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At least 595 records · Page 33

Influence of point defect accumulation on in-pile thermal conductivity degradation: Fuel rod defect distribution and deviation between in-pile and post irradiation thermal conductivity

As nuclear fuel burn-up increases, its thermal conductivity degrades due to the accumulation of defects that lead to increased phonon scattering rates. This results in a rise in the centerline temperature of the fuel rod, whereby heat generation must be decreased to avoid undesired behavior such as fuel melting and extensive fission gas release. Fuel performance codes are utilized to optimize the fuel's operational conditions; while they are based on established physical principles, their empirical nature limits their predictive capabilities. Recently, an effort has been made to develop predictive fuel performance codes for commonly used nuclear fuels, as well as accelerated qualification of advanced nuclear fuels. In this report, we elaborate on the importance of careful analysis of point defects’ impact on thermal conductivity in fuel performance analysis. Further, a model is presented where point defect concentration is estimated based on Rate Theory modeling and used as input to the Klemens-Callaway model to calculate their contribution to the degradation of thermal conductivity in UO 2 under prototypical irradiation conditions. This analysis suggests that point defect concentration is significant at the rim of the fuel pellet and neglecting this leads to underestimation of the centerline temperature, which may have consequences on fission gas behavior.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fuels Irradiation and Physics Database (FIPD) Development and Data Qualification FY24 Updates

The DOE-NE Advanced Reactor Technologies program has supported efforts to recover and preserve metallic fuel data generated throughout the past fast reactor R&D programs. Those efforts are currently focused on establishing databases for information from the experiments conducted during the Integral Fast Reactor program including data generated at EBR-II, FFTF, and TREAT reactors, as well as out of pile transient testing data. These databases are essential for future-licensing activities of metallic fuel based advanced fast reactors. This report describes the Metallic Fuels Irradiation & Physics Database (FIPD) development, content updates, data qualification status, and user support in FY24. Future plans are also provided.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Vehicle Technologies and Fuel Cell Technologies Office Research and Development Programs: Prospective Benefits Assessment for Medium- and Heavy-duty Vehicles

Through a diverse set of programs, the Vehicle Technologies and Fuel Cell Technologies Offices of the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) invest in early-stage vehicle and fuel cell research. The Vehicle Technologies Office (VTO) and the Fuel Cell Technologies Office (FCTO) are two offices that are encompassed within EERE’s Sustainable Transportation pillar. VTO conducts research and development (R&D) to provide low-cost, reliable, and efficient energy for the transportation of goods and people across America. FCTO has a comprehensive portfolio of activities that address the barriers facing the development and implementation of hydrogen and fuel cells, with the ultimate goals of decreasing our dependence on oil, reducing greenhouse gas (GHG) emissions, and enabling clean, reliable power generation through both transportation and stationary uses of hydrogen. This report quantifies the vehicle-level and national-level benefits of successful VTO and FCTO R&D applied to medium- and heavy-duty vehicles. The benefits estimated include reductions in energy use and GHG emissions from and changes in expenditures on medium- and heavy-duty vehicles on the road in the United States through the year 2050. The potential future benefits of successfully developing and implementing these technologies were analyzed by comparing a “Program Success” case to a base case (the “No Program” case). The Program Success case represents the future with successful implementation of VTO and FCTO technologies. The No Program case represents a future in which VTO or FCTO do not contribute to these technologies after Fiscal Year (FY) 2019. Three side cases were analyzed to assess the sensitivity of the projections of market adoption to future electricity prices (including infrastructure costs), the availability of electricity and hydrogen at public stations, and fuel cell system efficiency. Advanced vehicle technologies supported by VTO and FCTO programs can greatly increase the fuel economy of medium- and heavy-duty vehicles. As a result of EERE-supported technologies, the sales-weighted average fuel economy of the fleet of all new Class 7 and 8 trucks in the Program Success case is projected to be 1.2 times that of the trucks in the No Program case in 2035 and 1.3 times the baseline in 2050. These technologies in Classes 4–6 increase fuel economy by a factor of 1.46 in 2035 and 1.78 in 2050. The fuel economy of the entire on-road medium- and heavy-duty vehicle fleet, including all fuel types, is projected to be higher by 10%, reaching 9.1 mpgde in 2035, and by 25%, reaching 11.0 mpgde in 2050. The resulting petroleum savings in 2050 were estimated to be 0.75 million barrels per day, and reductions in GHG emissions in 2050 were estimated to 110 million metric tons of carbon dioxide equivalent (CO 2 -eq) per year. Such petroleum reductions result in significant reductions in fuel expenditure for medium- and heavy-duty vehicles, totaling approximately $37 billion annually by 2035. Figure ES-1 shows the difference in projected consumption of diesel fuel, electricity, and hydrogen in the No Program and Program Success cases. Negative values show the reduction in the Program Success case, relative to the No Program case.

