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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Patternable Mesoporous Thin Film Quantum Materials via Block Copolymer Self-Assembly: An Emergent Technology?

Recent developments in quantum materials hold promise for revolutionizing energy and information technologies. The use of soft matter self-assembly, for example, by employing block copolymers (BCPs) as structure directing or templating agents, offers facile pathways toward quantum metamaterials with highly tunable mesostructures via scalable solution processing. Here, we report the preparation of patternable mesoporous niobium carbonitride-type thin film superconductors through spin-coating of a hybrid solution containing an amphiphilic BCP swollen by niobia sol precursors and subsequent thermal processing in combination with photolithography. Spin-coated as-made BCP-niobia hybrid thin films on silicon substrates after optional photolithographic definition are heated in air to produce a porous oxide, and subsequently converted in a multistep process to carbonitrides via treatment with high temperatures in reactive gases including ammonia. Grazing incidence small-angle X-ray scattering suggests the presence of ordered mesostructures in as-made BCP-niobia films without further annealing, consistent with a distorted alternating gyroid morphology that is retained upon thermal treatments. Wide-angle X-ray scattering confirms the synthesis of phase-pure niobium carbonitride nanocrystals with rock-salt lattices within the mesoscale networks. Electrical transport measurements of unpatterned thin films show initial exponential rise in resistivity characteristic of thermal activation in granular systems down to 12.8 K, at which point resistivity drops to zero into a superconducting state. Magnetoresistance measurements determine the superconducting upper critical field to be over 16 T, demonstrating material quality on par with niobium carbonitrides obtained from traditional solid-state synthesis methods. Here. we discuss how such cost-effective and scalable solution-based quantum materials fabrication approaches may be integrated into existing microelectronics processing, promising the emergence of a technology with tremendous academic and industrial potential by combining the capabilities of soft matter self-assembly with quantum materials.

36 MATERIALS SCIENCE↗
DOE OSTI2023

The gut microbiome mediates adaptation to scarce food in Coleoptera

Beetles are ubiquitous cave invertebrates worldwide that adapted to scarce subterranean resources when they colonized caves. Here, we investigated the potential role of gut microbiota in the adaptation of beetles to caves from different climatic regions of the Carpathians. The beetles’ microbiota was host-specific, reflecting phylogenetic and nutritional adaptation. The microbial community structure further resolved conspecific beetles by caves suggesting microbiota-host coevolution and influences by local environmental factors. The detritivore species hosted a variety of bacteria known to decompose and ferment organic matter, suggesting turnover and host cooperative digestion of the sedimentary microbiota and allochthonous-derived nutrients. The cave Carabidae, with strong mandibula, adapted to predation and scavenging of animal and plant remains, had distinct microbiota dominated by symbiotic lineages Spiroplasma or Wolbachia. All beetles had relatively high levels of fermentative Carnobacterium and Vagococcus involved in lipid accumulation and a reduction of metabolic activity, and both features characterize adaptation to caves.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Hybrid quantum nanophotonic devices with color centers in nanodiamonds [Invited]

Optically active color centers in nanodiamonds offer unique opportunities for generating and manipulating quantum states of light. These mechanically, chemically, and optically robust emitters can be produced in mass quantities, deterministically manipulated, and integrated with a variety of quantum device geometries and photonic material platforms. Nanodiamonds with deeply sub-wavelength sizes coupled to nanophotonic structures feature a giant enhancement of light-matter interaction, promising high bitrates in quantum photonic systems. We review the recent advances in controlled techniques for synthesizing, selecting, and manipulating nanodiamond-based color centers for their integration with quantum nanophotonic devices.

Sahoo, Swetapadma (ORCID:0000000179281391)↗
DOE OSTI2022

Advancing Vision-based Feedback and Convolutional Neural Networks for Visual Outlier Detection

Machine learning has matured into a technology that has immediate applicability to the surveillance needs of nuclear material storage containers. These containers at LANL are the barrier preventing release of radioactive material to the workers, public, and environment during the storage period of the material. Annual surveillance activities can only provide coverage on a handful of containers. There is a significant need for surveillance tools to identify potential issues and precursors to containment failure that can be used during opportunistic inspections and, more generally, outside of annual surveillance activities. In this report we provide details on the advancement of our proposed embodiment that combines an automation system for taking pictures and a high-accuracy machine learning-driven object detection software. We further showcase the improvements on the software side with progress on extracting unique identification features and advances in detecting damage. The current state of the system captures subject matter expert training and a space-conscious design whose implementation is envisioned in the near future.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2020

