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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

Synthesis of fluorinated organic compounds using oxygen difluoride

Oxygen difluoride synthesis is a much simpler, higher-yield procedure than reactions originally followed to synthesize various fluorinated organic compounds. Extreme care is taken in working with oxygen difluoride as its reactions present severe explosion hazard.

Toy, M. S.↗

Chlorine-fluorine flame structure

Chlorine-fluorine flame, determining adiabatic propagation speed, refractive index field, temperature profile, composition distribution and atom concentrations

Ambs, L. L.↗

Preparation of stable colloidal dispersions in fluorinated liquids

Chemical method for separating oil from water by liquid barrier which can be positioned magnetically is described. Fluorocarbon liquids containing colloidal suspension of magnetite is proposed. Chemical composition of magnetite and fluorinated ether polymer are presented.

Kaiser, R.↗

Development of a metallic bellows expulsion device for fluorine service

A complete expulsion device was designed, fabricated, and tested in accordance with requirements specified by NASA to demonstrate the feasibility of using metallic bellows to expel liquid fluorine. Difficulties were experienced in obtaining leaktight welds at the bellows end terminals, but eventually three assemblies were successfully fabricted and cycle tested, one in LN2, two in LF2. The bellows performed well, except that they failed prematurely in LF2, apparently the result of small initiator cracks in the seam welds of the bellows.

Fearn, R. F.↗

Design, testing, fabrication and launch support of a liquid chemical barium release payload (utilizing the liquid fluorine-barium salt/hydrazine system)

A payload was designed which included a cryogenic oxidizer tank, a fuel tank, and burner section. Release of 30 lb of chemicals was planned to occur in 2 seconds at the optimum oxidizer to fuel ratio. The chemicals consisted of 17 lb of liquid fluorine oxidizer and 13 lb of hydrazine-barium salt fuel mixture. The fuel mixture was 17% barium chloride, 16% barium nitrate, and 67% hydrazine, and contained 2.6 lb of available barium. Two significant problem areas were resolved during the program: explosive valve development and burner operation. The release payload was flight tested, from Wallops Island, Virginia. The release took place at an altitude of approximately 260 km. The release produced a luminous cloud which expanded very rapidly, disappearing to the human eye in about 20 seconds. Barium ion concentration slowly increased over a wide area of sky until measurements were discontinued at sunrise (about 30 minutes).

Stokes, C. S.↗

Vehicle-scale investigation of a fluorine jet-pump liquid hydrogen tank pressurization system

A comprehensive analytical and experimental program was performed to evaluate the performance of a fluorine-hydrogen jet-pump injector for main tank injection (MTI) pressurization of a liquid hydrogen (LH2) tank. The injector performance during pressurization and LH2 expulsion was determined by a series of seven tests of a full-scale injector and MTI pressure control system in a 28.3 cu m (1000 cu ft) flight-weight LH2 tank. Although the injector did not effectively jet-pump LH2 continuously, it showed improved pressurization performance compared to straight-pipe injectors tested under the same conditions in a previous program. The MTI computer code was modified to allow performance prediction for the jet-pump injector.

Cady, E. C.↗