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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

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NASA NTRS1976

Remote sensing of atmospheric water vapor and liquid water with the Nimbus 5 microwave spectrometer

The Nimbus 5 satellite is provided with a passive microwave spectrometer (NEMS) incorporating channels at 22.235 and 31.4 GHz to measure atmospheric water vapor and liquid water over ocean. The discussion covers principles of atmospheric water determination, accuracy of measurements, observations of specific storms and fronts, and observations of water vapor and liquid water on a global scale. The NEMS experiment has demonstrated the ability of a two-channel microwave spectrometer to determine integrated abundances of water vapor and liquid water with estimated rms accuracies of 0.2 and 0.01 g per sq cm, respectively. The data can be used to plot global maps or accumulate global statistics.

Staelin, D. H.↗

NASA NTRS1978

Multispectral scanner system parameter study and analysis software system description, volume 2

The author has identified the following significant results. The integration of the available methods provided the analyst with the unified scanner analysis package (USAP), the flexibility and versatility of which was superior to many previous integrated techniques. The USAP consisted of three main subsystems; (1) a spatial path, (2) a spectral path, and (3) a set of analytic classification accuracy estimators which evaluated the system performance. The spatial path consisted of satellite and/or aircraft data, data correlation analyzer, scanner IFOV, and random noise model. The output of the spatial path was fed into the analytic classification and accuracy predictor. The spectral path consisted of laboratory and/or field spectral data, EXOSYS data retrieval, optimum spectral function calculation, data transformation, and statistics calculation. The output of the spectral path was fended into the stratified posterior performance estimator.

Landgrebe, D. A.↗

NASA NTRS1982

Some statistical performance characteristics of the 'ITD' modal identification algorithm

Performance characteristics of the Ibrahim time-domain algorithms are examined on a statistical basis. The method uses multiple free-response measurements from a test structure directly in the time domain, and displays varying accuracy, with the strongly excited modes identified most accurately and the weakly excited modes least accurately. Sets of computer-generated free-response functions for a simple 1-mode model are used to study the identification performance for several basic changes in the modal characteristics of the data, the user-selectable analysis constants, and the level of superimposed noise. Results indicate the existence of a direct and often linear effect of noise on the scatter of identified parameters, and good identification is maintained at the 1% noise level down to the point in frequency when only 1/4-cycle of data is analyzed.

Pappa, R. S.↗

NASA NTRS1983

Cost estimation model for advanced planetary programs, fourth edition

The development of the planetary program cost model is discussed. The Model was updated to incorporate cost data from the most recent US planetary flight projects and extensively revised to more accurately capture the information in the historical cost data base. This data base is comprised of the historical cost data for 13 unmanned lunar and planetary flight programs. The revision was made with a two fold objective: to increase the flexibility of the model in its ability to deal with the broad scope of scenarios under consideration for future missions, and to maintain and possibly improve upon the confidence in the model's capabilities with an expected accuracy of 20%. The Model development included a labor/cost proxy analysis, selection of the functional forms of the estimating relationships, and test statistics. An analysis of the Model is discussed and two sample applications of the cost model are presented.

Spadoni, D. J.↗

NASA NTRS1994

High-spatial-resolution passive microwave sounding systems

The principal contributions of this combined theoretical and experimental effort were to advance and demonstrate new and more accurate techniques for sounding atmospheric temperature, humidity, and precipitation profiles at millimeter wavelengths, and to improve the scientific basis for such soundings. Some of these techniques are being incorporated in both research and operational systems. Specific results include: (1) development of the MIT Microwave Temperature Sounder (MTS), a 118-GHz eight-channel imaging spectrometer plus a switched-frequency spectrometer near 53 GHz, for use on the NASA ER-2 high-altitude aircraft, (2) conduct of ER-2 MTS missions in multiple seasons and locations in combination with other instruments, mapping with unprecedented approximately 2-km lateral resolution atmospheric temperature and precipitation profiles, atmospheric transmittances (at both zenith and nadir), frontal systems, and hurricanes, (3) ground based 118-GHz 3-D spectral images of wavelike structure within clouds passing overhead, (4) development and analysis of approaches to ground- and space-based 5-mm wavelength sounding of the upper stratosphere and mesosphere, which supported the planning of improvements to operational weather satellites, (5) development of improved multidimensional and adaptive retrieval methods for atmospheric temperature and humidity profiles, (6) development of combined nonlinear and statistical retrieval techniques for 183-GHz humidity profile retrievals, (7) development of nonlinear statistical retrieval techniques for precipitation cell-top altitudes, and (8) numerical analyses of the impact of remote sensing data on the accuracy of numerical weather predictions; a 68-km gridded model was used to study the spectral properties of error growth.

