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At least 595 records · Page 33

In situ liquid SIMS analysis of uranium oxide

Trace analysis of nuclear materials in solid particles collected in the environment or particles in liquid slurry generated in nuclear material manufacturing processes can pinpoint elemental, organic, and isotopic signatures of nuclear fuel cycle activities and processes. Such information can support nuclear safeguards programs by increasing our ability to detect undeclared nuclear materials, routine activities for safeguarding at declared facilities, and illicit activities. However, trace radioactive material analysis in liquids and slurries is challenging using bulk approaches. For example, one drawback of sensitive analysis such as inductively coupled plasma mass spectrometry (ICP-MS) is that sample is consumed or destroyed as a result of the technical approach. We developed a vacuum compatible microfluidic interface to enable surface analysis of liquids and liquid-solid interactions using time-of-flight secondary ion mass spectrometry (ToF-SIMS). In this work, we illustrate initial results of liquid standards containing uranium using in situ liquid SIMS. Specifically a series of diluted uranium standards used for ICPMS analysis were studied and the limit of detection was estimated. Since the liquid SIMS analysis is almost nondestructive, the same sample can be analyzed by other more destructive approaches afterwards or saved for future references. Consequently, multimodal analysis is possible. Our results demonstrate that in situ liquid SIMS can be used as a new approach to analyze radioactive materials in liquid and slurry forms of relevance to the IAEA safeguards missions.

In situ liquid ToF-SIMS, uranium, limit of detecti↗

Particle Acceleration and Associated Emission from Relativistic Shocks

Five talks consist of a research program consisting of numerical simulations and theoretical development designed to provide an understanding of the emission from accelerated particles in relativistic shocks. The goal of this lecture is to discuss the particle acceleration, magnetic field generation, and radiation along with the microphysics of the shock process in a self-consistent manner. The discussion involves the collisionless shocks that produce emission from gamma-ray bursts and their afterglows, and producing emission from supernova remnants and AGN relativistic jets. Recent particle-in-cell simulation studies have shown that the Weibel (mixed mode two-stream filamentation) instability is responsible for particle (electron, positron, and ion) acceleration and magnetic field generation in relativistic collisionless shocks. 3-D RPIC code parallelized with MPI has been used to investigate the dynamics of collisionless shocks in electron-ion and electron-positron plasmas with and without initial ambient magnetic fields. In this lecture we will present brief tutorials of RPIC simulations and RMHD simulations, a brief summary of recent RPIC simulations, mechanisms of particle acceleration in relativistic shocks, and calculation of synchrotron radiation by tracing particles. We will discuss on emission from the collisionless shocks, which will be calculated during the simulation by tracing particle acceleration self-consistently in the inhomogeneous magnetic fields generated in the shocks. In particular, we will discuss the differences between standard synchrotron radiation and the jitter radiation that arises in turbulent magnetic fields.

Nishkawa, Ken-Ichi↗

Investigation of new superconducting materials for the next generation high-performance RF superconducting cavities for particle accelerators

In this DOE-funded project DE-SC0010081-020 Old Dominion University (ODU) in collaboration with University of Wisconsin (UW) and Jefferson Laboratory have investigated both experimentally and theoretically electromagnetic response and losses in multilayered superconducting structures made of new SRF materials which can push the field and Q performance limits of accelerating cavities.

43 PARTICLE ACCELERATORS↗

Force Balance and Substorm Effects in the Magnetotail

A model of the quiet time middle magnetotail is developed using a consistent orbit tracing technique. The momentum equation is used to calculate geocentric solar magnetospheric components of the particle and electromagnetic forces throughout the current sheet. Ions generate the dominant x and z force components. Electron and ion forces almost cancel in the y direction because the two species drift earthward at comparable speeds. The force viewpoint is applied to a study of some substorm processes. Generation of the rapid flows seen during substorm injection and bursty bulk flow events implies substantial force imbalances. The formation of a substorm diversion loop is one cause of changes in the magnetic field and therefore in the electromagnetic force. It is found that larger forces are produced when the cross-tail current is diverted to the ionosphere than would be produced if the entire tail current system simply decreased. Plasma is accelerated while the forces are unbalanced resulting in field lines within a diversion loop becoming more dipolar. Field lines become more stretched and the plasma sheet becomes thinner outside a diversion loop. Mechanisms that require thin current sheets to produce current disruption then can create additional diversion loops in the newly thinned regions. This process may be important during multiple expansion substorms and in differentiating pseudoexpansions from full substorms. It is found that the tail field model used here can be generated by a variety of particle distribution functions. However, for a given energy distribution the mixture of particle mirror or reflection points is constrained by the consistency requirement. The study of uniqueness also leads to the development of a technique to select guiding center electrons that will produce charge neutrality all along a flux tube containing nonguiding center ions without the imposition of a parallel electric field.