Media matters! Alterations in the loading and release of Histoplasma capsulatum extracellular vesicles in response to different nutritional milieus

Histoplasma capsulatum is a dimorphic fungus that most frequently causes pneumonia, but can also disseminate and proliferate in diverse tissues. H. capsulatum has a complex secretion system that mediates the release of macromolecule-degrading enzymes and virulence factors. The formation and release of extracellular vesicles (EVs) are an important mechanism for non-conventional secretion in both ascomycetes and basidiomycetes. H. capsulatum EVs contain diverse proteins associated with virulence and are immunologically active. Despite the growing knowledge of EVs from H. capsulatum and other pathogenic fungi, the extent that changes in the environment impact the sorting of organic molecules in EVs has not been investigated. In our research, we cultivated H. capsulatum with distinct culture media to investigate the potential plasticity in EV loading in response to differences in nutrition. Our findings reveal that nutrition plays an important role in EV loading and formation, which may translate into differences in biological activities of these fungi in various fluids and tissues.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

SIT 45: An interacting, compact, and star-forming isolated galaxy triplet

The underlying scenario of the formation and evolution of galaxy triplets is still uncertain. Mergers of galaxies in isolated triplets give us the opportunity to study the already complex merging process, with minimal contamination of other environmental effects that potentially allow and accelerate galaxy transitions from active star-forming to passive galaxies. The merging system SIT 45 (UGC 12589) is one of 315 systems in the SDSS-based catalogue of Isolated Triplets (SIT); it is an unusual isolated galaxy triplet, consisting of three merging late-type galaxies. The main aims of this work are to study the dynamical evolution and star formation history (SFH) of SIT 45, as well as its dependence on its local and large-scale environment. Methods. To study its dynamics, parameters such as the velocity dispersion (σ v ), the harmonic radius (R H ), the crossing time (H 0 t c ), and the virial mass (M vir ), along with the compactness of the triplet (S) were considered. To investigate the possible dependence of these dynamical parameters on the environment, the tidal force Q parameters (both local and large-scale) and the projected local density (η k ) were used. To constrain the SFH, we used CIGALE to fit its observed spectral energy distribution using multiwavelength data from the ultraviolet to the infrared. SIT 45 is one of the most compact triplets in the SIT, and it is also more compact than triplets in other samples. According to its SFH, SIT 45 presents star formation, where the galaxies also present recent (~200 Myr) star formation increase, indicating that this activity may have been triggered by the interaction. Its dynamical configuration suggests that the system is highly evolved in comparison to the SIT. However, this is not expected for systems composed of star-forming late-type galaxies, based on observations in compact groups. We conclude that SIT 45 is a system of three interacting galaxies that are evolving within the same dark matter halo; its compact configuration is a consequence of the ongoing interaction rather than being due to a long-term evolution (as suggested from its H 0 t c value). We consider two scenarios for the present configuration of the triplet, one where one of the members is a tidal galaxy, and another where this galaxy arrives to the system after the interaction. Both scenarios need further exploration. The isolated triplet SIT 45 is therefore an ideal system to study short timescale mechanisms (~10 8 yr), such as starbursts triggered by interactions which are more frequent at higher redshift.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Thermal adaptation of soil microbial growth traits in response to chronic warming

ABSTRACT Adaptation of soil microbes due to warming from climate change has been observed, but it remains unknown what microbial growth traits are adaptive to warming. We studied bacterial isolates from the Harvard Forest Long-Term Ecological Research site, where field soils have been experimentally heated to 5°C above ambient temperature with unheated controls for 30 years. We hypothesized that Alphaproteobacteria from warmed plots have (i) less temperature-sensitive growth rates; (ii) higher optimum growth temperatures; and (iii) higher maximum growth temperatures compared to isolates from control plots. We made high-throughput measurements of bacterial growth in liquid cultures over time and across temperatures from 22°C to 37°C in 2–3°C increments. We estimated growth rates by fitting Gompertz models to the growth data. Temperature sensitivity of growth rate, optimum growth temperature, and maximum growth temperature were estimated by the Ratkowsky 1983 model and a modified Macromolecular Rate Theory (MMRT) model. To determine evidence of adaptation, we ran phylogenetic generalized least squares tests on isolates from warmed and control soils. Our results showed evidence of adaptation of higher optimum growth temperature of bacterial isolates from heated soils. However, we observed no evidence of adaptation of temperature sensitivity of growth and maximum growth temperature. Our project begins to capture the shape of the temperature response curves, but illustrates that the relationship between growth and temperature is complex and cannot be limited to a single point in the biokinetic range. IMPORTANCE Soils are the largest terrestrial carbon sink and the foundation of our food, fiber, and fuel systems. Healthy soils are carbon sinks, storing more carbon than they release. This reduces the amount of carbon dioxide released into the atmosphere and buffers against climate change. Soil microbes drive biogeochemical cycling and contribute to soil health through organic matter breakdown, plant growth promotion, and nutrient distribution. In this study, we determined how soil microbial growth traits respond to long-term soil warming. We found that bacterial isolates from warmed plots showed evidence of adaptation of optimum growth temperature. This suggests that increased microbial biomass and growth in a warming world could result in greater carbon storage. As temperatures increase, greater microbial activity may help reduce the soil carbon feedback loop. Our results provide insight on how atmospheric carbon cycling and soil health may respond in a warming world.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