Staelin, D. H.↗

NASA NTRS1994

The Astrometric Imaging Telescope: Detection of planetary systems with imaging and astrometry

The Astrometric Imaging Telescope (AIT) is a proposed spaceborne observatory whose primary goal is the detecton and study of extra-solar planetary systems. It contains two instruments that use complementary techniques to address the goal. The first instrument, the Coronagraphic Imager, takes direct images of nearby stars and Jupiter-size planets. It uses a telescope with scattering-compensated optics and a high-efficiency coronagraph to separate reflected planet light from the central star light. Planet detections take hours; confirmations occur in months. With a program duration of about 2 years, about 50 stars are observed. The second instrument, the Astrometric Photometer, shares the same telescope and focal plane. It uses a Ronchi ruling that is translated across the focal plane to simultaneously measure the positions of each target star and about 25 reference stars with sufficient accuracy to detect Uranus-mass planets around hundreds of stars. Enough stars of several spectral types are observed to obtain a statistically significant measurement of the prevalence of planetary systems. This observing program takes about 10 years to complete. The combination of both instruments in a single telescope system results from a number of innovative solutions that are described in this paper.

Pravdo, Steven H.↗

NASA NTRS2000

TRMM/LIS Lightning: Going Beyond Climatological Composites

The high sensitivity, accuracy and pointing stability of the TRMM/LIS allows analysis of not only tropical bulk lightning production, but of storm cell-based statistics. Issues associated with per-storm flash rate identification are presented, including minimum detectable flash rate, 'unbiasing' the low end of observed storm flash rate spectra, and cell identification. Global lightning bulk composites are disaggregated into contributions from storm frequency of occurrence and per-storm flash rate, with the former dominating the global spatial distribution. Local examination of these fields reveals offsets between peaks in flashing storm occurrence and peaks in storm flash rate, often related to geographic effects and diurnal storm evolution. The correlation of storm-level statistics with theoretical measures of meso/large scale coupling (e.g., the gross moist stability of the tropical atmosphere as calculated by Neelin et al) is shown.

Boccippio, Dennis J.↗

DOE OSTI2025

Benchmarking large language models for materials synthesis: The case of atomic layer deposition

In this work, we introduce an open-ended question benchmark, ALDbench, to evaluate the performance of large language models (LLMs) in materials synthesis, and, in particular, in the field of atomic layer deposition, a thin film growth technique used in energy applications and microelectronics. Our benchmark comprises questions with a level of difficulty ranging from the graduate level to domain expert current with the state of the art in the field. Human experts reviewed the questions along the criteria of difficulty and specificity, and the model responses along four different criteria: overall quality, specificity, relevance, and accuracy. We ran this benchmark on an instance of OpenAI’s GPT-4o. The responses from the model received a composite quality score of 3.7 on a 1–5 scale, consistent with a passing grade. However, 36% of the questions received at least one below average score. An in-depth analysis of the responses identified at least five instances of suspected hallucination. Finally, we observed statistically significant correlations between the difficulty of the question and the quality of the response, the difficulty of the question and the relevance of the response, the specificity of the question, and the accuracy of the response as graded by the human experts. Furthermore, this emphasizes the need to evaluate LLMs across multiple criteria beyond difficulty or accuracy.

