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At least 595 records · Page 33

Detector response in time-of-flight mass spectrometry at high pulse repetition frequencies

Dead time effects in chevron configured dual microchannel plates (MCPs) are investigated. Response times are determined experimentally for one chevron-configured dual MCP-type detector and two discrete dynode-type electron multipliers with 16 and 23 resistively divided stages. All of these detectors are found to be suitable for time-of-flight mass spectrometry (TOF MS), yielding 3-6-ns (FWHM) response times triggered on a single ion pulse. It is concluded that, unless there are viable solutions to overcome dead time disadvantages for continuous dynode detectors, suitable discrete dynode detectors for TOF MS appear to have a significant advantage for high repetition rate operation.

Gulcicek, Erol E.↗

Investigation of isovaline enantiomeric excesses in CM meteorites using liquid chromatography time of flight mass spectrometry

The enantiomeric abundances of the alpha-dialkyl amino acid isovaline were measured in the CM2 meteorites Murchison and LEW 90500 using a new liquid chromatography-time of flight-mass spectrometry (LC-ToF-MS) technique coupled with OPA/NAC derivatization and UV fluorescence detection. Previous analyses of Murchison have shown that L-enantiomeric excesses of isovaline range from 0 to 15.2% with significant variation between meteorite fragments [1]. For this study, hot water extracts of interior fragments (> 2 cm from fusion crust) of the Murchison (USNM 6650.2, mass 6 g) and LEW 90500 (split 69, parent 1, mass 5 g) carbonaceous meteorites were analyzed. Enantiomeric excesses were measured using the single ion LC-ToF-MS trace for the OPA/NAC derivative of isovaline at d z 393.15 (Fig. 1). L-isovaline excesses in these meteorite samples ranged from 18.9 to 20.5% for Murchison and -0.5 to 3.0% for LEW 90500. The measured values for Murchison are the largest enantiomeric excesses for isovaline reported to date. The enantiomeric excesses of L-isovaline cannot be the result of interference from other C5 amino acid isomers present in the meteorites or terrestrial contamination from the landing site environments. The L-isovaline excesses in Murchison are inconsistent with the synthesis of all of the isovaline by the Strecker-cyanohydrin pathway on the CM meteorite parent body. The mechanism(s) for the formation of the enantiomeric asymmetry in isovaline in Murchison are currently unknown and it is not clear how the asymmetry of alpha-dialkyl amino acids could be transferred to the a-hydrogen protein amino acids common in all life on Earth today.

Glavin, Daniel P.↗

Protocol for Future Amino Acid Analyses of Samples Returned by the Stardust Mission

We have demonstrated that LC-ToF-MS coupled with UV fluorescence detection is a powerful tool for the detection of amino acids in meteorite extracts. Using this new analytical technique we were able to identify the extraterrestrial amino acid AIB extracted from fifteen 20 micron sized Murchison meteorite grains. We found that the amino acid contamination levels in Stardust aerogels was much lower than the levels observed in the Murchison meteorite. In addition, the alpha-dialkyl amino acids AIB and isovaline which are the most abundant amino acids in Murchison were not detected in the aerogel above blank levels. We are currently integrating LIF detection capability to our existing nanoflow LC-ToF-MS for enhanced sensitivity required for the analysis of amino acids in Stardust samples.

Glavin, D. P.↗

Fast Airborne Aerosol Size and Chemistry Measurements with the High Resolution Aerosol Mass Spectrometer during the MILAGRO Campaign