The cosmic web of X-ray active galactic nuclei seen through the eROSITA Final Equatorial Depth Survey (eFEDS)

Which galaxies in the general population turn into active galactic nuclei (AGNs) is a keystone of galaxy formation and evolution. Thanks to SRG/eROSITA’s contiguous 140 square degree pilot survey field, we constructed a large, complete, and unbiased soft X-ray flux-limited (FX > 6.5 × 10 -15 erg s -1 cm -2 ) AGN sample at low redshift, 0.05 < z < 0.55. Two summary statistics, the clustering using spectra from SDSS-V and galaxy-galaxy lensing with imaging from HSC, are measured and interpreted with halo occupation distribution and abundance matching models. Both models successfully account for the observations. We obtain an exceptionally complete view of the AGN halo occupation distribution. The population of AGNs is broadly distributed among halos with a mean mass of 3.9 -2.4 +2.0 × 10 12 M ⊙ . This corresponds to a large-scale halo bias of b(z = 0.34) = 0.99 -0.10 +0.08 . The central occupation has a large transition parameter, σ log 10 (M) = 1.28 ± 0.2. The satellite occupation distribution is characterized by a shallow slope, α sat = 0.73 ± 0.38. We find that AGNs in satellites are rare, with f sat < 20%. Most soft X-ray-selected AGNs are hosted by central galaxies in their dark matter halo. A weak correlation between soft X-ray luminosity and large-scale halo bias is confirmed (3.3σ). We discuss the implications of environmental-dependent AGN triggering. This study paves the way toward fully charting, in the coming decade, the coevolution of X-ray AGNs, their host galaxies, and dark matter halos by combining eROSITA with SDSS-V, 4MOST, DESI, LSST, and Euclid data.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

First results from a multiplexed and massive instrument with sub-electron noise Skipper-CCDs

Here, we present a new instrument composed of a large number of sub-electron noise Skipper-CCDs operated with a two stage analog multiplexed readout scheme suitable for scaling to thousands of channels. New, thick, 1.35 Mpix sensors, from a new foundry, are glued into a Multi-Chip Module (MCM) printed circuit board on a ceramic substrate which has 16 sensors each. The instrument, that can hold up-to 16 MCMs, a total of 256 Skipper-CCD sensors (called a Super-Module with ≈ 130 grams of active mass and 346 Mpix), is part of the R&D effort of the OSCURA experiment which will have ≈ 94 super-modules. Experimental results with 10 MCMs and 160 Skipper-CCDs sensors are presented in this paper. This is already the largest ever built instrument with single electron sensitivity CCDs using nondestructive readout, both, in terms of active mass and number of channels.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Phase-field model of coupled insulator-metal transitions and oxygen vacancy redox reactions

A predominant ubiquitous feature of strongly correlated oxides is the possible presence of oxygen vacancies, which has recently been shown to have profound effects on their electronic phase transitions. Here, we formulate a comprehensive phase-field model of intercoupled insulator-metal transitions and oxygen vacancy redox reactions, taking into account the valence electron state of oxygen vacancies. We use the model to study the voltage self-oscillation phenomenon in a prototypical strongly correlated oxide, VO 2 , and discover the mutual activation of the insulator-metal transition and oxygen vacancy redox reactions leading to systematic enhancement of the oscillation frequency. Furthermore, the established methodology and the mutual activation mechanism are generally applicable to understanding any insulator-metal transition dynamics in oxygen-deficient correlated oxides and improving the performance of voltage self-oscillation-based artificial neurons.