Kaufmann, Richard L.↗

Critical electron pitch angle anisotropy necessary for chorus generation

Simultaneous wave, resonant-particle, and ambient-plasma data from OGO 5 for chorus emissions on August 15, 1968, were found consistent with the theoretical critical pitch-angle-anisotropy condition for whistler-mode instability by Doppler-shifted electron cyclotron resonance. Local generation, as determined by wave normal measurements, occurred only when the pitch-angle anisotropy of resonant electrons required for instability substantially exceeded the critical anisotropy defined by Kennel and Petschek (1966).

Burton, R. K.↗

Simulation of pitch angle diffusion of charged particles in a disordered magnetic field

Results are reported for computer simulation experiments in which a statistical ensemble of random magnetic field realizations is generated, orbits of charged particles in the random fields are followed, and a pitch-angle diffusion coefficient is derived from the temporal evolution of the orbits. Diffusion coefficients predicted by three nonlinear theories are compared with the derived coefficients for the standard quasilinear theory of velocity diffusion, and the goals of future simulations are outlined.

Kaiser, T. B.↗

Electrostatically Enhanced Vortex Separator

Proposed device removes fine particles from high-pressure exhaust gas of chemical reactor. Negatively charged sectors on rotating disks in vortex generator attracts positively charged particles from main stream of exhaust gas. Electrostatic charge enhances particle-separating action of vortex. Gas without particles released to atmosphere.

Collins, Earl R.↗

Very Narrow Coronal Mass Ejections Producing Solar Energetic Particles

Aims. Our main aim is to study the relationship between low-energy solar particles (energies below 1 MeV) and very narrow coronal mass ejections (“jets” with angular width ≤ 20°). Methods. For this purpose, we considered 125 very narrow coronal mass ejections (CMEs) from 1999 to 2003 that are potentially associated with low-energy solar particles (LESPs). These events were chosen on the basis of their source location. We studied only very narrow CMEs at the western limb, which are expected to have good magnetic connectivity with Earth. Results. We found 24 very narrow CMEs associated with energetic particles such as ions (protons and 3He), electrons, or both. We show that arrival times at Earth of energetic particles are consistent with onset times of the respective CMEs, and that in the same time intervals, there are no other potential sources of energetic particles. We also demonstrate statistical differences for the angular width distributions using the Kolmogorov–Smirnov test for angular widths for these 24 events. We consider a coherent sample of jets (mostly originating from boundaries of coronal holes) to identify properties of events that produce solar energetic particles (velocities, widths, and position angles). Our study presents a new approach and result: very narrow CMEs can generate low-energy particles in the vicinity of Earth without other activity on the Sun. The results could be very useful for space weather forecasting.

Bronarska, K.↗

Real-time optimization of multi-cell industrial evaporative cooling towers using machine learning and particle swarm optimization

