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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Mathematical Modeling of Hydroxide-Exchange-Membrane Water Electrolyzer

Water electrolyzers can transform intermittent renewable energy like solar energy and wind energy into the chemical energy of hydrogen with zero greenhouse-gas emissions. The hydroxide-exchange membrane electrolyzer (HEME) combines the capability to produce pressurized hydrogen with the advantage of being able to use low or non-platinum group metal (PGM) electrocatalysts in the alkaline environment.1 Hydroxide salts, for example, KOH, are added to the HEME water feed on both anode and cathode to improve its performance. However, the specific mechanism of performance improvement still needs to be further understood. In addition, at high current densities, bubble evolution can result in mass-transport limitations, a less well studied phenomena. Mathematical modeling is ideal to explore these issues as it is cost and time efficient and can deconvolute the physics, processes, and observed phenomena and study the applied-voltage breakdown. In this work, we extend our previously developed 1D two-phase continuum model2 to study the varies processes in the HEME and provide insights on performance optimizations. First, the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) kinetics at different hydroxide concentrations have been studied by rotating disk electrodes (RDE) and implemented in the model. Then, the model is calibrated and validated against experimental HEME polarization curves for different KOH concentrations as a liquid electrolyte. The model clearly shows a performance increase with increasing KOH concentrations, which is consistent with the experimental results. The reduced ohmic resistance and increased electrochemical active surface area (ECSA) are the two main reasons for performance increase. The large amount of hydroxide in the liquid electrolyte not only helps to distribute the reactant hydroxide throughout the catalyst layer (CL), which reduces ohmic loss, but also enables reaction at the interface between the liquid electrolyte and electrocatalyst, which increases the ECSA. Applied-voltage breakdown demonstrates that the electrolyzer performance is dominated by anode kinetics and ohmic loss. A comparison with the DI water feed shows a more uniform current distribution in the anode CL when KOH is added, which indicates a higher utilization of the CL. Second, we present modeling on the effects of bubble coverage. As gas evolves, part of the ECSA is minimized due to bubble coverage. To account for this effect, an empirical relationship between the fractional bubble coverage and the current density is implemented in the model.3 The model shows this bubble coverage effect is more pronounced at large current densities with DI water feed. Acknowledgements This work was funded under the HydroGEN Consortium by the Energy Efficiency and Renewable Energy, Hydrogen and Fuel Cell Technologies Office, of the U. S. Department of Energy under contract number DE-AC02-05CH11231. References R. Abbasi, B. P. Setzler, S. Lin, J. Wang, Y. Zhao, H. Xu, B. Pivovar, B. Tian, X. Chen, G. Wu and Y. Yan, 31, 1805876 (2019). L. N. Stanislaw, M. R. Gerhardt and A. Z. Weber, ECS Transactions, 92, 767 (2019). H. Vogt and R. J. Balzer, Electrochimica Acta, 50, 2073 (2005).

Liu, Jiangjin↗
NASA NTRS1987

TOMS: The Antarctic ozone hole and ozone trends

The Total Ozone Mapping Spectrometer (TOMS) instrument aboard Nimbus 7 has proved invaluable for the investigation of the recent rapid decline in the springtime total ozone over the Antarctic. The principle problem discussed is that of observing the atmosphere over long periods of time to determine whether or not trends and/or slow oscillations are taking place. Total ozone is an excellent summary parameter for the state of the stratosphere. It responds to temperature changes, and in the long term, is expected to respond to chemical changes. Thus, when changes take place in total ozone, such as the springtime Antarctic decrease it is a clear indication of an important problem, both because of environmental potential and scientific importance. TOMS is actually an overkill for this problem. Significantly more data is taken than is necessary. Tests have shown that maps produced on a 2 by 4 degree grid are essentially equivalent to those produced from the entire gridded data set. Because the critical aspect of the search for changes in ozone is continuous data, reflight of a polar orbiting TOMS is important. Included in the flight should be a stratospheric temperature sensor and, if possible, a modification to obtain some ozone altitude information. A critical aspect of the problem is timeliness of the data. This is the only drawback of the existing TOMS. It is expected that in the very near future the processing will be done within two weeks of real time. This is critical to the process of discovery of phenomena such as the Antarctic ozone hole.

