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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Perfluoro (Imidoylamidine) diamidines

Perfluoroether triazine elastomers having improved properties are prepared from oligomeric imidoylamidines that were in turn, prepared by the process of: (1) reacting a perfluorodinitrile with liquid ammonia to yield a perfluorodiamidine, (2) isolating the perfluorodiamidine, (3) reacting the isolated diamidine with a perfluorodinitrile to yield a perfluoro(imidoylamidine) dinitrile, and then repeating the steps to sequentially grow an oligomer of desired molecular size. The isolated amidine and nitrile intermediates are also disclosed. The elastomers can be fashioned into seals, gaskets, and sealing components and the like.

Rosser, R. W.↗
NASA NTRS1986

A shock capturing technique for hypersonic, chemically relaxing flows

A fully coupled, shock capturing technique is presented for chemically reacting flows at high Mach numbers. The technique makes use of a total variation diminishing (TVD) dissipation operator which results in sharp, crisp shocks. The eigenvalues and eigenvectors of the fully coupled system, which includes species conversion equations in addition to the gas dynamics equations, are analytically derived for a general reacting gas. Species production terms for a model dissociating gas are introduced and are included in the algorithm. The convective terms are solved using a first-order TVD scheme while the source terms are solved using a fourth-order Runge-Kutta scheme to enhance stability. Results from one-dimensional numerical experiments are shown for a two species and a three species gas.

Eberhardt, S.↗
NASA NTRS1986

Numerical study of supersonic combustion using a finite rate chemistry model

The governing equations of two-dimensional chemically reacting flows are presented together with a global two-step chemistry model for H2-air combustion. The explicit unsplit MacCormack finite difference algorithm is used to advance the discrete system of the governing equations in time until convergence is attained. The source terms in the species equations are evaluated implicitly to alleviate stiffness associated with fast reactions. With implicit source terms, the species equations give rise to a block-diagonal system which can be solved very efficiently on vector-processing computers. A supersonic reacting flow in an inlet-combustor configuration is calculated for the case where H2 is injected into the flow from the side walls and the strut. Results of the calculation are compared against the results obtained by using a complete reaction model.

Chitsomboon, T.↗
NASA NTRS1987

Fire and heat resistant laminating resins based on malemeido and citraconimido substituted 1 -2,4- and -2,6- diaminobenzenes

A novel class of fire and heat resistant bisimide resins prepared by thermal polymerization of maleimido or citraconimido substituted 1-(dialkox phosphonyl) methyl-2-4 and -2,6-diamino benzenes was presented. The polymer precursors are prepared by reacting 1-(diorgano oxyphosphonyl) methyl-2-4- and -2,6-diamino benzenes with maliec anhydride or citraconic anhydride in a mole ratio 1:2. Chain extension of the monomers is achieved by reacting the mono-N-maleimido derivaties of 1 (diorgano oxyphosphonyl) methyl -2,4- and -2,6-diamino benzenes with aryl tetracarboxylic dianhydrides, such as benzophenone tetracarboxylic dianhydride, or aryl diisocyanates, such as methylene bis(4-phenyl isocyanate), in a mole ratio 2:1. The polymerization of the monomers is studied by diferential scanning calorimetry and the thermal stability of the polymers is ascertained by thermogravimetric analysis.

Mikroyannidis, John A.↗
NASA NTRS1987

Stability of bromine, iodine monochloride, copper (II) chloride, and nickel (II) chloride intercalated pitch-based graphite fibers

Four different grades of pitch-based graphite fibers (Amoco P-55, P-75, P-100. and P-120) were intercalated with each of four different intercalates: bromine (Br2), iodine monochloride (ICl), copper (II) chloride (CuCl2), and nickel (II) chloride (NiCl2). The P-55 fibers did not react with Br2 or NiCl2, and the P-75 did not react with NiCl2. The stability of the electrical resistance of the intercalated fibers was monitored over long periods of time in ambient, high humidity (100 percent at 60 C), vacuum (10 to the -6 torr), and high temperature (up to 400 C) conditions. Fibers with lower graphitization form graphite intercalation compounds (GIC's) which are more stable than those with higher graphitization (i.e., P-55 (most stable) greater than P-75 greater than P-100 greater than P-120 (least stable). Br2 formed the most stable GIC's followed in order of decreasing stability by ICl, CuCl2, and NiCl2. While Br2 GIC's had the most stability, ICl had the advantages of forming GIC's with slightly greater reduction in resistance (by about 10%) than Br2, and the ability to intercalate P-55 fiber. Transition metal chlorides are susceptible to water vapor and high temperature. The stability of fibers in composites differs.

