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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Prototype and Evaluation of AutoHelp: A Case-based, Web-accessible Help Desk System for EOSDIS

AutoHelp is a case-based, Web-accessible help desk for users of the EOSDIS. Its uses a combination of advanced computer and Web technologies, knowledge-based systems tools, and cognitive engineering to offload the current, person-intensive, help desk facilities at the DAACs. As a case-based system, AutoHelp starts with an organized database of previous help requests (questions and answers) indexed by a hierarchical category structure that facilitates recognition by persons seeking assistance. As an initial proof-of-concept demonstration, a month of email help requests to the Goddard DAAC were analyzed and partially organized into help request cases. These cases were then categorized to create a preliminary case indexing system, or category structure. This category structure allows potential users to identify or recognize categories of questions, responses, and sample cases similar to their needs. Year one of this research project focused on the development of a technology demonstration. User assistance 'cases' are stored in an Oracle database in a combination of tables linking prototypical questions with responses and detailed examples from the email help requests analyzed to date. When a potential user accesses the AutoHelp system, a Web server provides a Java applet that displays the category structure of the help case base organized by the needs of previous users. When the user identifies or requests a particular type of assistance, the applet uses Java database connectivity (JDBC) software to access the database and extract the relevant cases. The demonstration will include an on-line presentation of how AutoHelp is currently structured. We will show how a user might request assistance via the Web interface and how the AutoHelp case base provides assistance. The presentation will describe the DAAC data collection, case definition, and organization to date, as well as the AutoHelp architecture. It will conclude with the year 2 proposal to more fully develop the case base, the user interface (including the category structure), interface with the current DAAC Help System, the development of tools to add new cases, and user testing and evaluation at (perhaps) the Goddard DAAC.

Mitchell, Christine M.↗
NASA NTRSDate not supplied

Evolution of the Next Exploration Toilet through Human-in-the-Loop (HITL) Testing

Human waste collection in space is a unique and necessary function that all crewmembers must perform. The variability in how each crewmember uses the toilet to urinate and defecate introduces complexities and challenges with regards to overall hardware design. Because of this variability, it is important to consider crew inputs in all aspects of a toilet design especially with regards to crew interfaces that could impact overall waste collection. Access to crew feedback is essential to the design process and should be considered early and often through the various design phases. In 2020, NASA started a project for the Human Landing System (HLS) program to develop a Government Furnished Equipment (GFE) toilet option. The project is known as the Lavatory On-Orbit (LOO). During the early development of the LOO, the project team conducted several crew evaluations to collect and summarize valuable crew feedback on system design, function, and overall usability to influence the next design iteration. Because every person could use the system differently in space, it was extremely important to collect and analyze the data in a very methodical manner to appropriately influence the design based on the evaluation results. Establishing a standard process ensures consistent data collection from one evaluation to another, helps to maintain privacy for each test subject’s inputs and removes any potential bias from test subject to test subject. To date, the team has completed four crew evaluations on prototypes for the different LOO hardware. This paper will summarize the methodology used to conduct the evaluations as well as how data was collected and analyzed. The paper will also provide details on each of the evaluations and how the design was updated based on the results.

toilet↗
NASA NTRSDate not supplied

Evolution of the Next Exploration Toilet Through Human-in-the-Loop (HITL) Testing

Human waste collection in space is a unique and necessary function that all crewmembers must perform. The variability in how each crewmember uses the toilet to urinate and defecate introduces complexities and challenges with regards to overall hardware design. Because of this variability, it is important to consider crew inputs in all aspects of a toilet design especially with regards to crew interfaces that could impact overall waste collection. Access to crew feedback is essential to the design process and should be considered early and often through the various design phases. In 2020, NASA started a project for the Human Landing System (HLS) program to develop a Government Furnished Equipment (GFE) toilet option. The project is known as the Lavatory On-Orbit (LOO). During the early development of the LOO, the project team conducted several crew evaluations to collect and summarize valuable crew feedback on system design, function, and overall usability to influence the next design iteration. Because every person could use the system differently in space, it was extremely important to collect and analyze the data in a very methodical manner to appropriately influence the design based on the evaluation results. Establishing a standard process ensures consistent data collection from one evaluation to another, helps to maintain privacy for each test subject’s inputs and removes any potential bias from test subject to test subject. To date, the team has completed four crew evaluations on prototypes for the different LOO hardware. This paper will summarize the methodology used to conduct the evaluations as well as how data was collected and analyzed. The paper will also provide details on each of the evaluations and how the design was updated based on the results.

