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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Stabilization of NbTe 3 , VTe 3 , and TiTe 3 via Nanotube Encapsulation

The structure of MX 3 transition metal trichalcogenides (TMTs, with M a transition metal and X a chalcogen) is typified by one-dimensional (1D) chains weakly bound together via van der Waals interactions. This structural motif is common across a range of M and X atoms (e.g. NbSe 3 , HfTe 3 , TaS 3 ), but not all M and X combinations are stable. We report here that three new members of the MX 3 family which are not stable in bulk, specifically NbTe 3 , VTe 3 , and TiTe 3 , can be synthesized in the few- to single-chain limit via nano-confined growth within the stabilizing cavity of multi-walled carbon nanotubes. Transmission electron microscopy (TEM) and atomic-resolution scanning transmission electron microscopy (STEM) reveal the chain-like nature and the detailed atomic structure. The synthesized materials exhibit behavior unique to few-chain quasi-1D structures, such as multi-chain spiraling and a trigonal anti-prismatic rocking distortion in the single-chain limit. Density functional theory (DFT) calculations provide insight into the crystal structure and stability of the materials, as well as their electronic structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Iodine encapsulation in CNTs and its application for electrochemical capacitor

We report the experimental results for new type electrochemical capacitor using iodine redox reaction in single-walled carbon nanotubes (SWCNTs). It was found that the energy density of the present redox capacitor using SWCNTs is almost three times larger than that of the normal electric double layer capacitor.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2014

Roll-to-roll atomic layer deposition process for flexible electronics encapsulation applications

At present flexible electronic devices are under extensive development and, among them, flexible organic light-emitting diode displays are the closest to a large market deployment. One of the remaining unsolved challenges is high throughput production of impermeable flexible transparent barrier layers that protect sensitive light-emitting materials against ambient moisture. The present studies deal with the adaptation of the atomic layer deposition (ALD) process to high-throughput roll-to-roll production using the spatial ALD concept. We report the development of such a process for the deposition of 20 nm thickness Al{sub 2}O{sub 3} diffusion barrier layers on 500 mm wide polymer webs. The process uses trimethylaluminum and water as precursors at a substrate temperature of 105 °C. The observation of self-limiting film growth behavior and uniformity of thickness confirms the ALD growth mechanism. Water vapor transmission rates for 20 nm Al{sub 2}O{sub 3} films deposited on polyethylene naphthalate (PEN) substrates were measured as a function of substrate residence time, that is, time of exposure of the substrate to one precursor zone. Moisture permeation levels measured at 38 °C/90% relative humidity by coulometric isostatic–isobaric method were below the detection limit of the instrument (<5 × 10{sup −4} g/m{sup 2} day) for films coated at web moving speed of 0.25 m/min. Measurements using the Ca test indicated water vapor transmission rates ∼5 × 10{sup −6} g/m{sup 2} day. Optical measurements on the coated web showed minimum transmission of 80% in the visible range that is the same as the original PEN substrate.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Spatial atomic layer deposition: Performance of low temperature H{sub 2}O and O{sub 3} oxidant chemistry for flexible electronics encapsulation

Water and oxygen were compared as oxidizing agents for the Al{sub 2}O{sub 3} atomic layer deposition process using spatial atomic layer deposition reactor. The influence of the precursor dose on the deposition rate and refractive index, which was used as a proxy for film density, was measured as a function of residence time, defined as the time which the moving substrate spent within one precursor gas zone. The effect of temperature on the growth characteristics was also measured. The water-based process gave faster deposition rates and higher refractive indices but the ozone process allowed deposition to take place at lower temperatures while still maintaining good film quality. In general, processes based on both oxidation chemistries were able to produce excellent moisture barrier films with water vapor transmission rate levels of 10{sup −4} g/m{sup 2} day measured at 38 °C and 90% of relative humidity on polyethylene naphthalate substrates. However, the best result of <5 × 10{sup −5} was obtained at 100 °C process temperature with water as precursor.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Reducing Thermal Losses and Gains With Buried and Encapsulated Ducts in Hot-Humid Climates

