Experimental concepts of life detection for planetary exploration
Life detection for unmanned planetary exploration from extraterrestrial sample involving growth, gas changes and carbon dioxide fixation
Berdahl, B. J.↗
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Results for “Gas sampling”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Microchemical, microphysical, and adhesive properties of lunar material. II
Vacuum pumped Apollo 12 lunar soil sample 12001,118 gas exposure effects, interface microanalysis and adhesion measurements in ultrahigh vacuum system
Grossman, J. J.↗
The reaction of hydrogen peroxide with nitrogen dioxide and nitric oxide.
The reactions were studied with the aid of a mass spectrometer. A pinhole bleed system provided continuous sampling of the gas mixture in the cell during the reaction. It was found that the homogeneous reactions of nitric oxide and nitrogen dioxide with hydrogen peroxide are too slow to be of any significance in the upper atmosphere. However, the heterogeneous reactions may be important in the conversion of nitric oxide to nitrogen dioxide in the case of polluted urban atmospheres.
Gray, D.↗
Improved nondispersive infrared analyzer
Light from radiant energy source passes through filter, sample, and reference gas chambers to detector. Chamber with amount of gas to be measured is sealed. Filter may be gelatinous, interference, dispersive, or negative-gas, as required.
Dimeff, J.↗
Monitoring Air Pollution from Satellites (MAPS). Volume 1: Technical report
Performance tests on an electro-optical model of an infrared sensor for remote measurements of trace atmospheric gases are detailed; the instrument utilized a sample of the gas to be measured as spectral filter. Also reported is the development of radiometric calibration equipment that determines responses to simulated pollution effects. Results show excellent agreement with theoretical performance predictions with the exception of nonuniform radiance responses. Balance stability to an accuracy better than the rms noise level was demonstrated for the EOM in both the NH3 and CO modes for a period of two days under laboratory conditions. Flight test results show that the temperature range of the absorption cell is restricted to 255 K or higher.
Source record↗
Analysis of data from the Pioneer Venus Sounder Probe mass spectrometer
The composition of the lower atmosphere of the planet Venus from 62 km to the surface was measured by a neutral gas mass spectrometer onboard of the Pioneer Venus Sounder Probe. Fifty-one mass spectra were obtained with an average altitude resolution of approximately 1 km. The instrument measured the composition of the gases relative to CO2, the dominant gas, that is sampled from the Venus atmosphere through a special leak. The mass range extended from 1 to 208 amu with a sensitivity of the order of 1 ppm relative to CO2, but for the noble gases it was nearly 100 times better. A description of the instrument and the initial results are reported.
Hoffman, J. H.↗
Laboratory evaluation of an airborne ozone instrument that compensates for altitude/sensitivity effects
One problem encountered in the use of air-quality instrumentation on aircraft is the variation of instrument sensitivity with pressure as the result of altitude changes of the aircraft. Many instruments experience sensitivity changes of as much as a factor of 2 at altitudes of 6 km. Discussed are recent modifications to a chemiluminescent (ethylene) ozone detector that allow the instrument to automatically compensate for pressure/sensitivity effects. The modification provides automated mass flow rate control for both the sample and ethylene gas flows. The flow control systems maintain flow rate to within 15 percent for a 100-torr instantaneous pressure change, and flow rates are returned to the desired set points within 10 s after the pressure change. During simulated altitude changes (300 m/min from mean sea level to 3-km altitude), flow rates were controlled to within 3 percent of the set point. Laboratory data are summarized verifying the operation of the instrument for a pressure range of 760 torr (sea level) to 350 torr (approximately 20,000 ft) and an ozone concentration range from 20 to approximately 700 ppb.
Gregory, G. L.↗
The atmospheric lifetime experiment. I - Introduction, instrumentation, and overview
The Atmospheric Lifetime Experiment is designed to determine accurately the atmospheric concentrations of the four halocarbons CFCl3, CF2Cl2, CCl4, and CH3CCl3, and also of N2O with emphasis on measurement of their long-term trends in the atmosphere. Comparison of these concentrations and trends for the four halocarbons with estimates of their industrial emission rates then enables calculations of their global circulation rates and globally averaged atmospheric lifetimes. The experiment utilizes automated dual-column electron-capture gas chromatographs which sample the background air about 4 times daily at the following globally distributed sites: Adrigole, Ireland, Cape Meares, Oregon; Ragged Point, Barbados; Point Matatula, American Samoa, and Cape Grim, Tasmania. The climatology of these 'clean air' sites and their ability to describe the global air mass are reviewed. The instrumentation and methods for data acquisition and processing are then described. An overview of the data obtained and the trends derived during the 3-year period from July 1978 through June 1981 for each of the five species being measured is presented.