The concentration, size, and composition of non-refractory submicron aerosol (NR-PM(sub l)) was measured over Mexico City and central Mexico with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) onboard the NSF/NCAR C-130 aircraft as part of the MILAGRO field campaign. This was the first aircraft deployment of the HR-ToF-AMS. During the campaign the instrument performed very well, and provided 12 s data. The aerosol mass from the AMS correlates strongly with other aerosol measurements on board the aircraft. Organic aerosol (OA) species dominate the NR-PM(sub l) mass. OA correlates strongly with CO and HCN indicating that pollution (mostly secondary OA, SOA) and biomass burning (BB) are the main OA sources. The OA to CO ratio indicates a typical value for aged air of around 80 microg/cubic m (STP) ppm(exp -1). This is within the range observed in outflow from the Northeastern US, which could be due to a compensating effect between higher BB but lower biogenic VOC emissions during this study. The O/C atomic ratio for OA is calculated from the HR mass spectra and shows a clear increase with photochemical age, as SOA forms rapidly and quickly overwhelms primary urban OA, consistent with Volkamer et al. (2006) and Kleinman et al. (2008). The stability of the OA/CO while O/C increases with photochemical age implies a net loss of carbon from the OA. BB OA is marked by signals at m/z 60 and 73, and also by a signal enhancement at large m/z indicative of larger molecules or more resistance to fragmentation. The main inorganic components show different spatial patterns and size distributions. Sulfate is regional in nature with clear volcanic and petrochemical/power plant sources, while the urban area is not a major regional source for this species. Nitrate is enhanced significantly in the urban area and immediate outflow, and is strongly correlated with CO indicating a strong urban source. The importance of nitrate decreases with distance from the city likely due to evaporation. BB does not appear to be a strong source of nitrate despite its high emissions of nitrogen oxides, presumably due to low ammonia emissions. NR-chloride often correlates with HCN indicating a fire source, although other sources likely contribute as well. This is the first aircraft study of the regional evolution of aerosol chemistry from a tropical megacity.

DeCarlo, P. F.↗

NASA Tech Briefs, January 2006

Topics covered include: Semiautonomous Avionics-and-Sensors System for a UAV; Biomimetic/Optical Sensors for Detecting Bacterial Species; System Would Detect Foreign-Object Damage in Turbofan Engine; Detection of Water Hazards for Autonomous Robotic Vehicles; Fuel Cells Utilizing Oxygen From Air at Low Pressures; Hybrid Ion-Detector/Data-Acquisition System for a TOF-MS; Spontaneous-Desorption Ionizer for a TOF-MS; Equipment for On-Wafer Testing From 220 to 325 GHz; Computing Isentropic Flow Properties of Air/R-134a Mixtures; Java Mission Evaluation Workstation System; Using a Quadtree Algorithm To Assess Line of Sight; Software for Automated Generation of Cartesian Meshes; Optics Program Modified for Multithreaded Parallel Computing; Programs for Testing Processor-in-Memory Computing Systems; PVM Enhancement for Beowulf Multiple-Processor Nodes; Ion-Exclusion Chromatography for Analyzing Organics in Water; Selective Plasma Deposition of Fluorocarbon Films on SAMs; Water-Based Pressure-Sensitive Paints; System Finds Horizontal Location of Center of Gravity; Predicting Tail Buffet Loads of a Fighter Airplane; Water Containment Systems for Testing High-Speed Flywheels; Vapor-Compression Heat Pumps for Operation Aboard Spacecraft; Multistage Electrophoretic Separators; Recovering Residual Xenon Propellant for an Ion Propulsion System; Automated Solvent Seaming of Large Polyimide Membranes; Manufacturing Precise, Lightweight Paraboloidal Mirrors; Analysis of Membrane Lipids of Airborne Micro-Organisms; Noninvasive Diagnosis of Coronary Artery Disease Using 12-Lead High-Frequency Electrocardiograms; Dual-Laser-Pulse Ignition; Enhanced-Contrast Viewing of White-Hot Objects in Furnaces; Electrically Tunable Terahertz Quantum-Cascade Lasers; Few-Mode Whispering-Gallery-Mode Resonators; Conflict-Aware Scheduling Algorithm; and Real-Time Diagnosis of Faults Using a Bank of Kalman Filters.