Thermal losses and gains from ductwork installed in unconditioned spaces—such as attics, crawl spaces, and garages—can contribute significantly to the overall heating and cooling loads of single-family residential buildings, with estimated duct losses ranging from 10%–45 %. The impact is particularly severe in hot climates where air conditioning dominates and extensive duct systems are typically located in hot attics. The duct system inefficiencies are greatest at peak demand conditions when the attic is hottest and run times are the highest. The thermal losses and gains at the three single-story houses in Florida monitored in this study accounted for 15%–35% of the annual pre-retrofit heating and cooling energy use and 6%–25% of the total pre-retrofit annual utility bill. Even though a number of existing methods can effectively move ducts into the conditioned space, they are not currently being widely implemented. Physically locating the ducts within the conditioned space is most often applicable only to new construction projects and requires planning during design. Attics can be insulated at the roof deck with closed-cell polyurethane foam (ccSPF) to reduce duct losses and infiltration rates, but this method has high up-front costs and the potential to increase loads on the building enclosure. In hot-dry climates, attic duct systems can be buried under loose-fill insulation at a significantly lower cost to reduce thermal loads. In hot-humid climates, however, condensation on the duct jacket can occur when the humidity in the attic is high.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

OLED Lighting Substrate and Encapsulation System for Breakthrough Cost Reductions

OLED lighting is predicted to contribute a significant part of the US energy savings that will result from the implementation of Solid-State Lighting (SSL). OLED lighting adoption is predicted to reach approximately 5% of the lighting market by 2020. The primary purpose of this study was to address a barrier in OLED lighting adoption, this being OLED production costs. This project enabled the elimination of the anode patterning steps, by physically insulating the cathode contact area from the blanket coated ITO anode. Furthermore, this technology eliminates the need to change shadow masks between the organic materials and the cathode, making the OLED deposition machines simpler, lower cost, and less prone to particle generation. Finally, the process developed here permits the creation of a perfectly hermetic seal thereby eliminating the cost of desiccant materials. In this project, we successfully developed an ultrasonic soldering process to create a perfectly hermetic metal-on-glass bond. This required the evaluation of many ultrasonic solder materials, soldering parameters, and solder hardware configurations. In addition, methods to evaluate the hermeticity of the solder seal were developed and successfully tested. Our work demonstrated the ability to make a hermetic solder seal between a device glass and a cover glass using a Cerasolzer 155 ultrasonic solder. The resulting process could be leveraged to almost any OLED configuration. As we did not have the opportunity to produce a significant quantity of OLED devices for environmental testing, hermeticity was verified by measuring helium leakage rates through the seal. A second facet of this project required the development of a patterned glass frit insulating barrier over surface of the anode. To accomplish this, the appropriate insulator formulation and geometry needed to be established. In addition, this insulator needed to be robust enough to hold up to the ultrasonic soldering process previously mentioned. Given the aggressive nature of the ultrasonic soldering process, it was a significant challenge to develop an insulator which would withstand the resulting solder cavitation. The frit material and firing process turned out to be quite expensive and time consuming which was a major contributor to the higher than anticipated cost of this technology. In the end, it was found that a Vanadium Phosphate glass frit provided the most reliable insulator over the ITO.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2015

Recent Developments on Autonomous Corrosion Protection Through Encapsulation

This paper concerns recent progress in the development of a multifunctional smart coating, based on microencapsulation, for the autonomous detection and control of corrosion. Microencapsulation has been validated and optimized to incorporate desired corrosion control functionalities, such as early corrosion detection and inhibition, through corrosion-initiated release of corrosion indicators and inhibitors, as well as self-healing agent release triggered by mechanical damage. While proof-of-concept results have been previously reported, more recent research and development efforts have concentrated on improving coating compatibility and synthesis procedure scalability, with a targeted goal of obtaining easily dispersible pigment-grade type microencapsulated materials. The recent progress has resulted in the development of pH-sensitive microparticles as a corrosion-triggered delivery system for corrosion indicators and inhibitors. The synthesis and early corrosion indication results obtained with coating formulations that incorporate these microparticles are reported. The early corrosion indicating results were obtained with color changing and with fluorescent indicators.

Autonomous↗
DOE OSTI2015

Spent Fuel NDA Research Path for the Sweden Encapsulation-Repository

This set of slides provides a description of research performed to date on spent fuel NDA: Next Generation Safeguards Initiative Spent Fuel Project, and NDA analysis and research planned for CLINK. The general purpose is strengthening the technical toolkit of safeguard inspectors. Data mining is being applied to determine the optimal mathematical structure to match the complexity of spent fuel NDA signals and to enable a range of quantities to be estimated.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