Artificial intelligence↗

DOE OSTI2025

Comparing Compressed and Full-Modeling analyses with FOLPS: implications for DESI 2024 and beyond

The Dark Energy Spectroscopic Instrument (DESI) will provide unprecedented information about the large-scale structure of our Universe. In this work, we study the robustness of the theoretical modelling of the power spectrum of F OLPS , a novel effective field theory-based package for evaluating the redshift space power spectrum in the presence of massive neutrinos. We perform this validation by fitting the AbacusSummit high-accuracy N -body simulations for Luminous Red Galaxies, Emission Line Galaxies and Quasar tracers, calibrated to describe DESI observations. We quantify the potential systematic error budget of F OLPS finding that the modelling errors are fully sub-dominant for the DESI statistical precision within the studied range of scales. Additionally, we study two complementary approaches to fit and analyse the power spectrum data, one based on direct Full-Modelling fits and the other on the ShapeFit compression variables, both resulting in very good agreement in precision and accuracy. In each of these approaches, we study a set of potential systematic errors induced by several assumptions, such as the choice of template cosmology, the effect of prior choice in the nuisance parameters of the model, or the range of scales used in the analysis. Furthermore, we show how opening up the parameter space beyond the vanilla ΛCDM model affects the DESI observables. These studies include the addition of massive neutrinos, spatial curvature, and dark energy equation of state. We also examine how relaxing the usual Cosmic Microwave Background and Big Bang Nucleosynthesis priors on the primordial spectral index and the baryonic matter abundance, respectively, impacts the inference on the rest of the parameters of interest. This paper pathways towards performing a robust and reliable analysis of the shape of the power spectrum of DESI galaxy and quasar clustering using F OLPS .

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

The cosmology dependence of galaxy clustering and lensing from a hybrid N -body–perturbation theory model

ABSTRACT We implement a model for the two-point statistics of biased tracers that combines dark matter dynamics from N-body simulations with an analytic Lagrangian bias expansion. Using Aemulus, a suite of N-body simulations built for emulation of cosmological observables, we emulate the cosmology dependence of these non-linear spectra from redshifts z = 0 to z = 2. We quantify the accuracy of our emulation procedure, which is sub-per cent at $k=1\, h \,{\rm Mpc}^{-1}$ for the redshifts probed by upcoming surveys and improves at higher redshifts. We demonstrate its ability to describe the statistics of complex tracer samples, including those with assembly bias and baryonic effects, reliably fitting the clustering and lensing statistics of such samples at redshift z ≃ 0.4 to scales of $k_{\rm max} \approx 0.6\, h\,\mathrm{Mpc}^{-1}$. We show that the emulator can be used for unbiased cosmological parameter inference in simulated joint clustering and galaxy–galaxy lensing analyses with data drawn from an independent N-body simulation. These results indicate that our emulator is a promising tool that can be readily applied to the analysis of current and upcoming data sets from galaxy surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2026

Transient hydroperoxyalkyl intermediates (•QOOH) in isopentane oxidation. II. Isomer-resolved unimolecular dynamics

Transient carbon-centered hydroperoxyalkyl intermediates (•QOOH) in isopentane oxidation are characterized by their time- and energy-resolved unimolecular dissociation dynamics to hydroxyl (OH) and cyclic ether products. Two distinct •QOOH isomers are examined with radical sites at a primary carbon of one of the methyl groups (β-Me) or a secondary carbon (β-Et) of the ethyl group. Energy-dependent unimolecular rates are obtained from the time-dependent appearance of OH products for the two isomers and compared with statistical microcanonical rates computed using RRKM theory, including heavy-atom tunneling, based on high-level theoretical calculations. A benchmark-corrected approach is utilized to compute high-accuracy stationary-point energies, most importantly, transition-state barriers, for the •QOOH_Me and •QOOH_Et isomers in isopentane oxidation, building on higher-level reference calculations for the oxidation of ethane (C 2 H 5 O 2 ) and propane (C 3 H 7 O 2 ), respectively. Here, the measured rates are compared with RRKM calculations incorporating the benchmark-corrected transition-state parameters, a vibrationally adiabatic multidimensional hindered-rotor treatment of key torsions, and quantum tunneling. Agreement between experiment and theory validates the statistical description and shows faster decay for •QOOH_Et due to its lower barrier. Both β-QOOH isomers decay almost exclusively to OH + cyclic ether products under the conditions studied.