toilet↗
NASA NTRSDate not supplied

Evolution of the Next Exploration Toilet Through Human-in-the-Loop (HITL) Testing

Human waste collection in space is a unique and necessary function that all crewmembers must perform. The variability in how each crewmember uses the toilet to urinate and defecate introduces complexities and challenges with regards to overall hardware design. Because of this variability, it is important to consider crew inputs in all aspects of a toilet design especially with regards to crew interfaces that could impact overall waste collection. Access to crew feedback is essential to the design process and should be considered early and often through the various design phases. In 2020, NASA started a project for the Human Landing System (HLS) program to develop a Government Furnished Equipment (GFE) toilet option. The project is known as the Lavatory On-Orbit (LOO). During the early development of the LOO, the project team conducted several crew evaluations to collect and summarize valuable crew feedback on system design, function, and overall usability to influence the next design iteration. Because every person could use the system differently in space, it was extremely important to collect and analyze the data in a very methodical manner to appropriately influence the design based on the evaluation results. Establishing a standard process ensures consistent data collection from one evaluation to another, helps to maintain privacy for each test subject’s inputs and removes any potential bias from test subject to test subject. To date, the team has completed four rounds of crew evaluations with multiple crewmembers on prototypes for the different LOO subsystems. This paper will summarize the methodology used to conduct the evaluations as well as how data was collected and analyzed. The paper will also provide details on each of the evaluations and how the design was updated based on the results.

toilet↗
NASA NTRSDate not supplied

Evolution of the Next Exploration Toilet Through Human-in-the-Loop (HITL) Testing

Human waste collection in space is a unique and necessary function that all crewmembers must perform. The variability in how each crewmember uses the toilet to urinate and defecate introduces complexities and challenges with regards to overall hardware design. Because of this variability, it is important to consider crew inputs in all aspects of a toilet design especially with regards to crew interfaces that could impact overall waste collection. Access to crew feedback is essential to the design process and should be considered early and often through the various design phases. In 2020, NASA started a project for the Human Landing System (HLS) program to develop a Government Furnished Equipment (GFE) toilet option. The project is known as the Lavatory On-Orbit (LOO). During the early development of the LOO, the project team conducted several crew evaluations to collect and summarize valuable crew feedback on system design, function, and overall usability to influence the next design iteration. Because every person could use the system differently in space, it was extremely important to collect and analyze the data in a very methodical manner to appropriately influence the design based on the evaluation results. Establishing a standard process ensures consistent data collection from one evaluation to another, helps to maintain privacy for each test subject’s inputs and removes any potential bias from test subject to test subject. To date, the team has completed four rounds of crew evaluations with multiple crewmembers on prototypes for the different LOO subsystems. This paper will summarize the methodology used to conduct the evaluations as well as how data was collected and analyzed. The paper will also provide details on each of the evaluations and how the design was updated based on the results.

toilet↗
DOE OSTI2026

Cation Data for the East River Watershed, Colorado (2014-2025)