Source record↗

Transient Plume Model Testing Using LADEE Spacecraft Attitude Control System Operations

We have learned it is conceivable that the Neutral Mass Spectrometer on board the Lunarr Atmosphere Dust Environment Explorer (LADEE) could measure gases from surface-reflected Attitude Control System (ACS) thruster plume. At minimum altitude, the measurement would be maximized, and gravitational influence minimized ("short" time-of-flight (TOF) situation) Could use to verify aspects of thruster plume modeling Model the transient disturbance to NMS measurements due to ACS gases reflected from lunar surface Observe evolution of various model characteristics as measured by NMS Species magnitudes, TOF measurements, angular distribution, species separation effects

Woronowicz, Michael↗

Radiation Design of Ion Mass Spectrometers

In the harsh radiation environment of Jupiter and with the JUpiter ICy moon Explorer (JUICE) mission including two Europa flybys where local intensities are approx. 150 krad/month behind 100 mils of Al shielding, so background from penetrating radiation can be a serious issue for detectors inside an Ion Mass Spectrometer (IMS). This can especially be important for minor ion detection designs. Detectors of choice for time-of-flight (TOF) designs are microchannel plates (MCP) and some designs may include solid state detectors (SSD). The standard approach is to use shielding designs so background event rates are low enough that the detector max rates and lifetimes are first not exceeded and then the more stringent requirement that the desired measurement can successfully be made (i.e., desired signal is sufficiently greater than background noise after background subtraction is made). GEANT codes are typically used along with various electronic techniques, but such designs need to know how the detectors will respond to the simulated primary and secondary radiations produced within the instrument. We will be presenting some preliminary measurements made on the response of MCPs to energetic electrons (20 ke V to 1400 ke V) using a Miniature TOF (MTOF) device and the High Energy Facility at Goddard Space Flight Center which has a Van de Graaff accelerator.

Sittler, Ed↗

Development of a Robust, High Current, Low Power Field Emission Electron Gun for a Spaceflight Reflectron Time-of-Flight Mass Spectrometer

Carbon materials, including carbon nanotubes (CNTs) and nitrogen-incorporated ultrananocrystalline diamond (N-UNCD), have been of considerable interest for field emission applications for over a decade. In particular, robust field emission materials are compelling for space applications due to the low power consumption and potential for miniaturization. A reflectron time-of-flight mass spectrometer (TOF-MS) under development for in situ measurements on the Moon and other Solar System bodies uses a field emitter to generate ions from gaseous samples, using electron ionization. For these unusual environments, robustness, reliability, and long life are of paramount importance, and to this end, we have explored the field emission properties and lifetime of carbon nanotubes and nitrogen-incorporated ultrananocrystalline diamond (N-UNCD) thin films, the latter developed and patented by Argonne National Laboratory. We will present recent investigations of N-UNCD as a robust field emitter, revealing that this material offers stable performance in high vacuum for up to 1000 hours with threshold voltage for emission of about 3-4 V/lJm and current densities in the range of tens of microA. Optimizing the mass resolution and sensitivity of such a mass spectrometer has also been enabled by a parallel effort to scale up a CNT emitter to an array measuring 2 mm x 40 mm. Through simulation and experiment of the new extended format emitter, we have determined that focusing the electron beam is limited due to the angular spread of the emitted electrons. This dispersion effect can be reduced through modification of the electron gun geometry, but this reduces the current reaching the ionization region. By increasing the transmission efficiency of the electron beam to the anode, we have increased the anode current by two orders of magnitude to realize a corresponding enhancement in instrument sensitivity, at a moderate cost to mass resolution. We will report recent experimental and modeling results to describe the performance of a field emission electron gun as employed in the Volatile Analysis by Pyrolysis of Regolith (VAPoR) TOF-MS prototype.

