Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CLAYS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 595 records · Page 33

The Geologic History of Mars: An Astrobiology Perspective

Fourteen SNC meteorites contain information which must be incorporated with recent spaceflight data for developing Mars' geologic history. SNCs have crystallization ages of 4500 to 160 m.y. Tle oldest meteorite ALH84001 contains information on the Noachian period of Mars' history. There are no meteorites from the Hesperian period and the remaining 13 meteorites fall into two age groups within the Amazonian: The nakhlites around 1300 m.y. and the shergottites between 800-160 m.y. Oxygen isotopic analysis of Martian samples shows two distinct O2 reservoirs throughout Martian history indicating late additions of volatiles and a lack of plate tectonics prior to 3.9 Gy. Evidence for percolation of aqueous brines through impact-produced fractures in the rocky surface is contained in the 3.9 Gy-old ALH84001 carbonate deposits. These carbonates precipitated at approx. 100 C. At this time life had already evolved on Earth. Early Mars could have hosted life similar to the bacteria that inhabited early Earth. Potential microorganisms could have been transported into fractures by carbonate-bearing waters and their remains could have become incorporated into the precipitated carbonate. Since Mars had a weak magnetic field at this time, it can be hypothesized that some of the Martian microorganisms may have been similar to terrestrial magnetotactic bacteria. Over geologic time episodic cratering, and tectonic events have occurred on Mars along with the periodic release of subsurface waters which may have produced clays within SNC meteorites. The geochemical data contained within SNC meteorites complements previous observational data and the recent Mars Global Surveyor data to provide a geological and environmental history which spans almost the entire lifespan on Mars. One of the outstanding features of this model is the possible creation of an early (about 4 Gy) volatile reservoir distinct from the outgassed Mars volatiles, and the persistence of this reservoir throughout most, if not all of subsequent Mars' history. Within the framework of this history a potential scenario for a possible record of living organisms is provided by suggestive structures and organic signatures trapped within secondary mineral deposits and alteration features of some SNC meteorites. Tracing the differences in oxygen isotopic compositions within Martian components allows us to gain insight in the history of Mars.

Gibson, Everett K.↗

Late Holocene Environmental Changes from NY-NJ Estuaries

High-resolution records of environmental change in the lower Hudson estuary are quite rare. We present preliminary data from several marshes in the New York- New Jersey region in order to understand the late Holocene environmental history of this region. Our project includes salt marsh cores from Hackensack, Piermont, Staten Island, and Jamaica Bay. Our preliminary research has focused on a 11.15 m sediment core from Piermont Marsh, New York (40 deg N, 74 deg W) in an attempt to document the Holocene environmental history of the region. Lithology, loss -on -ignition (LOI), pollen, plant macrofossils, charcoal, and foraminifera were analyzed. Core lithology consists of peat, silts, and clays that vary in color and texture. The base of the core is AMS C-14 dated to 4190 yr BP. Preliminary low-resolution analysis of the core to date includes sampling at the 1-meter interval throughout the core. LOI of the sediments ranges from 1% to 85%. Average rate of deposition is about .26 cm/yr. Major changes in pollen percentages are visible throughout the core.

Peteet, Dorothy M.↗

Mineralogy of the Martian Surface: Crustal Composition to Surface Processes

Over the course of this award we have: 1) Completed and published the results of a study of the effects of hyperfine particles on reflectance spectra of olivine and quartz, which included the development of scattering codes. Research has also progressed in the analysis of the effects of fine particle sizes on clay spectra. 2) Completed the analysis of the mineralogy of dark regions, showed the insitu compositions are highly correlated to the SNC meteorites, and determined that the martian mantle was depleted in aluminum prior to 2-3 GA ago; Studies of the mineralogic heterogeneity of surficial materials on Mars have also been conducted. and 3) Performed initial work on the study of the physical and chemical processes likely to form and modify duricrust. This includes assessments of erosion rates, solubility and transport of iron in soil environments, and models of pedogenic crust formation.

Mustard, John F.↗

Late Holocene Environmental Changes from NY-NJ Estuaries

High-resolution records of environmental change in the lower Hudson estuary are quite rare. We present preliminary data from several marshes in the New York- New Jersey region in order to understand the late Holocene environmental history of this region. Our project includes salt marsh cores from Hackensack, Piermont, Staten Island, and Jamaica Bay. Our preliminary research has focused on a 11.15 m. sediment core from Piermont Marsh, New York (40 N, 74 W) in an attempt to document the Holocene environmental history of the region. Lithology, loss-on-ignition (LOI), pollen, plant macrofossils, charcoal, and foraminifera were analyzed. Core lithology consists of peat, silts, and clays that vary in color and texture. The base of the core is AMS C-14 dated to 4190 yr BP. Preliminary low-resolution analysis of the core to date includes sampling at the 1-meter interval throughout the core. LOI of the sediments ranges from 1% to 85%. Average rate of deposition is about .26 cm/yr. Major changes in pollen percentages are visible throughout the core.