Oxidation processes↗

NASA NTRS1961

Application of Monte Carlo Technique for Determining Maneuvering Loads from Statistical Information on Airplane Motions

Results of a statistical analysis of horizontal-tail loads on a fighter airplane are presented. The data were obtained from a number of operational training missions with flight at altitudes up to about 50,000 feet and at Mach numbers up to 1.22. The analysis was performed to determine the feasibility of calculating horizontal-tail load from data on the flight conditions and airplane motions. In the analysis the calculated loads are compared with the measured loads for the different types of missions performed. The loads were calculated by two methods: a direct approach and a Monte Carlo technique. The procedures used and some of the problems associated with the data analysis are discussed. frequencies of occurrence of tail loads of given magnitudes are derived from statistical information on the flight quantities. In the direct method, a time history of tail load is calculated from time-history measurements of the flight quantities. The Monte Carlo method could be useful for extending loads information for design of prospective airplanes . For the Monte Carlo method, the The results indicate that the accuracy of loads, regardless of the method used for calculation, is largely dependent on the knowledge of the pertinent airplane aerodynamic characteristics and center-of-gravity location. In addition, reliable Monte Carlo results require an adequate sample of statistical data and a knowledge of the more important statistical dependencies between the various flight conditions and airplane motions.

Hamer, Harold A.↗

DOE OSTI2025

Density functional theory-based surrogate kinetic models for heterogeneous reactions of hydrocarbon intermediates on silicon carbide

The increasing demand for high-performance materials in advanced technologies highlights the importance of achieving a fundamental understanding and potential control of silicon carbide (SiC) deposition processes. However, existing models often lack sufficient theoretical detail, relying heavily on empirical data and offering limited predictive capability. In particular, the complex surface chemistry governing SiC growth remains poorly understood. This study addresses these challenges by employing density functional theory (DFT) to investigate key heterogeneous reactions involving hydrocarbon intermediates on SiC surfaces, including dehydrogenation, hydrogenation, and carbon deposition. Transition state searches were conducted to identify reaction pathways and energy barriers. While first-principles calculations offer high accuracy, they are computationally intensive. To extend the utility of these first-principles results, vibrational analyses were performed using phonon-based statistical thermochemistry to compute temperature-dependent reaction rates which were used to develop Arrhenius-type surrogate kinetic models. Furthermore, the resulting framework provides a more rigorous, physically grounded basis for integrating atomistic insights into continuum-scale modeling, ultimately enabling improved prediction and optimization of SiC film growth in high-performance material systems.

Density Functional Theory↗

DOE OSTI2025

Constraining primordial non-Gaussianity from the large scale structure two-point and three-point correlation functions

Surveys of cosmological large-scale structure (LSS) are sensitive to the presence of local primordial non-Gaussianity (PNG), and may be used to constrain models of inflation. Local PNG, characterized by f NL ⁠, the amplitude of the quadratic correction to the potential of a Gaussian random field, is traditionally measured from LSS two-point and three-point clustering via the power spectrum and bi-spectrum. We propose a framework to measure f NL using the configuration space two-point correlation function (2pcf) monopole and three-point correlation function (3pcf) monopole of survey tracers. Our model estimates the effect of the scale-dependent bias induced by the presence of PNG on the 2pcf and 3pcf from the clustering of simulated dark matter haloes. We describe how this effect may be scaled to an arbitrary tracer of the cosmological matter density. The 2pcf and 3pcf of this tracer are measured to constrain the value of f NL ⁠. In LSS surveys, the effect of imaging systematics on two-point statistics is often degenerate with the PNG signal. Our proposed model employs three-point statistics primarily to break this degeneracy. Using simulations of luminous red galaxies observed by the Dark Energy Spectroscopic Instrument (DESI), we demonstrate the accuracy and constraining power of our method. Our forecast indicates the ability to constrain f NL to a precision of σf NL ≈ 22 with one year of DESI survey data, as well as the ability to constrain the imaging systematic weights in situ.