This data package contains mean values for cation concentration for water samples taken from the East River Watershed in Colorado. Inductively coupled plasma mass spectrometry (ICP-MS) has been used to measure the concentrations of elements of interest simultaneously for the East River Watershed, Colorado groundwater and surface water samples to inform insights on the biogeochemistry processes within the watershed. The East River is part of the Watershed Function Scientific Focus Area (WFSFA) located in the Upper Colorado River Basin, United States. For samples collected prior to 06-16-2021, the instrumentation, Elan DRC II, PerkinElmer SCIEX, automatically switches among the three models necessary to analyze all 37 elements. These 37 elements include: (1) Lithium (Li), Beryllium (Be), Boron (B), Sodium (Na), Magnesium (Mg), Aluminium (Al), Silicon (Si), Phosphorus (P), Titanium (Ti), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Caesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th), Uranium (U) using standard model, argon Ar as reaction gas, (2) Potassium (K), Calcium (Ca), Vanadium (V), Chromium (Cr), Manganese (Mn), Iron (Fe) using dynamic reaction cell (DRC) model, ammonia NH3 as reaction gas, and (3) Phosphorus (P) and Selenium (Se) using DRC model, oxygen O2 as reaction gas. Note for the samples with higher concentrations of chloride (Cl-), asenic (As) concentrations were analysed with DRC model (oxygen O2 as reaction gas) to avoid the interference of chloride. For samples collected on and after 06-16-2021, an advanced Agilent 8900 triple quadrupole inductively coupled plasma mass spectrometry system (Agilent 8900 QQQ ICP-MS, Agilent Technologies) has been used to measure the concentrations of interested 36 elements simultaneously for environmental samples, including (1) Lithium (Li), Beryllium (Be) and Boron (B) using standard no gas mode, (2) Sodium (Na), Magnesium (Mg), Aluminium (Al) Phosphorus (P), Potassium (K), Chromium (Cr), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Cesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th) and Uranium (U) using standard helium (He) collision mode, (3) Titanium (Ti) and Vanadium (V) using high Energy (HEHe) helium (He) collision mode, and (4) Silicon (Si), Calcium (Ca) and Selenium (Se) using standard H2 reaction mode. All samples were prepared/diluted with 2% (v/v) ultrapure nitric acid in Milli-Q water (18.2 mega ohm-cm), and analyzed under a rigorous quality assurance and quality control (QA/QC) process. This data package contains (1) a zip file (cation_data_2014_2025.zip) containing a total of 5,849 files: 5.848 data files of cation data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v6_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v6_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; (4) PDF and docx files for the detemination of Method Detection Limits (MDLs) for ICP-MS PerkinElmer DRC II instrumentation (Detemination_of_Method_Detection_Limits__MDLs__for_ICP_MS__PerkinElmer_Elan_DRC_II__LBL_Bldg74_Lab214D) for samples before November 2021; (5) PDF and docx files for the determination of MDLs for ICP-MS Agilent 8900 QQQ instrumentation (ICP_MS_Analysis_detection_limits_and_QA_QC_WenmingDong_updated_2026-08-06) for samples November 2021 and onward. Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 113 locations containing cation data. Update on 2021-04-11: Added Detemination of Method Detection Limits (MDLs) for ICP-MS document, which can be accessed as a PDF or with Microsoft Word. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated cation data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) removed suffix and prefix on two variables (“aqberylliumion_asberyllium” and “aqlithiumion_aslithium”), (5) added -9999 for empty numerical cells, and (6) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-01-05. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-10-16. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Updated versions of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2025 (September 30, 2025). Updated versions, as of 2026-08-06, of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2003

Single Event Effects Testing of the Linfinity SG1525A Pulse Width Modulator Controller

Pulse Width Modulator (PWM) Controllers are the heart of switching power supply systems in development today. The PWMs considered here have the same integration advantages as many other controllers but it also includes the interface drivers for the follow-on power Field Effect Transistors (FET). Previous work on these types of devices looked into the required test methodologies [ 11 and the impact of radiation on the soft start and shutdown circuits of typically incorporated in the technology [2]. Taking advantage of this previous work this study was undertaken to determine the single event destructive and transient susceptibility of the Linfinity SG1525A Pulse Width Modulator Controller. The device was monitored for transient interruptions in the output signals and for destructive events induced by exposing it to a heavy ion beam at the Texas A&M University Cyclotron Single Event Effects Test Facility. After exposing these devices to the beam, a new upset mode has been identified that can lead to catastrophic power supply system failure if this event would occur while drive power FETs off the two device outputs. The devices and the test methods used will be described first. This will be followed by a brief description of the data collected to date (not all data can be presented with the length constraints of the summary) and a summary of the key results.

