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NASA NTRS1990

Shocked forbidden O I 63 micron line emission from the supernova remnant IC 443

Observations of the fine-structure emission from the forbidden O I 63 micron line in the SNR IC 443 are presented. It is shown that the emission correlates well with the distribution of line emission from shock-excited molecular hydrogen, which leads to the conclusion that the line is shock-excited. X-ray heating as well as UV-heating from a photodissociation region is ruled out as a possible excitation mechanism for the emission. It is shown that the forbidden O I 63 micron line is an important contributor to the total emission in the IRAS 60 micron band, estimated as approximately 40-75 percent of the total band flux. An attempt to shock model the line emission from IC 443 is made; however, to match the observational evidence, it has to be assumed that the shock is J-type, and that the oxygen chemistry is suppressed so that oxygen remains in atomic form and does not get converted into H2O. However, no theoretical rationale for these assumptions can be provided.

Burton, Michael G.↗

NASA NTRS1990

Ground and lower excited states of methyl peroxy, CH3O2, radical - A computational investigation

The ground and lower excited states of methyl peroxy, CH3O2, radical have been investigated at the selected pseudofirst-order configuration interaction level by use of a double-zeta basis set. Selected singles and doubles calculations using a polarized double-zeta basis have been carried out on the two lowest states in the A-double prime symmetry. Dissociation energies with respect to CH3O2 yields CH3 + O2 and CH3O + O are computed to be 2.01 and 3.37 eV, respectively. Curve crossings between various states and photodissociation products are discussed and the dipole moment along various slices through the potential energy surface is evaluated.

Jafri, Jawed A.↗

NASA NTRS1990

Far-infrared spectroscopy of the DR 21 star formation region

Far-IR line and continuum observations of the DR 21 star formation region are presented. It is shown that the extended emission in the 63 micron forbidden O I, 35 micron forbidden Si II, and 158 micron forbidden C II lines is most likely produced in dense, warm photodissociation regions on the surfaces of atomic and molecular clumps of size smaller than 0.6 pc. The gas temperatures in these photoelectrically heated, predominantly atomic layers are 250-500 K and are maintained by FUV fluxes 10,000 or more times the average interstellar radiation field. Gas densities in the surface layers are in the range 10,000-50,000/cu cm. The gas phase abundance of Si(+) is inferred to be about 5 x 10 to the -6th relative to hydrogen, or about 0.15 of its solar abundance. The mass of atomic gas is at least 200 solar masses.

Lane, Adair P.↗

NASA NTRS1990

Far-infrared spectroscopy of NGC 6946, IC 342, and Arp 299

Researchers investigated the physical conditions in the infrared bright galaxies NGC 6946, IC 342, and Arp 299 through measurements of far-infrared emission lines from Si II, O I, C II, and O III using the facility Cooled Grating Spectrometer on the Kuiper Airborne Observatory. These data are interpreted using our theoretical models for photodissociation regions and H II regions. For the central 45 inches of these galaxies, researchers determined that the dominant excitation mechanism for the far infrared radiation (FIR) lines is far ultraviolet radiation (FUR) radiation from young stars, and the authors derived the total mass, density, and temperature of the warm atomic gas and the typical sizes, number densities, and filling factors for the interstellar clouds.

Lord, Steven D.↗

NASA NTRS1989

The evolution of organic mantles on interstellar grains

By laboratory simulation of the chemical processes on dust grains it was investigated how solid organic materials can be produced in the interstellar medium. The ice mantles that accrete on grains in molecular clouds, consisting primarily of H2O, CO, H2CO, NH3, and O2, are irradiated by the internal UV field, resulting in the storage of radicals upon photodissociation of the original molecules. Transient heating events lead to the production of oxygen-rich organic species by recombination reactions. The experiments indicated that in this way the observed amount of organic material can be produced if a grain passes a few times through a molecular cloud during its life. After the destruction of the cloud the grains enter a more diffuse medium. Here they are subjected to the interstellar UV field as well as to collisions with atomic hydrogen. Experiments show that the intense photoprocessing results in the removal of small species like H2O and NH3 as well as in carbonization of the organic molecules. Contrary to this, the atomic H flux will maintain a certain hydrogen level in the mantle. These processes likely convert the original, oxygen-rich organics into an unsaturated hydrocarbon type material such as that observed towards IRS 7 and in Comet Halley grains.

