Theoretical investigation - The scattering of light by a planetary atmosphere Final report, 15 Sep. 1965 - 21 Jun. 1966
Computed effects of specular reflection on scattering of light by Rayleigh planetary atmosphere
RAYLEIGH DISTRIBUTION↗
SEARCH · Engineering Papers
Results for “RAYLEIGH SCATTERING”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Minimizing systematic errors from atmospheric multiple scattering and satellite viewing geometry in coastal zone color scanner level IIA imagery
Water-leaving radiances and phytoplankton pigment concentrations are calculated from coastal zone color scanner (CZCS) radiance measurements by removing atmospheric Rayleigh and aerosol radiances from the total radiance signal measured at the satellite. The single greatest source of error in CZCS atmospheric correction algorithms in the assumption that these Rayleigh and aerosol radiances are separable. Multiple-scattering interactions between Rayleigh and aerosol components cause systematic errors in calculated aerosol radiances, and the magnitude of these errors is dependent on aerosol type and optical depth and on satellite viewing geometry. A technique was developed which extends the results of previous radiative transfer modeling by Gordon and Castano to predict the magnitude of these systematic errors for simulated CZCS orbital passes in which the ocean is viewed through a modeled, physically realistic atmosphere. The simulated image mathematically duplicates the exact satellite, Sun, and pixel locations of an actual CZCS image. Errors in the aerosol radiance at 443 nm are calculated for a range of aerosol optical depths. When pixels in the simulated image exceed an error threshhold, the corresponding pixels in the actual CZCS image are flagged and excluded from further analysis or from use in image compositing or compilation of pigment concentration databases. Studies based on time series analyses or compositing of CZCS imagery which do not address Rayleigh-aerosol multiple scattering should be interpreted cautiously, since the fundamental assumption used in their atmospheric correction algorithm is flawed.
Martin, D. L.↗
Black carbon aerosol number and mass concentration measurements by picosecond short-range elastic backscatter lidar
Abstract Black carbon aerosol emissions are recognized as contributors to global warming and air pollution. There remains, however, a lack of techniques to remotely measure black carbon aerosol particles with high range and time resolution. This article presents a direct and contact-free remote technique to estimate the black carbon aerosol number and mass concentration at a few meters from the emission source. This is done using the Colibri instrument based on a novel technique, referred to here as Picosecond Short-Range Elastic Backscatter Lidar (PSR-EBL). To address the complexity of retrieving lidar products at short measurement ranges, we apply a forward inversion method featuring radiometric lidar calibration. Our method is based on an extension of a well-established light-scattering model, the Rayleigh–Debye–Gans for Fractal-Aggregates (RDG-FA) theory, which computes an analytical expression of lidar parameters. These parameters are the backscattering cross-sections and the lidar ratio for black carbon fractal aggregates. Using a small-scale Jet A-1 kerosene pool fire, we demonstrate the ability of the technique to quantify the aerosol number and mass concentration with centimetre range-resolution and millisecond time-resolution.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Wavelength dependence of polarization. XIV - Atmosphere of Jupiter.
Jupiter polarization wavelength dependence noted in observations of 5 seconds diameter regions near poles and equator related to Rayleigh- Chandrasekhar molecular scattering theory
Gehrels, T.↗
The evaluation of satellite-borne weather radar system designs using real ground-based radar data
The paper presents method of evaluating proposed satellite radar systems using real radar data, and discusses methods of displaying the results which will hopefully facilitate easy comparison of systems. A single pencil beam pulsed radar system is considered while the precipitation data base comes from six rain days observed by SPANDAR. The many additional factors that must be considered in the radar equation such as attenuation and scattering (Mie and Rayleigh) are discussed along with some indication where possible errors lie.
