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At least 577 records · Page 32

Dynamical properties of a driven dissipative dimerized $S$ =1/2 chain

We consider the dynamical properties of a gapped quantum spin system coupled to the electric field of a laser, which drives the resonant excitation of specific phonon modes that modulate the magnetic interactions. Here, we deduce the quantum master equations governing the time-evolution of both the lattice and spin sectors, by developing a Lindblad formalism with bath operators providing an explicit description of their respective phonon-mediated damping terms. We investigate the nonequilibrium steady states (NESS) of the spin system established by a continuous driving, delineating parameter regimes in driving frequency, damping, and spin-phonon coupling for the establishment of physically meaningful NESS and their related nontrivial properties. Focusing on the regime of generic weak spin-phonon coupling, we characterize the NESS by their frequency and wave-vector content, explore their transient and relaxation behavior, and discuss the energy flow, the system temperature, and the critical role of the type of bath adopted. Our study lays a foundation for the quantitative modeling of experiments currently being designed to control coherent many-body spin states in quantum magnetic materials.

1-dimensional spin chains↗

Validation Data and Model Development for Fuel Assembly Response to Seismic Loads

Vibrations are inherently present in nuclear reactors, especially in cores and steam generators of pressurized water reactors (PWR). They can have significant effects on local heat transfer and wear and tear in the reactor and often set safety margins. The simulation of these multiphysics phenomena from first principles requires the coupling of several codes, which is one the most challenging tasks in modern computer simulation. Here an ambitious multiphysics multidisciplinary validation campaign is conducted. It relied on an integrated team of experimentalists and code developers to acquire benchmark and validation data for fluid-structure interaction codes. Data are focused on PWR fuel bundle behavior during seismic transients.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

A Computational-Experimental Study of Plasma Processing of Carbides at High Temperatures

The effects of plasma on carbides were computationally investigated for the ultimate development of adherent, dense scales such as Al 2 O 3 -TiO 2 systems toward oxidation resistance at 1873 K. An alumina scale forms on the carbide because of the significant stability of Al 2 O 3 as the outer scale adjacent to the gas phase compared to rutile, though TiO and Ti 2 O 3 may form as components of an inner layer of a complicated scale. A sequence of surface reactions starting with the adsorption of oxygen on the surface was applied to experimental data from Donnelly’s research group who reported the adsorption of O 2 in a plasma atmosphere as a function of power. In addition to the adsorbed oxygen (Oad) as the rate determining step, it controlled the cascading reaction sequence of the adsorbed species of AlO, AlO 2 and AlO 3 , as indicated in the present study. The rate of oxygen adsorption also depends on the ratio of the final to initial adsorbed oxygen as a function the oxygen potential. In a secondary research thrust, Ti 3 AlC was synthesized and subsequently oxidized. A 39Ti-14Al-47TiC (in wt%) mixture was equilibrated by using a pseudo-isopiestic technique to form ultimately an aggregate of Ti3AlC, Ti 2 AlC and TiC phases. The aggregate was primarily composed of Ti 3 AlC with minor amounts of Ti 2 AlC and TiC, as determined by an X-ray diffraction analysis. The Ti 3 AlC/Ti 2 AlC/TiC aggregate was subsequently oxidized at 1873 K to form a scale composed of an outer layer of Al 2 O 3 -TiO 2 -Al 2 TiO 5 with an inner layer consisting of TiO-Al 2 O 3 - Al 4 CO 3 . The measured scale thickness grew according to Wagner’s parabolic growth rate, which estimates an effective diffusion coefficient of 6 (10)-8 cm 2 /s. The scale appears to grow with Ti ions migrating outward from the Ti 3 AlC/Ti 2 AlC/TiC core and oxygen ions diffusing inwardly toward the core. The transient temperature distribution of a cylindrical, carbide packed bed (i.e., B4C) was simulated with COMSOL software to determine the response of the bed to a sudden temperature spike exposed to the outer wall of the bed. The temperature distribution of B4C was similarly heated and compared with Hf and Zr metal. The thermal conductivity of Hf and Zr is higher than the B4C packed bed and hence they respond quicker than B4C. The packed bed still takes approximately 1200 s to plateau the temperature distribution between the cylinder surfaces to the centerline of the carbide packed bed of 5 cm diameter. Though the modeling of the distributions in the carbide packed bed gives an understanding of the transient heat response behavior driven by radiation, the effect of the plasma on the surface temperature of individual carbide particles needs further investigation to understand the plasma contribution to densification of a carbide packed bed.

