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At least 577 records · Page 32

ComStock Measure Documentation: Heat Pump Rooftop Units with Standard Performance

This documentation focuses on a single end-use savings shape measure - heat pump rooftop units (HP-RTUs) with standard efficiencies that are prevalent in the current market. Today, these products are claimed as standard efficiency by the manufacturers and are most commonly installed. This document will primarily discuss the additional changes of performance and configuration of the standard efficiency HP-RTUs while a comprehensive overview of the fundamental modeling methodology and background of the HP-RTU measure, including applicability, sizing scheme, and other key assumptions can be found in the original documentation: Heat Pump RTU. The definition of "standard efficiency" can be a bit vague when considering detailed specifics other than efficiency metrics of a heat pump. Thus, we have focused on reflecting products where manufacturers claim as standard efficiency and products that are not top-of-the-line in their model lineup. Based on gathering information from eight products from four major manufacturers, there are some common (or relatively prevalent) characteristics and we have defined standard efficiency product as follows: direct drive outdoor unit fan, two stages of heat pump cooling, single stage heat pump heating (i.e., all compressors running at the same time), heat pump minimum lockout temperature of 0°F (-17.8°C), backup electric resistance heating, backup heating runs at the same time as heat pump heating , heat pump heating locking out below minimum operating temperature, IEER in between 11-13, and HSPF in between 8-8.9. There are cases where some of these products have other variations: a variable frequency drive fan, dual fuel (i.e., gas backup heating) option, three or more cooling stages, two stages of heat pump heating, no backup heating as default , etc. However, this work tried to reflect the most common and prevalent options for a standard efficiency product.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

PNNL Dose-per-Unit-Release Factors for Calculating Radionuclide Emissions Potential-to-Emit Doses

Revised PNNL-Richland campus dose-per-unit release factors based on the Environmental Protection Agency code CAP88-PC Version 4.1.1 code are provided. In addition to maximum receptor dose factors, maximum air concentration dose factors are provided. The PNNL-Sequim campus dose-per-unit release factors are included, as well, based on the Environmental Protection Agency code COMPLY Version 1.7.1.

40 CFR 61 Subpart H↗

Initial Uncertainty Analysis of Carbon Tetrachloride Contamination and Remediation in the Ringold A and Lower Mud Units at the Central Plateau

The long-term effectiveness of groundwater cleanup at the Hanford Site Central Plateau depends on predictive models that can capture key uncertainties in contaminant fate and transport. Carbon tetrachloride (CCl 4 ), a persistent and toxic compound, presents particular challenges due to variability in degradation rates, uncertainty in initial plume distribution, and subsurface heterogeneity. These uncertainties directly influence plume persistence, migration pathways, and remedy performance, and thus must be systematically evaluated to support long-term remediation planning. To address these gaps, a large-scale Monte Carlo analysis was conducted using the Plateau to River (P2R) model framework. The modeling approach parameterized three primary uncertainty factors: (1) degradation rate, (2) initial plume distribution, and (3) hydraulic conductivity. Degradation was represented as a first-order process, with half-lives ranging from 70 to 700 years. Initial plume distributions were created using a geostatistical simulation method (sgsim), which generates many equally plausible versions of how contaminants might be distributed underground. From this, 100 different scenarios were mapped onto the P2R grid. Variability in hydraulic conductivity was represented in a similar way, with 100 scenarios each for the Ringold Lower Mud and Ringold A units (layers 6 and 7), based on fitted exponential variograms and conditioned to well data. In total, more than 1000 realizations were simulated to assess plume behavior under uncertainty. Results demonstrate that degradation kinetics exert the strongest control over plume persistence: Shorter half-lives produced rapid mass reduction, while longer half-lives yielded persistent plumes with limited attenuation. A nonlinear response was observed, with steep mass reductions at half-lives greater than 200 years and near-linear declines beyond this threshold, reflecting interactions between degradation and pumping. The initial plume distribution strongly influenced early transport patterns, with broader sources generating larger plume footprints, although pump-and-treat operations constrained plume migration to managed areas. By comparison, hydraulic conductivity variability in the Ringold units had only a secondary influence, modifying spreading behavior without altering the dominant migration pathways governed by source configuration and hydraulic controls. Overall, the analysis highlights that uncertainty in degradation rate and initial plume configuration are the primary drivers of variability in plume predictions, while conductivity heterogeneity plays a limited role. These findings underscore the need for improved site-specific data on degradation processes and source characterization to enhance the reliability of long-term performance assessments and to better inform remedial decision-making at the Central Plateau.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Past Approaches for Spent Nuclear Fuel, Transuranic, and High-Level Waste Disposal in the United States—Part 2: Siting Process, Staged Development, and Public Preferences