Dobson, E. B.↗
Extreme ultraviolet dayglow observations with a helium gas absorption cell
During the Apollo-Soyuz Test Project, an extreme-ultraviolet photometer with a cyclically operated helium gas-absorption cell observed the daytime sky from an orbital altitude of 225 km. When the line of sight pointed more than 60 deg from the sun, the instrument detected 2 to 70 rayleighs of flux scattered from neutral geocoronal helium at wavelengths from 504 to 584 A. The instrument also detected other radiation in the band 500-700 A of similar spatial distribution to the helium flux, which was definitely not due to the He I 584-A spectral line and which has not been detected by previous experimenters in data from 400 km altitude. Possible sources of this radiation are discussed.
Freeman, J.↗
Photofragmentation-laser induced fluorescence - A new method for detecting atmospheric trace gases
A new method for the in situ detection of nonfluorescing molecular species is proposed: photofragmentation-laser induced fluorescence (PF-LIF). In this approach, the species to be detected is first laser photolyzed at a wavelength lambda (1), producing one or more vibrationally excited photofragments. Before vibrational relaxation occurs, one of these photofragments is pumped into a bonding excited state by a second laser pulse centered at wavelength lambda (2). Fluorescence is sampled at a wavelength lambda (3), where lambda (3) is less then lambda (2) and lambda (1). This pumping configuration thus permits massive discrimination against Rayleigh and Raman scattering as well as white noise fluorescence from the laser wavelengths lambda (1) and lambda (2). The technique should be both highly sensitive and selective for numerous atmospheric trace gases. Specific sampling schemes for detecting NO2, NO3, and HNO2 are proposed. Various noise sources and chemical interferences are discussed. Specific calculations that estimate the sensitivity of the PF-LIF system for detecting NO2, NO3, and HNO2 are given.
Rodgers, M. O.↗
A technique for determining daytime atmospheric oxide above 50 km from backscattered ultraviolet measurements
Airglow from gamma band resonance fluorescence of nitric oxide near 255 nm is calculated at several solar zenith angles. Data from the Nimbus 4 BUV wavelengths 273.5 to 287.6 nm is used to estimate the Rayleigh and ozone scattering contributions to the BUV 255.5 nm data and the remaining signal is attributed to NO airglow. The low solar zenith angle contributions by NO is less than 0.5%, and the high latitude/high zenith angle contribution exceeds 5%. This technique allows for estimating NO content above 50 km, as well as partitioning that content between the mesosphere and thermosphere.
Guenther, R. D.↗
Radiative aspects of Antarctic ozone hole in 1985
In order to investigate the radiative heating effects of aerosols during September - October, 1985, at Antarctica, researchers solved the radiative transfer equation using a one-dimensional model, which includes the absorption of solar energy by water vapor, carbon dioxide, ozone and aerosols, the thermal emission and absorption by the above species and in addition, Rayleigh and Mie scattering, and the surface scattering effects. In this calculation, they used data of ozone density, water vapor density and aerosol extinction at 0.385, 0.453, 0.525 and 1.02 mu m in the stratosphere obtained by SAGE II satellite and meteorological data from NOAA. Results show that the Antarctic stratosphere is nearly in radiative equilibrium during that period, if the effects of aerosols are excluded. It is also shown that the heating effects of aerosols are too small to cause effective upward motions, in spite of some ambiguous parameters such as aerosol composition. The parameter dependences of results are also discussed.
Akiyoshi, H.↗
The far ultraviolet reflection spectrum of Uranus - Results from the Voyager encounter
The present analysis of the 1250-1700 A region Uranus spectrum obtained by Voyager's US spectrometer characterizes these observation results as due primarily to solar light reflected from an H2 Rayleigh and Raman scattering atmosphere with small but measurable hydrocarbon absorption. The hydrocarbon abundances obtained are substantially lower than those at comparable levels of the Saturn or Jupiter atmospheres; it is suggested, in one-dimensional terms, that this is due to diffusive separation, in conjunction with photochemical depletion caused by a very low eddy-diffusion coefficient. Strong latitudinal variations in the hydrocarbon abundances are suggested in the subsolar, polar stratosphere.