Peteet, Dorothy M.↗

Clues from the SWIR: Mineralogical Constraints from 1 to 4 microns

Among the great Mars mineral problems are the predictions of both carbonates and clays as alteration products and the lack of observational evidence to support those predictions. In spite of geochemical evidence of sulfur and chlorine in the soils, assignment of specific sulfates and chlorides has remained elusive. The purpose of this contribution is to show several common alteration minerals that are consistent with the short-wave infrared surface spectra and geochemistry, briefly consider the silicate problem, propose an additional method of soil formation and review what surface measurements in the spectral range from approximately 1 to 4 microns can do to help resolve remaining ambiguities of surface mineralogy. Additional information is contained in the original extended abstract.

Calvin, W. M.↗

Microorganisms from Permafrost Viable and Detectable by 16SRNA Analysis: A Model for Mars

Preliminary studies of Arctic and Antarctic permafrost have shown that this environment harbors microorganisms which can be isolated in pure culture, and that these organisms can survive for a long period of time (up to 20 Ma) in permafrost. It is believed that the permanent subzero temperatures in permafrost and ice environments are the main parameters ensuring the longevity of microbes. In this project we studied permafrost cores from different areas of the Siberian Arctic and Antarctic, with ages from several thousand years up to several millions years (Ma). In general, Antarctic permafrost has a higher sand content, while Siberian permafrost has a texture more characteristic of clay or normal soil. Additional information is contained in the original extended abstract.

Tsapin, A. I.↗

H2O Adsorption Kinetics on Smectites

The adsorptive equilibration of H2O a with montomorillonite, a smectite clay has been measured. At low temperatures and pressures, equilibration can require many hours, effectively preventing smectites at the martian surface from responding rapidly to diurnal pressure and temperature variations.

Zent, Aaron P.↗

H2O Adsorption on Smectites: Application to the Diurnal Variation of H2O in the Martian Atmosphere

Observations of the Martian planetary boundary layer lead to interpretations that are baffling and contradictory. In this paper, we specifically address the question of whether or not water vapor finds a substantial diurnal reservoir in the Martian regolith. To address this issue, we have measured H2O adsorption kinetics on SWy-1, a Na-rich montmorillonite from Wyoming. The highest-temperature (273 K) data equilibrates rapidly. Data gathered at realistic H2O partial pressures and temperatures appropriate to early morning show two phenomena that preclude a significant role for smectites in diurnally exchanging a large column abundance. First, the equilibration timescale is longer than a sol. Second, the equilibrium abundances are a small fraction of that predicted by earlier adsorption isotherms. The explanation for this phenomenon is that smectite clay actually increases its surface area as a function of adsorptive coverage. At Mars-like conditions, we show that the interlayer sites of smectites are likely to be unavailable.

Zent, Aaron P.↗

Orbital Cyclicities Above and Below the Cretaceous-Tertiary Boundary, Umbria-Marche Region, Italy

In the Umbria-Marche region of central Italy, the deep basinal carbonate Scaglia Rossa Formation contains an important sequence of Cretaceous-Tertiary strata including a detailed paleomagnetic record and the distal impactoclastic Cretaceous-Tertiary boundary clay layer. In addition to this significant paleomagnetic and impactoclastic record, the Scaglia Rossa also contains potentially important stratigraphic evidence of relatively long-term oceanic and atmospheric consequences of the Cretaceous-Tertiary bolide catastrophe, which we will describe for the first time herein. Additional information is contained in the original extended abstract.

King, D. T., Jr.↗

Abrupt Changes at the Permian/Triassic Boundary: Tempo of Events from High-Resolution Cyclostratigraphy