This report presents pertinent aspects of the ~50-year United States experience in siting a mined geologic disposal repository for spent nuclear fuel (SNF), transuranic (TRU) waste, and high-level radioactive waste (HLW) as related to site selection and the staged process for site investigations as specified in the Nuclear Waste Policy Act of 1982 and generic and site-specific regulations of the US Department of Energy (DOE), US Environmental Protection Agency (EPA), and US Nuclear Regulatory Commission (NRC). The roles of the Environmental Impact Statement and guidance in international consensus standards by the International Atomic Energy Agency are also mentioned. The focus is on siting and developing the Waste Isolation Pilot Plant, an operating repository for TRU waste from atomic energy defense activities, and the proposed Yucca Mountain repository for commercial SNF and HLW. In the social dimension, the role of institutional stakeholders is described. Past national surveys related to waste management options for storage and disposal provide insight on public preferences of other stakeholders. The descriptions are intended to help other countries more fully understand the stages adopted for siting and developing repositories in the United States.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Bioenergy pathways within United States net-zero CO 2 emissions scenarios in the Energy Modeling Forum 37 study

The Energy Modeling Forum 37 study is organized around carbon dioxide (CO 2 ) mitigation scenarios reaching net-zero CO 2 emissions by 2050 in the United States. Here, this paper summarizes the potential contribution of bioenergy use in the electric power, transportation, industrial, and buildings sectors toward meeting that target based on model results. Thirteen modeling teams reported bioenergy consumption in the Reference and Net Zero scenarios. Consumption of bioenergy increased over time in the Reference scenario, from an average across models of 3.2 exajoules (EJ) in 2020 to 3.8 EJ in 2050. Average bioenergy consumption in 2050 increased further to 7.3 EJ in the Net Zero scenario. All scenarios that reach net-zero emissions required some form of carbon dioxide removal to offset emissions that are difficult to reduce. Carbon dioxide removal using bioenergy with CO 2 capture and storage (BECCS) varies widely across models, up to 1000 Mt CO 2 in 2050. Some models rely instead on direct air carbon capture and storage (DACCS), up to 2200 Mt CO 2 , and others use a combination of BECCS and DACCS. Model results show a strong inverse relationship between the amounts of BECCS and DACCS deployed. All modeling teams assumed a carbon sink from land use, land use change, and forestry, further offsetting a portion of emissions from fossil fuels and industry that are expensive to eliminate. Bioenergy consumption in 2050 decreased by an average of 1.5 EJ across eight models in a Net Zero+ scenario relative to the Net Zero scenario, due in part to a lower equilibrium carbon price resulting from optimistic cost assumptions for all energy technologies.

09 BIOMASS FUELS↗

Coccidioidomycosis Dynamics in Relation to Climate in the Southwestern United States: Cocci. and climate in the SW U.S.

Valley fever is endemic to the southwestern United States. Humans contract this fungal disease by inhaling spores of Coccidioides spp. Changes in the environment can influence the abundance and dispersal of Coccidioides spp., causing fluctuations in valley fever incidence. We combined county-level case records from state health agencies to create a regional valley fever database for the southwestern United States, including Arizona, California, Nevada, New Mexico, and Utah. We used this data set to explore how environmental factors influenced the spatial pattern and temporal dynamics of valley fever incidence during 2000–2015. We compiled climate and environmental geospatial data sets from multiple sources to compare with valley fever incidence. These variables included air temperature, precipitation, soil moisture, surface dust concentration, normalized difference vegetation index, and cropland area. We found that valley fever incidence was greater in areas with warmer air temperatures and drier soils. The mean annual cycle of incidence varied throughout the southwestern United States and peaked following periods of low precipitation and soil moisture. From year-to-year, however, autumn incidence was higher following cooler, wetter, and productive springs in the San Joaquin Valley of California. In southcentral Arizona, incidence increased significantly through time. By 2015, incidence in this region was more than double the rate in the San Joaquin Valley. Our analysis provides a framework for interpreting the influence of climate change on valley fever incidence dynamics. Our results may allow the U.S. Centers for Disease Control and Prevention to improve their estimates of the spatial pattern and intensity of valley fever endemicity.