early Universe↗

DOE OSTI2026

The DESI DR1 Peculiar Velocity Survey: Global Zero-point and H 0 Constraints

The Dark Energy Spectroscopic Instrument (DESI) in its first Data Release (DR1) already provides more than 100,000 galaxies with relative distance measurements. The primary purpose of this paper is to perform the calibration of the zero-point for the DESI Fundamental Plane and Tully–Fisher relations, which allows us to measure the Hubble constant, H 0 . This sample has a lower statistical uncertainty than any previously used to measure H 0 , and we investigate the systematic uncertainties in absolute calibration that could limit the accuracy of that measurement. We improve upon the DESI Early Data Release Fundamental Plane H 0 measurement by (a) using a group catalog to increase the number of calibrator galaxies and (b) investigating alternative calibrators in the nearby Universe. Our baseline measurement calibrates to the SH0ES/Pantheon+ type Ia supernovae, and finds H 0 = 73.7 ± 0.06 (stat.) ± 1.1 (syst.) km s −1 Mpc −1 . Calibrating to surface brightness fluctuation distances yields a similar H 0 . We explore measurements using other calibrators, but these are currently less precise since the overlap with DESI peculiar velocity tracers is much smaller. In future data releases with an even larger peculiar velocity sample, we plan to calibrate directly to Cepheids and the tip of the red giant branch, which will enable the uncertainty to decrease towards a percent-level measurement of H 0 . This will provide an alternative to supernovae as the Hubble flow sample for H 0 measurements.

Carr, Anthony [Korea Astronomy and Space Science I↗

NASA NTRS1977

Application of statistical inversion to ground-based microwave remote sensing of temperature and water vapor profiles

Surface-based observations of downwelling microwave thermal emission are related to temperature and humidity profiles via a standard integral equation of radiative transfer. Both in clear and in cloudy atmospheres, statistical inversion techniques are used to retrieve profiles from a data vector of brightness observations and surface meteorological constraints. For the clear case, accuracy predictions and profile retrievals are illustrated for: (1) single frequency angular scanned data; (2) multi-frequency angular scanned data; and (3) multi-frequency zenith data. For the last case predicted and achieved accuracies were compared in a recently conducted radiometric experiment. Retrievals of cloud contaminated radiometric data are elaborated.

Westwater, E. R.↗

NASA NTRS1981

Evaluation of TIROS-N and NOAA-6 satellite data: Comparisons of colocated soundings and analyses for a January case

An early January 1980 synoptic situation was used in evaluating the performance of TIROS-N and NOAA-6 operational temperature soundings. Visual and statistical comparisons of temperature and thickness fields were employed to determine the effects of manual screening of the satellite soundings and measure the accuracy of both the satellite soundings and analyses derived from them. Comparisons between the performance of TIROS-N and NOAA-6 were emphasized. Both satellites were able to correctly position the major troughs and ridges. Gradients were underestimated though, with troughs markedly too warm and ridges slightly too cold. The poorest data occurred near the surface and tropopause as reflected by larger standard deviations in those layers. The performance of TIROS-N was slightly superior to that of NOAA-6.

Schmidt, B. D.↗

NASA NTRS2004

Chromosome aberrations of clonal origin are present in astronauts' blood lymphocytes

Radiation-induced chromosome translocations remain in peripheral blood cells over many years, and can potentially be used to measure retrospective doses or prolonged low-dose rate exposures. However, several recent studies have indicated that some individuals possess clones of cells with balanced chromosome abnormalities, which can result in an overestimation of damage and, therefore, influence the accuracy of dose calculations. We carefully examined the patterns of chromosome damage found in the blood lymphocytes of twelve astronauts, and also applied statistical methods to screen for the presence of potential clones. Cells with clonal aberrations were identified in three of the twelve individuals. These clonal cells were present in samples collected both before and after space flight, and yields are higher than previously reported for healthy individuals in this age range (40-52 years of age). The frequency of clonal damage appears to be even greater in chromosomes prematurely condensed in interphase, when compared with equivalent analysis in metaphase cells. The individuals with clonal aberrations were followed-up over several months and the yields of all clones decreased during this period. Since clonal aberrations may be associated with increased risk of tumorigenesis, it is important to accurately identify cells containing clonal rearrangements for risk assessment as well as biodosimetry. Copyright 2003 S. Karger AG, Basel.

Chromosomes, Human/radiation effects/ultrastructur↗