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At least 595 records · Page 33

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DOE OSTI2023

Properties of Gaseous Deprotonated L-Cysteine S-Sulfate Anion [cysS-SO3]−: Intramolecular H-Bond Network, Electron Affinity, Chemically Active Site, and Vibrational Fingerprints

L-cysteine S-sulfate, Cys-SSO3H, and their derivatives play essential roles in biological chemistry and pharmaceutical synthesis, yet their intrinsic molecular properties have not been studied to date. In this contribution, the deprotonated anion [cysS-SO3]− was introduced in the gas phase by electrospray and characterized by size-selected, cryogenic, negative ion photoelectron spectroscopy. The electron affinity of the [cysS-SO3]• radical was determined to be 4.95 ± 0.10 eV. In combination with theoretical calculations, it was found that the most stable structure of [cysS-SO3]− (S1) is stabilized via three intramolecular hydrogen bonds (HBs); i.e., one O-H……N between the -COOH and -NH2 groups, and two N-H……O HBs between -NH2 and -SO3, in which the amino group serves as both HB acceptor and donor. In addition, a nearly iso-energetic conformer (S2) with the formation of an O-H……N-H……O-S chain-type binding motif competes with S1 in the source. The most reactive site of the molecule susceptible for electrophilic attacks is the linkage S atom. Theoretically predicted infrared spectra indicate that O-H and N-H stretching modes are the fingerprint region (2800 to 3600 cm−1) to distinguish different isomers. The obtained information lays out a foundation to better understand the transformation and structure–reactivity correlation of Cys-SSO3H in biologic settings.

74 ATOMIC AND MOLECULAR PHYSICS↗

NASA NTRS1971

Ionospheric nf sub H resonances: Frequency shifts versus plasma conditions

The Alouette 2 resonances observed near the harmonics of the electron cyclotron frequency f sub H reveal frequency shifts (relative to the n(f sub H) values derived from model field calculations) which can be interpreted in terms of plasma wave dispersion effects. These effects are observed on the 2(f sub H) resonance when it is near the resonance observed close to the upper hybrid frequency f sub T. The observations suggest that an oblique echo model may be required to give a proper interpretation of the 2(f sub H) resonance. Cyclotron damping can be ignored only when the angle between the propagation vector and the direction perpendicular to the earth's magnetic field B is less than a few degrees for the 2(f sub H) wave, and less than a few tenths of a degree for the n(f sub H) waves with n 2. The negative offset of the absolute value of B inferred from the plasma resonance observations is consistent with expectations based on recent OGO 3 and OGO 5 rubidium magnetometer observations at higher altitudes in the equatorial regions.

Benson, R. F.↗

NASA NTRS1975

Relationships between motion on isentropic surfaces from 3-H rawinsonde data and radar echoes

Vertical motion in insentropic surfaces obtained at 3-h intervals conducted on 11 and 12 May, 1974 is related to convection indicated by radar echoes. Temporal and spatial changes in vertical motion are shown and demonstrated to be associated with areas of convection. Large vertical motion was calculated, and it is shown that vertical motion changes as much as 20 cm s (-1) in a horizontal distance of 300 km. The rate of change of vertical motion is demonstrated to be as large a 8 cm s (-1)h(-1) from data taken at 3-h intervals, while data taken at 12-h intervals the same day displayed a maximum rate of change of 2 cm s(-1)n(-1). Radar observations confirmed that the intensity of convection varies as a result of the atmospheric variability as detected by 3-h data but is invisible in data taken at 12-h intervals.

Overall, J. W.↗

NASA NTRS1975

A search for H/-/ in the shell surrounding chi Ophiuchi

Assuming that chi Oph is an extreme Be star, some consequences are investigated for the interpretation that the IR excesses in such stars are produced by H(-) free-bound emission. The column density of H(-) in the shell surrounding chi Oph is estimated from the observed IR excess, and Copernicus UV spectrophotometric data are used to search for a predicted absorption feature at 1129.54 A due to H(-) and to derive an upper limit to the H(-) column density. No feature resembling the predicted H(-) line is seen in the spectrum of chi Oph, and a marked discrepancy is noted between the estimated column density and the derived upper limit. Possible causes of these discrepancies are discussed, including incorrect interpretation of the IR excess in extreme Be stars, incorrect theoretical calculations describing the predicted H(-) UV absorption line, and the possibility that the line of sight through the shell does not intersect the regions where the IR excess originates.