54 ENVIRONMENTAL SCIENCES↗

Introgression and persistence of cultivar alleles in wild carrot ( Daucus carota ) populations in the United States

Abstract Premise Cultivated species and their wild relatives often hybridize in the wild, and the hybrids can survive and reproduce in some environments. However, it is unclear whether cultivar alleles are permanently incorporated into the wild genomes or whether they are purged by natural selection. This question is key to accurately assessing the risk of escape and spread of cultivar genes into wild populations. Methods We used genomic data and population genomic methods to study hybridization and introgression between cultivated and wild carrot (Daucus carota) in the United States. We used single nucleotide polymorphisms (SNPs) obtained via genotyping by sequencing for 450 wild individuals from 29 wild georeferenced populations in seven states and 144 cultivars from the United States, Europe, and Asia. Results Cultivated and wild carrot formed two genetically differentiated groups, and evidence of crop–wild admixture was detected in several but not all wild carrot populations in the United States. Two regions were identified where cultivar alleles were present in wild carrots: California and Nantucket Island (Massachusetts). Surprisingly, there was no evidence of introgression in some populations with a long‐known history of sympatry with the crop, suggesting that post‐hybridization barriers might prevent introgression in some areas. Conclusions Our results provide support for the introgression and long‐term persistence of cultivar alleles in wild carrots populations. We thus anticipate that the release of genetically engineered (GE) cultivars would lead to the introduction and spread of GE alleles in wild carrot populations.

Plant Sciences↗

Sources of Corn for Ethanol Production in the United States: A Review and Decomposition Analysis of the Empirical Data

The use of corn for ethanol production in the United States quintupled between 2001 and 2009, generating concerns that this could lead to the conversion of forests and grasslands around the globe, known as indirect land-use change (iLUC). Estimates of iLUC and related ‘food versus fuel’ concerns rest on the assumption that the corn used for ethanol production in the United States would come primarily from displacing corn exports and land previously used for other crops. A number of modeling efforts based on these assumptions have projected significant iLUC from the increases in the use of corn for ethanol production. The current study tests the veracity of these assumptions through a systematic decomposition analysis of the empirical data from 2001 to 2009. The logarithmic mean divisia index decomposition method (Type I) was used to estimate contributions of different factors to meeting the corn demand for ethanol production. Results show that about 79% of the change in corn used for ethanol production can be attributed to changes in the distribution of domestic corn consumption among different uses. Increases in the domestic consumption share of corn supply contributed only about 5%. The remaining contributions were 19% from added corn production, and –2% from stock changes. Yield change accounted for about two-thirds of the contributions from production changes. Thus, the results of this study provide little support for large land-use changes or diversion of corn exports because of ethanol production in the United States during the past decade.

54 ENVIRONMENTAL SCIENCES↗

Regional patterns of postwildfire streamflow response in the Western United States: The importance of scale‐specific connectivity

Abstract Wildfires can impact streamflow by modifying net precipitation, infiltration, evapotranspiration, snowmelt, and hillslope run‐off pathways. Regional differences in fire trends and postwildfire streamflow responses across the conterminous United States have spurred concerns about the impact on streamflow in forests that serve as water resource areas. This is notably the case for the Western United States, where fire activity and burn severity have increased in conjunction with climate change and increased forest density due to human fire suppression. In this review, we discuss the effects of wildfire on hydrological processes with a special focus on regional differences in postwildfire streamflow responses in forests. Postwildfire peak flows and annual water yields are generally higher in regions with a Mediterranean or semi‐arid climate (Southern California and the Southwest) compared to the highlands (Rocky Mountains and the Pacific Northwest), where fire‐induced changes in hydraulic connectivity along the hillslope results in the delivery of more water, more rapidly to streams. No clear streamflow response patterns have been identified in the humid subtropical Southeastern United States, where most fires are prescribed fires with a low burn severity, and more research is needed in that region. Improved assessment of postwildfire streamflow relies on quantitative spatial knowledge of landscape variables such as prestorm soil moisture, burn severity and correlations with soil surface sealing, water repellency, and ash deposition. The latest studies furthermore emphasize that understanding the effects of hydrological processes on postwildfire dynamic hydraulic connectivity, notably at the hillslope and watershed scales, and the relationship between overlapping disturbances including those other than wildfire is necessary for the development of risk assessment tools.