The Permian/Triassic (P/Tr) boundary (251.4 +/- 3 Myr) is marked by the most severe mass extinction in the geologic record. Recently, precise absolute dating has bracketed the marine extinctions and associated carbon-isotope anomaly within less than 1 Myr. We improve this resolution through high-resolution stratigraphy across the P/Tr boundary in the 331-m Gartnerkofel-1 core and nearby Reppwand outcrop section (Carnic Alps, Austria) utilizing FFT and wavelet timeseries analyses of cyclic components in down-hole core logs of density and natural gamma-ray intensity, and carbon-isotopic ratios of bulk samples. The wavelet analysis indicates continuity of deposition across the P/Tr boundary interval, and the timeseries analyses show evidence for persistent cycles in the ratio of approximately 40: 10: 4.7: 2.3 meters, correlated with Milankovitch-band orbital cycles of approximately 412: 100: 40: 20 kyr (eccentricity 1 and 2, obliquity, and precession), and giving a consistent average sedimentation rate of approximately 10 cm/1,000 yr. Milankovitch periods in delta C-13 and density in these shallow-water carbonates were most likely the result of climatically induced oscillations of sea level and climate, coupled with changes in ocean circulation and productivity, that affected sedimentation. Fluctuations in gamma radiation reflect varying input of clay minerals and the presence of shaly interbeds. Throughout the P/Tr boundary interval in the core, the 100,000-year eccentricity cycle seems to be dominant. Weaker obliquity and precession cycles are in line with the location of the Austrian section in the latest Permian, close to the Equator in the western bight of the Tethys, where obliquity and precessional effects on seasonal contrast might be subdued. Using the improved resolution provided by cycle analysis in the GK-1 core, we find that the dramatic change in the faunal record that marks the P/Tr boundary takes place over less than 6m, or less than 60,000 years. In the nearby Reppwand outcrop section, the same faunal changes occurs over only 0.8 m or about 8,000 years, close to the limit of time-resolution induced by bioturbation and reworking in these sediments. The sharp negative global carbon-isotope shift took place within less than or equal to 40,000 yr, and the isotope excursions persisted for approximately 480,000 yr into the Early Triassic. The results indicate that the severe marine faunal event that marks the P/Tr boundary was very sudden, perhaps less than the resolution window in the GK-1 core, and suggest a catastrophic cause. The wavelet-analysis approach to high-resolution cyclostratigraphy can be applied to other P/Tr boundary sections, and when combined with precise absolute dating and magnetostratigraphic methods promises a significant increase in resolution in determining the correlation and tempo of the end-Permian extinctions and related events worldwide.

Rampino, M. R.↗

Detection and Characterization of Martian Volatile-Rich Reservoirs: The Netlander Approach

Geological and theoretical modeling do indicate that, most probably, a significant part of the volatiles present in the past is presently stocked within the Martian subsurface as ground ice, and as clay minerals (water constitution). The detection of liquid water is of prime interest and should have deep implications in the understanding of the Martian hydrological cycle and also in exobiology. In the frame of the 2005 joint CNES-NASA mission to Mars, a set of 4 NETLANDERs developed by an European consortium is expected to be launched between 2005 and 2007. The geophysical package of each lander will include a geo-radar (GPR experiment), a magnetometer (MAGNET experiment), a seismometer (SEIS experiment) and a meteorological package (ATMIS experiment). The NETLANDER mission offers a unique opportunity to explore simultaneously the subsurface as well as deeper layers of the planetary interior on 4 different landing sites. The complementary contributions of all these geophysical soundings onboard the NETLANDER stations are presented.

Banerdt, B.↗

Low Velocity Earth-Penetration Test and Analysis

Modeling and simulation of structural impacts into soil continue to challenge analysts to develop accurate material models and detailed analytical simulations to predict the soil penetration event. This paper discusses finite element modeling of a series of penetrometer drop tests into soft clay. Parametric studies are performed with penetrometers of varying diameters, masses, and impact speeds to a maximum of 45 m/s. Parameters influencing the simulation such as the contact penalty factor and the material model representing the soil are also studied. An empirical relationship between key parameters is developed and is shown to correlate experimental and analytical results quite well. The results provide preliminary design guidelines for Earth impact that may be useful for future space exploration sample return missions.

Fasanella, Edwin L.↗

Paleoenvironmental History of JoCo Marsh, Jamaica Bay, New York

Sediment cores from JoCo Marsh, located in Jamaica Bay, NY were analyzed for plant macrofossil and foraminifera records. These records reflect changes in vegetation, sea level, climate and human intervention. Better understanding of past environmental changes provides information for future preservation and protection of the estuary. A 2.81 m core was retrieved from JoCo, a high marsh area located on the eastern side of Jamaica Bay. The lithology of the core differs from high levels of sand, with small amounts of clay, in the bottom 0.8 meters, to salt marsh peat in the upper 2 meters of the core. Basal wood in the sand was dated to about 2060 yr BP. Elphidium foraminifera dominate the basal sands, along with Scirpus seeds, wood, and charcoal. These sands include fish scales which are tentatively identified as killifish, suggesting shallow pools. The transition to marsh peat is dominated by sedge seeds, and declines in charcoal. The peat appears to be dominated by salt marsh grasses. At 2 m the foraminifera change to include mainly Trochammina species and other undifferentiated agglutinates. The upper portion of the core is dominated by Salicornia seeds along with Trochammina and Miliammina or Quinqueloculia. The history of this marsh will be integrated with other records of marsh environmental change along the US eastern seaboard.