Stolarski, Richard S.↗
DOE OSTI2022

Two-dimensional quantum universality in the spin-1/2 triangular-lattice quantum antiferromagnet Na 2 BaCo(PO 4 ) 2

An interplay of geometrical frustration and strong quantum fluctuations in a spin-1/2 triangular-lattice antiferromagnet (TAF) can lead to exotic quantum states. Here, we report the neutron-scattering, magnetization, specific heat, and magnetocaloric studies of the recently discovered spin-1/2 TAF Na 2 BaCo(PO 4 ) 2 , which can be described by a spin-1/2 easy axis XXZ model. The zero-field neutron diffraction experiment reveals an incommensurate antiferromagnetic ground state with a significantly reduced ordered moment of about 0.54(2) μ B /Co. Different magnetic phase diagrams with magnetic fields in the a b plane and along the easy c -axis were extracted based on the magnetic susceptibility, specific heat, and elastic neutron-scattering results. In addition, two-dimensional (2D) spin dispersion in the triangular plane was observed in the high-field polarized state, and microscopic exchange parameters of the spin Hamiltonian have been determined through the linear spin wave theory. Consistently, quantum critical behaviors with the universality class of d = 2 and ν z = 1 were established in the vicinity of the saturation field, where a Bose–Einstein condensation (BEC) of diluted magnons occurs. The newly discovered quantum criticality and fractional magnetization phase in this ideal spin-1/2 TAF present exciting opportunities for exploring exotic quantum phenomena.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Polarized Resonant X-ray Scattering to Measure Molecular Orientation and Conformation in Organic Nanostructures

The ordering of organic (carbon-based) molecules into nanostructures drives useful materials properties for applications such as organic light emitting diodes, flexible batteries, and polymer nanocarriers. However, there is a current lack of techniques to measure this ordering. X-ray scattering techniques involving molecular resonances have shown promise in identifying molecular types, locations, and orientation. However, resonant soft X-ray scattering (RSoXS) techniques have not been developed even lacking basic optical models. The objectives achieved by this research were the development of methods, models, and analysis techniques that harness these resonant phenomena in X-ray scattering measurements to quantitatively probe ordering of organic molecules within devices and nanostructures. This award resulted in 11 peer reviewed publications with two others soon to be submitted. New physical models for X-ray scattering that accurately describe these complex molecular resonances enable measurements of how molecules assemble, orient and conform at the nanometer scale. These new techniques were applied to both organic electronic devices and aqueous nanoparticles being developed for hydrocarbon sequestration. This new measurement capability will enable characterization of structure-property relationships that lead to disruptive technologies of printable, stretchable, and biocompatible devices based on organic materials.

14 SOLAR ENERGY↗
DOE OSTI2024

Laser-driven quasi-static B-fields for magnetized high-energy-density experiments

We present measurements of magnetic fields generated in laser-driven coil targets irradiated by laser pulses of nanosecond duration, 1.053 μm wavelength, 500 J energy, and ∼1015 W/cm2 intensity, at the LULI2000 facility. Using two perpendicular probing axes, proton deflectometry is used to characterize the coil current and static charge at different times. Results reveal various deflection features that can be unambiguously linked to a looping quasi-steady current of well-understood polarity or to a static charging of the coil surface. Measured currents are broadly consistent with predictions from a laser-driven diode-current source and lumped circuit model, supporting the quasi-steady assessment of the discharges. Peak magnetic fields of ∼50 T at the center of 500-μm-diameter coils, obtained at the moderate laser intensity, open up the use of such laser-driven coil targets at facilities worldwide to study numerous phenomena in magnetized high-energy-density plasmas, and its potential applications.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Mutual spin-phonon driving effects and phonon eigenvector renormalization in nickel (II) oxide

The physics of mutual interaction of phonon quasiparticles with electronic spin degrees of freedom, leading to unusual transport phenomena of spin and heat, has been a subject of continuing interests for decades. Despite its pivotal role in transport processes, the effect of spin-phonon coupling on the phonon system, especially acoustic phonon properties, has so far been elusive. By means of inelastic neutron scattering and first-principles calculations, anomalous scattering spectral intensity from acoustic phonons was identified in the exemplary collinear antiferromagnetic nickel (II) oxide, unveiling strong spin-lattice correlations that renormalize the polarization of acoustic phonon. In particular, a clear magnetic scattering signature of the measured neutron scattering intensity from acoustic phonons is demonstrated by its momentum transfer and temperature dependences. The anomalous scattering intensity is successfully modeled with a modified magneto-vibrational scattering cross-section, suggesting the presence of spin precession driven by phonon. The renormalization of phonon eigenvector is indicated by the observed “geometry-forbidden” neutron scattering intensity from transverse acoustic phonon. Importantly, the eigenvector renormalization cannot be explained by magnetostriction but instead, it could result from the coupling between phonon and local magnetization of ions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1993