Howard, J. W., Jr.↗
NASA NTRS2023

Coronal Heating as Determined by the Solar Flare Frequency Distribution Obtained by Aggregating Case Studies

Flare frequency distributions represent a key approach to addressing one of the largest problems in solar and stellar physics: determining the mechanism that counterintuitively heats coronae to temperatures that are orders of magnitude hotter than the corresponding photospheres. It is widely accepted that the magnetic field is responsible for the heating, but there are two competing mechanisms that could explain it: nanoflares or Alfvén waves. To date, neither can be directly observed. Nanoflares are, by definition, extremely small, but their aggregate energy release could represent a substantial heating mechanism, presuming they are sufficiently abundant. One way to test this presumption is via the flare frequency distribution, which describes how often flares of various energies occur. If the slope of the power law fitting the flare frequency distribution is above a critical threshold, α = 2 as established in prior literature, then there should be a sufficient abundance of nanoflares to explain coronal heating. We performed >600 case studies of solar flares, made possible by an unprecedented number of data analysts via three semesters of an undergraduate physics laboratory course. This allowed us to include two crucial, but nontrivial, analysis methods: preflare baseline subtraction and computation of the flare energy, which requires determining flare start and stop times. We aggregated the results of these analyses into a statistical study to determine that α = 1.63 ± 0.03. This is below the critical threshold, suggesting that Alfvén waves are an important driver of coronal heating.

Astrostatistics distributions↗
DOE OSTI2022

Femtosecond diffraction and dynamic high pressure science

Solid-state material at high pressure is prevalent throughout the Universe, and an understanding of the structure of matter under such extreme conditions, gleaned from x-ray diffraction, has been pursued for the best part of a century. The highest pressures that can be reached to date (2 TPa) in combination with x-ray diffraction diagnosis have been achieved by dynamic compression via laser ablation. The past decade has witnessed remarkable advances in x-ray technologies, with novel x-ray Free-Electron-Lasers (FELs) affording the capacity to produce high quality single-shot diffraction data on timescales below 100 fs. We provide a brief history of the field of dynamic compression, spanning from when the x-ray sources were almost always laser-plasma based, to the current state-of-the art diffraction capabilities provided by FELs. We give an overview of the physics of dynamic compression, diagnostic techniques, and the importance of understanding how the rate of compression influences the final temperatures reached. We provide illustrative examples of experiments performed on FEL facilities that are starting to give insight into how materials deform at ultrahigh strain rates, their phase diagrams, and the types of states that can be reached. We emphasize that there often appear to be differences in the crystalline phases observed between the use of static and dynamic compression techniques. We give our perspective on both the current state of this rapidly evolving field and some glimpses of how we see it developing in the near-to-medium term.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRSDate not supplied

NASA Exploration Toilet Hardware Status and Crew Feedback from ISS Artemis-2 Demonstration

The Universal Waste Management System (UWMS), ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Technical progress continues to be made with each on-orbit operation and will ultimately culminate with nominal US crew use of the hardware on ISS. During 2023, the Artemis-2 Demonstration was started, and this paper discusses issues encountered, on-orbit troubleshooting, subsequent ground failure investigation and proposed repairs as well as near-term plans to resume the Artemis-2 demo. Also discussed is an update to the commercial-off-the-shelf (COTS) Conductivity Monitor which is planned to be flown for the resumption of the demo along with additional UWMS hardware and Toilet Integration Hardware (TIH). An updated design of the commode seat and fecal bag for Artemis-2 UWMS will be demonstrated on ISS and a summary of the hardware is included in the paper. Use of the hardware during the first days of the aborted demonstration by crewmembers and feedback received is summarized as well as hardware updates resulting from that feedback. The paper will also provide an overview of the demo results to date that inform the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗
NASA NTRSDate not supplied