Schutte, Willem A.↗

NASA NTRS1990

The 158 micrometer (CII) line: A measure of global star formation activity in galaxies

Some 158 micron (CII) fine structure line observations from a sample of fourteen gas rich galaxies are reported. These measurements confirm and generalize previous basic results that the (CII) line is bright amounting to approximately 0.1 to 1 percent of the Far Infra Red (FIR) luminosity of the nuclear regions of galaxies; the (CII) line is formed in the warm (temperature of the gas is greater than 200 K), dense (n sub H greater than 1000/cu cm) photodissociated gas at the interfaces between giant molecular clouds and ionized gas regions and is therefore associated with the molecular gas component in spiral galaxies; the (CII) line tracks the FIR continuum in a manner consistent with the PDR models; the integrated (CII) to isotope (12)CO (transition 1 to 0) line ratio is large (greater than or equal to 1000) in all galaxies studied, and is similarly large for galactic molecular clouds; the (CII) line is therefore energetically very important for the study of giant molecular clouds. Conclusions obtained from these results are given.

Stacey, G. J.↗

NASA NTRS1991

High resolution infrared astronomy satellite observations of a selected spiral galaxy

The H I, infrared, CO, H alpha and H beta band observations of M51, the prototypical grand-design spiral galaxy, are used to study the consequences of star formation for the distribution of H I and dust. Using the new Very Large Array (VLA) map of 21 cm emission, the Owens Valley Radio Observatory CO mosaic map, and an H alpha imate, new tests were performed with the idea of Tilanus and Allen that the H I is largely a photodissociation product in star-forming regions. It is confirmed that the H I spiral arms are generally coincident with the H II region arms, and offset downstream from the CO arms. The radial distributions of total gas, H alpha and H I surface density have a simple explanation in the dissociation picture. The distributions also demonstrate how the surface density of H I might be related to the star formation efficiency in molecule-rich galaxies. The large width of the H I regions along the arms compared to that of the giant H II regions can be understood in terms of a simple calculation of the expected size of an H I region associated with a typical giant H II region. The longer lifetime of the stars producing dissociating radiation vs. those producing ionizing radiation and the relatively long molecular formation timescale will also contribute to the greater width of the H I arms if stars are continuously forming on the arms. The lack of detailed coincidence of the H I and H II regions along the inner arms has a variety of possible explanations. Two simple tests were performed to probe the origins of the IRAS emission in M51. First, it was found that the infrared excess (IFE) of M51 is 24, suggesting that a substantial fraction of the infrared emission arises from dust heated by photons which do not originate in massive star-formaing regions. Second, radial cuts through the IRAS bands show that at 12, 25, and 60 microns, the arm-interarm contrast of the IRAS emission is substantially less than that of the H alpha emission, providing further evidence for the explanation and for the existence of a broadly distributed dust component. Deconvolved IRAS maps have improved resolution but do not change this finding.

Kulkarni, S. R.↗

NASA NTRS1990

Observations of CH in comets P/Brorsen-Metcalf and P/Halley

A common feature in the visual spectra of comets is the A squared delta - chi squared pi transition of CH at 4314 A (delta v = 0). This feature is very weak and is easily lost in the continuum or noise. However, the oscillator strength is very small, so even a weak feature indicates a large amount of CH. Understanding the parent of the CH in the comae of comets is very important for understanding the chemistry of comets and, thus, the early solar nebula. Potential parents for the CH are CH4 or more complex hydrocarbons, including polyoxy methanes (POMs). The ratio of CH4 to H2O is indicative of possible sites of formation of the comets. Past observations of comets have shown that the CH is present in the coma. However, because of the intrinsic weakness of the feature and the ease of photodissociating CH, the distribution of the CH in the coma has only been traced in the inner coma, where the fall-off is still 1/p, where p is the impact parameter. The first data sets tracing the distribution of CH to large distances from the nucleus in two comets is presented. Some preliminary models are presented pertaining to the parent of the CH.