Liberman, Louisa↗

Salt Marsh Formation in the Lower Hudson River Estuary

Salt marshes are constant depositional environments and as a result contain accurate indicators of past relative sea level rise and salinity. The Hudson River marshes are at least twice as deep when compared to coastal marshes on either side of the mouth of the Hudson. The reason for this difference in sedimentation is unclear. This study uses macrofossil data as well as sediment stratigraphy in order to understand the formation and evolution of these marshes. The composition of seeds, roots, shoots and foraminifera, are used to indicate past sea levels. The four sites involved in this study are, from south to north, the Arthur Kill Marsh in Staten Island (40 36 N, 74 77W), Piermont marsh (N 4100; 73 55W) Croton Point (41 14 N; 73 50W) and Iona Island (41 18N, 73 58W). These are all tidally influenced but with increasing distances from the New York Bight, which gives a good spectrum of tidal influence. AMS-C14 dates on basal macrofossils will document the time of each marsh formation. Basal material from Arthur Kill (8 m) includes freshwater seeds such as Viola, Potomageton and Alnus along with Salix buds. Basal material from Croton Point (10 m) includes fibrous woody material, foraminifera and Zanichellia seeds and other brackish vegetational components. The basal material from Piermont (13.77 m) is lacking any identifiable macrofossils between 150 and 500 microns. The basal material from Iona Island (10 m) has vegetation such as Scirpus and Cyperus seeds, probably implying a brackish environment. The freshwater origin of the Arthur Kill marsh in Staten Island is significant because it predates either sea level rise or the western channel incision. Additional implications for this study include evidence for changes in river channel geomorphology. Reasons for the relatively deeper river marshes include possible basal clay compaction, high production due to river and marine nutrients as well as tectonic activity. This study provides the groundwork for more high-resolution studies of these marshes to understand the fluctuations in salinity caused by relative sea level rise, tectonic faulting and/or changes in precipitation/evaporation.

Merley, Michael↗

Geochemical and Mineralogical Analyses of Palagonitic Tuffs and Altered Rinds of Pillow Lavas on Iceland and Applications to Mars

Samples of altered pillow lavas and hyalotuffs were collected from a volcanic Tuya and hyaloclastite ridge in western Iceland. Altered basaltic material from regions such as Hloudufell Tuya and Thorolfsfell Ridge may be similar to the surface fines on Mars, which are thought to contain altered basaltic components as well. Geochemical and mineralogical analyses have been performed on the Icelandic samples in order to characterize the properties that distinguish palagonitization from other forms of low temperature alteration in this environment. Major elements were measured using an electron microprobe and mineralogy was determined through X-ray diffraction and visible- infrared reflectance spectroscopy. The primary focus in this study was on the less than 2 microns size fractions of the Hloudufell altered pillow and Thorolfsfell palagonitic tuff samples. The palagonitic tuff contained more crystalline clay minerals and has a higher Al/Fe ratio. The altered pillow lava contained higher abundances of nanophase iron oxides/oxyhydroxides. The extended visible region spectra of the less than 2 microns fractions of both Icelandic samples are similar to bright Martian soils measured by Pathfinder.

Bishop, Janice↗

Mars Eolian Geology at Airphoto Scales: The Large Wind Streaks of Western Arabia Terra

More than 27,000 pictures at aerial photograph scales (1.5-12 m/pixel) have been acquired by the Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) since September 1997. The pictures are valuable for testing hypotheses about geologic history and processes of Mars. Of particular interest are eolian features connected to surface albedo patterns. This work is focused on low-albedo wind streaks, some over 100 km long, in western Arabia Terra. Each streak is widest where it originates at an impact crater (typically 25-150 km diameter). The streaks taper downwind. Within the associated craters there is a lower-albedo surface that, in nearly all observed cases, includes barchan dunes indicative of transport in the same direction as the wind streaks. Upwind of the dunes there is usually an outcrop of layered material that might have served as a source for dune sand. MOC images show that the west Arabia streaks consist of a smooth-surfaced, multiple-meters-thick, mantle (smooth at 1.5 m/pixel) that appears to be superposed on local surfaces. No dunes are present, indicating that down-streak transport of sediment via saltation and traction have not occurred. Two models might explain the observed properties: (1) the streaks consist of dark silt- and clay-sized grains deflated from the adjacent crater interiors and deposited from suspension or (2) they are remnants (protected in the lee of impact crater rims) of a formerly much larger, regional covering of low albedo, smooth-surfaced mantle. The latter hypothesis is based on observation of low albedo mantled surfaces occurring south of west Arabia in Terra Meridiani. For reasons yet unknown, a large fraction of the martian equatorial regions are covered by low albedo, mesa-forming material that lies unconformably atop eroded layered and cratered terrain. Both hypotheses are being explored via continued selective targeting of new MOC images as well as analyses of the new data.