Temperature and abundances in the Jovian auroral stratosphere. 2: Ethylene as a probe of the microbar region

Individual emission lines of ethylene (C2H4) near 10.5 micron were measured from the equatorial and north polar regions of Jupiter. Observations were made at a spectral resolution of 0.00083/cm using infrared heterodyne spectroscopy at the NASA Infrared Telescope Facility of Mauna Kea, Hawaii. The line shape information possible with this resolving power permitted the retrieval of quiescent ethylene abundances and the investigation of abundance and thermal structure variability in the polar auroral region. A rough distribution of the north polar emission as a function of longitude was obtained with an instantaneous field of view (full width at half maximum) of approximately 1 arc sec on the planet. The greatest C2H4 emission was observed near the nominal north polar methane hot spot (60 deg N, 180 deg longitude, System III, 1965). It was found to be confined to less than 10 deg longitude on the planet. Using a Voyager-derived thermal profile, retrieved ethylene mole fractions for equatorial and north polar quiescent (non-hot spot) regions were consistent with results from existing photochemical models. At the hot spot an 18-fold increase in abundance was required near the 10-microbar level to reproduce the data. Alternatively varying the stratospheric thermal profile, a 67-137 K increase in temperature was required at the approximately 10-microbar level to satisfy the observed emission, if the C2H4 mole fraction is fixed to the quiescent value. These results provide the first direct probe of the upper stratosphere of Jupiter and give upper limits to the temperature increase near the source of the north polar thermal infrared aurora. Combined with results from similar measurements of auroral ethane emission (Livengood et al., this issue) probing the 1-mbar region, altitude information on the thermal structure can be obtained for the first time. The ethylene line emission region extends to the few microbar pressure level and may overlap the region where the H2 ultraviolet aurora is formed; thus it can be used as a probe of the coupling between the ultraviolet and thermal infrared phenomena.

Kostiuk, Theodor↗
NASA NTRS1973

Millimeter wavelength observations of solar active regions

Polarization properties of active regions at 9 mm are discussed, and the observed degree of polarization is used to obtain an estimate of chromospheric magnetic fields. Also discussed is the polarization structure at 9 mm of an active region that produced a minor flare around 1900 UT on September 28, 1971. Total power observations indicate that new regions develop, or weak regions intensify at millimeter wavelengths as a result of bursts at distant sites. The spectra of the peak flux density of moderately strong bursts observed at 9 mm show a sharp drop toward the shorter millimeter wavelengths. The weak bursts at 3.5 mm are manifest mainly as heating phenomena.

Kundu, M. R.↗
NASA NTRS1981

The aurora - An electrical discharge phenomenon surrounding the earth

An attempt to model the processes underlying the appearance of auroral phenomena as a chain of events beginning with power production and resulting in auroral light emissions is presented. Power is produced by the interaction of the solar wind with the earth magnetosphere, creating a dynamo effect which is a function of the solar wind speed and the magnitude and orientation of the solar wind magnetic field. The dynamo power generates the convective motion of magnetospheric plasma, and subsequent magnetic-field aligned currents communicate the dynamo power to the polar ionosphere. The currents close as Pederson currents, and the associated Lorentz force accelerates the ionosphere in the direction of the convective motion. An electric potential structure develops at a few thousand km height, forcing current-carrying electrons to flow down the field lines to the ionosphere, where interactions with atmospheric constituents create auroral displays.

Akasofu, S.-I.↗
NASA NTRS1995

The solar/interplanetary event of 14 April 1994 observed by Yohkoh/SXT

The polar crown event of April 14 1994 is one of the largest scale eruptive events observed by the Yohkoh/SXT. Associated with the formation of an arcade of soft X-ray loops at the Sun was the detection of an interplanetary forward/reverse shock event by the Ulysses spacecraft some 4-7 days later. The relationship between the coronal and interplanetary signatures of these events is important if we are to address fully the initialization and consequent acceleration of interplanetary phenomena, such as CMEs and counter-streaming electrons, originating at the Sun. From detailed analysis of the energetics of the arcade formed during the eruption of April 14 1994, we find peak temperatures and emission measures of approximately 5MK and approximately 10(exp 48)cm(exp -3) respectively. The total thermal content of the arcade loop structure observed in soft X-rays is calculated to be some 5 x 10(exp 29) ergs. The development of these parameters as the event proceeds and their relationship to the dynamics of the eruption are investigated. Although spanning a longitudinal range of some 150 degrees the April 14 event displayed the typical helmet streamer structure normally associated with coronal mass ejections These helmet streamers are thought to be related to the global solar magnetic field through the heliospheric current sheet (HCS). The arcade formation, together with the eruption of material into interplanetary space, signifies a large-scale reconfiguration of the coronal magnetic field. We examine the effects of the formation of such a coronal arcade structure on the HCS and discuss the dynamics involved with the passage of a large scale disturbance through the interplanetary magnetic field.