Gaier, James R.↗
NASA NTRS1987

Fire and heat resistant laminating resins based on maleimido and citraconimido substituted 1-(diorgano oxyphosphonyl) methyl -2,4- and -2,6- diaminobenzenes

A class of fire and heat resistant bisimide resins prepared by thermal polymerization of maleimido or citraconimido substituted 1-((dialkoxyphosphonyl) methyl)-2-4 and -2,6-diaminobenzenes are described. The polymer precursors are prepared by reacting 1-((diorganooxyphosphonyl) methyl)-2-4 and -2,6-diaminobenzenes with maleic anhydride or citraconic anhydride in a mole ratio 1:2. Chain extension of the monomers is achieved by reacting the mono-N-maleimido derivatives of 1-((diorganooxyphosphonyl) methyl)-2,4 and -2,6-diaminobenzenes with aryl tetracarboxylic dianhydrides, such as benzophenone tetracarbocylic dianhydride, or aryl diisocyanates, such as methylenebis (4-phenylisocyanate), in a mole ratio 2:1. The polymerization of the monomers is studied by differential scanning calorimetry (DSC) and the thermal stability of the polymers is ascertained by thermogravimetric analysis (TGA).

Mikroyannidis, John A.↗
NASA NTRS1987

Numerical study of finite-rate supersonic combustion using parabolized equations

A set of partial differential equations, describing the two-dimensional supersonic chemically-reacting flow of the hydrogen-air system, is formulated such that the equations are parabolic in the streamwise direction. A fully-implicit fully-coupled finite-difference algorithm is used to develop a computer code which solves the governing equations by marching in the streamwise direction. The combustion process is modeled by a two-step finite-rate chemistry whereas turbulence is simulated by an algebraic turbulence model. Results of two calculations of internal supersonic reacting flow show fairly good agreement with the results obtained by the more costly full Navier-Stokes procedure.

Chitsomboon, T.↗
NASA NTRS1986

Meteoric material and the behavior of upper stratospheric polar zone

Ozone mixing ratios as a function of pressure level and time are presented based on data obtained with the Nimbus-7 SBUV instrument between 1979 and 1984, and implications of this data for the explanations of the spring Antarctic ozone depletion are considered. It is suggested that meteoric atoms react with the atmosphere to bond to OH, and subsequently react with HCl to form salts, resulting in the accumulation of chlorine during polar winter. The sudden release of this chlorine from photodissociation of these salts during spring could account for the loss of ozone in the upper atmosphere.

Aikin, A. C.↗
NASA NTRS1988

CFD validation experiments for internal flows

Computational Fluid Dynamics (CFD) validation experiments at NASA Lewis Research Center are described. The material presented summarizes the research in three areas: Inlets, Ducts and Nozzles; Turbomachinery; and Chemically Reacting Flows. The specific validation activities are concerned with shock-boundary layer interactions, vortex generator effects, large low speed centrifugal compressor measurements, transonic fan shock structure, rotor/stator kinetic energy distributions, stator wake shedding characteristics, boundary layer transition, multiphase flow and reacting shear layers. These experiments are intended to provide CFD validation data for the internal flow fields within aerospace propulsion system components.