Edgett, Kenneth S.↗

Abiotic Versus Biotic Weathering Of Olivine As Possible Biosignatures

We are investigating the weathering of silicate minerals by both purely inorganic, and biologically mediated processes using field-emission scanning electron microscopy (FESEM) and energy dispersive x-ray spectroscopy (EDS). By resolving surface textures and chemical compositions of weathered surfaces at the sub-micron scale we hope to be able to distinguish abiotic from biotic weathering processes and so establish a new biosignature applicable to the study of astromaterials including but not limited to the Martian meteorites. Sterilized olivine grains (San Carlos, Arizona) no more than 1-2 mm in their longest dimension were optically assayed to be uniform in color and free of inclusions were selected as weathering subjects. Prior to all experiments surface morphologies and Fe/Mg ratios were determined for each grain using FE-SEM and EDS. Experiments were divided into two categories abiotic and biotic and were compared with "naturally" weathered samples. For the preliminary experiments, two trials (open and closed to the ambient laboratory environment) were performed under abiotic conditions, and three trials under biotic conditions (control, day 1 and day 2). The open system abiotic trials used sterile grains heated at 98 C and 200 C for both 24 and 48 hours in 1L double distilled de-ionized water. The closed system abiotic trials were conducted under the same conditions but in a sealed two layer steel/Teflon "bomb" apparatus. The biotic trials used sterile grains mounted in a flow-through device attached to a wellhead on the Columbia River aquifer. Several discolored, altered, grains were selected to document "natural" weathering surface textures for comparison with the experimental samples. Preliminary results indicate there are qualitative differences in weathered surface textures among all the designed experiments. The olivine grains in abiotic trials displayed etching, pitting, denticulate margins, dissolution and clay formation. The scale of the features ranged from tens to a few microns with textures that remained relatively sharp and were crystallographically controlled. These results were comparable to that observed in the "naturally" weathered comparison/reference grains. Chemical analysis by EDS indicates these textures correlated with the relative loss of Mg and Fe cations by diffusional processes. In contrast the biotic results indicated changes in the etching patterns on the scale of hundreds of nm, which are neither sharp nor crystallographically controlled (nanoetching). Organisms, organic debris and/or extracellular polymeric substances (biofilm) were often in close proximity or direct contact with the nanoetching. While there are many poorly constrained variables in natural weathering experiments to contend with, such as the time scale, the chemistry of the fluids and degree of biologic participation, some preliminary observations can be made: (1) certain distinct surface textures appear correlated with the specific processes giving rise to these textures; (2) the process of diffusing cations can produce many similar styles of surface textural changes; and (3) the main difference between abiotic and biotically produced weathering is the scale (microns versus nanometers) and the style (crystallographically versus noncrystallographically controlled) of the textural features. Further investigation into nanosize scale surface textures should attempt to quantify both textures and chemical changes of the role of microorganisms in the weathering of silicates. Additional experiments addressing nanoscale textures of shock features for comparison with the current data set.

Longazo, Teresa G.↗

The Mineralogy of Martian Dust: Design and Analysis Considerations for an X-Ray Diffraction/X-Ray Fluorescence (XRD/XRF) Instrument for Exobiological Studies

A principal objective of Mars exploration is the search for evidence of past life which may have existed during an earlier clement period of Mars history. We would like to investigate the history of surface water activity (which is a requirement for all known forms of life) by identifying and documenting the distribution of minerals which require water for their formation or distribution. A knowledge of the mineralogy of the present Martian surface would help to identify areas which, due to the early activity of water, might have harbored ancient life. It would be desirable to establish the presence and characterize the distribution of hydrated minerals such as clays, and of minerals which are primarily of sedimentary origin such as carbonates, silica and evaporites. Mineralogy, which is more critical to exobiological exploration than is simple chemical analysis (absent the detection of organics), will remain unknown or will at best be imprecisely constrained unless a technique sensitive to mineral structure such as powder X-ray diffraction (XRD) is employed. Additional information is contained in the original extended abstract.

Blake, David↗