Studies in fundamental chemistry of fuel cell reactions Quarterly report, 1 Apr. - 30 Jun. 1969
Research developments in fuel cell chemistry
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Research developments in fuel cell chemistry
Effects of carbon dioxide on trapped electrolyte hydrogen-oxygen alkaline fuel cells
Weight reduction and configuration of fuel cell
A manually operated fuel-cell system was modified to be monitored and controlled by a digital computer. The purpose was to have a test item with which to study possible system-computer interface problems. The modification consisted of installing solenoid valves, circuitry, transducers, and limit switches on the system. These modifications permit computer control of load current, reactant purge, water removal, and electrolyte concentration and computer initiation of system shutdown.
The completion of the study is reported for the regenerative fuel cell subsystem (RFCS) as an energy storage process for use aboard the space shuttle launched modular space station (MSS). The MSS mission requirements, and RFCS are discussed, and a comparison between RFCS and a nickel cadmium battery subsystem is presented. Development costs are also discussed.
The current status of research and development programs on batteries and fuel cells and the technology goals being pursued are discussed. Emphasis is placed upon those technologies relevant to earth orbital electric energy storage applications.
The important considerations that presently exist for achieving commercial acceptance of fuel cells are centered on cost (which translates to efficiency) and lifetime. This paper addresses the questions of electrocatalyst utilization within porous electrode structures and the preparation of low-cost noble metal electrocatalyst combinations with extreme dispersions of the metal. Now that electrocatalyst particles can be prepared with dimensions of 10 A, either singly or in alloy combinations, a very large percentage of the noble metal atoms in a crystallite are available for reaction. The cost savings for such electrocatalysts in the present commercially driven environment are considerable.
After several years of development of the regenerative fuel cell (RFC) as the electrochemical storage system to be carried by the future space station, the official stance has now been adopted that nickel hydrogen batteries would be a better system choice. RFCs are compared with nickel hydrogen and other battery systems for space platform applications.
The component materials used in the fabrication of phosphoric acid fuel cells (PAFC) must have mechanical, chemical, and electrochemical stability to withstand the moderately high temperature (200 C) and pressure (500 kPa) and highly oxidizing nature of phosphoric acid. This study discusses the chemical and structural stability, performance and corrosion data on certain catalysts, catalyst supports, and electrode support materials used in PAFC applications.
An account is given of the development status of phosphoric acid fuel cells' high performance catalyst and electrode materials. Binary alloys have been identified which outperform the baseline platinum catalyst; it has also become apparent that pressurized operation is required to reach the desired efficiencies, calling in turn for the use of graphitized carbon blacks in the role of catalyst supports. Efforts to improve cell performance and reduce catalyst costs have led to the investigation of a class of organometallic cathode catalysts represented by the tetraazaannulenes, and a mixed catalyst which is a mixture of carbons catalyzed with an organometallic and a noble metal.
An air-cooled, hydrogen-air solid polymer electrolyte (SPE) fuel cell with a membrane electrode assembly operatively associated with a fluid flow plate having at least one plate cooling channel extending through the plate and at least one air distribution hole extending from a surface of the cathode flow field into the plate cooling channel.
An improved system for interconnects in a fuel cell. In one embodiment, the membranes are located in parallel with one another, and current flow between them is facilitated by interconnects. In another embodiment, all of the current flow is through the interconnects which are located on the membranes. The interconnects are located between two electrodes.
Performance of direct methanol fuel cells with sputter-deposited Pt-Ru anodes was investigated.
Carbides, nitrides, nitrocarbides, and carbonitrides of iron examined for catalytic activity in oxygen reduction reaction in potassium hydroxide - peroxide fuel cells
Gas pressure reduction in silver-zinc batteries by installing miniature hydrogen-oxygen fuel cell
Metal, alloy, and metal compound testing for corrosion resistance and activity as oxygen electrodes for hydrox fuel cell with alkaline electrolyte
Catalysts for Aerozine-50 reforming and nitrogen tetroxide decomposition for development of rocket fuel cells operating on storable propellant
Theory, operation, and testing of components, single and multicell assemblies, static moisture removal subsystem, and mathematical model of hydrogen-oxygen membrane fuel cell system