Alexander, D.↗
DOE OSTI2025

Enhanced ferromagnetism in monolayer Cr 2 Te 3 via topological insulator coupling

Exchange-coupled interfaces are pivotal in exploiting two-dimensional (2D) ferromagnetism. Due to the extraordinary correlations among charge, spin, orbital and lattice degrees of freedom, layered magnetic transition metal chalcogenides (TMCs) bode well for exotic topological phenomena. Here we report the realization of wafer-scale Cr 2 Te 3 down to monolayer (ML) on insulating SrTiO 3 (111) and/or Al 2 O 3 (001) substrates using molecular beam epitaxy. Robust ferromagnetism persists in the 2D limit. In particular, the Curie temperature T C of 2 ML Cr 2 Te 3 increases from 100 K to ∼120 K when proximitized to topological insulator (TI) (Bi,Sb) 2 Te 3 , with substantially boosted magnetization as observed via polarized neutron reflectometry. Our experiments and theory strongly indicate that the Bloembergen–Rowland interaction is likely universal underlying T C enhancement in TI-coupled magnetic heterostructures. The topological-surface-enhanced magnetism in 2D TMC enables further exchange coupling physics and quantum hybrid studies, including paving the way to realize interface-modulated topological electronics.

36 MATERIALS SCIENCE↗
NASA NTRS1972

The use of the three dimensional coherency matrix in analyzing the polarization properties of plane waves

A technique for analyzing the polarization properties of plane waves is developed which offers a number of advantages over methods currently used in the analysis of both ground and satellite observations of waves. This technique reduces the computations required to find the wave normal vector, is less sensitive to common noise sources, and is amenable to analog implementation. This technique is applied specifically to the analysis of a proton whistler, but may also be used in most studies of ULF, ELF, and VLF magnetic wave phenomena.

Means, J. D.↗
NASA NTRS2000

In-Situ Environmental Measurements Needed for Future Mars Missions

Existing measurements and modeling studies indicate that the climate and general circulation of the thin, predominately CO2 Martian atmosphere are characterized by large-amplitude variations with a wide range of spatial and temporal scales. Remote sensing observations from Earth-based telescopes and the Mariner 9, Viking, Phobos, and Mars Global Surveyor (MGS) orbiters show that the prevailing climate includes large-scale seasonal variations in surface and atmospheric temperatures (140 to 300 K), dust optical depth (0.15 to 1), and water vapor (10 to 100 precipitable microns). These observations also provided the first evidence for episodic regional and global dust storms that produce even larger perturbations in the atmospheric thermal structure and general circulation. In-situ measurements by the Viking and Mars Pathfinder Landers reinforced these conclusions, documenting changes in the atmospheric pressure on diurnal (5%) and seasonal (>20%) time scales, as well as large diurnal variations in the near-surface temperature (40 to 70 K), wind velocity (0 to 35 m/s), and dust optical depth (0.3 to 6). These in-situ measurements also reveal phenomena with temporal and spatial scales that cannot be resolved from orbit, including rapid changes in near-surface temperatures (+/- 10 K in 10 seconds), large near-surface vertical temperature gradients (+/- 15 K/meter), diurnally-varying slope winds, and dust devils . Modeling studies indicate that these changes are forced primarily by diurnal and seasonal variations in solar insolation, but they also include contributions from atmospheric thermal tides, baroclinic waves (fronts), Kelvin waves, slope winds, and monsoonal flows from the polar caps.

Crisp, D.↗
NASA NTRS1987

The origin of rigidly rotating magnetic field patterns on the sun

Using analytical calculations and numerical simulations, it is shown that a meridional component of magnetic-flux transport will offset the shearing effect of differential rotation and give rise to rigidly rotating patterns of large-scale magnetic field. The nonaxisymmetric field attains a striped polarity pattern which rotates rigidly like a barber pole while its individual small-scale flux elements rotate at the differential rate of the latitudes they are crossing. On the sun, the meridional transport is provided by supergranular diffusion possibly assisted by a small poleward flow. New sources of flux retard this process and exclude the rigid rotation from the sunspot belts until well into the declining phase of the sunspot cycle. This mechanism accounts for a number of heretofore unexplained phenomena including the tendency for coronal holes to rotate rigidly during the declining phase of the sunspot cycle.