Southard, Adrian E.↗

LVGEMS Time-of-Flight Mass Spectrometry on Satellites

NASA fs investigations of the upper atmosphere and ionosphere require measurements of composition of the neutral air and ions. NASA is able to undertake these observations, but the instruments currently in use have their limitations. NASA has extended the scope of its research in the atmosphere and now requires more measurements covering more of the atmosphere. Out of this need, NASA developed multipoint measurements using miniaturized satellites, also called nanosatellites (e.g., CubeSats), that require a new generation of spectrometers that can fit into a 4 ~4 in. (.10 ~10 cm) cross-section in the upgraded satellites. Overall, the new mass spectrometer required for the new depth of atmospheric research must fulfill a new level of low-voltage/low-power requirements, smaller size, and less risk of magnetic contamination. The Low-Voltage Gated Electrostatic Mass Spectrometer (LVGEMS) was developed to fulfill these requirements. The LVGEMS offers a new spectrometer that eliminates magnetic field issues associated with magnetic sector mass spectrometers, reduces power, and is about 1/10 the size of previous instruments. LVGEMS employs the time of flight (TOF) technique in the GEMS mass spectrometer previously developed. However, like any TOF mass spectrometer, GEMS requires a rectangular waveform of large voltage amplitude, exceeding 100 V -- that means that the voltage applied to one of the GEMS electrodes has to change from 0 to 100 V in a time of only a few nanoseconds. Such electronic speed requires more power than can be provided in a CubeSat. In the LVGEMS, the amplitude of the rectangular waveform is reduced to about 1 V, compatible with digital electronics supplies and requiring little power.

Herrero, Federico↗

Tandem Mass Spectrometry on a Miniaturized Laser Desorption Time-of-Flight Mass Spectrometer

Tandem mass spectrometry (MSMS) is a powerful and widely-used technique for identifying the molecular structure of organic constituents of a complex sample. Application of MSMS to the study of unknown planetary samples on a remote space mission would contribute to our understanding of the origin, evolution, and distribution of extraterrestrial organics in our solar system. Here we report on the realization of MSMS on a miniaturized laser desorption time-of-flight mass spectrometer (LD-TOF-MS), which is one of the most promising instrument types for future planetary missions. This achievement relies on two critical components: a curved-field reflectron and a pulsed-pin ion gate. These enable use of the complementary post-source decay (PSD) and laser-assisted collision induced dissociation (L-CID) MSMS methods on diverse measurement targets with only modest investment in instrument resources such as volume and weight. MSMS spectra of selected molecular targets in various organic standards exhibit excellent agreement when compared with results from a commercial, laboratory-scale TOF instrument, demonstrating the potential of this powerful technique in space and planetary environments.

Li, Xiang↗

Characterization of a Carbon Nanotube Field Emission Electron Gun for the VAPoR Miniaturized Pyrolysis-Time-of-Flight Mass Spectrometer

We are developing the VAPoR (Volatile Analysis by Pyrolysis of Regolith) instrument towards studying soil composition, volatiles, and trapped noble gases in the polar regions of the Moon. VAPOR will ingest a soil sample and conduct analysis by pyrolysis and time-of-flight mass spectrometry (ToF-MS). Here, we describe miniaturization efforts within this development, including a carbon nanotube (CNT) field emission electron gun that is under consideration for use as the electron impact ionization source for the ToF-MS.

Getty, Stephanie↗

Overview of Phobos/Deimos Regolith Ion Sample Mission (PRISM) Concept

Far more definitive information on composition is required to resolve the question of origin for the Martian moons Phobos and Deimos. Current infrared spectra of the objects are inconclusive due to the lack of strong diagnostic features.Definitive compositional measurements of Phobos could be obtained using in-situ X-ray, gamma-ray, or neutronspectroscopy or collecting and returning samples to Earth for analysis. We have proposed, in lieu of those methods, toderive Phobos and Deimos compositional data from secondary ion mass spectrometry (SIMS) measurements by calibratingthe instrument to elemental abundance measurements made for known samples in the laboratory. We describe thePhobos/Deimos Regolith Ion Sample Mission (PRISM) concept here. PRISM utilizes a high-resolution TOF plasma composition analyzer to make SIMS measurements by observing the sputtered species from various locations of the moons' surfaces. In general, the SIMS technique and ion mass spectrometers complement and expand quadrupole mass spectrometer measurements by collecting ions that have been energized to higher energies, 50-100 eV, and making measurements at very low densities and pressures. Furthermore, because the TOF technique accepts all masses all the time,it obtains continuous measurements and does not require stepping through masses. The instrument would draw less than10 W and weigh less than 5 kg. The spacecraft, nominally a radiation-hardened 12U CubeSat, would use a low-thrust SolarElectric Propulsion system to send it on a two-year journey to Mars, where it would co-orbit with Deimos and then Phobos