33 ADVANCED PROPULSION SYSTEMS↗

Development of an Impinging-jet Fuel-injection Valve Nozzle

During an investigation to determine the possibilities and limitations of a two-stroke-cycle engine and ignition, it was necessary to develop a fuel injection valve nozzle to produce a disk-shaped, well dispersed spray. Preliminary tests showed that two smooth jets impinging upon each other at an angle of 74 degrees gave a spray with the desired characteristics. Nozzles were built on this basis and, when used in fuel-injection valves, produced a spray that fulfilled the original requirements. The spray is so well dispersed that it can be carried along with an air stream of comparatively low velocity or entrained with the fuel jet from a round-hole orifice. The characteristics of the spray from an impinging-jet nozzle limits its application to situations where wide dispersion is required by the conditions in the engine cylinder and the combustion chamber.

Spanogle, J A↗

Resumption of SFR Overpower Testing and Post-Transient Examination of the THOR-C-2 Irradiation Test

Transient overpower testing for fuel safety research and development has resumed at Idaho National Laboratory. The THOR-C-2 commissioning test has been performed and post-transient examination has been performed revealing the intended creep rupture failure near the top of the fuel zone. This paves the way for future testing on previously irradiated fuels that will support fuel development and qualification.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

EXTINCTION DROPLET SIZING MEASUREMENTS IN DIESEL RELEVANT SPRAYS

A new diagnostic for the quantification of Sauter Mean Diameter (SMD) in high-pressure fuel sprays has been recently developed using combined optical and x-ray measurements at the Georgia Institute of Technology and Argonne National Laboratory, respectively. This diagnostic utilizes liquid scattering extinction measurements from diffuse back-illumination (DBI) imaging, conducted at Georgia Tech, and liquid absorption measurements from x-ray radiography, conducted at Argonne’s Advanced Photon Source. The new diagnostic, entitled the Scattering Absorption Measurement Ratio (SAMR), quantifies two-dimensional distributions of path-integrated SMD, enabling construction of the spatial history of drop size development within practical fuel sprays. This technique offers unique benefits over conventional drop-sizing methods in that it can be more robust in optically dense regions of the spray, while also providing high spatial resolution of the corresponding droplet field. The spatially-resolved SMD measurements that result from the SAMR diagnostic will be especially valuable to the engine modeling community for the quantitative validation of spray submodels in engine CFD codes. The methodology for quantification of SMD distributions using the SAMR technique has been previously introduced. This thesis aims to extend the initial development of the SAMR technique by presenting in detail: the experimental methodologies used in the SAMR technique, including the development of an ideal DBI setup for this technique; the data processing methodologies developed by the author; two-dimensional Sauter Mean Diameter measurements within diesel sprays for various experimental conditions; a summary of the various sources of measurement uncertainty; an assessment for how the sources of uncertainty affect the quantified SMD; and paths to improve the technique moving forward. The SMD results show that for low ambient density conditions droplets decrease in size as radial and axial position increases. For high ambient density conditions, however, the droplets show a stable size near the spray centerline and steadily increase in size as distance from the centerline increases. Additionally, this work provides 2-D droplet sizing maps which are particularly useful for model validation.