Snow, T. P., Jr.↗

NASA NTRS1980

CO observations of several galactic H II regions

Maps of the CO emission at a resolution of 8 arcmin are presented for seven H II regions or H II region groups; the results of a search for CO emission near seven more are also given. CO was detected near all but two of the observed objects. The distribution of (C-12)O and (C-13)O near S142, S157, and S159 was mapped at a resolution of 2.3 arcmin. The S147/S153 group of H II regions is shown to consist of physically related objects; it is a region of active star formation. The results show a complicated molecular cloud structure near most observed H II regions. There is a tendency for decreasing CO cloud mass when H II regions in more evolved stages are observed. The relevance of these results for the understanding of individual H II region/molecular cloud complexes, and for general aspects of the star-formation process, is briefly discussed.

Israel, F. P.↗

NASA NTRS1982

Low-resolution Mg II h and k observations of solar type stars

Observations with the International Ultraviolet Explorer (IUE) have made possible a comparison between chromospheric radiative loss rates in the Mg II h and k lines and the Ca II H and K lines. Observations made by Stencel et al. (1980) confirm the findings of Linsky et al. (1979) that the chromospheric radiative loss rates in h and k and H and K are about equal for supergiants, but the h and k loss rate is greater than the H and K loss rate in giants. It is pointed out that this may result from physical differences between the lower chromospheres of giants and supergiants. The present investigation has the objective to explore the possibility of determining relative chromospheric radiative loss rates in F and G dwarf stars with low-resolution IUE spectra. It is found that this is possible. Cluster stars were selected to provide two temperature sequences at two slightly different metal abundances.

Barry, D. C.↗

NASA NTRS1984

Consequences of a chromospheric temperature gradient on the width of H Alpha in late-type giants

An analytic expression for the integrated H alpha optical depth profile is derived for a one dimensional slab geometry model chromosphere, with electron temperature increasing as a power law with height. The formula predicts H alpha opacity and profile width to be sensitive functions of the thermal gradient. Application of the model to observation reveals that broad H alpha absorption widths in G and K giant stars are consistent with a mean H alpha chromospheric optical depth of 50, while narrower widths in M stars indicate slightly lower opacities. It is proposed that differences in H alpha width between late-type giants of similar spectral type may be due, in part, to differences in their chromospheric thermal gradient, and associated H alpha opacity.

Zarro, D. M.↗

NASA NTRS1984

Consequences of a chromospheric temperature gradient on the width of H-alpha in late-type giants

Zarro, D. M.↗

NASA NTRS1985

An explanation for the H Ly-alpha longitudinal asymmetry in the equatorial spectrum of Jupiter - An outcrop of paradoxical energy deposition in the exosphere

An analysis of the Voyager EUV spectra of the Jupiter sunlit equatorial emissions shows no evidence for a substantial dependence of atomic hydrogen abundance on magnetic longitude, required by earlier theories of the H Ly-alpha longitudinal asymmetry. An explanation for the H Ly-alpha bulge phenomenon is advanced in this work that conforms to the observations and does not require a strong asymmetry in atomic hydrogen abundance. It is proposed that the H Ly-alpha bulge is caused by a combination of proton collisional transfer of H(2s) atoms in the H(2p) state, and production through recombination of H2(+) and H3(+), in an asymmetric ionosphere. According to the present model a large fraction of the observed H Ly-alpha emission from the equatorial region is electron excited, at least at times of solar maximum.