NASA Exploration Hardware Status and Crew Feedback from Artemis-2 Demonstration

The Universal Waste Management System (UWMS), ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Technical progress continues to be made with each on-orbit operation and will ultimately culminate with nominal US crew use of the hardware on ISS. During 2023, the Artemis-2 Demonstration was started, and this paper discusses issues encountered, on-orbit troubleshooting, subsequent ground failure investigation and proposed repairs as well as near-term plans to resume the Artemis-2 demo. Also discussed is an update to the commercial-off-the-shelf (COTS) Conductivity Monitor which is planned to be flown for the resumption of the demo along with additional UWMS hardware and Toilet Integration Hardware (TIH). An updated design of the commode seat and fecal bag for Artemis-2 UWMS will be demonstrated on ISS and a summary of the hardware is included in the paper. Use of the hardware during the first days of the aborted demonstration by crewmembers and feedback received is summarized as well as hardware updates resulting from that feedback. The paper will also provide an overview of the demo results to date that inform the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗
DOE OSTI2021

Selective and noncovalent targeting of RAS mutants for inhibition and degradation

Activating mutants of RAS are commonly found in human cancers, but to date selective targeting of RAS in the clinic has been limited to KRAS(G12C) through covalent inhibitors. Here, we report a monobody, termed 12VC1, that recognizes the active state of both KRAS(G12V) and KRAS(G12C) up to 400-times more tightly than wild-type KRAS. The crystal structures reveal that 12VC1 recognizes the mutations through a shallow pocket, and 12VC1 competes against RAS-effector interaction. When expressed intracellularly, 12VC1 potently inhibits ERK activation and the proliferation of RAS-driven cancer cell lines in vitro and in mouse xenograft models. 12VC1 fused to VHL selectively degrades the KRAS mutants and provides more extended suppression of mutant RAS activity than inhibition by 12VC1 alone. These results demonstrate the feasibility of selective targeting and degradation of KRAS mutants in the active state with noncovalent reagents and provide a starting point for designing noncovalent therapeutics against oncogenic RAS mutants.

60 APPLIED LIFE SCIENCES↗
NASA NTRSDate not supplied

NASA Exploration Toilet Hardware Status and Crew Feedback from ISS Artemis-2 Demonstration

The Universal Waste Management System (UWMS), ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Technical progress continues to be made with each on-orbit operation and will ultimately culminate with nominal US crew use of the hardware on ISS. During 2023, the Artemis-2 Demonstration was started, and this paper discusses issues encountered, on-orbit troubleshooting, subsequent ground failure investigation and proposed repairs as well as near-term plans to resume the Artemis-2 demo. Also discussed is an update to the commercial-off-the-shelf (COTS) Conductivity Monitor (CCM) which is planned to be flown for the resumption of the demo along with additional UWMS hardware and Toilet Integration Hardware (TIH). An updated design of the commode seat and fecal bag for Artemis-2 UWMS will be demonstrated on ISS and a summary of the hardware is included in the paper. Use of the hardware during the first days of the aborted demonstration by crewmembers and feedback received is summarized as well as hardware updates resulting from that feedback. The paper will also provide an overview of the demo results to date that inform the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗
NASA NTRS2006

Applying Registry Services to Spaceflight Technologies to Aid in the Assignment of Assigned Numbers to Disparate Systems and Their Technologies to Further Enable Interoperability