33 ADVANCED PROPULSION SYSTEMS↗

EXTINCTION DROPLET SIZING MEASUREMENTS IN DIESEL RELEVANT SPRAYS

A new diagnostic for the quantification of Sauter Mean Diameter (SMD) in high-pressure fuel sprays has been recently developed using combined optical and x-ray measurements at the Georgia Institute of Technology and Argonne National Laboratory, respectively. This diagnostic utilizes liquid scattering extinction measurements from diffuse back-illumination (DBI) imaging, conducted at Georgia Tech, and liquid absorption measurements from x-ray radiography, conducted at Argonne’s Advanced Photon Source. The new diagnostic, entitled the Scattering Absorption Measurement Ratio (SAMR), quantifies two-dimensional distributions of path-integrated SMD, enabling construction of the spatial history of drop size development within practical fuel sprays. This technique offers unique benefits over conventional drop-sizing methods in that it can be more robust in optically dense regions of the spray, while also providing high spatial resolution of the corresponding droplet field. The spatially-resolved SMD measurements that result from the SAMR diagnostic will be especially valuable to the engine modeling community for the quantitative validation of spray submodels in engine CFD codes. The methodology for quantification of SMD distributions using the SAMR technique has been previously introduced. This thesis aims to extend the initial developmen of SAMR technique by presenting in detail: the experimental methodologies used in the SAMR technique, including the development of an ideal DBI setup for this technique; the data processing methodologies developed by the author; two-dimensional Sauter Mean Diameter measurements within diesel sprays for various experimental conditions; a summary of the various sources of measurement uncertainty; an assessment for how the sources of uncertainty affect the quantified SMD; and paths to improve the technique moving forward. The SMD results show that for low ambient density conditions droplets decrease in size as radial and axial position increases. For high ambient density conditions, however, the droplets show a stable size near the spray centerline and steadily increase in size as distance from the centerline increases. Additionally, this work provides 2-D droplet sizing maps which are particularly useful for model validation.

33 ADVANCED PROPULSION SYSTEMS↗

Measurement of Sauter Mean Diameter (SMD) in Diesel Sprays Using a Scattering-Absorption Measurement Ratio (SAMR) Technique

A new diagnostic for the quantification of Sauter Mean Diameter (SMD) in high-pressure fuel sprays has been recently developed using combined optical and x-ray measurements at the Georgia Institute of Technology and Argonne National Laboratory, respectively. This diagnostic utilizes liquid scattering extinction measurements from diffuse back-illumination imaging, conducted at Georgia Tech, and liquid absorption measurements from x-ray radiography, conducted at Argonne’s Advanced Photon Source. The new diagnostic, entitled the Scattering Absorption Measurement Ratio (SAMR), quantifies two-dimensional distributions of path integrated SMD, enabling construction of the spatial history of drop size development within practical fuel sprays. This technique offers unique benefits over conventional drop-sizing methods in that it can be more robust in optically dense regions of the spray, while also providing high spatial and temporal resolution of the corresponding droplet field. The methodology for quantification of SMD distributions using the SAMR technique has been previously introduced and demonstrated in diesel sprays using the Engine Combustion Network Spray D injector, however a more detailed treatment of measurement uncertainties has been needed. In the current work, we present a summary of the various sources of measurement uncertainty in the SAMR diagnostic, like those due to the experimental setup, data processing methods, and theoretical assumptions, and assess how these sources of uncertainty affect the quantified SMD. The spatially-resolved SMD measurements that result from the SAMR diagnostic will be especially valuable to the engine modeling community for the quantitative validation of spray submodels in engine CFD codes. Careful evaluation and quantification of measurement uncertainties is important to support accurate model validation and to ensure the development of more predictive spray models.

33 ADVANCED PROPULSION SYSTEMS↗

Measurement of Sauter mean diameter in diesel sprays using a scattering–absorption measurement ratio technique

A new diagnostic for the quantification of Sauter mean diameter in high-pressure fuel sprays has been recently developed using combined optical and X-ray measurements at the Georgia Institute of Technology and Argonne National Laboratory, respectively. This diagnostic utilizes liquid scattering extinction measurements from diffuse back-illumination imaging, conducted at Georgia Tech, and liquid absorption measurements from X-ray radiography, conducted at Argonne’s Advanced Photon Source. The new diagnostic, entitled the scattering–absorption measurement ratio, quantifies two-dimensional distributions of path-integrated Sauter mean diameter, enabling the construction of the spatial history of drop size development within practical fuel sprays. This technique offers unique benefits over conventional drop-sizing methods in that it can be more robust in optically dense regions of the spray, while also providing high spatial resolution of the corresponding droplet field. The methodology for quantification of Sauter mean diameter distributions using the scattering–absorption measurement ratio technique has been previously introduced and demonstrated in diesel sprays using the Engine Combustion Network Spray D injector; however, a more detailed treatment of measurement uncertainties has been needed. In this work, we present a summary of the various sources of measurement uncertainty in the scattering–absorption measurement ratio diagnostic, like those due to the experimental setup, data processing methods, and theoretical assumptions, and assess how these sources of uncertainty affect the quantified Sauter mean diameter. The spatially resolved Sauter mean diameter measurements that result from the scattering–absorption measurement ratio diagnostic will be especially valuable to the engine modeling community for the quantitative validation of spray submodels in engine computational fluid dynamics codes. Careful evaluation and quantification of measurement uncertainties are important to support accurate model validation and to ensure the development of more predictive spray models.