Shemansky, D. E.↗

NASA NTRS1985

Seasonal, diurnal, and solar cyclical variations of the limiting H(+) flux in the earth's topside ionosphere

Seasonal and solar cyclical variations in the limiting H(+) flux are compared over the solar minimum-to-maximum interval 1974-80. The comparisons are made on the bases of values derived with the MSIS-83 and -77 models, which in turn are based on Atmospheric Explorer-E O(+) and H(+) data from the ionosphere. The H(+) flux is obtained by integration of the H(+) continuity equation along magnetic flux tubes. The seasonal and cyclical variations are dominated by the neutral hydrogen density, although the O(+) boundary density, scale height and O(+)-H reaction somewhat ameliorate the changes caused by the density variations. Finally, the plasmasphere experienced an order of magnitude decrease in H(+) in going from solar minimum to maximum, which could have been caused by longer limiting flux escapes through more, longer-lived, shorter flux tubes.

Richards, P. G.↗

NASA NTRS1987

Giant H II regions in M81

H-alpha and VLA radio continuum observations at wavelengths of 6 and 20 cm are used to study the distribution of extinction and the distribution of giant radio H II regions along the spiral arms in M81. The radial distribution of visual extinction Av in the plane of M81 shows no trend, with an upper limit 0.1 mag/kpc for the radial extinction gradient and a mean Av of 1.1 + or - 0.4 mag. Nearly all the giant radio H II regions lie along the spiral arms or the inner H I ring. The radial distribution of the set of giant radio H II regions exhibits a strong maximum at a galactocentric distance R roughly 300 arcsec. Unless molecular hydrogen in M81 is also concentrated near R roughly 300 arcsec, the data disagree with Visser's (1980) model for star formation associated with a density wave. Some suggestions are made about how to change the ballistic particle model of Leisawitz and Bash to agree with the observed radial distribution of giant radio H II regions.

Kaufman, Michele↗

NASA NTRS1988

Spectral dilation of L(B,H)-valued measures and its application to stationary dilation for Banach space valued processes

Let B be a Banach space and H and K two Hilbert spaces. The spectral dilation of L(B,H)-valued measures is studied and it is shown that the recent results of Makagon and Salehi (1986) and Rosenberg (1982) on the dilation of L(K,H)-valued measures can be extended to hold for the general Banach space setting of L(B,H)-valued measures. These L(B,H)-valued measures are closely connected to the Banach space valued processes. This connection is recalled and as application of spectral dilation of L(B,H)-valued measures the well known stationary dilation results for scalar valued processes is extended to the case of Banach space valued processes.

Miamee, A. G.↗

NASA NTRS1990

The H-alpha light curves of novae in M31

H-alpha and B light curves are presented for 11 M31 novae, four of which were well observed near maximum. These data, along with the H-alpha light curves of two Galactic novae, demonstrate that a nova's maximum H-alpha flux occurs days or weeks after its continuum maximum at a monochromatic intensity 1-2 magnitudes above its peak flux in B. Moreover, after this maximum is achieved, a typical nova will radiate a third as many photons in H-alpha as in the entire B bandpass. The most interesting part of a nova's H-alpha light curve, however, is its decline. It is found that, regardless of a nova's speed, its H-alpha decay rate after maximum is almost identical to its decay rate in B. This behavior suggests that most of a nova's optical luminosity during early decline is continuum emission from the nebula, rather than direct radiation from the central source.

Ciardullo, Robin↗

NASA NTRS1989

Spectral dilation of L(B,H)-valued measures and its application to stationary dilation for Banach space valued processes

Let B be a Banach space and H and K to Hilbert spaces. The spectral dilation of L(B,H)-valued measures is studied and it is shown that the recent results of Makagon and Salehi (1986) and Rosenberg (1982) on the dilation of L(K,H)-valued measures can be extended to hold for the general Banach space setting of L(B,H)-valued measures. These L(B,H)-valued measures are closely connected to the Banach space valued processes. This connection is recalled and as application of spectral dilation of L(B,H)-valued measures the well known stationary dilation results for scalar valued processes is extended to the case of Banach space valued processes.