36 MATERIALS SCIENCE↗
DOE OSTI2023

A 2K Design for the Low Beta Quadrupoles Q1ApF/Q1BpF for the Interaction Region of the Electron-Ion Collider (EIC)

The forward hadron magnets of the planned electron-ion collider (EIC) at Brookhaven National Laboratory (BNL) present a set of unique challenges. In addition to the typical magnet requirements in terms of aperture, gradient, and field quality, the field leakage from the hadron magnets to the electron apertures must be negligible. Due to the close proximity of the two apertures the shielding solution for the electron beam can affect the field quality of the hadron magnets. Here, in this paper, a design for the Q1ApF/Q1BpF low beta quadrupoles based on NbTi Rutherford cable operating at 2K is presented. In this design the electron beam shielding and the required field quality in the hadron magnets are achieved using a set of cutouts in the iron yoke solely without resorting to active shielding. The chosen layout along with the key parameters are presented and their effect on hadron magnets in term of field quality and operational margins are also discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Periodic Fast Radio Bursts from Young Neutron Stars

Fast radio bursts (FRBs) are highly energetic radio pulses from cosmological origins. Despite an abundance of detections, their nature remains elusive. At least a subset of FRBs is expected to repeat, as the volumetric FRB rate surpasses that of any known cataclysmic event, which has been confirmed by observations. One of the proposed mechanisms to generate repeating FRBs is supergiant pulses from young and highly spinning neutron stars (NSs), in which case FRBs could inherit the periodicity of their parent NS. Here we examine the consequences of such a population of periodic fast radio bursts (PFRBs). We calculate the rate and lifetime of PFRB progenitors, and find that each newly born highly spinning NS has to emit a number ${N}_{\mathrm{PFRB}}\sim {10}^{2}$ of detectable bursts during its active lifetime of $\tau \sim 100$ yr, after which it becomes too dim and crosses a PFRB "death line" analogous to the pulsar one. We propose several tests of this hypothesis. First, the period of PFRBs would increase over time, and their luminosity would decrease, due to the NS spin-down. Second, PFRBs may show modest amounts of rotation measure, given the lack of expelled matter from the pulsar, as opposed to the magnetar-sourced FRBs proposed to explain the first repeater FRB 121102. As an example, we study whether the second confirmed repeater (FRB 180814) is a PFRB, given the preference for an inter-pulse separation of 13 ms within its sub-bursts. We show that, if confirmed, this period would place FRB 180814 in a different category as FRB 121102. We develop tests that would identify—and characterize—the prospective population of PFRBs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Priming mechanisms providing plants and microbes access to mineral-associated organic matter

Mineral-associated organic matter (MAOM) is considered a stable reservoir for soil nutrients that influences long-term soil carbon (C) and nitrogen (N) dynamics. However, recent experimental and theoretical evidence shows that root exudates may mobilize MAOM, thereby providing plants and microbes access to a large and N-rich pool. Given the mechanisms underlying MAOM C and N mobilization remain largely untested, we examined direct and indirect pathways by which root exudates destabilize this nutrient pool in laboratory mesocosms. We simulated root exudation with 13 C-labeled oxalic acid to test whether root exudates are directly capable of mobilizing MAOM from mineral surfaces; and with 13 C-labeled glucose to test whether indirect stimulation of microbial and extracellular enzyme activity leads to MAOM decomposition. We also tested the potential for oxalic acid and glucose to mobilize MAOM in an additional subset of sterilized soils to clarify the potential for non-microbial pathways of MAOM destabilization. Over the course of the 12-day MAOM incubation with and without simulated exudates, we measured C cycling (CO 2 respiration rates, 13 C–CO 2 efflux), N cycling (inorganic N pools, gross N mineralization) and related microbial processes (enzyme activities and microbial community composition via phospholipid fatty acid analysis). Both of the simulated root exudates enhanced MAOM-C mineralization, with cumulative respiration increasing 35–89% relative to the water-only control. Likewise, glucose additions enhanced the production of an exo-cellulase and a chitinase by up to 130% and 39%, respectively, while oxalic acid enhanced oxidative enzyme activities up to 91% greater than control rates. We observed a positive association between glucose-induced shifts in enzyme activities, MAOM-C mineralization, and gross ammonification. Oxalic acid additions were associated with initial increases in fungal relative abundance and in sterile soils appeared to stimulate the release of metals and dissolved organic nitrogen into exchangeable pools. Our results indicate that common root exudates, like glucose and oxalic acid, can significantly increase the turnover and potential release of C and N from MAOM through indirect (e.g., enzyme induction) and direct (e.g., mobilization of metal oxides) mechanisms.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Lighting up hot stuff