Prinn, R. G.↗
Radiative effects of the arctic haze
During the recent Arctic Gas and Aerosols Sampling Project flight series, the absorption of solar radiation by the Arctic haze was measured directly for the first time. Absorpton was measured in three narrow band channels, and the measurements were used to calibrate a high resolution solar flux model, which was then used to compute atmospheric heating rates. Analyses of data from three flights with estimated optical depths of 0.26, 0.17, and 0.31 at 500 nm produced instantaneous solar heating rates of the order of 1.1 to 1.5 K/day. These rates are greater by a factor of 2 to 3 than heating in the absence of the haze. Possible climatic implications are briefly discussed.
Valero, F. P. J.↗
Aerosol distributions and an arctic aerosol front during AGASP - Norwegian Arctic
Vertical profiles of aerosol characteristics obtained near Svalbard, Norway, during the Arctic Gas and Aerosol Sampling Program indicate that high aerosol concentrations and strong visible haze were distributed throughout the troposphere. Layers of Arctic haze were observed in both dry air and moist air. A research flight on March 31, 1983, crossed a previously undocumented Arctic aerosol front structure. Condensation nucleus concentrations of 450/cu cm within the polluted continental air mass south of the front decreased to 80/cu cm within the clean Arctic air north of the front. Aerosols above the Aitken size range decreased one order of magnitude in both number and mass across this same air mass boundary.
Ratz, W. E.↗
Elemental composition of arctic particulate matter
Measurements were made of the elemental composition of particulate matter collected in flights in the Arctic in spring 1983 as part of the Arctic Gas and Aerosol Sampling Program (AGASP). Ten samples of size-selected particles were analyzed by four nondestructive techniques at Davis. Concentrations were determined for H, C, N, and O by Forward Alpha Scattering Techniques (FAST) and for elements heavier than fluorine by Particle Induced X-ray Emission (PIXE). Total mass was measured gravimetrically, and optical absorption was measured using the Laser Integrating Plate Method (LIPM). Results of the analyses show dramatic differences in concentrations and elemental ratios from the Alaskan Arctic to the Norwegian Arctic, with indications of wood smoke and sulfuric acid in the arctic atmosphere.
Cahill, T. A.↗
The electron density in M82 from the S III mid-infrared line ratio
Strong detections have been made of both the 18.7 microns and 33.4 microns lines of S III in the irregular galaxy M82. This represents the first detection of the 33.4 microns line in an extragalactic object. These measurements sample the ionized gas component which dominates the observed infrared forbidden line and infrared hydrogen recombination line emission. From the ratio of the line fluxes an electron density of 120 (+ 280, - 120) per cu cm is deduced. This result is in agreement with previous estimates of the density derived from high-frequency radio continuum measurements and an assumed emitting volume. They impose further constraints on possible starburst models.
Houck, J. R.↗
Springtime surface ozone fluctuations at high Arctic latitudes and their possible relationship to atmospheric bromine
At high Arctic stations such as Barrow, Alaska, springtime near-surface ozone amounts fluctuate between the highest and lowest values seen during the course of the year. Episodes when the surface ozone concentration is essentially zero last up to several days during this time of year. In the Arctic Gas and Aerosol Sampling Program (AGASP-I and AGASP-II) in 1983 and 1986, it was found that ozone concentrations often showed a very steep gradient in altitude with very low values near the surface. The cold temperatures, and snow-covered ground make it unlikely that the surface itself would rapidly destroy significant amounts of ozone. The AGASP aircraft measurements that found low ozone concentrations in the lowest layers of the troposphere also found that filterable excess bromine (the amount of bromine in excess of the sea salt component) in samples collected wholly or partially beneath the temperature inversion had higher bromine concentrations than other tropospheric samples. Of the four lowest ozone minimum concentrations, three of them were associated with the highest bromine enrichments. Surface measurements of excess filterable bromine at Barrow show a strong seasonal dependence with values rising dramatically early in March, then declining in May. The concentration of organic bromine gases such as bromoform rise sharply during the winter and then begin to decline after March with winter and early spring values at least three times greater than the summer minimum.