Povinelli, Louis A.↗
NASA NTRS1988

Numerical solutions of the complete Navier-Stokes equations

The physical phenomena within supersonic flows that sustain chemical reactions are investigated. An earlier study to develop accurate physical models for supersonic reacting flowfields focused on 2-D laminar shear layers. The objective is to examine the mixing and subsequent combustion within turbulent reacting shear layers. To conduct this study, a computer program has been written to solve the axisymmetric Reynolds averaged Navier-Stokes equations. The numerical method uses a cell-centered finite volume approach and a Runge Kutta time stepping scheme. The Reynolds averaged equations are closed using the eddy viscosity concept. Several zero-equation models have been tested by making calculations for an H2-air nonreacting coaxial jet flow. Comparisons made with experimental data show that Cohen's eddy viscosity model provides best agreement. The finite rate chemistry model used in the study of 2-D laminar shear layers is incorporated into the computer program and data is compared from a recent experiment performed at NASA Langley.

Hassan, H. A.↗
NASA NTRS1988

Chemical durability of high-temperature superconductor YBa2Cu3O(7-x) in aqueous environments

The stability of YBa2Cu3O(7-x) in water and 100-percent humidity has been investigated at three temperatures, using pH measurements, X-ray diffraction, and scanning electron microscopy. The oxide-ceramic superconductor is highly unstable; it reacts rapidly with water and degrades in moisture. Dissolution of the oxide perovskite in water is highly incongruent. The corrosion products are found to be BaCO3, CuO, O2, etc. Barium hydroxide is first formed and further reacts with atmospheric CO2 to form needle-shaped crystals of BaCO3. For any practical applications, devices made from these materials would have to be protected with an impermeable coating to prevent deterioration from atmosphere.

Bansal, Narottam P.↗
NASA NTRS1988

Antarctic ozone depletion chemistry - Reactions of N2O5 with H2O and HCl on ice surfaces

In a study concerning Antarctic ozone depletion, reactions of dinitrogen pentoxide with water and hydrochloric acid were studied on ice surfaces in a Knudsen cell flow reactor. The N2O5 reacted on ice at 185 K to form condensed-phase nitric acid (HNO3). This reaction may provide a sink for odd nitrogen, NO(x), during the polar winter, a requirement in nearly all models of Antarctic ozone depletion. The reaction of N2O5 on HCl-ice surfaces at 185 K produced gaseous nitryl chloride (ClNO2) and condensed-phase HNO3 and proceeded until all of the HCl within the ice was depleted. The ClNO2 which did not react or condense on ice at 185 K, can be readily photolyzed in the Antarctic spring to form atomic chlorine for catalytic ozone destruction cycles. The other photolysis product, gaseous nitrogen dioxide may be important in the partitioning of NO(x) between gaseous and condensed phases in the Antarctic winter.

Tolbert, Margaret A.↗
NASA NTRS1988

Experimental studies in vortex pair motion coincident with a liquid reaction

An experimental examination of the coincidence of a liquid reaction (acid/base) with the formation of a vortex pair structure is described in which emphasis is placed on the evolution of the strained diffusion layer and reacted core structures. Flow visualization of the reaction process is achieved via the technique of chemically sensitive LIF. The observed growth of reacted core structures associated with each vortex is compared with theoretically predicted behavior (Marble, 1983; Karagozian and Marble, 1986). Vortex pair separation is also compared with theoretical correlations, and the relevance of the analogy between a fast liquid reaction and a gaseous reaction is discussed.

Karagozian, A. R.↗
NASA NTRS1988

The origin of type C inclusions from carbonaceous chondrites

The origin of type C inclusions found in carbonaceous chondrites and the relationship of the type C inclusions to other Ca- and Al-rich chondrules are discussed on the basis of major-element composition of these objects. The results on bulk composition analysis of primary phase assemblages in eight Allende-type inclusions and an Allende glass-spinel inclusion were found to be consistent with the following scenario: (1) the condensation of melilite + spinel + perovskite +/- hibonite +/- CaAl4O7; (2) the reaction of melilite + spinel with SiO2(g); (3) the removal of inclusions from further interaction with the reacting gas; (4) melting with little or no volatilization; (5) crystallization; (6) alteration; and (7) incorporation of inclusions into host meteorite. Type C inclusions are considered to be precursors to Al-rich chondrules in ordinary and enstatite chondrites, i.e., they are considered to be a spinel-rich class of type A that reacted with silica from a coexisting gas to produce anorthite plus diopside.