Hallema, Dennis W.↗

A fast scheme to calculate electronic couplings between P3HT polymer units using diabatic orbitals for charge transfer dynamics simulations

We propose a fast and accurate calculation method to compute the electronic couplings between molecular units in a thiophene-ring-based polymer chain mimicking a real organic semiconducting polymer, poly(3-hexylthiophene). Through a unit block diabatization scheme, the method employed minimal number of diabatic orbitals to compute the site energies and electronic couplings, which were validated by comparing with benchmark density functional theory calculations. In addition, by using the obtained electronic couplings, a quantum dynamics simulation was carried out to propagate a hole initially localized in a thiophene-ring unit of the polymer chain. Here, this work establishes a simple, efficient, and robust means for the simulation of electron or hole transfer processes in organic semiconducting materials, an important capability for study and understanding of the class of organic optoelectronic and photovoltaic materials.

36 MATERIALS SCIENCE↗

Contribution of eastern North Pacific tropical cyclones and their remnants on flooding in the western United States

Recent studies have focused on identifying the spatial coverage of heavy rainfall associated with tropical cyclones (TCs) and their remnants (TC‐events) throughout the southwestern United States from eastern North Pacific storms. Yet little is known about the larger spatial contribution of these storms among extreme floods over the western United States. This paper examines the spatial and fractional contribution of 103 TC‐events among annual maximum streamflow at 1,429 long‐term U.S. Geological Survey (USGS) streamgages with at least 30 years of daily discharge data over the 1958–2010 water years. The highest fractional contributions to annual daily maxima by these storms (~5–14%) are found in southern California, Arizona, southernmost Nevada and Utah, southern and western New Mexico, central Colorado, and Texas. While nearly 32% of the streamgages have at least one annual maximum that was generated by a TC‐event, TC‐events play a limited role in contributing to the upper tail of the flood peak distribution across the western United States.

Barth, Nancy A.↗

Multi‐year hydroclimatic droughts and pluvials across the conterminous United States

Abstract Time series of water‐year runoff for 2,109 hydrologic units (HUs) across the conterminous United States (CONUS) for the 1900 through 2014 period were used to identify drought and pluvial (i.e., wet) periods. Characteristics of the drought and pluvial events including frequency, duration, and severity were examined and compared. Additionally, a similar analysis was performed using gridded tree‐ring reconstructions of the Palmer Drought Severity Index (PDSI) for the period 1475 through 2005 to place the drought and pluvial characteristics determined using water‐year runoff for 1900 through 2014 in the context of multi‐century climate variability. The temporal and spatial variability of droughts and pluvials determined using runoff for the 1900 through 2014 period indicated that most drought events in the CONUS occurred before about 1970, whereas most pluvial periods occurred after about 1970. This change in the frequencies of drought and pluvial events around 1970 was largely related to an increase in fall (October through December) precipitation across much of the central United States. Also, the duration and severity of droughts and pluvials identified using runoff for the 1900 through 2014 period generally were not significantly different from the drought and pluvial characteristics identified using the PDSI for the 1475 through 2005 period.

McCabe, Gregory J.↗

Diurnal cycle of precipitation over the tropics and central United States: intercomparison of general circulation models

Diurnal precipitation is a fundamental mode of variability that climate models have difficulty in accurately simulating. Here, in this work, the diurnal cycle of precipitation (DCP) in participating climate models from the Global Energy and Water Exchanges' DCP project is evaluated over the tropics and central United States. Common model biases such as excessive precipitation over the tropics, too frequent light-to-moderate rain, and the failure to capture propagating convection in the central United States still exist. Over the central United States, the issues of too weak rainfall intensity in climate runs is well improved in their hindcast runs with initial conditions from numerical weather prediction analyses. But the improvement is minimal over the central Amazon. Incorporating the role of the large-scale environment in convective triggering processes helps resolve the phase-locking issue in many models where precipitation often incorrectly peaks near noon due to maximum insolation over land. Allowing air parcels to be lifted above the boundary layer improves the simulation of nocturnal precipitation which is often associated with the propagation of mesoscale systems. Including convective memory in cumulus parameterizations acts to suppress light-to-moderate rain and promote intense rainfall; however, it also weakens the diurnal variability. Simply increasing model resolution (with cumulus parameterizations still used) cannot fully resolve the biases of low-resolution climate models in DCP. The hierarchy modeling framework from this study is useful for identifying the missing physics in models and testing new development of model convective processes over different convective regimes.