Yelle, Roger V.↗
Three-dimensional quantitative flow diagnostics
The principles, capabilities, and practical implementation of advanced measurement techniques for the quantitative characterization of three-dimensional flows are reviewed. Consideration is given to particle, Rayleigh, and Raman scattering; fluorescence; flow marking by H2 bubbles, photochromism, photodissociation, and vibrationally excited molecules; light-sheet volume imaging; and stereo imaging. Also discussed are stereo schlieren methods, holographic particle imaging, optical tomography, acoustic and magnetic-resonance imaging, and the display of space-filling data. Extensive diagrams, graphs, photographs, sample images, and tables of numerical data are provided.
Miles, Richard B.↗
Nonintrusive spectroscopic techniques for supersonic/hypersonic aerodynamics and combustion diagnostics
This paper presents an overview of the primary nonintrusive diagnostic techniques being developed by the NASA Langley Research Center to address the validation needs of Computational Fluid Dynamic (CFD) codes. The techniques include absorption in the UV and IR, Laser Induced Fluorescence, electron beam fluorescence, and a number of scattering techniques including Rayleigh, spontaneous Raman, and several coherent Raman spectroscopies. Most of the techniques are highly specialized, require complex data interpretation, and can satisfy only a few of the CFD needs. For these reasons, the evolving trend in flowfield diagnostics appears to favor a mode in which the diagnostic researcher, the experimental aerodynamicist, and the CFD community jointly define experiments based on the aeronautical requirements and on available diagnostic techniques.
Exton, R. J.↗
In situ detection of tropospheric OH and HO2 by laser-induced fluorescence in a detection chamber at low pressure
Just as in the method of Hard and O'Brien, ambient air is pulled through an approximately 1 mm diameter inlet into a detection chamber that is maintained at a pressure of 2.4 torr. The ambient air stream travels through the detection chamber with a velocity of greater than 100 m sec(exp -1) in a narrow stream, constrained by the addition of an inert gas flow (0.4 torr). The OH molecule is both excited and detected in the A(exp 2)Sigma (v' = 0) yields X(exp 2)II (v'' = 0) transition at 308 nm. Light from a copper vapor-pumped dye laser (rep. rate = 10kHz; pulse length = 20 ns; linewidth = .1 cm(exp -1), and average power = 15 mW), resonant with the Q(sub 1)(3) transition, is multipassed through a White cell and intercepts the air stream as 24 non-overlapping 2mm by 5mm beams. A fast microchannel plate detector is turned off during the laser pulse to prevent saturation of the detector due to Rayleigh and chamber scattering. It is turned on 30-100 nsec after the end of the laser pulse for 300 ns to collect resonance fluorescence from OH. HO2 is detected by chemical conversion to OH by reaction with reagent NO, followed by OH detection. Both the detection sensitivity and the inlet characteristics must be understood for any in situ instrument. For the calibration of the detection sensitivity, OH is produced quantitatively by the fast H + NO2 yields OH + NO reaction in a low pressure, flowing discharge tube connected to the detection chamber. The inlet transmission of OH inlet is calibrated separately.
Brune, William H.↗
Validation of Temperature Measurements from the Airborne Raman Ozone Temperature and Aerosol Lidar During SOLVE
The Airborne Raman Ozone, Temperature and Aerosol Lidar (AROTEL) participated in the recent Sage III Ozone Loss and Validation Experiment (SOLVE) by providing profiles of aerosols, polar stratospheric clouds (PSCs), ozone and temperature with high vertical and horizontal resolution. Temperatures were derived from just above the aircraft to approximately 60 kilometers geometric altitude with a reported vertical resolution of between 0.5 and 1.5 km. The horizontal footprint varied from 4 to 70 km. This paper explores the measurement uncertainties associated with the temperature retrievals and makes comparisons with independent, coincident, measurements of temperature. Measurement uncertainties range from 0.1 K to approximately 4 K depending on altitude and integration time. Comparisons between AROTEL and balloon sonde temperatures retrieved under clear sky conditions using both Rayleigh and Raman scattered data showed AROTEL approximately 1 K colder than sonde values. Comparisons between AROTEL and the Meteorological Measurement System (MMS) on NASA's ER-2 show AROTEL being from 2-3 K colder for altitudes ranging from 14 to 18 km. Temperature comparisons between AROTEL and the United Kingdom Meteorological Office's model showed differences of approximately 1 K below approximately 25 km and a very strong cold bias of approximately 12 K at altitudes between 30 and 35 km.