36 MATERIALS SCIENCE↗

Experimental and Theoretical Studies of Ultrafast Vibrational Energy Transfer Dynamics in Energetic Materials

Energy transfer through anharmonically-coupled vibrations influences the earliest chemical steps in shockwave-induced detonation in energetic materials. A mechanistic description of vibrational energy transfer is therefore necessary to develop predictive models of energetic material behavior. We performed transient broadband infrared spectroscopy on hundreds of femtoseconds to hundreds of picosecond timescales as well as density functional theory and molecular dynamics simulations to investigate the evolution of vibrational energy distribution in thin film samples of pentaerythritol tetranitrate (PETN) , 1,3,5 - trinitroperhydro - 1,3,5 - triazine (RDX) , and 2,4,6 - triamino 1,3,5 - trinitrobenzene (TATB). Experimental results show dynamics on multiple timescales, providing strong evidence for coupled vibrations in these systems, as well as material-dependent evolution on tens to hundreds of picosecond timescales. Theoretical results also reveal pathways and distinct timescales for energy transfer through coupled vibrations in the three investigated materials, providing further insight into the mechanistic underpinnings of energy transfer dynamics in energetic material sensitivity.

36 MATERIALS SCIENCE↗

Report on Assessment of Advanced Reactor Fuel Performance

Three activities have been performed in FY 2019 to support the Advanced Fuel Cycle Campaign, which include assessment of annular fuel performance in an ultra-high burnup sodium-cooled reactor (SFR), modeling of annular fuel behavior during a transient scenario, and feasibility of a sustainable closed fuel cycle utilizing melt-refining process. Annular fuel performance parameters, including temperature profile, swelling strain, and cumulative damage fraction (CDF), in a 3000 MWt Sustainable Sodium-cooled Fast Reactor (SSFR) were assessed using the BISON fuel performance code. The SSFR is once-through ultra-long-life core based on a 34-batch fuel management scheme with 1.5-year cycle length. The fuel residence time in the SSFR is 51 years and the average discharged burnup is about 30%. Annular fuel has potential to irradiate for ultra-high burnup without major fuel-cladding mechanical interaction. This feature is achieved by using a low smeared density (~55%). In the SSFR design, however, 75% smeared density and a thick fuel pin were preferred to maintain criticality for 51 years. Due to the high smeared density and thick fuel pin configuration, the annular fuel was predicted to suffer premature cladding failure before reaching the discharge burnup of the SSFR. The current fuel creep model predicts a prominent creep strain due to gravity over the half-century irradiation, which may significantly affect the evolution of CDF. Thus, in order to use the annular fuel in an ultra-high burnup core such as the SSFR, a low smeared density and thin annular fuel is strongly recommended.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Integrated Multi-Fidelity Model and Co-Simulation Platform for Distribution System Transient and Dynamic Analysis—DistribuDyn

As inverter-based, distributed energy resources (DERs) and variable loads continue to proliferate across distribution systems, it is increasingly important to understand their impacts on system stability and reliability. However, most commercially available simulation tools for distribution planning primarily focus on steady-state and quasi-steady state analysis, offering limited capabilities to study transient and dynamic behaviors.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Overview of IMPACT Data Acquisition System and Data Reduction Process