Plasmonic heating by nanoparticles has been used to promote a range of chemical reactions. Now, thermoplasmonic activation has been applied to latent ruthenium catalysts, enabling olefin metathesis initiated by visible and infrared light. Additionally, the desire to harness light to drive chemical transformations has surely existed as long as the study of chemistry itself. In the earliest documented applications, light was used simply as a heat source — for example, in the distillation of liquids. Since that time, our knowledge of how light and matter interact has increased exponentially, with greater mechanistic and molecular understanding enabling modern photochemists to design molecules with a myriad of finely tuned optical properties for catalysis, biochemistry, optoelectronics and more. Nonetheless, the design and optimization of molecules to achieve specific optical properties is still challenging, and for some applications, a return to the ‘simplest’ transformation — that of light to heat — can offer a more efficient approach to achieve light-mediated chemical reactions. Now, writing in Nature Chemistry, Yossi Weizmann and colleagues describe a strategy for organic and polymer synthesis driven by the conversion of light to heat.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

U.S. Offshore Wind Energy Noise Reduction Associated with Installation of Fixed-Bottom Foundations: Workshop Report

As offshore wind energy development grows in the United States, solutions are needed to reduce the underwater noise and substrate vibration generated during fixed-bottom turbine installation to help protect marine life. Monopiles are currently the main turbine foundation type installed globally and impact pile driving, the primary installation method, can be a major source of noise and vibration generation during wind farm construction. Opportunities exist to reduce the amount of noise and vibration produced during future offshore wind farm development. The use of alternative foundation types and installation methods, as well as innovative noise abatement technologies, would help reduce the potential detrimental effects on sensitive marine species. To explore these opportunities, the Department of Energy’s Wind Energy Technologies Office, in collaboration with the Bureau of Ocean Energy Management and the National Oceanic and Atmospheric Administration, funded the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory to organize, host, and facilitate a virtual workshop in December 2022. The goal of the workshop was to gather input from the offshore wind energy community on noise reduction strategies for the installation of fixed-bottom offshore wind turbines in U.S. waters across multiple regions, including the U.S. Atlantic Coast, Gulf of Mexico, and Great Lakes to inform recommendations on future research. The joint lab team convened industry representatives, subject matter experts, and regulators to discuss potential pathways to reduce noise and vibration associated with fixed-bottom turbine installation, including the practicality of using alternative foundations and installation methods, the effectiveness of noise abatement technologies, as well as research and monitoring needs. In preparation for the workshop, the team invited experts to be part of a steering committee and worked with its members to help focus activities to meet the workshop goals. Additional pre-workshop activities included developing the invitee list and workshop agenda, reviewing existing Construction and Operations Plans (COP) for proposed offshore wind projects, distributing a brief questionnaire to industry representatives, and drafting the workshop discussion questions and Mural boards. In total, 128 workshop participants provided over 600 comments in response to the 17 group discussion questions used over two workshop sessions. Overarching recommendations highlighted across themes included future investments to provide data sharing, consistency, transparency, and opportunities for sharing best available science, knowledge, and expertise. The joint lab team synthesized the comments and identified four key research and development themes that could help advance the successful implementation of noise and vibration reduction strategies (see report). This report provides an overview of the workshop goals and scope, reviews the pre-workshop activities, presents brief summaries of participant feedback, and concludes with detailed research themes and recommendations for future investments. Appendix A includes the group discussion questions, Appendix B includes the results of the COP review, and Appendix C includes the results of the industry questionnaire. Overall, there was a high level of interest and engagement in the workshop. The sessions provided an opportunity for significant exchange of information between workshop participants from across sectors. Participants identified a variety of opportunities for next steps towards the noise reduction of offshore wind turbine installation in U.S. waters, including recommendations for future investments to provide certainty in the use of new technologies associated with alternative foundation types, noise abatement systems, and efficacy monitoring.