To date very little effort has been made to provide interoperability between various space agency projects. To effectively get to the Moon and beyond systems must interoperate. To provide interoperability, standardization and registries of various technologies will be required. These registries will be created as they relate to space flight. With the new NASA Moon/Mars initiative a requirement to standardize and control the naming conventions of very disparate systems and technologies are emerging. The need to provide numbering to the many processes, schemas, vehicles, robots, space suits and technologies (e.g. versions), to name a few, in the highly complex Constellation Initiative is imperative. The number of corporations, developer personnel, system interfaces, people interfaces will require standardization and registries on a scale not currently envisioned. It would only take one exception (stove piped system development) to weaken, if not, destroy interoperability. To start, a standardized registry process must be defined that allows many differing engineers, organizations and operators the ability to easily access disparate registry information across numerous technological and scientific disciplines. Once registries are standardized the need to provide registry support in terms of setup and operations, resolution of conflicts between registries and other issues will need to be addressed. Registries should not be confused with repositories. No end user data is "stored" in a registry nor is it a configuration control system. Once a registry standard is created and approved, the technologies that should be registered must be identified and prioritized. In this paper, we will identify and define a registry process that is compatible with the Constellation Initiative and other non related space activities and organizations. We will then identify and define the various technologies that should use a registry to provide interoperability. The first set of technologies will be those that are currently in need of expansion namely the assignment of satellite designations and the process which controls assignments. Second, we will analyze the technologies currently standardized under the Consultative Committee for Space Data Systems (CCSDS) banner. Third, we will analyze the current CCSDS working group and birds of a feather activities to ascertain registry requirements. Lastly, we will identify technologies that are either currently under the auspices of another

Bradford, Robert N.↗
NASA NTRS2006

Applying Registry Services to Spaceflight Technologies to Aid in the Assignment of Assigned Numbers to Disparate Systems and their Technologies to Further Enable Interoperability

To date very little effort has been made to provide interoperability between various space agency projects. To effectively get to the Moon and beyond systems must interoperate. To provide interoperability, standardization and registries of various technologies will be required. These registries will be created as they relate to space flight. With the new NASA Moon/Mars initiative, a requirement to standardize and control the naming conventions of very disparate systems and technologies is emerging. The need to provide numbering to the many processes, schemas, vehicles, robots, space suits and technologies (e.g. versions), to name a few, in the highly complex Constellation initiative is imperative. The number of corporations, developer personnel, system interfaces, people interfaces will require standardization and registries on a scale not currently envisioned. It would only take one exception (stove piped system development) to weaken, if not, destroy interoperability. To start, a standardized registry process must be defined that allows many differing engineers, organizations and operators the ability to easily access disparate registry information across numerous technological and scientific disciplines. Once registries are standardized the need to provide registry support in terms of setup and operations, resolution of conflicts between registries and other issues will need to be addressed. Registries should not be confused with repositories. No end user data is "stored" in a registry nor is it a configuration control system. Once a registry standard is created and approved, the technologies that should be registered must be identified and prioritized. In this paper, we will identify and define a registry process that is compatible with the Constellation initiative and other non related space activities and organizations. We will then identify and define the various technologies that should use a registry to provide interoperability. The first set of technologies will be those that are currently in need of expansion namely the assignment of satellite designations and the process which controls assignments. Second, we will analyze the technologies currently standardized under the Consultative Committee for Space Data Systems (CCSDS) banner. Third, we will analyze the current CCSDS working group and Birds of a Feather (BoF) activities to ascertain registry requirements. Lastly, we will identify technologies that are either currently under the auspices of another standards body or technologies that are currently not standardized. For activities one through three, we will provide the analysis by either discipline or technology with rationale, identification and brief description of requirements and precedence. For activity four, we will provide a list of current standards bodies e.g. IETF and a list of potential candidates.