58 GEOSCIENCES↗

Nominal Power Assimilation in Leningradskaya NPP No. 1 Unit After Service Life Characteristics Restoration of the Graphite Stack

The maximum graphite temperature upon increasing the reactor power in the No. 1 unit of the Leningradskaya NPP to 80% of the nominal value in November–December 2013 after the restoration of the service life characteristics of the graphite stack is presented. A comparative analysis is made of the temperature regime of the graphite stack at power equal to 80 and 100% of nominal value before and after restoration of the service life characteristics at nominal helium content in the gas mixture blown through the reactor space. A comparison is made of the maximum temperature of the graphite stack of the reactors in the No. 1 unit of the Leningradskaya NPP and No. 2 unit of the Kursk NPP upon startup and assimilation of the power after restoration of the service life characteristics. The effect of the restoration of the service life characteristics on the thermohydraulic regime of the fuel channels in the reactor is studied.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Controlling the aqueous solubility of PNIPAM with hydrophobic molecular units

The effect of co-polymerization of thermo-sensitive polymers with hydrophilic or hydrophobic co-monomers on the LCST and the structure of proximal water remains a fundamental and challenging problem. Here, in this study, we employ all-atom molecular dynamics simulations to investigate the aqueous solubility of a thermo-sensitive polymer, poly(N-isopropylacrylamide) (PNIPAM), a hydrophobic polymer polystyrene (PS) and block co-polymers of PNIPAM-co-PS. The simulations of pure oligomers of PNIPAM and PS and their co-polymers are conducted below and above the LCST of PNIPAM to elucidate the effect of increase in number of PS units in PNIPAM-co-PS co-polymers on the coil-to-globule transition of PNIPAM and structure of proximal water. Our simulations suggest that while the LCST of pure PNIPAM oligomers is strongly associated with the structural changes in the proximal water molecules present near PNIPAM, inclusion of PS units disrupts the interactions between PNIPAM and water and promotes the faster dehydration of PNIPAM chains above its LCST. This phenomenon is manifested by a coil-to-globule transition in PNIPAM chains present in PNIPAM-co-PS co-polymers at much shorter times as compared to the pure PNIPAM oligomers. Our results also reveal that with increase in the number of PS units in PNIPAM-co-PS co-polymers the coil-to-globule transition is accelerated.

36 MATERIALS SCIENCE↗

Emissions implications of downscaled electricity generation scenarios for the western United States

This study explores how emissions from electricity generation in the Western Interconnection region of the U.S. might respond in circa 2030 to contrasting scenarios for fuel prices and greenhouse gas (GHG) emissions fees. We examine spatial and temporal variations in generation mix across the region and year using the PLEXOS unit commitment and dispatch model with a production cost model database adapted from the Western Electricity Coordinating Council. Emissions estimates are computed by combining the dispatch model results with unit-specific, emissions-load relationships. Wind energy displaces natural gas and coal in scenarios with relatively expensive natural gas or with GHG fees. Correspondingly, annual emissions of NOx, SO2, and CO2 are reduced by 20-40% in these cases. NOx emissions, which are a concern as a precursor of ground-level ozone, are relatively high and consistent across scenarios during summer, when peak electricity loads occur and wind resources in the region are comparatively weak. Accounting for the difference in start-up versus stabilized NOx emissions rates for natural gas plants had little impact on region-wide emissions estimates due to the dominant contribution from coal-fired plants, but would be more important in the vicinity of the natural gas units.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Radiofrequency exposure in the Neonatal Medium Care Unit

The aims of this study were to characterize electromagnetic fields of radiofrequency (RF-EMF) levels generated in a Neonatal Medium Care Unit and to analyze RF-EMF levels inside unit’s incubators. Spot and long-term measurements were made with a dosimeter. The spot measurement mean was 1.51±0.48 V/m. Higher values were found in the proximity to the window and to the incubator evaluated. Mean field strength for the entire period of 17 h was 0.81 (±0.07) V/m and the maximum value was 1.58 V/m for long-term RF-EMF measurements in the incubator. Values found during the night period were higher than those found during the day period. It is important to consider RF-EMF exposure levels in neonatal care units, due to some evidence of adverse health effects found in children and adults. Characterization of RF-EMF exposure may be important to further investigate the mechanisms and underlying effects of electromagnetic fields (EMF) on infant health. A prudent avoidance strategy should be adopted because newborns are at a vulnerable stage of development and the actual impact of EMF on premature infants is unknown. - Highlights: • The increasing use of RF-EMF suggests an urgent need for more research in this field. • Health consequences of RF-EMF exposure on infants are not well known. • Description of RF-EMF exposure is vital in further study mechanisms on infant health. • Considering newborns vulnerability, it is wise to adopt a prudent avoidance strategy.

54 ENVIRONMENTAL SCIENCES↗