Existing electrical generating stations must operate with greater flexibility due to increasing renewable energy penetration on the electrical grid, and many coal-fired power stations have transitioned away from baseload operation to load-following operation to aid in grid stability. In cases where multiple independently controlled cooling tower cells are used in parallel for the cooling purposes of such stations, there is an opportunity to increase plant efficiency through data-driven optimization across their full load ranges. This work presents a novel application of real-time optimization using machine learning and particle swarm optimization on a multi-cell induced-draft cooling tower servicing a coal-fired power station under variable load. This is the first work to demonstrate simultaneous optimization of a multi-cell cooling tower, in addition to using machine learning for closed-loop control on a cooling tower. A novel control configuration is presented that ensures original control logic is not adversely affected and that the overall plant process is not disrupted using only existing hardware and operational data. To verify this methodology, the 12 independent cooling tower cells are simulated in parallel using historic operating data to demonstrate the effectiveness of real-time optimization compared to current practice. An artificial neural network is trained to predict overall cooling tower power consumption using only operational data and ambient conditions with an R2 value of greater than 0.96. The real-time optimization using particle swarm yields 6.7% annual energy usage savings compared to current practices, although the extent of the real-time savings varies greatly with both plant load and environmental conditions. This is particularly significant for a variable load situation because frequent ramping typically results in reduced overall efficiency. Furthermore, this proposed AI-based solution presents an opportunity to improve the overall heat rate of a load-following coal-fired power plant without the need to perform extensive first-principles modeling or add additional hardware to the cooling tower, resulting in more resources conserved and less overall emissions per unit of electricity generated.

42 ENGINEERING↗

Soft-error generation due to heavy-ion tracks in bipolar integrated circuits

Both bipolar and MOS integrated circuits have been empirically demonstrated to be susceptible to single-particle soft-error generation, commonly referred to as single-event upset (SEU), which is manifested in a bit-flip in a latch-circuit construction. Here, the intrinsic characteristics of SEU in bipolar (static) RAM's are demonstrated through results obtained from the modeling of this effect using computer circuit-simulation techniques. It is shown that as the dimensions of the devices decrease, the critical charge required to cause SEU decreases in proportion to the device cross-section. The overall results of the simulations are applicable to most integrated circuit designs.

Zoutendyk, J. A.↗

Modification of a very large thermal-vacuum test chamber for ionosphere and plasmasphere simulation

No large-volume chamber existed which could simulate the ion and electron environment of near-earth space. A very large thermal-vacuum chamber was modified to provide for the manipulation of the test volume magnetic field and for the generation and monitoring of plasma. Plasma densities of 1 million particles per cu cm were generated in the chamber where a variable magnetic flux density of up to 0.00015 T (1.5 gauss) was produced. Plasma temperature, density, composition, and visual effects were monitored, and plasma containment and control were investigated. Initial operation of the modified chamber demonstrated a capability satisfactory for a wide variety of experiments and hardware tests which require an interaction with the plasma environment. Potential for improving the quality of the simulation exists.

Pearson, O. L.↗

Relatively low-temperature pyrolysis of silane in free space

The continuous flow pyrolyzer is a free space reactor that is used to study the effects of concentration, flow rate and temperature in making solar-grade silicon by pyrolysis of silane gas. Work with the continuous flow pyrolyzer is within the DOE-sponsored Low-Cost Solar Array Project. The work has led to a new theoretical treatment of silane pyrolysis in free space at relatively low temperatures (550 C to 750 C). It involves a sequential, three-step mechanism of particle growth: first, silicon atom generation by homogeneous reaction; second, coagulation to a 0.1 micron particle due to Brownian motion and van der Waals forces; and finally, chemical vapor deposition by heterogeneous reaction to final particle size.

Levin, H.↗

Method of Manufacturing a Humidity Sensing Material

A method is provided for manufacturing a humidity sensing material. Particles of a trivalent rare earth hydroxide or oxide (such as lanthanum hydroxide) are mixed with particles of barium oxide and titanium dioxide in specified proportions. The particle mixture is heated to generate a sintered mixture that is milled. The resulting milled particles are mixed with glass particles, an organic surfactant, a solvent, an organic vehicle, and an alkali hydroxide. The resulting liquid mixture is deposited as a layer thereof onto a substrate. The substrate and layer thereon are processed to remove liquid portions of the liquid mixture. Such liquid removal processing includes at least one cycle of heating the layer followed by a corresponding cycle of cooling the layer in a nitrogen atmosphere containing less than 25 parts per million of oxygen.