Sheeley, N. R., Jr.↗
NASA NTRS1990

Earth observations during Space Shuttle mission STS-28 - 8-13 August 1989

An overview of the STS-28 earth observation is provided with attention given to meteorology, oceanographic phenomena, and human activity such as urban environments and related land uses. Environmental observations discussed include evidence of a monsoon, vegetation changes such as deforestation, and water pollution and eutrophication of major rivers. Particular attention is paid to atmospheric palls in both the Northern and Southern Hemispheres. Discussion of geological observations focuses on the Mount St. Helens volcano and the little-recognized landform type, the immense illuvial cone. Observation techniques include use of color infrared film and two types of polarization observations.

Whitehead, Victor S.↗
NASA NTRS1995

Velocity variation in the high-latitude solar wind

The Ulysses spacecraft has been observing the properties of the high-latitude solar wind during a period of declining and minimum solar activity when the Sun displayed well-developed polar coronal holes. Poleward of approximately 40 deg, Ulysses remained continuously within the flow from the polar coronal hole. All was not quiet within that flow, however. In addition to coronal mass ejections seen at latitudes as high as 60 deg, there were mini-high velocity streams with amplitudes as large as 100 km/s and well developed compression regions on their leading edges and there were large-amplitude Alfven waves. The alpha-particles participate in the mini-stream variations, but not in the Alfven waves, which provides a method of separating the two phenomena. The duration of the mini-streams was typically a few days whereas the periods of the Alfven waves were usually less than 12 hours. Other properties of the mini-streams will be summarized.

Neugebauer, M.↗
NASA NTRS1981

Dynamics of the outer radiation belts in relation to polar substorms and hot plasma injections at geostationary altitude

Geostationary satellite and ground measurements of dynamic variations of the outer radiation belts and their relations with the development of auroral structures during magnetospheric substorms are analyzed. A comparison of measurements of the H or X geomagnetic field components made by seven auroral stations with ATS-6 low-energy and high-energy particle measurements during the multiple-onset substorm of Aug. 16, 1974 is presented which demonstrates that while the decrease in energetic particle fluxed ends only at the time of a strong substorm onset, rapid motions of the outer radiation belts may occur during the flux decrease. All-sky photographs of auroral phenomena taken at Fort Yukon and College, Alaska are then compared with ATS-1 energetic particle flux measurements in order to demonstrate the relation between flux decreases and increases and distinct substorm phases. Results support the hypothesis of a magnetospheric substorm precursor which appears to be an instability growing at the inner boundary of the plasma layer and approaching the earth, and underline the importance of current and magnetic field variations in charged particle dynamics.

Sauvaud, J. A.↗
DOE OSTI2021

High yield polar direct drive fusion neutron sources at the National Ignition Facility

Polar direct drive neutron source experiments were performed at the National Ignition Facility showing substantial improvement in total neutron yield and efficiency of conversion of laser energy to fusion output. Plastic capsules 3–4 mm in diameter were filled with 1.5 mg/cc of deuterium–tritium (DT) fuel and imploded with laser beam pointing and defocus designed to compensate for polar asymmetry introduced by the facility beam entrance angles. Radiation-hydrodynamics simulations were employed to optimize the multi-dimensional laser and target parameter space, within facility and target fabrication constraints. Ensembles of 1D simulations tuned to match the outputs of early shots in the series were used to design subsequent shots in the series. This allowed the later shots to be designed based on empirically motivated sensitivities to laser and target input parameters, while eliminating the need to explicitly model phenomena such as hydrodynamic instabilities and nonlinear laser–plasma interactions. Additionally, one experiment with a 3.0 mm diameter CH capsule produced 13.6 kJ (4.81 × 10 15 DT neutrons) from a laser input below the NIF optics damage threshold at 585 kJ, 328 TW. Two experiments with 4.0 mm capsules produced 31.3 and 33.6 kJ of fusion output (1.11 × 10 16 and 1.19 × 10 16 DT neutrons) with 1.10 MJ, 390 TW and 1.26 MJ, 425 TW of laser input, respectively.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