Beckett, John R.↗
NASA NTRS1988

Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures

The heterogeneous interactions of ClONO2, HCl, and HNO3 with sulfuric acid surfaces were studied using a Knudsen cell flow reactor. The surfaces studied, chosen to simulate global stratospheric particulate, were composed of 65-75 percent H2SO4 solutions at temperatures in the range -63 to -43 C. Heterogeneous loss, but not reaction, of HNO3 and HCl occurred on these surfaces; the measured sticking coefficients are reported. Chlorine nitrate reacted on the cold sulfuric acid surfaces, producing gas-phase HOCl and condensed HNO3. CLONO2 also reacted with HCl dissolved in the 65-percent H2SO4 solution at -63 C, forming gaseous Cl2. In all cases studied, the sticking and/or reaction coefficients were much larger for the 65-percent H2SO4 solution at -63 C than for the 75-percent solution at -43 C.

Tolbert, Margaret A.↗
NASA NTRS1989

Making Multicore, Multishell Microspheres

Multiple streams of fluids combined to produce various structures. Spherical or nearly spherical micro-shells containing two or more discrete inclusions produced by proposed technique. Pairs of coaxial nozzles combined in arrays of two or more. Each pair of nozzles generate inner jet surrounded by sheath of fluid. Multiple jets combined to form droplets composed of shells and cores. Spheres designed so cores combine to mix or react only after leaving shell generator. Similarly, two or more shell-wall materials mix or react after leaving generator.

Morrison, Andrew D.↗
NASA NTRS1985

Ceramic oxide reactions with V2O5 and SO3

Ceramic oxides are not inert in combustion environments, but can react with, inter alia, SO3, and Na2SO4 to yield low melting mixed sulfate eutectics, and with vanadium compounds to produce vanadates. Assuming ceramic degradation to become severe only when molten phases are generated in the surface salt (as found for metallic hot corrosion), the reactivity of ceramic oxides can be quantified by determining the SO3 partial pressure necessary for molten mixed sulfate formation with Na2SO3. Vanadium pentoxide is an acidic oxide that reacts with Na2O, SO3, and the different ceramic oxides in a series of Lux-Flood type of acid-base displacement reactions. To elucidate the various possible vanadium compound-ceramic oxide interactions, a study was made of the reactions of a matrix involving, on the one axis, ceramix oxides of increasing acidity, and on the other axis, vanadium compounds of increasing acidity. Resistance to vanadium compound reaction increased as the oxide acidity increased. Oxides more acidic than ZrO2 displaced V2O5. Examination of Y2O3- and CeO2-stabilized ZrO2 sintered ceramics which were degraded in 700 C NaVO3 has shown good agreement with the reactions predicted above, except that the CeO2-ZrO2 ceramic appears to be inexplicably degraded by NaVO3.

Jones, R. L.↗
NASA NTRS1988

Fire and heat resistant laminating resin based on maleimido and citraconimido substituted 1-(diorganooxyphosphonyl-methyl)-2,4- and -2,6-diaminobenzenes

The subject invention pertains to a novel class of fire-and heat-resistant bisimide resins prepared by thermal polymerization of maleimido or citraconimido substituded 1-(dialkoxyphosphonyl)-methyl-2-4 and -2,6-diaminobenzenes. Typical polymer presursors have the chemical structure wherein R is alkyl, substituted alkyl or aryl, and R sup 1 is hydrogen or lower alkyl. The polymer precursors are prepared by reacting 1-(diorganooxyphosphonyl)methyl-2-4 and -2,6-diaminobenzenes with maleic anhydride or citraconic anhydride in a mole ratio 1:2. Chains extension of the monomers is achieved by reacting the mono-N-maleimido derivatives of 1-(diorganooxyphosphonyl)methyl-2,4 and -2,6-diaminobenzenes with aryl tetracarboxylic dianhydrides, such as benzophenone tetracarboxylic diandydride, or aryl diisocyanates, such as methylenebis (4-phenylisocyanate), in a mole ratio 2:1. The polymerization of the monomers is studied by differential scanning calorimetry (DSC) and the thermal stability of the polymers is ascertained by thermogravimetric analysis (TGA).

James M Beggs↗