42 ENGINEERING↗

A methodology to develop multi-physics dynamic fuel cell system models validated with vehicle realistic drive cycle data

Fuel cell (FC) technology has been identified as a technically attractive solution to decarbonize the transportation sector, especially for heavy-duty vehicles. In this context, the industry and the scientific community are in need of advanced fuel cell systems (FCS) models that are able to replicate real -world operating conditions. Due to the scarcity of said models in the open literature, this study aimed to develop a comprehensive methodology to calibrate and validate multi -physics dynamic FCS models. Therefore, the key contribution of this paper is the detailed description of the calibration process for each component and the calibration order. The specific focus here was to accurately describe the behavior of the FC stack as well as the cathode, anode, and cooling circuits of the balance of plant. The model was calibrated with the aid of experimental data from a Toyota Mirai FC electric vehicle, which was predominantly retrieved from the vehicle's Controller Area Network (CAN) bus system thereby negating the need for major intrusion into the powertrain system. The validation process was deemed successful with the model being able to truthfully replicate the characteristics of the FC vehicle operated on the World-wide harmonized Light duty Test Cycle (WLTC) 3b and US06 driving cycle. The time -resolved physical parameters such as the cathode pressure, mass flow, or the FC stack temperature were captured with high fidelity, while the overall performance parameters such as the H2 consumption in the stack and the system, and the compressor energy consumption were predicted accurately with a deviation lower than 0.47%, 1.75% and 1.89% with respect to the experimental data, respectively.

Lopez-Juarez, Marcos↗

Advanced propulsion engine assessment based on a cermet reactor

A preferred Pratt & Whitney conceptual Nuclear Thermal Rocket Engine (NTRE) has been designed based on the fundamental NASA priorities of safety, reliability, cost, and performance. The basic philosophy underlying the design of the XNR2000 is the utilization of the most reliable form of ultrahigh temperature nuclear fuel and development of a core configuration which is optimized for uniform power distribution, operational flexibility, power maneuverability, weight, and robustness. The P&W NTRE system employs a fast spectrum, cermet fueled reactor configured in an expander cycle to ensure maximum operational safety. The cermet fuel form provides retention of fuel and fission products as well as high strength. A high level of confidence is provided by benchmark analysis and independent evaluations.

Parsley, Randy C.↗

Investigating Radiation-Induced Actinide Species in Solution

Our fundamental understanding of actinide radiation-induced redox chemistry is crucial to nuclear fuel cycle development, due to the unavoidable exposure of these elements to ionizing radiation fields, both inherent and from in-process applications. Plutonium (Pu) and americium (Am) both possess multiple oxidation states, the careful manipulation of which are essential in the study and utilization of their rich chemistry, developing new nuclear technologies, and securing the long-term sustainability of nuclear power. However, knowledge in this area is far from complete. Consequently, we have studied the radiation-induced chemistry of both Pu and Am through a variety of techniques. Temperature-controlled electron pulse radiolysis has been used to study Am for the first time, determining the feasibility of Am redox reactions under used nuclear fuel reprocessing conditions, (e.g. nitric acid, non-ambient temperature). Additionally, we have developed an experimentally evaluated multi-scale computer model for the prediction of gamma radiation-induced Pu redox chemistry due to radiolysis and disproportionation reactions in concentrated nitric acid solutions.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Resumption of SFR Overpower Testing and Post-Transient Examination of the THOR-C-2 Irradiation Test