Cochran, Anita L.↗

NASA NTRS1990

Modeling the dust size distribution in comets with dust fragmentation

A hydrodynamic model was developed of a spherically symmetric dusty gas flow in a cometary atmosphere assuming a single fluid, inviscid, perfect gas. The hydrodynamics for gas and dust, which involves the gas drag force (momentum transfer), heat exchange between gas and dust, photodissociation energy for H2O gas, and radiative heating and cooling terms for dust particles, are solved using the Gear method for stiff, coupled differential equations. Calculations were done with a dust size distribution for radii alpha = 0.01 micron to 10 cm with densities variable with the size. A nucleus size of 4.0 km radius with a density of 0.5 g/cu cm and a total dust-to-gas mass ratio chi = 1 was adopted. There are indications from in situ observations that dust particle fragment into smaller ones. Fragmentation of dust particles was incorporated into the model. This is done by adding source and sink terms in the continuity equations for the dust. Lifetimes for the decay of dust particles were assumed as a function of particle size. It is also assumed that dust particles always fragment only into the next smaller size.

Konno, Ichishiro↗

NASA NTRS1990

A multigenerational Monte Carlo model of a comet coma

A steady state multigenerational Monte Carlo model was developed to describe the distribution of a neutral coma species which was produced after several photodissociation steps. This distribution can be compared with either line profiles derived from long slit spectroscopic observations or narrow band imaging, and be used to determine the elemental abundances present in the comet coma. A Monte Carlo model was chosen due to limitations in standard forms of more analytic models, such as those of Haser and Festou. In contrast to the analytical models, the Monte Carlo method can be modified to include new physical parameters.

Ferro, Anthony J.↗

NASA NTRS1991

Nonequilibrium radiation and chemistry models for aerocapture vehicle flowfields, volume 2

A technique was developed for predicting the character and magnitude of the shock wave precursor ahead of an entry vehicle and the effect of this precursor on the vehicle flow field was ascertained. A computational method and program were developed to properly model this precursor. Expressions were developed for the mass production rates of each species due to photodissociation and photoionization reactions. Also, consideration was given to the absorption and emission of radiation and how it affects the energy in each of the energy modes of both the atomic and diatomic species. A series of parametric studies were conducted covering a range of entry conditions in order to predict the effects of the precursor on the shock layer and the radiative heat transfer to the body.

Carlson, Leland A.↗

NASA NTRS1989

The UV photochemistry of C2N2

The absorption, emission, and photodissociation yield spectra of C2N2 were measured in the 220 and 210 nm region near the 4(0)1 and 1(0)1 4(0)1 bands of the A 1 sigma + from the X 1 sigma + system. The emission spectrum showed very few lines which appeared in the absorption spectrum. Moreover, the emission had 660 ns lifetime and, at 210 nm a very large electronic emission quenching rate. Laser induced fluorescence was used to measure the relative yield of CN radicals as a function of photolysis wavelength. This spectrum seemed to follow the absorption spectrum below the dissociation threshold. Energy in the CN fragments appeared to be statistically distributed.

Halpern, Joshua B.↗

NASA NTRS1989

XeCl laser pumped iodine laser using t-C4F9I

An iodine photodissociation laser using t-C4F9I as the active material was pumped by an XeCl laser. An iodine laser output energy of 3 mJ with pulse duration of 25 ns was obtained when the pumping pulse energy was 80 mJ, the iodide pressure was 70 torr, and the reflectance of the output mirror was 85 percent. The high pumping efficiency and low threshold pump power achieved in this experiment are attributable to the high absorption cross section at the pump laser wavelength (308 nm) of the iodide used.