This report documents the development of the data acquisition system (DAS) and data reduction methodologies for the Irradiated Material Property Accelerated Characterization Test (IMPACT) experiment at the Advanced Test Reactor (ATR). The IMPACT experiment is designed to enable in-pile measurement of thermal conductivity in metallic nuclear fuels, specifically U-10Zr, using an instrumented thermal conductivity probe. The DAS supports both passive temperature monitoring and active thermal interrogation of the probe through controlled AC and DC excitation. Significant modifications to laboratory-scale systems were required to accommodate the higher resistance paths associated with the in-pile application. Custom electronics and relay-controlled measurement sequencing were developed to enable the measurement and sufficient power delivery to the sensing region. A reduced-order, axisymmetric thermal model based on the thermal quadrupoles method is presented to support data interpretation. This model enables efficient evaluation of transient heat transfer behavior and facilitates solution of the inverse problem required to extract thermal properties from measured signals. Multiple boundary condition formulations are discussed to address varying experimental time scales and geometries. Additionally, machine learning techniques are introduced to support data reduction and improve confidence in inverse solutions. Convolutional neural networks are applied to identify the presence of gas gaps and other evolving geometric features that significantly impact thermal response during irradiation. These efforts contribute to the broader integration of digital twin frameworks and real-time modeling capabilities within the Advanced Fuels Campaign.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Rheological effects on friction in elastohydrodynamic lubrication

An analytical and experimental investigation is presented of the friction in a rolling and sliding elastohydrodynamic lubricated contact. The rheological behavior of the lubricant is described in terms of two viscoelastic models. These models represent the separate effects of non-Newtonian behavior and the transient response of the fluid. A unified description of the non-Newtonian shear rate dependence of the viscosity is presented as a new hyperbolic liquid model. The transient response of viscosity, following the rapid pressure rise encountered in the contact, is described by a compressional viscoelastic model of the volume response of a liquid to an applied pressure step. The resulting momentum and energy equations are solved by an iterative numerical technique, and a friction coefficient is calculated. The experimental study was performed, with two synthetic paraffinic lubricants, to verify the friction predictions of the analysis. The values of friction coefficient from theory and experiment are in close agreement.

Trachman, E. G.↗

New electron trap in p-type Czochralski silicon

A new electron trap (acceptor level) was discovered in p-type Czochralski (CZ) silicon by current transient spectroscopy. The behavior of this trap was found to be similar to that of the oxygen thermal donors; thus, 450 C annealing increases the trap concentration while high-temperature annealing (1100-1200 C) leads to the virtual elimination of the trap. The new trap is not observed in either float-zone or n-type CZ silicon. Its energy level depends on the group III doping element in the sample. These findings suggest that the trap is related to oxygen, and probably to the acceptor impurity as well.

Mao, B.-Y.↗

Thermo-viscoplastic analysis of hypersonic structures subjected to severe aerodynamic heating

A thermoviscoplastic computational method for hypersonic structures is presented. The method employs unified viscoplastic constitutive model implemented in a finite element approach for quasi-static thermal-structural analysis. Applications of the approach to convectively cooled hypersonic structures illustrate the effectiveness of the approach and provide insight into the transient inelastic structural behavior at elevated temperatures.

Thornton, Earl A.↗

Thermo-viscoplastic analysis of hypersonic structures subjected to severe aerodynamic heating

A thermoviscoplastic computational method for hypersonic structures is presented. The method employs a unified viscoplastic constitutive model implemented in a finite element approach for quasi-static thermal-structural analysis. Applications of the approach to convectively cooled hypersonic structures illustrate the effectiveness of the approach and provide insight into the transient inelastic structural behavior at elevated temperatures.