Miamee, A. G.↗

NASA NTRS1990

H-alpha spectra of dynamic chromospheric processes in five well-observed X-ray flares

Simultaneous H-alpha and hard X-ray (HXR) spectra were obtained for five solar flares to determine the relationship of H-alpha profiles and the nonthermal part of the flare represented by the hard X-ray burst. All five flares exhibited impulsive-phase redshifted H-alpha in emission, which was temporarily and spatially associated with intense HXR emission and broad impulsive-phase H-alpha wings. A few small regions within two flares showed a blueshifted H-alpha emission which appeared only early in the impulsive phase and was temporally correlated with the HXR emission but not with broad H-alpha wings. Finally, there were both redshifted and blueshifted absorption spectra with properties fully consistent with those known for erupting and untwisting filaments.

Canfield, Richard C.↗

NASA NTRS1991

The interstellar C-H stretching band near 3.4 microns - Constraints on the composition of organic material in the diffuse interstellar medium

The composition and history of dust in the diffuse ISM was studied using 3600-2700/cm absorption spectra of objects which have widely varying amounts of visual extinctions along different lines of sight. The 3300/cm and 2950/cm features are attributed to O-H and C-H stretching vibrations, respectively. The O-H feature in OH 32.8-0.3 is suggestive of circumstellar water ice and is probably not due to material in the diffuse ISM. The features in the 3100-2700/cm region are attributed either to C-H vibrations or to M stars. The spectra of the latter show a series of narrow features in this region that are identified with photospheric OH. Objects in which these bands are seen include OH 01-477, T629-5, and the Galactic center source IRS 7. The C-H stretch feature of diffuse ISM dust has subpeaks which fall within 5/cm of C-H stretching vibrations in the -CH2- and -CH3 groups of saturated aliphatic hydrocarbons.

Sandford, S. A.↗

NASA NTRS1991

The discovery of a long H I plume near the peculiar galaxy NGC 2782 (ARP 215)

The peculiar starburst galaxy NGC 2782 (Arp 215) is mapped in the 21-cm H I line using the VLA, and a massive H I plume extending about 5 arcmin toward the northwest is discovered which contains 1.4 x 10 to the 9th solar mass of atomic hydrogen (about 40 percent of the total H I mass of the system). There is also a shorter H I structure extending toward the east, which contains 6.6 x 10 to the 8th solar mass of H I. In the Arp Atlas photograph, NGC 2782 has a disturbed body with bright arcs, possibly ripples, throughout the disk, and a pronounced stellar tail extending 2.7 arcmin toward the east. The eastern H I structure is associated with the beginning of this stellar tail. PDS scanning of the Palomar plates in the vicinity of NGC 2782 reveals a low surface-brightness counterpart to the long HI plume in the northwest. The most likely formation scenario for NGC 2782 is a merger, possibly of unequal mass galaxies, where at least one of the galaxies is gas rich.

Smith, Beverly J.↗

NASA NTRS1992

Observations of the structure and vertical transport of the polar upper ionosphere with the EISCAT VHF radar. II - First investigations of the topside O(+) and H(+) vertical ion flows

EISCAT VHF radar was used to investigate the vertical flows of H(+) and O(+) ions in the topside high-latitude ionosphere. The radar transmitted a single long pulse to probe the ionosphere from 300 to 1200 km altitude. A calculation scheme is developed to deduce the H(+) drift velocity from the coupled momentum equations of H(+), O(+), and the electrons, using the radar data and a neutral atmosphere model. The H(+) vertical drift velocity was expressed as a linear combination of the different forces acting on the plasma. Two nights, one very quiet, one with moderate magnetic activity, were used to test the technique and to provide a first study of the morphology and orders of magnitudes of ion outflow fluxes over Tromso. O(+) vertical flows were found to be downward or close to zero most of the time in the topside ionosphere; they appeared to be strongly correlated with magnetic activity during the disturbed night. H(+) topside ion fluxes were always directed upward, with velocity reaching 500-1000 m/s. A permanent outflow of H(+) ions is inferred.

Wu, Jian↗