Oltmans, Samuel J.↗
Airborne measurements of tropospheric ozone destruction and particulate bromide formation in the Arctic
Aircraft profiles of O3 concentrations over the Arctic ice pack in spring exhibit a depletion of O3 beneath the surface temperature inversion. One such profile from the NOAA WP-3D Arctic Gas and Aerosol Sampling Program (AGASP) flights in April, 1986 north of Alert, NWT (YLT, 82.5 N) is shown. The gradient of O3 across the temperature inversion, which is essentially a step function from tropospheric values (35 to 40 ppbv) to 0, is somewhat masked by a 1-min running mean applied to the data. Evidence is presented that O3 destruction beneath the Arctic temperature inversion is the result of a photochemical reaction between gaseous Br compounds and O3 to produce particulate Br aerosol. It is noted that in springtime, O3 at the Alert Baseline Station regularly decreases from 30 to 40 ppbv to near 0 over the period of a few hours to a day. At the same time, there is a production of particulate Br with a near 1.0 anti-correlation to O3 concentration. Surface concentrations of bromoform in the Arctic exhibit a rapid decrease following polar sunrise. AGASP aircraft measurements of filterable bromine particulates in the Arctic (March-April, 1983 and 1986) are shown. The greatest concentrations of Br aerosol (shown as enrichment factors relative to to Na in seawater, EFBR (Na)) were observed in samples collected beneath the surface temperature inversion over ice. Samples collected at the same altitude over open ocean (off Spitzbergen) labeled Marine did not exhibit similar Br enrichments. A second region of particulate Br enrichment was observed in the lower stratosphere, which regularly descends to below 500 mb (5.5 km) in the high Arctic. The NOAA WP-3D flew in the stratosphere on all AGASP flights and occasionally measured O3 concentrations in excess of 300 ppbv.
Schnell, Russell C.↗
Aerosol formation and distribution in the Arctic during AGASP-II, March-April 1986
The Arctic Gas and Aerosol Sampling Program has undertaken the determination of the distribution, transport, chemistry, aerosol physics, and radiative effects of the 'Arctic haze' air-pollution phenomenon. Attention has been given the April 2-3, 1986 haze zone, with large condensation nuclei, SO2, and soot-carbon concentrations, which appeared near the Barrow Baseline Station. The composite trajectory of the haze zone has been determined, as has its probable source region. After travelling 10,000 km, the haze still had SO2, aerosol black carbon, and condensation nuclei concentrations in excess of those measured off the East Coast of the U.S. in January of the same year.
Schnell, Russell C.↗
The effects of the Arctic haze as determined from airborne radiometric measurements during AGASP II
The effect of the Arctic-haze aerosol on the parameters of solar radiation was investigated using airborne radiometric measurements of radiation parameters during the second Arctic Gas and Aerosol Sampling Project. Simultaneously with absorption measurements, optical depths and total, direct, and scattered radiation fields were determined. The experimentally determined parameters were used to define an aerosol model, which was then used to calculate atmospheric heating rate profiles. It was found that, besides the increased absorption (30 to 40 percent) and scattering of radiation by the atmosphere, Arctic haze reduces the surface absorption of solar energy by 6 to 10 percent, and the effective planetary albedo over ice surfaces by 3 to 6 percent.
Valero, Francisco P. J.↗
On the transfer of stratospheric ozone into the troposphere near the North Pole
A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (about 85 deg N, about 90 deg W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the arctic tropopause appear to be capable of contributing significantly to the ozone budget of the arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.
Oltmans, Samuel J.↗
The 158 micrometer (CII) line: A measure of global star formation activity in galaxies
Some 158 micron (CII) fine structure line observations from a sample of fourteen gas rich galaxies are reported. These measurements confirm and generalize previous basic results that the (CII) line is bright amounting to approximately 0.1 to 1 percent of the Far Infra Red (FIR) luminosity of the nuclear regions of galaxies; the (CII) line is formed in the warm (temperature of the gas is greater than 200 K), dense (n sub H greater than 1000/cu cm) photodissociated gas at the interfaces between giant molecular clouds and ionized gas regions and is therefore associated with the molecular gas component in spiral galaxies; the (CII) line tracks the FIR continuum in a manner consistent with the PDR models; the integrated (CII) to isotope (12)CO (transition 1 to 0) line ratio is large (greater than or equal to 1000) in all galaxies studied, and is similarly large for galactic molecular clouds; the (CII) line is therefore energetically very important for the study of giant molecular clouds. Conclusions obtained from these results are given.
Stacey, G. J.↗