Transient overpower testing for fuel safety research and development has resumed at Idaho National Laboratory. The THOR-C-2 commissioning test has been performed and post-transient examination has been performed revealing the intended failure near the top of the fuel zone. This paves the way for future testing on previously irradiated fuels that will support fuel development and qualification.

advanced reactors↗

Fuel conservative aircraft engine technology

NASA's Aircraft Energy Efficiency Program, initiated in an effort to minimize the adverse impact of the worldwide fuel crisis, will develop technology for more fuel-efficient subsonic transport aircraft. The program includes three major propulsion projects: (1) Engine Component Improvement, directed at current engines, (2) Energy Efficient Engine, directed at new turbofan engines, and (3) Advanced Turboprops, directed at technology for advanced turboprop-powered aircraft. The present paper reviews the current status of each of these projects and describes some of the technologies and recent accomplishments.

Nored, D. L.↗

Studies of Low and Intermediate Temperature Oxidation of Propane up to 100 Atm in a Supercritical-Pressure Jet-Stirred Reactor

Here, the low and intermediate temperature oxidation of propane has been investigated by using a novel supercritical pressure jet stirred reactor (SP-JSR) with and without 20% CO 2 additions at fuel lean and rich conditions at 10 and 100 atm and 500–1000 K. The mole fractions of C 3 H 8 , O 2 , CO, CO 2 , CH 2 O, C 2 H 4 , CH 3 CHO, and C 3 H 6 were quantified by using a micro-gas chromatograph (µ-GC). The experiment showed that different from that of 10 atm, at 100 atm only a weak negative temperature coefficient (NTC) behavior was observed because of the significant shift of the intermediate temperature HO 2 chemistry to lower temperature. In addition, at 100 atm, existing models in literatures could successfully capture the onset temperatures of the low and intermediate chemistry, while under-predict the fuel oxidation quantitatively and fail to capture the NTC behavior between 650 and 780 K at both fuel lean and rich conditions. Similar discrepancy was observed in studies of n-butane and dimethyl ether (DME) oxidations in literatures, implying that there existed large uncertainties in hierarchy model development of fuels with low temperature chemistries at extremely high pressures. Reaction pathways and sensitivity analyses showed that RO 2 competing reactions through (P1) RO 2 = QOOH, (P2) RO 2 = C 3 H 6 + HO 2 , (P3) RO 2 + CH 2 O/HO 2 = RO 2 H + HCO / O 2 dominated the low and intermediate temperature chemistries, followed by HO 2 / H 2 O 2 chemistry at 100 atm, which differed from the dominant pathway through QOOH consumption reactions at lower pressures. Especially, P3 is a new pathway of RO 2 consumption at high pressures, which was not observed in importance at low pressures. Special attention should be paid to the accurate computations of n-C 3 H 7 O 2 / i-C 3 H 7 O 2 + CH 2 O and n-C 3 H 7 O 2 / i-C 3 H 7 O 2 + in the P3 pathway and n-C 3 H 7 O 2 / i-C 3 H 7 O 2 decomposition reactions in the P2 pathway at high pressures.

33 ADVANCED PROPULSION SYSTEMS↗

Development and formulation of physics based metallic fuel models and comparison to integral irradiation data

Metallic fuel has an important historical significance in the development of nuclear reactors and continues to be relevant to the progression of advanced test and power reactors. A number of models, ranging from empirical to mechanistic, have been developed and implemented in various fuel performance codes to describe U-Zr and U-Pu-Zr fuel and typical fast reactor cladding materials. One challenge of using these models to simulate fuel performance is the inevitable tangling of coupled phenomena that can cloud proper implementation, calibration, and eventual utilization of new models. Here in an effort to provide a baseline capability that will facilitate the use of advanced models, new capabilities have been implemented into the fuel performance code BISON specific to metallic fuel simulations, ranging from materials properties, fission gas release and swelling calculations, coolant channel models, and cladding correlations. These models have been applied to the X441/X441A EBR-II experimental assembly data, a set of irradiated metallic UPuZr fuel rods of varying pin designs. The models implemented in BISON are able to capture the general trend of the expected response of the fuel and cladding to irradiation in EBR-II, especially when considering the spread in experimental measurements and the uncertainties inherited from the historical material models. Ultimately, the models outlined here provide the baseline capabilities on which new models can build upon in order to improve the prediction of metallic fuel performance simulations in off-normal designs or operations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