Thornton, Earl A.↗

Test and evaluation of load converter topologies used in the Space Station Freedom Power Management and distribution DC test bed

Power components hardware in support of the Space Station Freedom dc Electrical Power System were tested. One type of breadboard hardware tested is the dc Load Converter Unit, which constitutes the power interface between the electric power system and the actual load. These units are dc to dc converters that provide the final system regulation before power is delivered to the load. Three load converters were tested: a series resonant converter, a series inductor switchmode converter, and a switching full-bridge forward converter. The topology, operation principles, and tests results are described, in general. A comparative analysis of the three units is given with respect to efficiency, regulation, short circuit behavior (protection), and transient characteristics.

Lebron, Ramon C.↗

Step voltage analysis for the catenoid lightning protection system

The main objective of the proposed overhead Catenoid Lightning Protection System (CLPS) is personnel safety. To ensure working personnel's safety in lightning situations, it is necessary that the potential difference developed across a distance equal to a person's pace (step voltage) does not exceed a separately established safe voltage in order to avoid electrocution (ventricular fibrillation) of humans. Therefore, the first stage of the analytical effort is to calculate the open circuit step voltage. An impedance model is developed for this purpose. It takes into consideration the earth's complex impedance behavior and the transient nature of the lightning phenomenon. In the low frequency limit, this impedance model is shown to reduce to results similar to those predicted by the conventional resistor model in a DC analysis.

Chai, J. C.↗

Test and evaluation of load converter topologies used in the Space Station Freedom power management and distribution dc test bed

Power components hardware in support of the Space Station freedom dc Electric Power System were tested. One type of breadboard hardware tested is the dc Load Converter Unit, which constitutes the power interface between the electric power system and the actual load. These units are dc to dc converters that provide the final system regulation before power is delivered to the load. Three load converters were tested: a series resonant converter, a series inductor switch-mode converter, and a switching full-bridge forward converter. The topology, operation principles, and test results are described, in general. A comparative analysis of the three units is given with respect to efficiency, regulation, short circuit behavior (protection), and transient characteristics.

Lebron, Ramon C.↗

Vacuum drying of spent fuel storage canisters/casks - 'just how much water could be left in there, anyway?' - 15233

The process of moving spent fuel assemblies from wet storage in the spent fuel pool to dry storage in an inert gas environment within a canister or cask typically involves two main stages. In the first stage, the bulk of the water is removed by a draining or siphoning operation, conducted with pressure inside the canister maintained at 1.3 to 2 atm. This process removes most of the water in the cask cavity, but residual water can be left behind, in three main regions. The largest region, typically, is the bottom of the cavity below the end of the siphon tube. A second general class of locations, also located at the bottom of the cask cavity, consists of the 'dashpots' at the ends of the various non-fuel tubular structures within the fuel assemblies. For PWR assemblies, these are the control rod guide sleeve tubes and instrumentation thimbles. For BWR assemblies, these are the water rods of various designs and control blade ends in some configurations. A third class of locations consists of porous material within the cavity that can absorb water, such as thin ceramic neutron poison plates, and ostensibly intact fuel rods that nevertheless might have pinholes or fine cracks in the cladding that could allow pool water to creep inside the fuel rod. To remove residual water from these locations, the second stage of drying operations utilizes vacuum drying, by reducing the pressure sufficiently to convert the water to vapor that can then be pumped out of the canister cavity. In this operation, the cask cavity pressure is slowly reduced from the nominal condition of (1.3-2.0 atm (1000-1520 torr), to a final target pressure below 3 torr (0.004 atm). This is typically accomplished in three to five stages, with prescribed 'hold' points defined in procedures or in the Technical Specifications, to preclude sudden pressure spikes due to flashing of water to steam, or development of large local temperature gradients in the fuel rods or other cask internal components. This paper discusses the various locations in the system where residual water may 'hang up' in the cask, and presents a discussion of the physical basis for the effectiveness of vacuum drying for removing it. Results and conclusions based on realistic qualitative and quantitative evaluations of the transient heat transfer behavior of the system are presented, based on detailed modeling of a range of spent fuel canister designs and decay heat loads, most notably the 24P Dry Shielded Canisters (DSCs) stored at the Rancho Seco Independent Spent Fuel Storage Installation (ISFSI), the NAC-MPC modules at Maine Yankee, the 24P DSCs stored at Calvert Cliffs, and the Holtec HI-STORM modules at Hope Creek. The evaluations presented here show that ice formation within a spent fuel canister is highly unlikely, due to the availability of a large thermal source term in the form of the decay heat load of the spent fuel. The formation of ice is an operational concern, since it mainly affects operation of equipment external to the canister (i.e., the hoses, valves, and fittings of the vacuum drying equipment.) Evaluations are presented for quantifying the amount of residual water that could remain in the cask cavity, even after successful drying operations, since vacuum drying is a limit process, and by definition, cannot remove all of the water from the cavity, no matter how long the operation goes on, even if all of it is in vapor form. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Simplified Fission Product Poison Model for Operator Training