Burris, John↗
An Improved Retrieval of Tropospheric Nitrogen Dioxide from GOME
We present a retrieval of tropospheric nitrogen dioxide (NO2) columns from the Global Ozone Monitoring Experiment (GOME) satellite instrument that improves in several ways over previous retrievals, especially in the accounting of Rayleigh and cloud scattering. Slant columns, which are directly fitted without low-pass filtering or spectral smoothing, are corrected for an artificial offset likely induced by spectral structure on the diffuser plate of the GOME instrument. The stratospheric column is determined from NO2 columns over the remote Pacific Ocean to minimize contamination from tropospheric NO2. The air mass factor (AMF) used to convert slant columns to vertical columns is calculated from the integral of the relative vertical NO2 distribution from a global 3-D model of tropospheric chemistry driven by assimilated meteorological data (Global Earth Observing System (GEOS)-CHEM), weighted by altitude dependent scattering weights computed with a radiative transfer model (Linearized Discrete Ordinate Radiative Transfer), using local surface albedos determined from GOME observations at NO2 wavelengths. The AMF calculation accounts for cloud scattering using cloud fraction, cloud top pressure, and cloud optical thickness from a cloud retrieval algorithm (GOME Cloud Retrieval Algorithm). Over continental regions with high surface emissions, clouds decrease the AMT by 20- 30% relative to clear sky. GOME is almost twice as sensitive to tropospheric NO2 columns over ocean than over land. Comparison of the retrieved tropospheric NO2 columns for July 1996 with GEOS-CHEM values tests both the retrieval and the nitrogen oxide radical (NOx) emissions inventories used in GEOS-CHEM. Retrieved tropospheric NO2 columns over the United States, where NOx emissions are particularly well known, are within 18% of GEOS-CHEM columns and are strongly spatially correlated (r = 0.78, n = 288, p less than 0.005). Retrieved columns show more NO2 than GEOS-CHEM columns over the Transvaal region of South Africa and industrial regions of the northeast United States and Europe. They are lower over Houston, India, eastern Asia, and the biomass burning region of central Africa, possibly because of biases from absorbing aerosols.
Martin, Randall V.↗
Molecular-Based Optical Measurement Techniques for Transition and Turbulence in High-Speed Flow
High-speed laminar-to-turbulent transition and turbulence affect the control of flight vehicles, the heat transfer rate to a flight vehicle's surface, the material selected to protect such vehicles from high heating loads, the ultimate weight of a flight vehicle due to the presence of thermal protection systems, the efficiency of fuel-air mixing processes in high-speed combustion applications, etc. Gaining a fundamental understanding of the physical mechanisms involved in the transition process will lead to the development of predictive capabilities that can identify transition location and its impact on parameters like surface heating. Currently, there is no general theory that can completely describe the transition-to-turbulence process. However, transition research has led to the identification of the predominant pathways by which this process occurs. For a truly physics-based model of transition to be developed, the individual stages in the paths leading to the onset of fully turbulent flow must be well understood. This requires that each pathway be computationally modeled and experimentally characterized and validated. This may also lead to the discovery of new physical pathways. This document is intended to describe molecular based measurement techniques that have been developed, addressing the needs of the high-speed transition-to-turbulence and high-speed turbulence research fields. In particular, we focus on techniques that have either been used to study high speed transition and turbulence or techniques that show promise for studying these flows. This review is not exhaustive. In addition to the probe-based techniques described in the previous paragraph, several other classes of measurement techniques that are, or could be, used to study high speed transition and turbulence are excluded from this manuscript. For example, surface measurement techniques such as pressure and temperature paint, phosphor thermography, skin friction measurements and photogrammetry (for model attitude and deformation measurement) are excluded to limit the scope of this report. Other physical probes such as heat flux gauges, total temperature probes are also excluded. We further exclude measurement techniques that require particle seeding though particle based methods may still be useful in many high speed flow applications. This manuscript details some of the more widely used molecular-based measurement techniques for studying transition and turbulence: laser-induced fluorescence (LIF), Rayleigh and Raman Scattering and coherent anti-Stokes Raman scattering (CARS). These techniques are emphasized, in part, because of the prior experience of the authors. Additional molecular based techniques are described, albeit in less detail. Where possible, an effort is made to compare the relative advantages and disadvantages of the various measurement techniques, although these comparisons can be subjective views of the authors. Finally, the manuscript concludes by evaluating the different measurement techniques in view of the precision requirements described in this chapter. Additional requirements and considerations are discussed to assist with choosing an optical measurement technique for a given application.