Rolin, Terry D.↗

Characterization of the Emissions and Crystalline Silica Content of Airborne Dust Generated from Grinding Natural and Engineered Stones

Abstract In this study, we systematically characterized the airborne dust generated from grinding engineered and natural stone products using a laboratory testing system designed and operated to collect representative respirable dust samples. Four stone samples tested included two engineered stones consisting of crystalline silica in a polyester resin matrix (formulations differed with Stones A having up to 90wt% crystalline silica and Stone B up to 50wt% crystalline silica), an engineered stone consisting of recycled glass in a cement matrix (Stone C), and a granite. Aerosol samples were collected by respirable dust samplers, total dust samplers, and a Micro-Orifice Uniform Deposit Impactor. Aerosol samples were analyzed by gravimetric analysis and x-ray diffraction to determine dust generation rates, crystalline silica generation rates, and crystalline silica content. Additionally, bulk dust settled on the floor of the testing system was analyzed for crystalline silica content. Real-time particle size distributions were measured using an Aerodynamic Particle Sizer. All stone types generated similar trimodal lognormal number-weighted particle size distributions during grinding with the most prominent mode at an aerodynamic diameter of about 2.0-2.3 μm, suggesting dust formation from grinding different stones is similar. Bulk dust from Stone C contained no crystalline silica. Bulk dust from Stone A, Stone B, and granite contained 60, 23, and 30wt% crystalline silica, respectively. In Stones A and B, the cristobalite form of crystalline silica was more plentiful than the quartz form. Only the quartz form was detected in granite. The bulk dust, respirable dust, and total dust for each stone had comparable amounts of crystalline silica, suggesting that crystalline silica content in the bulk dust could be representative of that in respirable dust generated during grinding. Granite generated more dust per unit volume of material removed than the engineered stones, which all had similar normalized dust generation rates. Stone A had the highest normalized generation rates of crystalline silica, followed by granite, Stone B, and Stone C (no crystalline silica), which likely leads to the same trend of respirable crystalline silica (RCS) exposure when working with these different stones. Manufacturing and adoption of engineered stone products with formulations such as Stone B or Stone C could potentially lower or eliminate RCS exposure risks. Combining all the effects of dust generation rate, size-dependent silica content, and respirable fraction, the highest normalized generation rate of RCS consistently occurs at 3.2-5.6 µm for all the stones containing crystalline silica. Therefore, removing particles in this size range near the generation sources should be prioritized when developing engineering control measures.

Public, Environmental & Occupational Health↗

Active doping controls the mode of failure in dense colloidal gels

Mechanical properties of disordered materials are governed by their underlying free energy landscape. In contrast to external fields, embedding a small fraction of active particles within a disordered material generates nonequilibrium internal fields, which can help to circumvent kinetic barriers and modulate the free energy landscape. In this work, we investigate through computer simulations how the activity of active particles alters the mechanical response of deeply annealed polydisperse colloidal gels. We show that the “swim force” generated by the embedded active particles is responsible for determining the mode of mechanical failure, i.e., brittle vs. ductile. We find, and theoretically justify, that at a critical swim force the mechanical properties of the gel decrease abruptly, signaling a change in the mode of mechanical failure. The weakening of the elastic modulus above the critical swim force results from the change in gel porosity and distribution of attractive forces among gel particles, while below the critical swim force, the ductility enhancement is caused by an increase of gel structural disorder. Above the critical swim force, the gel develops a pronounced heterogeneous structure characterized by multiple pore spaces, and the mechanical response is controlled by dynamical heterogeneities. We contrast these results with those of a simulated monodisperse gel that exhibits a nonmonotonic trend of ductility modulation with increasing swim force, revealing a complex interplay between the gel energy landscape and embedded activity.

Zhou, Tingtao (ORCID:000000021766719X)↗

Signatures of particle acceleration at SN1987a

Young SNRs may be bright sources of energetic photons and neutrinos generated by the collisions of particles accelerated within the remnant. Due to the large opacity of the shell at these early times, a photon signal may be suppressed; at later times, due to adiabatic losses of the magnetically-trapped particles in the expanding envelope, both neutron and neutrino signals will begin to decrease. There is therefore a window during which the secondary photon signal will be at its maximum. It is presently noted that if the observed decline of the optical light curve of SN1987a is due to Ni-56, Co-56 decay, this may place upper limits on such other sources of light as a central pulsar.

Gaisser, T. K.↗