Accurate but simple models of xenon and samarium concentration variation with reactor power changes are desirable to support development of reactor theory fundamentals training material for power or research reactor operators. Generation of plots of xenon and samarium concentrations with time can be made without reliance on the nuclear properties of a particular reactor core if the differential equations governing the time-dependent behavior of xenon and samarium and their precursors are recast in terms of equilibrium values. There is currently no method available for generating realistic plots of fission product behavior during power transients that is accessible to Operations training instructors other than hand drawings or adaption of existing commercial material. (authors)

07 ISOTOPE AND RADIATION SOURCES↗

A LOCA Analysis Tool: Coupling RELAP5-3D to BISON

Experimental evidence illustrates that at burnups slightly above the current regulatory limit of a rod-averaged burnup of 62 MWd/kgU, the ceramic UO 2 inside light-water reactor fuel rods becomes susceptible to a phenomenon known as fuel fragmentation, relocation, and dispersal (FFRD) during a loss of coolant accident (LOCA) transient. The severity of FFRD is strongly influenced by the zirconium-based (Zircaloy) cladding behavior during the LOCA transient. A Technology Commercialization Fund (TCF) project was awarded to an Electric Power Research Institute (EPRI)/Idaho National Laboratory team to create a LOCA analysis tool that couples BISON to the systems/thermal-hydraulics code RELAP5-3D [1] for analysis of LOCA scenarios. In addition, further refinements to existing BISON models were identified as necessary to more accurately represent more recent experimental evidence from the Studsvik Cladding Integrity Project (SCIP) and other experimental programs.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Three-Dimensional Mathematical Model of Oxygen Transport Behavior in Electroslag Remelting Process

A transient three-dimensional model has been proposed to investigate the oxygen transport behavior in electroslag remelting process. The electromagnetism, heat transfer, multiphase flow, and species transport were calculated simultaneously by finite volume method. The volume of fluid approach was adopted to trace the metal–slag–air three-phase flow. Based on the necessary thermodynamics of oxygen transport behavior, a kinetic model was established to predict the mass source terms in species transport equation. The kinetic correction factor was proposed to account for the effect of the oxide scale formed on the electrode on the FeO content in slag. Finally, the effect of applied current on the oxygen transfer was studied. The predicted result agrees well with the measured data when the kinetic correction factor is set to be 0.5. The temperature distribution that affects the thermodynamics differs at the interfaces. The oxygen in air is absorbed into slag due to the oxidation at the slag/air interface. The Fe{sub 2}O{sub 3} in slag and the oxide scale contribute to the increase of FeO content in slag, and the latter one plays the leading role. The oxygen transfer from slag to metal mainly occurs during the formation of the droplet at the slag/metal droplet interface. With the current increasing from 1200 to 1800 A, the oxygen content increases from 76.4 to 89.8 ppm, and then slightly declines to 89.2 ppm when the current increases to 2100 A.

36 MATERIALS SCIENCE↗