Bathel, Brett F.↗
Modeling Relativistic Electron Precipitation Bremsstrahlung X-Ray Intensities at 10-100 km Manned Vehicle Altitudes
Relativisitic electron precipitation (REP) events occur when beams or bunches of relativistic electrons of magnetospheric origin enter the Earth's atmosphere, typically at auroral latitudes. REP events are associated with a variety of space weather effects, including production of transitional and bremsstrahlung radiation, catalytic depletion of stratospheric ozone, and scintillation of transionospheric radio waves. This study examines the intensities of x‐rays produced at airliner, manned balloon, and space reuseable launch vehicles (sRLVs). The monoenergetic beam is modeled in cylindrical symetry using the paraxial ray equation. Bremsstrahlung photon production is calculated using the traditional Sauter‐Elwert cross‐section, providing x‐ray emission spectra differential in energy and angle. Attenuation is computed for a plane‐stratified standard atmosphere, and the loss processes include photoionization, Rayleigh and Compton scattering, electron‐positron pair production, and photonuclear interaction. Peak altitudes of electron energy deposition and bremsstrahlung x‐ray production were calculated for beams of energies from 1 MeV through 100 MeV. The altitude peak of bremsstrahlung deposition was consistently and significantly lower that that of the electron deposition due to the longer mean free paths of x‐rays compared to electrons within the atmosphere. For example, for a nadir‐directed monoenergetic 5 MeV beam, the peak deposition altitude was calculated to be 42 km, but the resulting bremsstrahlung deposition peaked at 25 km. This has implications for crew and passenger safety, especially with the growth of the space tourism industry. A survey of results covering the 1‐100 MeV spectrum for the three altitude ranges of interest will be presented.
Krause, L. Habsh↗
A Fast and Sensitive New Satellite SO2 Retrieval Algorithm based on Principal Component Analysis: Application to the Ozone Monitoring Instrument
We describe a new algorithm to retrieve SO2 from satellite-measured hyperspectral radiances. We employ the principal component analysis technique in regions with no significant SO2 to capture radiance variability caused by both physical processes (e.g., Rayleigh and Raman scattering and ozone absorption) and measurement artifacts. We use the resulting principal components and SO2 Jacobians calculated with a radiative transfer model to directly estimate SO2 vertical column density in one step. Application to the Ozone Monitoring Instrument (OMI) radiance spectra in 310.5-340 nm demonstrates that this approach can greatly reduce biases in the operational OMI product and decrease the noise by a factor of 2, providing greater sensitivity to anthropogenic emissions. The new algorithm is fast, eliminates the need for instrument-specific radiance correction schemes, and can be easily adapted to other sensors. These attributes make it a promising technique for producing longterm, consistent SO2 records for air quality and climate research.
Principal component analysis↗