. The latter has been the subject of our research activities during this reporting period.

Elosegui, Pedro↗

Investigation of Polar Stratospheric Cloud Solid Particle Formation Mechanisms Using ILAS and AVHRR Observations in the Arctic

Satellite observations of denitrification and ice clouds in the Arctic lower stratosphere in February 1997 are used with Lagrangian microphysical box model calculations to evaluate nucleation mechanisms of solid polar stratospheric cloud (PSC) particles. The occurrences of ice clouds are not correlated in time and space with the locations of back trajectories of denitrified air masses, indicating that ice particle surfaces are not always a prerequisite for the formation of solid PSCs that lead to denitrification. In contrast, the model calculations incorporating a pseudoheterogeneous freezing process occurring at the vapor-liquid interface can quantitatively explain most of the observed denitrification when the nucleation activation free energy for nitric acid dihydrate formation is raised by only approx.10% relative to the current published values. Once nucleated, the conversion of nitric acid dihydrate to the stable trihydrate phase brings the computed levels of denitrification closer to the measurements. INDEX TERMS: 0305 Atmospheric Composition and Structure: Aerosols and particles (0345, 4801); 0320 Atmospheric Composition and Sb~lctureC: loud physics and chemistry; 0340 Atmospheric Composition and Structure: Middle atmosphere-composition and chemistry

Irie, H.↗

Conceptual Design of In-Space Vehicles for Human Exploration of the Outer Planets

During FY-2002, a team of engineers from TD30/Advanced Concepts and TD40/Propulsion Research Center embarked on a study of potential crewed missions to the outer solar system. The study was conducted under the auspices of the Revolutionary Aerospace Systems Concepts activity administered by Langley Research Center (LaRC). The Marshall Space Flight Center (MSFC) team interacted heavily with teams from other Centers including Glenn Research Center, LaRC, Jet Propulsion Laboratory, and Johnson Space Center. The MSFC team generated five concept missions for this project. The concept missions use a variety of technologies, including magnetized target fusion (MTF), magnetoplasmadynamic thrusters, solid core reactors, and molten salt reactors in various combinations. The Technical Publication (TP) reviews these five concepts and the methods used to generate them. The analytical methods used are described for all significant disciplines and subsystems. The propulsion and power technologies selected for each vehicle are reviewed in detail. The MSFC team also expended considerable effort refining the MTF concept for use with this mission. The results from this effort are also contained within this TP. Finally, the lessons learned from this activity are summarized in the conclusions section.

Adams, R. B.↗

Scaling Equations for Ballistic Modeling of Solid Rocket Motor Case Breach

This paper explores the development of a series of scaling equations that can take a known nominal motor performance and scale it for small and growing case failures. This model was developed for the Malfunction-Turn Study as part of Return to Flight activities for the Space Shuttle program. To verify the model, data from the Challenger accident (STS- 51L) were used. The model is able to predict the motor performance beyond the last recorded Challenger data and show how the failed right hand booster would have performed if the vehicle had remained intact.

McMillin, Joshua E.↗