Bradford, Robert N.↗
DOE OSTI2022

Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO 2 Reduction

Catalysts promoting multielectron charge delocalization offer selectivity for the CO 2 reduction reaction (CO 2 RR) over the competing hydrogen evolution reaction. Here, we show metal–ligand exchange coupling as an example of charge delocalization that can determine the efficiency for photocatalytic CO 2 RR. A comparative evaluation of iron and cobalt complexes supported by the redox-active ligand tpyPY2Me establishes that the two-electron reduction of [Co(tpyPY2Me)] 2+ ([Co] 2+ ) occurs at potentials 770 mV more negative than the [Fe(tpyPY2Me)] 2+ ([Fe] 2+ ) analogue by maximizing the exchange coupling in the latter compound. The positive shift in the reduction potential promoted by metal–ligand exchange coupling drives [Fe] 2+ to be among the most active and selective molecular catalysts for photochemical CO 2 RR reported to date, maintaining up to 99% CO product selectivity with total turnover numbers (TONs) and initial turnover frequencies exceeding 30,000 and 900 min –1 , respectively. In contrast, [Co] 2+ shows much lower CO 2 RR activity, reaching only ca. 600 TON at 83% CO product selectivity under similar conditions accompanied by rapid catalyst decomposition. Further, the spin density plots of the two-electron reduced [Co] 0 complex implicate a paramagnetic open-shell doublet ground state compared to the diamagnetic open-shell singlet ground state of reduced [Fe] 0 , rationalizing the observed negative shift in two-electron reduction potentials from the [M] 2+ species and lowered CO 2 RR efficiency for the cobalt complex relative to its iron congener. This work emphasizes the contributions of multielectron metal–ligand exchange coupling in promoting effective CO 2 RR and provides a starting point for the broader incorporation of this strategy in catalyst design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1995

Marketing Remote Sensing Data for North Pacific Fisheries Development and Management

Fish poaching, drug trafficking, ocean dumping, and other illegal activities are important problems on the high seas and in national economic zones. The primary thrust of the EOCAP II project, "Marketing Remote Sensing Data for North Pacific Fisheries Development and Management", was to use space-based sensors to improve the effectiveness of marine monitoring, control, and surveillance (MCS). Our initial objectives were to concentrate on the development of MCS tools using Advanced Very High Resolution Radiometry (AVHRR) and Synthetic Aperture Radar (SAR) data. Although we have successfully completed development of an initial version of our SAR-based monitoring tool (OmniVision), project activity has resulted in a much broader application of space-based assets to marine applications. Based in part on work commenced within EOCAP II, a new company, Ocean and Coastal Environmental Sensing, Inc. (OCENS), has been launched and the development of several new software products outside of the MCS arena initiated. One of those products, SeaStation, is near completion with a Fall, 1995 release date. Equity investment in OCENS now totals $70,000-with an additional amount being sought in the first round of financing. One of the pre-eminent objectives of EOCAP II is to make contributions to the US economy and job growth through the expansion of commercial uses of remotely sensed data. OCENS and the software products it is introducing into marine and coastal zone markets responds to this primary object*e. EOCAP II funding leveraged the market and technical know-how of OCENS founders into smart products that benefit marine and coastal zone users. Although technical difficulties and geopolitical shifts damaged the commercial feasibility of initial project objectives, the flexibility of the EOCAP II program now permits long-term business success. This in no small part stems from the fact that the EOCAP program recognizes the realities of small and start-up businesses and does not attempt to force these conditions to fit the apparent needs of big government. Instead, EOCAP works with those who know their market best in order to produce successful products and expanding businesses.

Source record↗
NASA NTRS1999

Unpressurized Logistics Carriers for the International Space Station: Lessons Learned

The International Space Station has been in development since 1984, and has recently begun on orbit assembly. Most of the hardware for the Space Station has been manufactured and the rest is well along in design. The major sets of hardware that are still to be developed for Space Station are the pallets and interfacing hardware for resupply of unpressurized spares and scientific payloads. Over the last ten years, there have been numerous starts, stops, difficulties and challenges encountered in this effort. The Space Station program is now entering the beginning of orbital operations. The Program is only now addressing plans to design and build the carriers that will be needed to carry the unpressurized cargo for the Space Station lifetime. Unpressurized carrier development has been stalled due to a broad range of problems that occurred over the years. These problems were not in any single area, but encompassed budgetary, programmatic, and technical difficulties. Some lessons of hindsight can be applied to developing carriers for the Space Station. Space Station teams are now attempting to incorporate the knowledge gained into the current development efforts for external carriers. In some cases, the impacts of these lessons are unrecoverable for Space Station, but can and should be applied to future programs. This paper examines the progress and problems to date with unpressurized carrier development identifies the lessons to be learned, and charts the course for finally accomplishing the delivery of these critical hardware sets.

Robbins, William W., Jr.↗