Clark, Pamela↗

Overview of Phobos/Deimos Regolith Ion Sample Mission (PRISM) Concept

Far more definitive information on composition is required to resolve the question of origin for the Martian moons Phobos and Deimos. Current infrared spectra of the objects are inconclusive due to the lack of strong diagnostic features. Definitive compositional measurements of Phobos could be obtained using in-situ X-ray, gamma-ray, or neutron spectroscopy or collecting and returning samples to Earth for analysis. We have proposed, in lieu of those methods, to derive Phobos and Deimos compositional data from secondary ion mass spectrometry (SIMS) measurements by calibrating the instrument to elemental abundance measurements made for known samples in the laboratory. We describe the Phobos/Deimos Regolith Ion Sample Mission (PRISM) concept here. PRISM utilizes a high-resolution TOF plasma composition analyzer to make SIMS measurements by observing the sputtered species from various locations of the moons' surfaces. In general, the SIMS technique and ion mass spectrometers complement and expand quadrupole mass spectrometer measurements by collecting ions that have been energized to higher energies, 50-100 eV, and making measurements at very low densities and pressures. Furthermore, because the TOF technique accepts all masses all the time, it obtains continuous measurements and does not require stepping through masses. The instrument would draw less than 10 W and weigh less than 5 kg. The spacecraft, nominally a radiation-hardened 12U CubeSat, would use a low-thrust Solar Electric Propulsion system to send it on a two-year journey to Mars, where it would co-orbit with Deimos and then Phobos at distances as low as 27 km.

Dibraccio, Gina↗

Lunar Asset Messaging and On Orbit Navigation

NASA has titled its 2020 thrust for the Moon, Artemis. The increased focus on the Moon as a destination for future human and robotic expeditions necessitates general purpose navigational and communications infrastructure reducing their complexity to help establish a sustained presence. A framework through which Lunar missions can relay communications and localize their positions shifts the burden from the individual mission and enables resource allocation tailored to mission-specific goals. During the summer of 2020, student interns under the Innovation to Flight (i2F) program at the National Aeronautics and Space Administration’s (NASA) Jet Propulsion Laboratory (JPL) in collaboration with the University of Colorado Boulder designed, built, and tested a prototype framework capable of providing surface assets with communication and positioning services. The team utilized the existing i2F CubeSat bus in addition to developing several CubeSat engineering development units (EDUs), a ground vehicle, and a ground station to simulate a scenario in which a lunar surface mission is supported by these services. A primary goal of the summer was to develop a method for localizing the ground vehicle through trilateration. Distances are inferred from the round-trip time of flight (ToF) of radio signals between an asset and several elements. Signals were sent and received using LimeSDR software defined radios on-board both the ground vehicle and the EDUs; ToF and trilateration were calculated on a Qualcomm Snapdragon development board located within the LA MOON payload data system. The ModalAI chipset on the Qualcomm was instrumental in executing visual based position estimation. Communications was facilitated through a bent-pipe approach addressing the NASA requirement to provide solutions for in communication denied locations. The ground vehicle relayed information to other surface assets in addition to its ground station through the supporting constellation. This project demonstrates the feasibility of a lunar CubeSat constellation for the support of surface assets and explores packaging and operations of the components critical to trilateration and bent-pipe communication into a standard CubeSat form factor. When implemented, this framework will open a door for new surface missions designed with lower power requirements and increased operational access.