Hwang, In Heon↗

NASA NTRS1990

On the fragmentation of protogalactic clouds

After its initial collapse, a protogalactic cloud is expected to be shock heated to its virial temperature of about 1 million K. This temperature lies near a very unstable region of the cooling curve, so that density enhancements will be expected to grow rapidly as the protogalaxy cools to lower temperatures. In this contribution, the dynamical effects on the growth of perturbations are examined. It is shown that perturbations with large initial amplitudes lead to the formation of H2, which results in rapid cooling to 100 K, and the formation of population III stars. Perturbations with small initial amplitudes, however, do not cool significantly ahead of the background, do not develop strong contrasts with the background, and so cannot induce the formtion of H2. They thus remain near 10,000 K, forming a population of protoclusters with masses of about 10 to the 7th solar masses, somewhat larger than typical globular cluster masses. Contamination by metals from a primordial generation of stars may lead to cooling and a significant reduction of the Jeans mass. Photodissociation induced by a background source of hard photons can also prevent cooling below 10,000 K, enhancing the formation of protoclusters relative to stars.

Murray, Stephen D.↗

NASA NTRS1990

Atmospheric emissions and trends of nitrous oxide deduced from 10 years of ALE-GAGE data

Long-term measurements of nitrous oxide (N2O) obtained during the Atmospheric Lifetime Experiment (ALE) and the Global Atmospheric Gases Experiment (GAGE) for a period from 1978 to 1988 are presented and interpreted. It is observed that the average concentration in the Northern Hemisphere is 0.75 +/- 0.16 ppbv higher than in the Southern Hemisphere and that the global average linear trend in N2O lies in the range from 0.25 to 0.31 percent/year. The measured trends and latitudinal distributions are shown to be consistent with the hypothesis that stratospheric photodissociation is the major atmospheric sink for N2O, while the cause of the N2O trend is suggested to be a combination of a growing tropical source and a growing Northern mid-latitude source. A 10-year average global N2O emission rate of (20.5 +/- 2.4) x 10 to the 12th g N2O/year is deduced from the ALE/GAGE data.

Prinn, R.↗

NASA NTRS1990

Interpretation of aircraft measurements of NO, ClO, and O3 in the lower stratosphere

Results are presented from an October 17, 1988, flight of the NASA ER-2 stratospheric research aircraft. The flight sampled a nearly constant air mass at 20 km altitude, near 39 deg N latitude, from before sunrise until near noon. The instrumentation on board simultaneously measured NO, ClO, O3, temperature, and pressure. The measurements are combined with modeled photodissociation coefficients and known reaction kinetics to infer abundances of other important species, and the results are compared to previous estimates as a test for consistency in the understanding of the photochemical processes governing the species distributions.

Kawa, S. R.↗

NASA NTRS1990

Formation of ozone by irradiation of oxygen at 248 nanometers

While Slanger et al. (1988) have reported that the 248-nm KrF laser radiation generates ozone from oxygen, despite this wavelength's exceeding of the conventionally accepted photodissociation threshold of 242.4 for the ground electronic state, the initiating mechanism for this ozone formation remains obscure. It is presently suggested that the initiating step is the absorption of the 248-nm radiation by O2. In a reply to the present authors, Slanger et al. indicate that their original experiment should have been performed by introducing pure O2 into a baked cell, with the start time defined by the unblocking of the 248-nm laser.

Freeman, D. E.↗

NASA NTRS1991

A new spherical model for computing the radiation field available for photolysis and heating at twilight

Accurate computation of atmospheric photodissociation and heating rates is needed in photochemical models. These quantities are proportional to the mean intensity of the solar radiation penetrating to various levels in the atmosphere. For large solar zenith angles a solution of the radiative transfer equation valid for a spherical atmosphere is required in order to obtain accurate values of the mean intensity. Such a solution based on a perturbation technique combined with the discrete ordinate method is presented. Mean intensity calculations are carried out for various solar zenith angles. These results are compared with calculations from a plane parallel radiative transfer model in order to assess the importance of using correct geometry around sunrise and sunset. This comparison shows, in agreement with previous investigations, that for solar zenith angles less than 90 deg adequate solutions are obtained for plane parallel geometry as long as spherical geometry is used to compute the direct beam attenuation; but for solar zenith angles greater than 90 deg this pseudospherical plane parallel approximation overstimates the mean intensity.

Dahlback, Arne↗