ACCURATE BOND ENERGIES OF BIODIESEL METHYL ESTERS FROM MULTIREFERENCE AVERAGED COUPLED-PAIR FUNCTIONAL CALCULATIONS
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The Amazon forest plays an important role in the tropical circulation and global water and biogeochemical cycles. However, the common Amazon precipitation biases in global climate models undermine our ability to understand future changes in the Amazon and their global consequences. The Community Earth System Model exhibits a persistent wet season dry bias over the southwestern Amazon. The bias is also characterized by inaccurate diurnal timing and intensity of rainfall events. Analysis of a diverse set of simulations suggests that the bias originates from local processes. A known land model bias in the partitioning of surface energy fluxes is found not to contribute significantly to the rainfall bias. Key model processes are identified to be the low-level divergent circulation controlling horizontal moisture flow and the sensitivity of the modeled deep convection to the lower tropospheric moisture. The lower tropospheric moisture divergence dictates the spatiotemporal distributions of convective precipitation through parameterized entrainment mixing, which generally improves the rainfall diurnal cycle. However, it also limits convective precipitation over the areas with frequent and large-scale divergence in the lower troposphere. The southwestern Amazon is such an area, particularly in the late afternoon, although uncertainty exists in the low-level flow in the simulation and reanalyses. One way to sustain rainfall in the presence of low-level divergence is a convective trigger based on both the moisture and temperature changes by large-scale processes, which is shown to help in reducing the dry bias.
Different cloud types are generated over Antarctica as a result of various synoptic conditions. The cloud characteristics affect their impact on the surface energy budget. In this study, the dominating synoptic regimes over Antarctica (centered on the Ross Ice Shelf) are classified using self-organizing map (SOM) analysis, applied over long-term ERA-Interim 700 hPa geopotential height data. The corresponding cloud properties over McMurdo Station (measured as part of the AWARE campaign) are described and discussed with respect to the synoptic settings and sea-ice extent conditions. Cloud radiative forcing calculations are performed as well, and a particular focus is given to the net longwave “radiatively cloudy/opaque” (RO) regime. These results are compared with measurements performed at the West Antarctic Ice Sheet (WAIS) Divide to examine their variability and applicability to other Antarctic locations. It is found that the McMurdo cloud properties are strongly affected by the regional mesoscale cyclonic activity, which counterweights the larger-scale synoptic regime influence, while the WAIS clouds are more susceptible to the varying synoptic settings. In addition, it is suggested that the positive trend in the (frequent) cyclonic activity near the Antarctic coastal regions makes ice-clouds an increasing prominent contributor for the RO cases, especially during freeze-up and maximum sea-ice conditions.
Abstract A regional perspective is taken to investigate the intriguing ∼25‐day periodicity in the Southern Hemisphere (SH) baroclinic annular mode (BAM) and the possible underlying mechanisms. Results show that the 25‐day periodicity exists not only in the zonal average but also in the regional average of eddy activity as long as the domain of the average is wide enough to accommodate a wave packet. The favorable domain for the ∼25 days periodicity is located downstream of the largest baroclinicity in midlatitudes. The wave activity developed there can travel circumglobally several times with a typical group velocity of 25 m s −1 , and reenter the domain every 12.5 days, setting the base periodicity. A slower oceanic oscillation at a time scale of ∼100 days in the same region appears to select and reinforce the multiples of 12.5 days, giving rise to a pronounced ∼25‐day periodicity in the wave activity.
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