Huang, Calvin↗

The Plasma Proton Environment within Saturn’s F-G Ring Gap as Observed by the Cassini Plasma Spectrometer Ion Mass Spectrometer during Saturn Orbit Insertion

We report on the detection of protons and the potential detection of H 2 + between Saturn's F and G rings based on Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) time-of-flight (TOF) composition measurements acquired during Saturn Orbit Insertion (SOI) outbound pass. The range in dipole L shell is 2.3 < L < 2.8. Initial results based on TOF data were presented in E. C. Sittler et al., 2017. Here we present the latest results of our analysis. During the SOI outbound pass between the F and G rings the CAPS IMS was in a mode of reduced post-acceleration voltage at -6 kV instead of the usual -14.6 kV. This reduced voltage still allows the analysis of protons since 6 keV protons are minimally scattered by the instrument’s ultrathin carbon foils when compared to heavier ions O + and O 2 + , scattering. Background noise from penetrating radiation and ghost peaks produced by foil-scattered O + ions within the instrument were considered in our analysis. The analysis allowed determination of the proton density, temperature and flow velocity, accounting for spacecraft potential by assuming a convected Maxwellian for the proton velocity distribution function. We find average proton density n P = 3.2 ± 1.1 #/cm 3 , proton temperature T P = 1.74 ± 0.12 eV, proton rotational flow speed V P = 24 ± 1.5 km/s and spacecraft potential  SC = -0.8 ±1.5 V. These results are compared with previous theoretical estimates of H + and H 2 + ions within Saturn’s inner magnetosphere.

E C Sittler↗

PID techniques: Alternatives to RICH Methods

In this review article we discuss the recent progress in PID techniques other than the RICH methods. In particular we mention the recent progress in the Transition Radiation Detector (TRD), dE/dx cluster counting, and Time Of Flight (TOF) techniques. The TRD technique is mature and has been tried in many hadron colliders. It needs space though, about 20cm of detector radial space for every factor of 10 in the {pi}/e rejection power, and this tends to make such detectors large. Although the cluster counting technique is an old idea, it was never tried in a real physics experiment. Recently, there are efforts to revive it for the SuperB experiment using He-based gases and waveform digitizing electronics. A factor of almost 2 improvement, compared to the classical dE/dx performance, is possible in principle. However, the complexity of the data analysis will be substantial. The TOF technique is well established, but introduction of new fast MCP-PMT and G-APD detectors creates new possibilities. It seems that resolutions below 20-30ps may be possible at some point in the future with relatively small systems, and perhaps this could be pushed down to 10-15ps with very small systems, assuming that one can solve many systematic issues. However, the cost, rate limitation, aging and cross-talk in multi-anode devices at high BW are problems. There are several groups working on these issues, so progress is likely. Table 6 summarizes the author's opinion of pros and cons of various detectors presented in this paper based on their operational capabilities. We refer the reader to Ref.40 for discussion of other more general limits from the PID point of view.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Neutron-induced fission cross-section of 233U in the energy range 0.5<En<20 MeV

The neutron-induced fission cross-section of 233U has been measured at the CERN n TOF facility relative to the standard fission cross-section of 235U between 0.5 and 20MeV. The experiment was performed with a fast ionization chamber for the detection of the fission fragments and to discriminate against α-particles from the natural radioactivity of the samples. The high instantaneous flux and the low background of the n TOF facility result in data with uncertainties of ≈ 3%, which were found in good agreement with previous experiments. The high quality of the present results allows to improve the evaluation of the 233U(n,f) cross-section and, consequently, the design of energy systems based on the Th/U cycle.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Neutron-induced fission cross-section of (233)U in the energy range 0.5 < E(n) < 20 MeV

The neutron-induced fission cross-section of {sup 233}U has been measured at the CERN n-TOF facility relative to the standard fission cross-section of {sup 235}U between 0.5 and 20MeV. The experiment was performed with a fast ionization chamber for the detection of the fission fragments and to discriminate against a {alpha}-particles from the natural radioactivity of the samples. The high instantaneous flux and the low background of the n-TOF facility result in data with uncertainties of {approx}3%, which were found in good agreement with previous experiments. The high quality of the present results allows to improve the evaluation of the {sup 233}U (n,f) cross-section and, consequently, the design of energy systems based on the Th/U cycle.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