17 WIND ENERGY↗
DOE OSTI2022

Discrimination of phosgene from cyanogen chloride in recovered chemical munitions using tagged neutron interrogation with high-resolution gamma-ray spectroscopy

The Associated Particle technique has recently been utilized with a germanium-based high-resolution $\gamma$-ray spectrometer and assessed for its capability to improve field identification of recovered chemical warfare (CW) materiel through prompt gamma-ray neutron activation analysis (PGNAA) measurements. An accurate chemical identification is necessary for the safe handling, destruction, and disposal of such hazardous items. A particularly challenging pair of CW agents commonly found in recovered munitions are phosgene (CG) and cyanogen chloride (CK), which have two of three elements in common, i.e. chlorine and carbon, but differ in the third being either oxygen or nitrogen. The detection of both latter elements is complicated by high oxygen concentration in the field environment which interferes with the small signal produced from the chemical agents. The matter is further complicated by the precautionary field practice of overpacking recovered munitions with vermiculite in larger steel multiple round containers (MRCs), which places additional oxygen-rich material around the munition while further attenuating an already weak signal emitted from the munition center. Here, this work reports quantitative results from realistic field measurements of CG and CK simulants in mock 4.2-inch mortar rounds overpacked with vermiculite in a large MRC. Results obtained with the AP technique are compared to those obtained with the traditional PGNAA approach for both overpacked- and bare-munition measurements. The AP technique is shown to provide a much more confident discrimination between the two chemicals, particularly for the more challenging field-relevant overpacked measurements, where a significant gain in sensitivity to all the key elements chlorine, carbon, nitrogen and oxygen is achieved.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Accessing the Subsurface Biosphere Within Rocks Undergoing Active Low-Temperature Serpentinization in the Samail Ophiolite (Oman Drilling Project)

The Oman Drilling Project established an “Active Alteration” multi-borehole observatory in peridotites undergoing low-temperature serpentinization in the Samail Ophiolite. The highly serpentinized rocks are in contact with strongly reducing fluids. Distinct hydrological regimes, governed by differences in rock porosity and fracture density, give rise to steep redox (Eh +200 to –750 mV) and pH (pH range 8.5–11.2) gradients within the 300–400 m deep boreholes. The serpentinites and fluids host an active subsurface ecosystem. Microbial cell abundances in serpentinite vary at least six orders of magnitude, from ≤3.5 × 10 1 to 2.9 × 10 7 cells/g. Low levels of biological sulfate reduction (2–1,000 fmol/cm 3 /day) can be detected in rock cores, particularly in rocks in contact with reduced groundwaters with pH < 10.5. Thermodesulfovibrio is the predominant sulfate reducer identified via metagenomic sequencing of adjacent groundwater communities. Here, we infer that transport and reaction of microbially generated sulfide with the serpentine and brucite assemblages gives rise to optical darkening and sulfide overprinting, including the formation of tochilinite-vallerite group minerals, potentially serving as an indicator that this system is inhabited by microbial life. Olivine mesh-cores replaced with ferroan brucite and minor awaruite, abundant veins containing hydroandradite garnet and polyhedral serpentine, and late-stage carbonate veins are suggested as targets for future spatially resolved life-detection investigations. The high-quality whole-round core samples that have been preserved can be further probed to define how life distributes itself and functions within a system where chemical disequilibria are sustained by low-temperature water/rock interaction, and how biosignatures of in situ microbial activity are generated.

58 GEOSCIENCES↗
DOE OSTI2025

Achieving designed texture and flows in bulk active nematics using optimal control theory

Being intrinsically nonequilibrium, active materials can potentially perform functions that would be thermodynamically forbidden in passive materials. However, active systems have diverse local attractors that correspond to distinct dynamical states, many of which exhibit chaotic turbulent-like dynamics and thus cannot perform work or useful functions. Designing such a system to choose a specific dynamical state is a formidable challenge. Motivated by recent advances enabling optogenetic control of experimental active materials, we describe an optimal control theory framework that identifies a spatiotemporal sequence of light-generated activity that drives an active nematic system toward a prescribed dynamical steady state. Active nematics are unstable to spontaneous defect proliferation and chaotic streaming dynamics in the absence of control. We demonstrate that optimal control theory can compute activity fields that redirect the dynamics into a variety of alternative dynamical programs and functions. This includes dynamically reconfiguring between states, selecting and stabilizing emergent behaviors that do not correspond to attractors, and are hence unstable in the uncontrolled system. Furthermore, our results provide a roadmap to leverage optical control methods to rationally design structure, dynamics, and function in a wide variety of active materials.

Complex systems theory↗